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 NEET-2021-22 [XIIth Batch]

Test-02 Hydrocarbon

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Target Marks : 180 Date : 25/04/2021
Time : 50 min Sub. : Chemistry
1. Find out (B) in the following reaction. AlCl
8. CH3 – CH2 – CH2 – CH3 Δ3  CH3  CH  CH3
|
CH3 CH3
|
CH3– C  CH2 – Cl Na

 ether
 A is Above reaction is an example of :
| 1) isomerization 2) polymerization
CH3
3) cracking 4) de-hydrogenation
9. What is the major product of the reaction?
1) 2)
hv
+ Br2  ?

Br
3) 4) Br
1) 2)
2. Symmetrical alkanes are prepared by :
1) Wurtz reaction 2) Frankland reaction
3) Kolbe’s reaction 4) All 3) Br 4)
Br
3. Which of the following alkane will be formed in high
yield by Wurtz reaction? 10. The order of reactivity of halogens in aliphatic
substitution reactions is
1) 2) 1) Br2 > Cl2 > F2 2) Cl2 > Br2 > F2
3) F2 > Cl2 > Br2 4) F2 > Br2 > Cl2
3) 4) 11. Halogenation of alkanes is an example of
1) Electrophilic substitution
4. The compounds formed at anode in the electrolysis 2) Nucleophilic substitution
of an aqueous solution of CH3COOK are:
3) Free radical substitution
1) C2H6 and CO2 2) C2H4 and CO2
4) Oxidation
3) CH4 and H2 4) CH4 and CO2
CH3
|
H SO 4
12. CH3CH2  C  CH  CH3 2 
 P
heat (Major)
5. I. II. III. | |
CH3 OH

Which of the following orders in correct for the ease What is the major product P in the above reaction ?
of decarboxylation of these acids? CH3
1) I > II > III 2) III > II > I |
1) CH3CH2  CH  CH  CH2
3) II > I > III 4) II > III > I
6. The treatment of CH3MgX with CH3 CH3
CH3C  C – H produces | |
2) CH3  CH  CH  CH  CH2
1) CH4 2) CH3 – CH = CH2
H H CH 3
| | |
3) CH3C  C – CH3 4) CH3– C = C –CH3 3) CH CH  C  CH  CH
3 2 2
|
7. In alkanes, the bond angle is CH 3
1) 109.50 2) 109 0
3) 120 0 4) 180 0 CH3 CH3
| |
4) CH3CH2  C  C  CH3

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 1

 H
19. Observe the following reactions and predict the
2
13. The reaction, RC  CR Lindlar's
 catalyst gives the main
 nature of A and B.
product as

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HBr
1) cis-Alkene 2) trans-Alkene B 
H 2O 2

3) Alkane 4) None of these
14. In the reaction,
HBr Alc.KOH n
 B    C Re
A 
d
 Propane.
Ni / 473 573K 1) A and B both are
What is 'A' ?
1) ethene 2) propene
3) ethane 4) propane 2) A and B both are
15. HBr reacts with CH2 = CH – OCH3 under anhydrous
conditions at room temperature to give
1) CH3CHO and CH3Br 3) A is & B is
2) BrCH2CHO and CH3OH
3) BrCH2 – CH2 – OCH3
4) H3C – CHBr – OCH3 4) A is & B is
ROOR
 [X]  [Y] ; [X]
16. CH3CH2 – CH = CH2 + HBr 
Major Minor
20. H3C  CH  CH  CH2  HBr  A ; A (predominantly) is
& [Y] respectively are |
CH3
1) BrCH2CH2CH = CH2 & C2H5 – CHBr – CH3
2) C2H5–CH2CH2–Br & Br–CH2CH2–CH=CH2 1) CH3  CH  CH  CH3
3) C2H5 – CH2 – CH2Br & C2H5–CHBr – CH3 | |
Br CH3
4) C2H5CHBr – CH3 & C2H5 – CH2 – CH2 Br
2) CH3  CH  CH  CH3
17. The reaction of CH3CH = CH OH with | |
CH3 Br
HBr gives
3) CH3  CH  CH2  CH2 Br
|
1) CH3CHBrCH2 OH CH3

