Revision-DPP-5 Chemistry English PDF

PHYSICAL CHEMISTRY
 
TARGET : JEE(MAIN) 2019

INFORM ATIO
E E ST
DPP
DAILY PRACTICE PROBLEMS
Course : VIJETA (JP) & ANOOP (EP) Date : 14.12.2019

NO. 5
T E S T IN F O R M A T I O N
DATE : 18.12.2019 MPT-3 (ONLINE)
Syllabus : Equivalent Concept, Mole concept, Gaseous State (Real & Ideal Gas), d & f-Block Element,
Aromatic compounds, Carbonyl compound, Acid & Acid derivatives, Biomolecule, polymer, chemistry in
every day life and Environmental chemistry
DPP Syllabus : Equivalent Concept, Mole concept, Gaseous State (Real & Ideal Gas), d & f-Block Element
DPP No. # 5
Total Marks : 300 Max. Time: 180 min.
Single correct Objective ('–1' negative marking) Q.1 to Q.60 (4 marks) [240]
Integer type Questions (‘0’ negative marking) Q.61 to Q.75 (4 marks) [60]
SECTION - I
Straight Objective Type
This section contains 60 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which ONLY ONE is correct.
1. The sulphate of a metal M contains 9.87% of M. This sulphate is isomorphous with ZnSO4.7H2O . The
atomic weight of M is
(1) 40.3 (2) 36.3 (3) 24.3 (4) 11.3
2. In the reaction 2Na 2S2O3  I2  Na 2S4O6  2NaI , the equivalent weight of Na2S2O3 (mol. wt. = M) is
equal to
(1) M (2) M/2 (3) M/3 (4) M/4
3. What is the concentration of nitrate ions if equal volumes of 0.1 M AgNO3 and 0.1 MNaCl are mixed
together?
(1) 0.1 M (2) 0.2 M (3) 0.05 M (4) 0.25 M
4. 1.25 g of a solid dibasic acid is completely neutralised by 25 ml of 0.25 molar Ba(OH)2 solution.
Molecular mass of the acid is
(1) 100 (2) 150 (3) 120 (4) 200
5. Ratio of Cp and C v of a gas X is 1.4, the number of atom of the gas ‘X’ present in 11.2 litres of it at NTP
will be
(1) 6.02  1023 (2) 1.2  1023 (3) 3.01 1023 (4) 2.01 1023
6. On reduction with hydrogen, 3.6 g of an oxide of metal left 3.2 g of metal. If the vapour density of metal
is 32, the simplest formula of the oxide would be
(1) MO (2) M2O3 (3) M2O (4) M2O5
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7. 250 ml of a sodium carbonate solution contains 2.65 grams of Na 2CO3 . If 10 ml of this solution is
diluted to one litre, what is the concentration of the resultant solution (mol. wt. of Na 2CO3 =106)
(1) 0.1 M (2) 0.001 M (3) 0.01 M (4) 104 M
8. Mohr's salt is dissolved in dil. H2SO4 instead of distilled water to

