ATHENAWORLDSCHOOL

TERM I
IEXAMI
NATI
ON(
2021-
22)

SUB:CHEMI
STRY(
043)

Cl
ass–XI

MM -
35 TI
ME-2HOUR

Dat
e-3/
3/2022
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GENERALI ONS:
NSTRUCTI
Readt
hef
oll
owi
ngi
nst
ruct
ionscar
eful
l
y.
1.Ther
ear
e12quest
ionsi
nthi
squest
ionpaperwi
thi
nter
nal
choi
ce.
2.SECTI
ONA-Q.No.1t
o3ar
ever
yshor
tanswerquest
ionscar
ryi
ng2mar
kseach.
3.SECTI
ONB-Q.No.4t
o11ar
eshor
tanswerquest
ionscar
ryi
ng3mar
kseach.
4.SECTI
ONC-Q.No.12i
scasebasedquest
ioncar
ryi
ng5mar
ks.
5.Al
lquest
ionsar
ecompul
sor
y.
6.Useofl
ogt
abl
esandcal
cul
ator
sisnotal
l
owed

SECTI
ONA

1)Wr
it
etheexpr
essi
onf
orKc (
2x1=2)

4NO(
g)+6H20(
g)⇋ 4NH3(
g)+5O2(
g)
2)Whati
sabsol
utezer
o? (
2x1=2)

3)Whyal
kal
imet
aldi
ssol
vedi
nli
qui
dNH3gi
vedeepbl
uecol
ouri
nsol
uti
on?

(
2x1=2)

SECTI
ONB

4)I
napr
ocess701Jofheati
sabsor
bedbyasy
stem and394Jofwor
k
donebysy
stem.Whati
schangei
nint
ernal
ener
gyf
ort
hepr
ocess?

(
3x1=3)

0
5)At25cand760mm ofHgpr
essur
eagasoccupi
es600ml
vol
ume.
Whatwi
ll
beitspr
essur
eatahei
ghtwher
etemper
atur
eis100cand
vol
umeofgasis640ml? (
3x1=3)

Or

Der
ivet
hei
deal
gasequat
ion?

6)a)Asol
uti
onofNa2CO3i
sal
kal
i
ne.Why
? (
1+2=3)

b)BeOi
sinsol
ubl
ebutBeSO4i
ssol
ubl
einwat
er.Why
?

Or

Expl
ainthesigni
fi
canceofsodi
um,
pot
assi
um,
magnesi
um and
cal
cium i
nbiologi
calf
lui
ds.

7)WhyLi
Fisal
mosti
nsol
ubl
einwat
erwher
easLi
Cli
ssol
ubl
einwat
erand
al
soi
nacet
one? (
3x1=3)

8)a)Expl
ainconf
ormat
ions? (
1+2=3)
 b)Gi
vedi
ff
erentconf
ormat
ionofet
hane

i
)Sawhor
ser
epr
esent
ati
on

i
i
)Newmannpr
oject
ion

9)Descr
ibef
ri
edal
craf
treact
ionwi
thsui
tabl
eexampl
e. (
3x1=3)

Or

Howwi
l
lyouconv
ertet
hanoi
caci
dint
obenzene?

10)Whati
smeantbycat
enat
ion?Whydoescar
bonshowt
hepr
oper
tyof
cat
enat
iont
omaxi
mum ext
ent (
3x1=3)

Or

Whati
sthest
ateofhy
bri
dizat
ionofcar
boni
n

i
) CO32-

i
i
) Di
amond

i
i
i) Gr
aphi
te

11) Howdoy
ouaccountf
ort
hef
ormat
ionofet
hanedur
ingchl
ori
nat
ionof
met
hane? (
3x1=3)

SECTI
ONC

12)Readt
hef
oll
owi
ngandanswert
hequest
ionsf
rom (
i)t
o(i
v)gi
venbel
ow

I
nter
molecul
arfor
cesarefor
cesofat
tract
ionandrepul
sionbetween
i
nter
act
ingpart
icl
es.Theyar
eweakforcesandgeneral
l
yaf f
ectthe
phy si
calandchemi calpr
operti
esofmat ter
.Att
ract
ivei
ntermolecul
ar
forcesar eknownasv anderWal l
sforces.Theyvar
yconsider
ablyin
magni tude.Theyincl
udedispersi
onforcesorLondon-f
orces,dipol
e-
dipoleanddi pol
einduceddipol
ef or
ces.

Londonfor
cesexi
stbetweenneutr
alatomsornon-pol
armolecul
es.
Thedipol
e–dipol
ef or
cesexi
stsbetweendi
pol
eendsofpolar
molecul
esandarethestr
ongestofal
lvanderWall
sfor
ces.

Dipolei
nduceddipol
efor
cesexi
stbet
weenpolarmol
ecul
eshav
ing
permanentdipol
eHbondingi
saspecial
typeofdi
pol
e-di
pol
e
i
nteract
ion.

i
) Whymagnitudeofi
nter
acti
onener
gyofLondonf
orcesdepends
onpol
ari
sabil
it
yofpart
icl
es?
i
i
) Whyaredi
pol
e-di
polei
nteracti
onconsider
edstrongert
han
London–f
orcesbutweakerthani
on-ioninter
acti
on?
i
i
i) OutofHFandH2Owhi
chhasst
rongerH-bondi
ngi
nter
act
ion?

i
v) Whi
chtypeofi
nter
molecul
arf
orcesar
epr
esenti
nthe
mol
ecul
esHF,HCl,
HBrandHI? (
1+1+1+2=5)

Or

a)Howwill
youcalcul
atet
hepar
ti
alpr
essur
eofasusi
ngDal
ton’
s
l
awofpar
ti
alpr
essure?

b)Whatar
ethepost
ulat
esofki
net
ict
heor
yofgas?