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 NEET-2021-22 [XIIth Batch]

Test-05 : Solution

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Target Marks : 180 Date : 16/05/2021
Time : 50 min Sub. : Chemistry
1. If 0.1 M solutions of each electrolyte are taken 8. The osmotic pressure of equimolar solutions
and if all electrolytes are completely dissociated, of glucose, sodium chloride and barium
then whose boiling point will be highest ? chloride will be in the order:
1) Glucose 2) KCl 1) BaCl2 > NaCl > glucose
3) BaCl2 4) K4[Fe(CN)6] 2) BaCl2 > glucose > NaCl
2. Colligative properties depend on 3) Glucose > BaCl2 > NaCl
1) the nature of the solute particles dissolved in 4) NaCl > BaCl2 > glucose
solution 9. Consider the following aqueous solution and
2) the number of solute particles in solution assume 100% ionisation of electrolytes
3) the physical properties of the solute particles I) 0.1 m urea II) 0.04 m Al2(SO4)3
dissolved in solution III) 0.05 m CaCl2 IV) 0.005 m NaCl
4) the nature of solvent particles The correct statement regarding the above solu-
3. The V.P. of water at room temperature is 23.8 tions is
mm Hg. The V.P. of an aq. solution of sucrose 1) freezing point will be lowest for solution I
with mole fraction of water 0.9, is equal to 2) freezing point will be highest for solution IV
1) 23.9 mm Hg 2) 24.2 mmHg 3) vapour pressure will be highest for solution II
3) 21.42 mm Hg 4) 31.44 mmHg 4) osmotic pressure will be highest for solution III
4. Which of the following solutions will have the 10. Which one of the statements given below
lowest vapour pressure ? concerning properties of solutions, describe a
1) 0.1 M Na3PO4 2) 0.1 M Na2SO4 colligative effect?
3) 0.1 M BaCl2 4) 0.1 M Urea 1) Boiling point of pure water decreases by the
5. Two solvents A and B have values of Kb in the addition of ethanol
ratio of 1 : 2. A two molal solution of a 2) Vapour pressure of pure water decreases by the
nonelectrolyte in A has Tb = 2.4°C, the value addition of nitric acid
of T for one molal solution of another non- 3) Vapour pressure of pure benzene decreases by
electrolyte in B will the addition of naphthalene
1) 2.4 K 2) 0.12 K 4) Boiling point of pure benzene increases by the
3) 0.24 K 4) none of these addition of toluene
6. The depression of freezing point of equimolar 11. Consider this figure and select the correct
solutions of HCl, CuSO4 and Na2SO4 are in the statement.
ratio of
1) 1:2:3 2) 2:5:3 0.1 M 0.05 M
3) 2:2:3 4) 1:1:1 KCI BaCl2
solution solution
7. During depression of freezing point in a
solution, the following are in equilibrium
1) liquid solvent, solid solvent 1) BaCl2 flows towards the KCl solution
2) liquid solvent, solid solute 2) KCl flows towards the BaCl2 solution
3) liquid solute, solid solvent 3) There will be no movement of any solution
4) liquid solute, solid solute 4) First KCl flows towards BaCl2 then reverse
process takes place

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 1

12. 18 g of glucose (C6H12O6) is added to 178.2 g of 19. A solution containing 28 g phosphorus in 315
water. The vapour pressure of water for this gm CS2 (b.p. = 46.3°C) boils at 47.9°C (Kb for
aqueous solution at 100°C is CS2 is 2.34). What will be the molecular formula