(1) Enhance the rate of dissolution (2) Prevent cationic hydrolysis
(3) Increase the rate of ionisation (4) Increase its reducing strength
9. KMnO4 reacts with oxalic acid according to the equation,
2MnO4  5C2O24  16H  2Mn2  10CO2  8H2O , here 20 ml of 0.1 M KMnO4 is equivalent to
(1) 20 ml of 0.5 M H2C2O4 (2) 50 ml of 0.1 M H2C2O4
(3) 50 ml of 0.5 M H2C2O4 (4) 20 ml of 0.1 M H2C2O4
10. A solution containing Na 2CO3 and NaOH requires 300 ml of 0.1 N HCl using phenolpthalein as an
indicator. Methyl orange is then added to the above titrated solution when a further 25 ml of 0.2 N HCl
is required. The amount of NaOH present in solution is (NaOH  40,Na2CO3  106)
(1) 0.6 g (2) 1.0 g (3) 1.5 g (4) 2.0 g
11. KMnO4 reacts with ferrous ammonium sulphate according to the equation
MnO4  5Fe 2   8H  Mn2   5Fe 3   4H2O , here 10 ml of 0.1 M KMnO4 is equivalent to
(1) 20 ml of 0.1 M FeSO4 (2) 30 ml of 0.1 M FeSO4
(3) 40 ml of 0.1 M FeSO4 (4) 50 ml of 0.1 M FeSO4
12. The ratio of amounts of H2S needed to precipitate all the metal ions from 100 ml of 1 M AgNO 3 and 100
ml of 1 M CuSO4 will be
(1) 1 : 1 (2) 1 :2 (3) 2 : 1 (4) None of these
M
13. A solution of 10 ml FeSO4 was titrated with KMnO4 solution in acidic medium. The amount of
10
KMnO4 used will be
(1) 5 ml of 0.1 M (2) 10 ml of 1.1 M (3) 10 ml of 0.5 M (4) 10 ml of 0.02 M
14. The ratio of the molar amounts of H2S needed to precipitate the metal ions from 20mL each of
1M Cd(NO3 )2 and 0.5M CuSO4 is
(1) 1 : 1 (2) 2 : 1 (3) 1 : 2 (4) Indefinite
15. 10 dm3 of N2 gas and 10 dm3 of gas X at the same temperature contain the same number of molecules. The
gas X is :
(1) CO (2) CO 2 (3) H2 (4) NO
16. The set of numerical coefficient that balances the equation K 2CrO 4  HCl  K 2Cr2O7  KCl  H2O is
(1) 1, 1, 2, 2, 1 (2) 2, 2, 1, 1, 1 (3) 2, 1, 1, 2, 1 (4) 2, 2, 1, 2, 1
17. A 100 ml solution of 0.1 n HCl was titrated with 0.2 N NaOH solution. The titration was discontinued
after adding 30 ml of NaOH solution. The remaining titration was completed by adding 0.25 N KOH
solution. The volume of KOH required for completing the titration is
(1) 70 ml (2) 32 ml (3) 35 ml (4) 16 ml
PAGE-2
18. In the following reaction, which choice has value twice that of the equivalent mass of the oxidising agent
SO2  H2O  3S  2H2O
(1) 64 (2) 32 (3) 16 (4) 48
19. The Vander Waal's equation explains the behaviour of

(1) Ideal gases (2) Real gases (3) Vapour (4) Non-real gases
20. Gases deviate from the ideal gas behaviour because their molecules
(1) Possess negligible volume (2) Have forces of attraction between them
(3) Are polyatomic (4) Are not attracted to one another
21. The compressibility factor of a gas is defined as Z  PV / RT . The compressibility factor of ideal gas is
(1) 0 (2) Infinity (3) 1 (4) –1
22 In Vander Waal's equation of state for a non-ideal gas, the term that accounts for intermolecular forces
is
 a 
(1) (V  b) (2) (RT)1 (3)  P   (4) RT
 V2 
23. Vander Waal's equation of state is obeyed by real gases. For n moles of a real gas, the expression will
be
 P na   V   a 
(1)       RT (2)  P   (V  b)  nRT
 n V2   nb   V2 
 na   n2a 
(3)  P   (nV  b)  nRT (4)  P  2  (V  nb)  nRT
 V2   V 

24. Any gas shows maximum deviation from ideal gas at

(1) 0o C and 1 atmospheric pressure (2) 100o C and 2 atmospheric pressure
(3)  100o C and 5 atmospheric pressure (4) 500o C and 1 atmospheric pressure
25. The temperature at which the second virial coefficient of real gas is zero is called
(1) Critical temperature (2) Eutetic point
(3) Boiling point (4) Boyle's temperature
26. When is deviation more in the behaviour of a gas from the ideal gas equation PV  nRT
(1) At high temperature and low pressure (2) At low temperature and high pressure
(3) At high temperature and high pressure (4) At low temperature and low high pressure
27. The ratio of root mean square velocity to average velocity of gas molecules at a particular temperature
is
(1) 1.086 : 1 (2) 1 : 1.086 (3) 2 : 1.086 (4) 1.086 : 2
28. Which is not true in case of an ideal gas

