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 NEET-2021-22 [XIIth Batch]

Test-13 : H.D.A. + Solid State

RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * *
Target Marks : 180 Date : 11/07/2021
Time : 50 min Sub. : Chemistry
1. Consider the following organic compound 5. The correct statement about the compounds I
and II is
1 3 5 7

2 4 6
To make it a chiral the attack should be on I. II.
carbon
1) 1 2) 4 1) I and II are identical
3) 3 4) 7 2) I and II are diastereoisomers
3) I and II are enantiomers
COOH COOMe
| | 4) I is not meso while II is meso
H  C  OH HO  C  H
| 6. Which of the following has ‘R’ configuration.
2. I. II. |
H  C  OH HO  C  H
| | COCH 3 OH
COOMe COOH | |
1) H  C  CH 2  OH 2) Cl  C  C 2 H 5
Structure I and II are | |
OH CH 3
1) enantiomers
2) meso compounds
NH 2 CH 3
3) diastereoisomers | |
3) H  C  C 2 H 5 4) H  C  OH
4) Identical | |
3. The compound given below are CH 3 C2 H 5

7. Which of the following has ‘R’ configuration

i)
C  CH
|
ii) 1) HO  C  CH2  OH
|
SH
1) enantiomers
2) identical CHO
3) diastereoisomers |
2) HO  C  COCH 3
4) metameres |
H
4. Consider the following representation

COCH 3
|
3) H  C  C 2 H 5
|
CH 3
they are
1) enantiomers C  CH
|
2) diastereoisomers 4) CH 3  C  CH  CH 2
3) conformational isomers |
C 2H 5
4) identical

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 1

8. The reaction described 13. For the following halides, order of rate of
reaction with AgNO3 or rate of SN1 :

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1) SN1 2) SN2
3) E1 4) E2
1) I > III > II 2) II > III > I
9. An SN2 reaction at on asymmetric carbon atom
3) I > II > III 4) III > I > II
of a compound always gives
1) an enantiomers of a substrate CH3
2) a product with same optical rotation H Br NaI/acetone
14. 
(S N 2) condition
 P, Product (P) is :
3) a mixture of diastereomisomers H Cl
4) a single stereoisomers CH3
10. Which among the following has highest B.P.
CH3
Cl H I
1) 2)
Cl 1)
H Cl

Cl CH3
3) 4) Cl

CH3
11. Give the major product of the following
H I
reaction.
2) Cl H
CH3

CH3
I H
1) 3)
H Cl
CH3

2)
4)

15. Which of the following compound give same

3) SN1 and SN2 product?

1) 2)

4)

3) 4)
12. Which of following is least reactive towards
SN1? 16. SN1 reactivity of the halides,
i. (CH3)3 CBr ii. (C6H5)2CHBr
iii.(C6H5)2C(CH3)Br iv. (CH3)2CHBr
1) 2)
will be in the order
1) iv > i > ii > iii
2) ii > i > iii > iv
3) 4) 3) i > iii > ii > iv
4) iii > ii > i > iv

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 2

 21. The rate of solvolysis of tert-butyl bromide by
maximum in which of the following solvents?
17. , product (A) is : 1) Et2 O 2) CCl4

RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * *
3) EtOH 4) H2 O
22. Which halide reacts most rapidly via an SN2
mechanism?

1) I 2) Cl
1) 2)