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1) 759.00 torr 2) 7.60 torr of phosphorus (Assume complete association)
3) 76.00 torr 4) 752.40 torr 1) P4 2) P8
0
13. If P and P are the vapoure pressure of solvent 3) P2 4) none of these
and solution and n1 and n2 are the moles of 20. 1 mole each of the following olutes are taken
solute and solvent respectively: in 5 moles of water,
 n1   n2  A. NaCl B. K2SO4
1) P° = P  n  n  2) P° = P  n  n  C. Na3PO4 D.glucose
 1 2   1 2 
Assuming 100%, ionisation of the electrolyte,
 n2  relative lowering of vapour pressure will be
3) P = P°  n  n  4) P = P × n1 in the order
 1 2 
1) A < B < C < D 2) D < C < B < A
14. Which one is a colligative property?
3) D < A < B < C 4) equal
1) boiling point 2) vapour pressure
21. Consider the following solution ionisation
3) osmotic pressure 4) freezing point
being 100%, assume molarity = molality
15. 1.00 g of a non-electrolyte solute (molar mass
I. 0.05 M NaNO3 II. 0.075 M CuSO4
250 g mol–1) was dissolved in 51.2 g of benzene.
If the freezing point depression constant, Kf III. 0.14 M sucrose IV. 0.04 M BaCl2
of benzene is 5.12 K kg mol–1, the freezing point The correct order for decreasing freezing point
of benzene will be lowered by is
1) 0.5 K 2) 0.2 K 1) I > IV > III > II 2) II > III > IV > I
3) 0.4 K 4) 0.3 K 3) IV > II > I > III 4) III > II > IV > I
16. Which salt may show the same value of vant 22. The relative lowering in vapour pressure is
Hoff factor (i) as that of K4 Fe(CN)6 in very proportional to the ratio of number of
dilute solution state? 1) solute molecules to solvent molecules
1) Al2 (SO4)3 2) NaCl 2) solvent molecules to solute molecules
3) Al(NO3)3 4) Na2 SO4
3) solute molecules to the total number of
17. X3Y2 (i = 5) when reacted with A2B3(i = 5) in molecules in solution
aqueous solution gives brown colour. These
4) solvent moelcules to the total number of
are separated by a semipermeable membrane
molecules in solution
AB as shown. Due to osmosis there is
23. Vapour pressure of a pure liquid X is 2 atm at
300K. It is lowered to 1 atm on dissolving 1g of
Y in 20 g of liquid X. If molar mass of X is 200,
what is the molar mass of Y ?
1) 20 2) 50
3) 100 4) 200
1) brown colour formation in side X 24. A solution containing 12.5 g of non-electrolyte
substance in 185 g of water shows boiling point
2) brown colour formation in side Y
elevation of 0.80 K. Calculate the molar mass
3) formation in both of the sides X and Y of the substance. (Kb = 0.52 K kg mol–1)
4) no brown colour formation
1) 53.06 g mol–1 2) 25.3 g mol–1
18. An aqueous solution of glucose boils at
3) 16.08 g mol–1 4) 43.92 g mol–1
100.01°C. The molal elevation constant for
water is 0.5 K mol –1 kg. The number of
molecules of glucose in the solution containing
100g of water is
1) 6.023 × 1023 2) 6.023 × 1022
3) 12.046 × 1020 4) 12.046 × 1023

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 2

25. 2 g of sugar is added to one litre of water to 29. What does point A and B represent in the
give sugar solution. What is the effect of following diagram ?
addition of sugar on the boiling point and A B
1 atm

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freezing point of water ?
1) Both boiling point and freezing point increase

pressure
Vapour
2) Both boiling point and freezing point decrease Tb
Tb0
Tb
3) Boiling point increases and freezing point
decreases Temperature/K

4) Boiling point decreases and freezing point Point A Point B

increases 1) Boiling point of solvent Boiling point of
26. What weight of glycerol should be added to solution
600 g of water in order to lower its freezing 2) Boiling point of solution Boiling point of
point by 10°C ? (Kf = 1.86° Cm–1)
solvent
1) 496 g 2) 297 g
3) Boiling point of solute Boiling point of
3) 310 g 4) 426 g
solvent
27. If semipermeable membrane is placed between
4) Boiling point of solvent Boiling point of
the solvent and solution as shown in the given
figure then solute
30. Identify (i), (ii) and (iii) in the following
daigram.