(1) It cannot be converted into a liquid
(2) There is no interaction between the molecules
(3) All molecules of the gas move with same speed
(4) At a given temperature, PV is proportional to the amount of the gas
29. Postulate of kinetic theory is

(1) Atom is indivisible
(2) Gases combine in a simple ratio
(3) There is no influence of gravity on the molecules of a gas
(4) None of the above
PAGE-3
30. According to kinetic theory of gases,
(1) There are intermolecular attractions
(2) Molecules have considerable volume
(3) No intermolecular attractions
(4) The velocity of molecules decreases after each collision
31. In deriving the kinetic gas equation, use is made of the root mean square velocity of the molecules
because it is
(1) The average velocity of the molecules
(2) The most probable velocity of the molecules
(3) The square root of the average square velocity of the molecules
(4) The most accurate form in which velocity can be used in these calculations
32. Kinetic energy of a gas depends upon its

(1) Molecular mass (2) Atomic mass (3) Equivalent mass (4) None of these
33. The kinetic theory of gases perdicts that total kinetic energy of a gaseous assembly depends on
(1) Pressure of the gas (2) Temperature of the gas
(3) Volume of the gas (4) Pressure, volume and temperature of the gas
34. If P, V, T represent pressure, volume and temperature of the gas, the correct representation of Boyle's
law is
1
(1) V  (at constant P) (2) PV  RT
T
(3) V  1 / P (at constant T) (4) PV  nRT
35. At constant temperature, in a given mass of an ideal gas

(1) The ratio of pressure and volume always remains constant
(2) Volume always remains constant
(3) Pressure always remains constant
(4) The product of pressure and volume always remains constant
36. Air at sea level is dense. This is a practical application of

(1) Boyle's law (2) Charle's law (3) Avogadro's law (4) Dalton's law
37. If 20 cm3 gas at 1 atm. is expanded to 50 cm3 at constant T, then what is the final pressure
1 1 1
(1) 20  (2) 50  (3) 1   50 (4) None of these
50 20 20
38. Amongst TiF62 , CoF63 , Cu 2 Cl 2 and NiCl 42 (Atomic number Ti  22, Co  27, Cu  29, Ni  28 ). The
colourless species are
(1) CoF63 and NiCl 42 (2) TiF62 and CoF63
(3) Cu 2 Cl 2 and NiCl 42 (4) TiF62 and Cu 2 Cl 2
39. The colour of K 2 Cr2 O7 changes from red orange to lemon yellow on treatment with aqueous KOH
because of
(1) The reduction of Cr VI to Cr III
(2) The formation of chromium hydroxide
(3) The conversion of dichromate to chromate
(4) The oxidation of potassium hydroxide to potassium peroxide
40. The form of iron having the highest carbon content is

(1) Cast iron (2) Wrought iron (3) Strain steel (4) Mild steel
PAGE-4
41. Aqueous solution of ferric chloride is
(1) Acidic (2) Basic (3) Neutral (4) Amphoteric
42. The spin magnetic moment of cobalt in the compound Hg[Co(SCN)4 ] is

(1) 3 (2) 8 (3) 15 (4) 24
heat
43. 4 K 2 Cr2 O7   4 K 2 CrO 4  3O2  X . In the above reaction X is
(1) CrO 3 (2) Cr 2 O7 (3) Cr 2 O3 (4) CrO 5
44. Which of the following is not oxidized by O3

(1) KI (2) FeSO 4 (3) KMnO4 (4) K 2 MnO4
45. Ferrous sulphate on strong heating gives

