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 NEET-2021-22 [XIIth Batch]

Test-14 : H.D.A. + Solid State

RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * *
Target Marks : 180 Date : 18/07/2021
Time : 50 min Sub. : Chemistry
4. The product of the following SN2 reaction is
CH 3
CH 3CH 2ONa
|
1. B  CH3CH 2OH
 CH3– C  Br  A
 (major)
(Major) CH3CH 2OH
|
CH 3

A and B respectively are

CH 3
|
1) CH3– C  OCH 2CH 3 in both case
| 1) 2)
CH 3

CH 3
|
2) CH3– C  CH 2 in both case
3) 4)
CH 3 CH3
|
3) CH3– C  OCH 2CH 3 and C=CH2
| CH3 5. Which of the following alkyl bromide will give
CH 3 rearrange product under SN1 reaction?

CH 3 1)
CH3 |
4) C=CH2 and CH3– C  OCH 2CH 3
CH3 |
CH 3
2)
2. Which is least reactive towards nucleophilic
substitution (SN2)?
1) CH2=CH–CH2Cl 2) (CH3)3C–Cl 3)

Cl
3) 4) CH3–CH(Cl)CH3 4)

3. In a SN2 substitution reaction of the type 6. Which of the following most reactive in SN2
reaction?
DMF
R–Br + Cl–   R–Cl + Br–
1) CH3Br + OH– 
 CH3OH + Br–
which one of the following has the highest
relative rate? 2) CH3– CH –CH3 + OH–CH3– CH  CH3  Br


| |
Br OH
CH 3
|
1) CH3– CH  CH 2 Br 2) CH3– C  CH 2 Br  H 2O
3) CH3CH2OH   CH2=CH2
| |
CH 3 CH 3
4) (CH3)3C–Br + OH– 
 (CH3)3COH + Br–
3) CH3CH2Br 4) CH3CH2CH2Br

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 1

7. The structure of the major product formed in 9. The major product formed in the reaction,
the following reaction is

RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * *
is

1)

1) 2)

2)

3) 4)
3)

4)
10. , Major product (A) is :

8. The major of the following reaction is

1) 2)

1) 2)

3) 4)

3) 4)

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 2

 15. ?
11. Product.

RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * *
Major product of the reaction is :
Product of the reaction is
I. II.

1) 2)

III. IV.

3) 4)

V.
12. Given the major product of the following
reaction. 1) I 2) II
3) III 4) IV
16. In the given reaction :

1) 2) [X], X is

3) 4) 1) 2)

13. The reaction described as :

3) 4)

1) SE2 2) SE1 17. Compare rate of reaction with Ag NO3 or rate
3) SN2 4) SN1 of SN1 reaction :
14. Assuming no other changes, what is the effect
of doubling only the concentration of the
nucleophile in the following reaction?

(CH3)3CBr + I 
 (CH3)3CI + Br

1) No change 1) i > ii > iii

2) Double the rate 2) ii > iii > i
3) Triple the rate 3) iii > i > ii
4) Quadruples the rate 4) ii > i > iii

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 3

18. Among the bromides I-III given below, the 23. Which of the following S N2 reaction is the
order of reactivity SN1 reaction is : fastest?
1) CH3CH2CH2CH2Br + OH– 

RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * *
CH3CH2CH2CH2OH + Br–
2) CH3CH2CHBrCH3 + OH– 
CH3CH2CH2CH2OH + HBr
1) III > I > II 2) III > II > I 3) CH3CH2CHBrCH3 + OH– 
3) II > III > I 4) II > I > III CH3CH2CHOHCH3 + Br–
19. Which of the following compounds will be 4) CH3CH2CHBrCH3 + H2O
most reactive for SN1 reactions? CH3CH2CHOHCH3 + HBr

24. Graphite is an example of

1) 2) 1) Ionic solid 2) Covalent solid
3) Metallic crystal 4) None of these
25. In a Hexagonal crystal :
1)  =  =   90o; a = b = c
3) 4)
2)  =  =  = 90o; a = b  c
3)  =  =  = 90o; a  b  c
4)  =  = 90o,  = 120o; a = b  c
 

20. Compare rate of reaction with Ag NO 3
or rate 26. The most unsymmetrical and symmetrical
of SN1 reaction systems are, respectively :