1) the solvent molecules will flow through the

membrane from solution to pure solvent
2) the solvent molecules will flow continuously 1) i- solution, ii- Frozen solvent, iii-Liquid solvent
till the equilibrium is attained 2) i-Frozone solvent, ii-Solution, iii- Liquid solvent
3) the flow of the solvent from its side to solution 3) i-Frozene sovlent, ii-Liquid solvent, iii-Solution
side across a semipermeable membrane can be 4) i- Solution, ii-Liquid solvent, iii-Frozen solvent
stopped if some extra pressure (called osmotic
31. Solutions A, B, C and D are respectively 0.1 M
pressure)is applied on the solution
glucose, 0.05 M NaCl, 0.05 M BaCl2 and 0.1 M
4) Both (2) and (3) AlCl3 . Which one of the following pairs is
28. A solution of urea (mol. mass 56 g mol–1) boils isotonic ?
at 100.18 °C at the atmospheric pressure. If Kf 1) A and B 2) B and C
and Kb for water are 1.86 and 0.512 K kg mol–1
3) A and D 4) A and C
respectively, the above solution will freeze at
32. Arrange the following aqueous solutions in
1) 0.654°C 2) – 0.654°C
the order of their increasing boiling points.
3) 6.54°C 4) – 6.54 °C I. 10–2 M NaCl II. 10–3 M MgCl2
III. 10–4 M Urea IV. 10–4 M NaCl
1) I < II < IV< III 2) III < IV < II < I
3) II < I < III < IV 4) IV < III < I = I

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 3

33. Choose the correct statement 40. Which of the following statements is not
1) The boiling point of the solution falls on correct?
increasing the amount of the solute 1) aqueous solutions of NaCl and urea are same

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2) The freezing point of the solution is lowered on vapour pressure
adding more of solvent 2) 1 M sucrose solution and 1M glucose solution
3) The freezing point of the solution is raised on are isotonic
adding more of solute 3) Molecular mass of acetic acid and benzoic acid
4) The freezing point of the solution decreases on is higher than normal mass in cryoscopic
increasing the amount of the solute methods
34. 1.00g of a non-electrolyte solute dissolved in Tb K b
50g of benzene lowered the freezing point of 4) For the same solution, T  K
f f
benzene by 0.40K.The freezing point
depression constant of benzene is 5.12K kg 41. The ratio of the value of any elevation of
–1
mol .The molar mass of the solute is boiling point for KCl solution to that for sugar
is nearly _____ times.
1) 128 g mol 1 2) 256 g mol 1
1) 1 2) 0.5
3) 64 g mol 1 4) 32 g mol 1 3) 2 4) 2.5
35. Freezing point of urea solution is – 0·6°C. How 42. For a dilute solution, the Raoul’t law states
much urea (M.W. = 60 g/mole) is required to that _______ .
be dissolved in 3 kg of water? (Kf = 1·5°C kg 1) the lowering of vapour pressure is equal to mole
mol–1) fraction of solute
1) 36 g 2) 24 g 2) the relative lowering of vapour pressure is equal
3) 72 g 4) 60 g to mole fraction of solute
36. When mercuric iodide is added to the aqueous 3) the relative lowering of vapour pressure is
solution of potassium iodide, the proportional to amount of solute
1) freezing point is raised 4) the vapour pressure of the solution is equal to
mole fraciton of the solute
2) freezing point is lowered
43. The vapour pressure of pure solvent and solute
3) freezing point does not change
are 120 mmHg and 108 mmHg, respectively. The
4) boiling point does not change mole fraction of the solvent in the solution
37. At 25°C, the highest osmotic pressure is ______.
exhibited by 0.1 M solution of 1) 0.1 2) 0.9
1) CaCl2 2) KCl 3) 120/108 4) 1.08
3) Glucose 4) Urea. 44. On dissolving 18 g solid in 100 g H2O at 20°C,
38. The molal elevation constant is the ratio of water vapour pressure decreases from 17.53
the elevation in B.P. to mm to 17.22 mm. The molecular weight of solid
1) Molarity is _____ .
2) Molality 1) 18 g mol–1 2) 183 g mol–1
3) Mole fraction of solute 3) 27 g mol–1 4) 274 g mol–1
4) Mole fraction of solvent. 45. The boling point of 0·1M aqueous solutions
39. An aqueous solution containing 1 g of urea of urea, NaCl and K2SO4 are in the ratio
boils at 100· 25 o C. The aqueous solution 1) 1 : 1 : 1 2) 1 : 2 : 3
containing 3 g of glucose in the same volume 3) 1 : 1 : 1 : 5 4) 2 : 4 : 3
will boil at
1) 100·75oC 2) 100·5oC
3) 100°C 4) 100.25°C

Prof. Motegaonkar S. R. M.Sc. Che. Gold Medalist, SET/NET--JRF Qualified 4