(1) SO2 (2) Fe 2 (SO4 )3 (3) FeO  SO3 (4) Fe 2 O3  SO2  SO3
46. Copper displaces which of the metal from their salt solutions
(1) AgNO 3 (2) ZnSO4 (3) FeSO4 (4) All of these
47. Which of the following pair of ions may exhibit same colour
(1) Cr    and Fe   (2) Ti    and V   (3) Fe    and Mn  (4) Cu  and Ni  
48. Cerium (Z  58) is an important member of the lanthanoids. Which of the following statements about
cerium is incorrect
(1) The +4 oxidation state of cerium is not known in solutions
(2) The +3 oxidation state of cerium is more stable than the +4 oxidation state
(3) The common oxidation states of cerium are +3 and +4
(4) Cerium (IV) acts as an oxidizing agent
49. In acidic medium potassium dichromate acts as an oxidant according to the equation,
Cr2O72   14 H   6e   2Cr 3   7H2O . What is the equivalent weight of K 2 Cr 2 O7 ? (mol. Wt. = M)
(1) M (2) M / 2 (3) M / 3 (4) M / 6
50. AgCl dissolves in a solution of NH 3 but not in water because
(1) NH 3 is a better solvent than H 2 O (2) Ag  forms a complex ion with NH 3

(3) NH 3 is a stronger base than H 2 O (4) The dipole moment of water is higher than NH 3
51. When hypo solution is added to cupric sulphate solution, the blue colour of the latter is discharged, due
to formation of
(1) CuS 2 O3 (2) Na 2 S4 O6 (3) [Cu6(S2O3)5]–4 (4) Cu 2 O
52. Light green crystals of ferrous sulphate lose water molecule and turn brown on exposure to air. This is
due to its oxidation to
(1) Fe 2 O3 (2) Fe 2 O3 .H 2 O (3) Fe(OH)SO4 (4) Fe 2 O3  FeO
53. Which one of the following is reduced by hydrogen peroxide in acid medium
(1) Potassium permanganate (2) Potassium iodide
(3) Ferrous sulphate (4) Potassium ferrocyanide
54. Suppose 40% w/w aqueous solution of glucose (C6H12O6) and 20% w/w aqueous solution of urea
(NH2CONH2) have equal molarity, then which solution has higher density :
(1) Both have equal density (2) Glucose solution
(3) Urea solution (4) Cannot be predicted
PAGE-5
55. How many ml water should be added to 100ml HCl solution (d = 1.5 g/ml) 80% by wt. to make it a
solution of 40% by wt. of density = 1 g/ml.
(1) 100 ml (2) 300 ml (3) 200 ml (4) none of these
56. In the redox reaction

MnO4- + C2O42- + H+  Mn2+ + CO2 + H2O (Unbalance equation)
20 mL of 0.1 M KMnO4 react quantitatively with
(1) 20 mL of 0.1 M oxalate (2) 40 mL of 0.1 M oxalate
(3) 50 mL of 0.25 M oxalate (4) 50mL of 0.1 M oxalate
57. X forms of oxide X2O3. 0.36 grams of X forms 0.56 grams of X2O3. So the atomic weight of X is :
(1) 36 (2) 565 (3) 28.2 (4) 43.2
58. An unknown gaseous hydrocarbon and oxygen gas are mixed in volume ratio 1 : 7 respectively and
exploded. The resulting mixture upon cooling occupied a volume of V mL, half of which got absorbed in
aq. KOH (absorbs CO2) and the remaining half was absorbed in alkalline pyrogallol solution (absorbs
O2). Assuming all volumes to be measured under identical conditions :
(1) The molecular formula of hydrocarbon can be C2H6.
(2) The resulting mixture obtained after cooling contains 50% O 2 and 50% CO by mole.
(3) The molecular formula of hydrocarbon can be C3H4.
(4) Molecular mass of hydrocarbon is definitely less than 28 u.
59. Diborane (B2H6) reacts with water to give boric acid (H3BO3) and hydrogen gas. How much boric acid
can be prepared using 98 g of diborane and 81 g of H2O ? (Take: atomic mass B = 11)
(1) 93 g (2) 98 g (3) 104 g (4) 112 g
60. What volume of 0.2 M Ba(OH)2 must be added to 300 mL of a 0.08 M HCl solution to get a solution in
which the molarity of hydroxyl (OH–) ions is 0.08 M ?
(1) 375 mL (2) 300 mL (3) 225 mL (4) 150 mL
SECTION-II :
(INTEGER TYPE QUESTIONS)
This section contains Fifteen (15) questions. The answer to each question is NUMERICAL VALUE with two
digit integer and decimal upto one digit.
61. Calculate the molar volume of Van der waal's gas at 8.21 atm and 500 K temperature. Given a = 8.21
atm L2 mole–2 and b = 0.2 Lmol-1.
62. Calculate number of carbon atoms in molecular formula of a compound with minimum possible molar
mass having following composition (by mass) S = 16%, C = 4%, O = 4%
63. The oxidation number of Cr in the product of the reaction of K2Cr2O7 with KOH is
64. Number of pairs of ions which are coloured in aqueous solutions ?