Br
2) CH3CH2CHBr OH |
4) CH3  C  CH2 CH3
|
CH3
3) CH3CHBrCH2 Br
21. Which products are formed during the addition of
Br2 on ethylene in presence of aqueous NaCl solution
4) CH3CH2CHBr Br 1) CH 2Br  CH2Br 2) CH2Br CH2Cl
3) CH2Cl CH2Cl 4) Both (1) and (2)
22. Ethylene reacts with sulphur monochloride to give
18.
1) Phosgene 2) Mustard gas
3) Ethylene chloride 4) None of these

23. dil.
 H2SO4


1) 2) OH
1) OH 2)

HO
3) OH 4)

3) 4)

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 2

 28. The general formula of alkynes is
24. dil. H2SO4

 1) CnH2n+2 2) CnH2n
CH = CH – CH3 3) CnH2n–2 4) CnH2n–4

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29. A compound on heating with silver powder gives the
1) first member in the alkyne series. That compound
CH2 – CH – CH3 is
1) Ethyl halide
OH
2) Ethylene halide
3) Acetylene tetrahalide
2) 4) Haloform
CH – CH2 – CH3 30. The garlic smell of Acetylene is due to the presence
of
OH
1) H 2 S 2) SO 2
3) (1) and (2) 3) PH3 4) Both H2S & PH3

4) OH
CH2 – CH2 – CH3
31. CC–C  C Li
/ NH
3( l)
 Product :

25. CH2 on ozonolysis gives 1)

O 2)
1) + HCHO

CHO
2)
3) Both (1) and (2)

COCH3
3) 4)

4) None of these

CH3
CH2Br
32. H3C–C  Product
26. N.B.S.


(A)
1) an optically active compound
2) an optically inactive compound
CH3
CH3 3) a racemic mixture
CH3 C H 4) a distereomeric mixture
CH3 C Br
33. Which of the following reacts with ammonical
N.B.S.
 cuprous chloride ?
1) CH4 2) C2H2
(B)
3) C2H6 4) C6H6
Which has faster rater 34. In the reaction
1) A 2) B HgSO
CH3 – CH2C  CH  4  X, the compouond X is
H SO 2 4
3) both have equal rate4) none
27. In the reaction, O
Alkaline
||
CH3 – CH = CH2   X; 'X' is 1) CH3–CH2– C – CH3
KMnO 4
2) CH3–CH2–CH2–CHO
1) propylene glycol 2) ethylene glycol
3) CH3–CH2–CH2–COOH
3) propyl alcohol 4) both 1 and 2
4) None of these

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 3

35. The acidic nature of hydrogens in acetylene can be 41. The major products (P, Q) in the given reaction
explained by the reaction with are:
1) Sodium metal

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2) Ammonical cuprous chloride solution
3) Ammonical silver nitrate solution
4) All the above
36. The colour of the precipitate formed when acetylene
1)
is passed through ammonical cuprous chloride
solution is
1) White 2) Red
3) Blue 4) Green
2)
37. In the halogenation of aromatic nucleus, the halogen
carrier, used to generate the species is :
1) Cl 2) Cl+
3) Cl– 4) Cl2– 3)
38. The attacking species in aromatic sulphonation is:
1) SO 3 2) H3SO4+
3) HSO4– 4) SO 2+
39. Xylene on oxidation with acidic KMnO4 gives: 4)
1) phthalic acid 2) isophthalic acid
3) terephthalic acid 4) all of these 42. The major product U in the following reactions is:
40. What product are formed when the following
compound is treated with Br2 in the presence of
FeBr3?

CH3

CH3 1) 2)

CH3 CH3
Br
and
1) CH3 CH3
Br 3) 4)

CH3 CH3 43. Which of the following ions is produced when we

Br Br prepare nitrating mixture by mixing together
2) concentrated HNO3 and concentrated H2SO4?
and
CH3 CH3 1) NO 2 2) NO 2

CH3 CH3 3) NO 3 4) SO 3 H
Br
44. Aromatic compounds undergo most easily.
and
3) 1) nucleophilic substitution
CH3 CH3
2) electrophilic substitution
Br 3) nucleophilic addition
4) electrophilic addition
CH3 CH3 45. Benzene reacts with n-propyl chloride in the
presence of anhydrous AlCl3 to give predominantly:
and 1) isopropyl benzene
4)
CH3 Br CH3 2) no reaction
Br 3) n-propylbenzene
4) 3-propyl-1-chlorobenzene

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 4