I
3) 4)
Br
23. Which of the following factors has no effect
3) 4) on the rate of SN1 reactions?
1) The nature of the alkyl halide
2) The nature of the leaving group
18. In the given reaction : 3) The concentration of the alkyl halide
4) The concentration of the nucleophile
24. Solid CO2 is an example of
1) Molecular crystal 2) Ionic crystal
3) Covalent crystal 4) Metallic crystal
25. The property of crystalline solid is not
1) Anisotropic 2) Isotropic
1) 2) 3) Hard 4) Dense
26. Amorphous substances show
(A) Short and long range order
(B) Short range order
3) 4) (C) Long range order
(D) Have no sharp M.P.
19. Which one of the following compounds will 1) A and C are correct
be most reacti ve f or SN1 reactions? 2) B and C are correct
3) C and D are correct
4) B and D are correct
1) 2) 27. Diamond is an example of
1) Solid with hydrogen bonding
2) Electrovalent solid
3) Covalent solid
3) 4) 4) Glass
28. Given :
20. Among the bromides I-III given below, the Column A Column B
order of reactivity SN1 reaction is : A Ionic Solid I NaCl
B Metallic Solid II Fe
C Covalent Solid III C (graphite)
D Molecular Solid IV Dry ice
1) A-II, B-I, C-IV, D-III 2) A-I, B-II, C-III, D-IV
1) III > I > II 2) III > II > I 3) A-III, B-II, C-I, D-IV 4) A-II, B-IV, C-I, D-III
3) II > III > I 4) II > I > III
Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 3
29. Which of the following is an example of 39. If an atom is present in the centre of the cube,
covalent crystal solid the participation of that atom per unit cell is
1) Si 2) NaF 1

RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * * RCC * *
3) Al 4) Ar 1) 2) 1
4
30. Which of the following statements about 1 1
amorphous solids is incorrect 3) 4)
2 8
1) They melt over a range of temperature
40. In a face centred cubic cell, an atom at the face
2) They are anisotropic contributes to
3) They is no orderly arrangement of particles 1) 1/4 part 2) 1/8 part
4) They are rigid and incompressible 3) 1 part 4) 1/2 part
31. Tetragonal crystal system has the following 41. The edge of unit cell of FCC Xe crystal is 620
unit cell dimensions pm. The radius of Xe atom is
1) a = b = c and  =  =  = 90o 1) 219.25 pm 2) 235.16 pm
2) a = b  c and  =  =  = 90o 3) 189.37 pm 4) 209.87 pm
3) a  b  c and  =  =  = 90o
42. Total volume of atoms present in a face centred
4) a = b  c and  =  = 90o,  = 120o cubic unit cell of a metal is (r is atomic radius)
32. Example of unit cell with crystallographic
20 3 24 3
dimensions a  b  c,  =  = 90o,   90o is 1) r 2) r
3 3
1) Calcite 2) Graphite
12 3 16 3
3) Rhombic sulphur 4) Monoclinic sulphur 3) r 4) r
3 3
33. a  b  c and      follow
43. Percentages of free space in cubic close packed
1) Triclinic 2) Monoclinic
structure and in simple cubic structure are
3) Rhombohedral 4) Tetrahedral
respectively :
34. The total number of Bravais lattice in a crystal 1) 48% and 26% 2) 30% and 26%
is
3) 26% and 48% 4) 32% and 48%
1) 7 2) 14
44. A match box exhibits :
3) 230 4) 32
1) Cubic geometry
35. The number of nearest neighbour particles
2) Monoclinic geometry
around each particle in a face centred cubic
3) Orthorhombic geometry
lattice/unit cell is
4) Tetragonal geometry
1) 4 2) 6
45. Graphite is a soft solid lubricant extremely
3) 8 4) 12
difficult to melt. The reason for this anomalous
36. For a crystal system a = b = c and  =  =  = 90o
behaviour is that graphite :
1) Tetragonal 2) Hexagonal
1) Is a non-crystalline substance
3) Rhombohedral 4) Monoclinic
2) Is an allotropic form of diamond
37. Na and Mg crystallize in bcc and fcc type 3) Has molecules of variable molecular masses like
crystals respectively, then the number of atoms polymers
of Na and Mg present in the unit cell of their 4) Has carbon atoms arranged in large plates of
respective crystal is rings of strongly bound carbon atoms with weak
1) 4 and 2 2) 9 and 14 interplate bonds.
3) 14 and 9 4) 2 and 4
38. The fraction of total volume occupied by the
atoms present in a simple cube is
 
1) 2)
6 3 2
 
3) 4)
4 2 4

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 4