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CH EMISTRY\TOPIC WISE DPP_PDF\D PP-1_Text Sol uti on Equi val ent Conc ept, M ol e Conc ept

CHAMP-2024
CHEMISTRY REVISION DPP
TARGET : JEE (Main) 2024
NO. 01
Syllabus : Equivalent Concept, Mole Concept

SECTION - I
Multiple Choice Questions (MCQ)
This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which ONLY ONE is correct.

1. The sulphate of a metal M contains 9.87% of M. This sulphate is isomorphous with ZnSO 4.7H2O. The
atomic weight of M is :
(1) 40.3 (2) 36.3 (3) 24.3 (4) 11.3
2. In the reaction 2Na2S2O3 + I2  Na2S4O6 + 2Nal the equivalent weight of Na2S2O3 (mol. wt. = M) is
equal to
(1) M (2) M/2 (3) M/3 (4) M/4
3. 1.25 g of a solid dibasic acid is completely neutralised by 25 ml of 0.25 molar Ba(OH) 2 solution.
Molecular mass of the acid is
(1) 100 (2) 150 (3) 120 (4) 200
4. Ratio of Cp and Cv of a gas X is 1.4, the number of atom of the gas ‘X’ present in 11.2 litres of it at NTP
will be
(1) 6.02×1023 (2) 1. 2×1023 (3) 3.01×1023 (4) 2.01×1023
5. 250 ml of a sodium carbonate solution contains 2.65 grams of Na 2CO3 . If 10 ml of this solution is
diluted to one litre, what is the concentration of the resultant solution (mol. wt. of Na2CO3 = 106)
(1) 0.1 M (2) 0.001 M (3) 0.01 M (4) 10–4 M
6. Mohr's salt is dissolved in dil. H2SO4 instead of distilled water to
(1) Enhance the rate of dissolution (2) Prevent cationic hydrolysis
(3) Increase the rate of ionisation (4) Increase its reducing strength
7. KMnO4 reacts with oxalic acid according to the equation
here 20 ml of 0.1 M KMnO4 is equivalent to
(1) 20 ml of 0.5 M H2C2O4 (2) 50 ml of 0.1 M H2C2O4
(3) 50 ml of 0.5 M H2C2O4 (4) 20 ml of 0.1 M H2C2O4
8. KMnO4 reacts with ferrous ammonium sulphate according to the equation

here 10 ml of 0.1 M KMnO4 is equivalent to

(1) 20 ml of 0.1 M FeSO4 (2) 30 ml of 0.1 M FeSO4
(3) 40 ml of 0.1 M FeSO4 (4) 50 ml of 0.1 M FeSO4
9. The ratio of amounts of H2 needed to precipitate all the metal ions from 100 ml of 1 M AgNO 3 and 100
ml of 1 M CuSO4 will be
(1) 1 : 1 (2) 1 :2 (3) 2 : 1 (4) None of these

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 M
10. A solution of 10 ml FeSO4 was titrated with KMnO4 solution in acidic medium. The amount of
10
KMnO4 used will be
(1) 5 ml of 0.1 M (2) 10 ml of 1.1 M (3) 10 ml of 0.5 M (4) 10 ml of 0.02 M
11. The ratio of the molar amounts of H2S needed to precipitate the metal ions from 20 mL each of
1MCd(NO3)2 and 0.5M CuSO4 is
(1) 1 : 1 (2) 2 : 1 (3) 1 : 2 (4) Indefinite
12. 10 dm3 of N2 gas and 10 dm 3 of gas X at the same temperature contain the same number of molecules.
The gas X is :
(1) CO (2) CO2 (3) H2 (4) NO
13. A 100 ml solution of 0.1 n HCl was titrated with 0.2 N NaOH solution. The titration was discontinued
after adding 30 ml of NaOH solution. The remaining titration was completed by adding 0.25 N KOH
solution. The volume of KOH required for completing the titration is
(1) 70 ml (2) 32 ml (3) 35 ml (4) 16 ml
14. Suppose 40% w/w aqueous solution of glucose (C6H12O6) and 20% w/w aqueous solution of urea
(NH2CONH2)have equal molarity, then which solution has higher density :
(1) Both have equal density (2) Glucose solution
(3) Urea solution (4) Cannot be predicted
15. How many ml water should be added to 100ml HCl solution (d = 1.5 g/ml) 80% by wt. to make it a
solution of 40% by wt. of density = 1 g/ml.
(1) 100 ml (2) 300 ml (3) 200 ml (4) none of these
16. In the redox reaction
MnO4– + C2O42- + H+ Mn2+ + CO2 + H2O (Unbalance equation)
20 mL of 0.1 M KMnO4 react quantitatively with
(1) 20 mL of 0.1 M oxalate (2) 40 mL of 0.1 M oxalate
(3) 50 mL of 0.25 M oxalate (4) 50mL of 0.1 M oxalate
17. X forms of oxide X2O3. 0.36 grams of X forms 0.56 grams of X2O3. So the atomic weight of X is :
(1) 36 (2) 565 (3) 28.2 (4) 43.2
18. An unknown gaseous hydrocarbon and oxygen gas are mixed in volume ratio 1 : 7 respectively and
exploded. The resulting mixture upon cooling occupied a volume of V mL, half of which got absorbed in
aq. KOH (absorbs CO2) and the remaining half was absorbed in alkalline pyrogallol solution (absorbs
O2). Assuming all volumes to be measured under identical conditions :
(1) The molecular formula of hydrocarbon can be C2H6.
(2) The resulting mixture obtained after cooling contains 50% O 2 and 50% CO by mole.
(3) The molecular formula of hydrocarbon can be C3H4.
(4) Molecular mass of hydrocarbon is definitely less than 28 u.
19. Diborane (B2H6) reacts with water to give boric acid (H 3BO3) and hydrogen gas. How much boric acid
can be prepared using 98 g of diborane and 81 g of H2O ? (Take: atomic mass B = 11)
(1) 93 g (2) 98 g (3) 104 g (4) 112 g
20. What volume of 0.2 M Ba(OH)2 must be added to 300 mL of a 0.08 M HCl solution to get a solution in
which the molarity of hydroxyl (OH–) ions is 0.08 M ?
(1) 375 mL (2) 300 mL (3) 225 mL (4) 150 mL

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 SECTION-II
(NUMERICAL VALUE TYPE QUESTIONS)
This section contains Five (5) questions. The answer to each question is NUMERICAL VALUE with twodigit
integer and decimal upto one digit.

21. Calculate number of carbon atoms in molecular formula of a compound with minimum possible molar
mass having following composition (by mass) S = 16%, C = 4%, O = 4%
22. The oxidation number of Cr in the product of the reaction of K2Cr2O7 with KOH is
23. 3.5 g of a metal nitride M3N upon analysis was found to contain 2.1 g of metal M. Then, find the number
of gram-atoms in 63 g of metal M.
24. A sample of CH4 gas has the same mass as 2 × 107 molecules of C4H8. How many CH4 molecules are
present in the sample ?
25. Find total moles of S8 obtained if all S from 3 mole of S4N4 and 196 g H2SO4 and 128 g SO2 is converted
into S8.

Answer Key_DPP No.-1

1. (3) 2. (1) 3. (4) 4. (1) 5. (2) 6. (2) 7. (2)
8. (4) 9. (2) 10. (4) 11. (2) 12. (1) 13. (4) 14. (2)
15. (3) 16. (4) 17. (4) 18. (3) 19. (1) 20. (4) 21. (4)
22. (6) 23. (9) 24. (7) 25. (2)

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