CH2–Br
1) Tetragonal, Cubic 2) Triclinic, Cubic
Br Br
3) Rhombohedral, Hexagonal
i. ii. iii. 4) Orthorhombic, Cubic
27. What are the number of atoms per unit cell
1) i > ii > iii 2) ii > iii > i and the number of nearest neighbours in a
3) iii > ii > i 4) iii > i > ii simple cubic structure ?
21. Assuming no other changes, what is the effect 1) 1, 6 2) 4, 12
of doubling both the concentration of the alkyl 3) 2, 8 4) 2, 6
halide and the nuclephile in the following 28. What are the number of atoms per unit cell
reaction? and the number of nearest neighbours in a
(CH3)3CBr + I 
 (CH3)3CI + Br
body centered cubic structure ?
1) 4, 12 2) 1, 6
1) No change
3) 2, 8 4) 2, 5
2) Double the rate
29. The body centered cubic cell of chromium has
3) Triples the rate a edge length of 0.288 nm. Calculate the density
4) Quadruples the rate of chromium (g/cm3) :
22. Without exception, S N2 reaction at chiral (Atomic weight = Cr = 52.0)
carbon gives : 1) 6.80 2) 7.60
1) enantiomer of substrate 3) 6.60 4) 7.23
2) product of opposite polarity 30. Molybdenum (At. wt. = 96 g mol–1) crystallizes
3) diastereomeric mixture as bcc crystal. If density of crystal is 10.3 g/cm3,
4) only one stereoisomer then radius of Mo atom is (use NA = 6 × 1023)
1) 111 pm 2) 314 pm
3) 135.96 pm 4) None of these

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 4

31. Cu, Ag, Au have close-packing of the type : 39. How much part of any corner constituent
1) Hexagonal close-packing particle actually belongs to a particular unit
cell ?
2) Cubic close-packing

RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * *
3) Body-centred cubic packing 1 1
1) th 2) th
4) Malleability is not related to type of packing 4 6
32. The atomic radius of strontium (Sr) is 215 pm 1 1
and it crystallizes with a cubic closest packing. 3) th 4) th
8 10
Edge length of the cube is :
40. In a face centred cubic lattice, atom A occupies
1) 430 pm 2) 608.2 pm the corner positions and atom B occupies the
3) 496.53 pm 4) None of these face centre positions. If one atom of B is
33. Which one of the following is a good conductor missing from one of the face centred points,
of electricity ? the formula of the compound is
1) Diamond 2) Graphite 1) A2B 2) AB2
3) Silicon 4) Amorphous carbon 3) A2B2 4) A2B5
34. Which of the following is true for diamond ? 41. Which of the following is true about the value
of refractive index of quartz glass ?
1) Diamond is a good conductor of electricity
1) Same in all directions
2) Diamond is soft
2) Different in different directions
3) Diamond is a bad conductor of heat 3) Cannot be measured
4) Diamond is made up of C, H and O 4) Always zero
35. Sodium metal crystallizes as a body-centred 42. Edge length of unit cell of chromium metal is
cubic lattice with the cell edge 4.29 Å. What is 287 pm with bcc arrangement. The atomic radius
the radius of sodium atom ? is of the order :
1) 1.857 × 10–8 cm 2) 2.371 × 10–7 cm 1) 124.27 pm 2) 287 pm
3) 3.817 × 10–8 cm 4) 9.312 × 10–7 cm 3) 574 pm 4) 143.5 pm
36. A compound is formed by elements X and Y. 43. The sharp melting point of crystalline solids is
This crystallizes in the cubic structure when due to
atoms X are the corners of the cube and atoms 1) A regular arrangement of constituent particles
Y are at the centre of the body. The simplest observed over a short distance in the crystal
formula of the compound is : lattice
1) XY 2) XY2 2) A regular arrangement of constituent particles
observed over a long distance in the crystal
3) X2Y 4) XY4
lattice
37. Three elements A, B and C crystallize into a
3) Same arrangement of constituent particles in
cubic solid lattice. Atoms A occupy the corners,
different directions
B atoms, the cube centres and C atoms, the
4) Different arrangement of constituent particles
edge. The formula of the compound is :
in different directions
1) ABC 2) ABC2
44. In a cubic unit cell, seven of the eight corners
3) ABC3 4) ABC4 are occupied by atoms A and centres of faces
38. If a is the length of the side of a cube, the are occupied by atoms B. The general formula
distance between the body centered atom and of the compound is :
one corner atom in the cube will be : 1) A7B6 2) A7 B12
3) A7 B24 4) A24 B7
3 3
1) a 2) a 45. A metal X crystallises in a face-centered cubic
4 2
arrangement with the edge length 862 pm. What
2 4 is the shortest separation of any two nuclei of
3) a 4) a the atom ?
3 3
1) 406 pm 2) 707 pm
3) 862 pm 4) 609.6 pm
Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 5