(i) Ti3+, V3+ (ii) Cu+, Sc3+ (iii) Fe2+, Fe3+ (iv) Co2+ , Ni2+
2+
(v) Zn , Ag +
65. How many of the following oxides show amphoteric nature?

V2O3, V2O5, CrO, CrO3, Cr2O3, Mn2O7, FeO, Cu2O, ZnO.
66. How many of the following aqueous solutions are colored ?

V4+, V3+, V2+, Cr3+, Mn3+, Ti4+, Co2+, Ni2+, Cu2+, Zn2+, Sc3+, Ti3+
67. 3.5 g of a metal nitride M3N upon analysis was found to contain 2.1 g of metal M. Then, find the number
of gram-atoms in 63 g of metal M.
PAGE-6
68. A sample of CH4 gas has the same mass as 2 × 107 molecules of C4H8. How many CH4 molecules are
present in the sample ?
(Report your answer as X, where Number of CH4 molecules = X × 107)
69. Find total moles of S8 obtained if all S from 3 mole of S4N4 and 196 g H2SO4 and 128 g SO2 is
converted into S8.
70. The mass of hydrocarbon (in gram) that should be burnt to produce 11.2 L CO 2 (dH2O = 1 g/ml) and 18
ml H2O at STP is.
71. A mercury column of length 10 cm is in the middle of a horizontal tube of length 1 m closed at both
ends containing same amount of a gas in both columns. If the tube is placed vertically, the mercury
225
column will shift through a distance of cm from its initial position. Find the final pressure of gas in
13
upper column (in cm of Hg) when the tube is placed vertically.
72. An L.P.G. cylinder contains 15 kg of butane gas at 27°C and 10 atmospheric pressure. It was leaking
and its pressure fell down to 8 atmospheric pressure after one day. The gas leaked (in kg) is.
73. Calculate the change in pressure (in atm) when 2 mole of NO and 16 g O 2 in a 6.25 litre originally at
27°C react to produce the maximum quantity of NO2 possible according to the equation.
1
(Take R  atm L/mol K)
12
2NO(g) + O2(g)  2NO2(g)
74. Let Z be the compressibility factor for a real gas at critical conditions and Vander Waal constant b is
R  TC 
dipendent as b = m  P  , then find the product (Z × m).
 C
75. Compressibility factor (Z) for N2 at – 23ºC and 25 atm pressure is 1.2. Calculate moles of N 2 gas
required to fill a gas cylinder of 7 liter capcacity under the given conditions :
 1 1 1 
 Use R  12 lt atmmol K 
 
ANSWER KEY OF REVISION DPP No. # 5

1. (3) 2. (1) 3. (3) 4. (4) 5. (1) 6. (4) 7. (1)
8. (2) 9. (2) 10. (2) 11. (4) 12. (2) 13. (4) 14. (2)
15. (1) 16. (4) 17. (4) 18. (2) 19. (2) 20. (2) 21. (3)
22. (3) 23. (4) 24. (3) 25. (4) 26. (2) 27. (1) 28. (3)
29. (4) 30. (3) 31. (4) 32. (4) 33. (2) 34. (3) 35. (4)
36. (1) 37. (1) 38. (4) 39. (3) 40. (1) 41. (1) 42. (3)
43. (3) 44. (3) 45. (4) 46. (1) 47. (3) 48. (1) 49. (4)
50. (2) 51. (3) 52. (3) 53. (1) 54. (2) 55. (3) 56. (4)
57. (4) 58. (3) 59. (1) 60. (4) 61. (5) 62. (4) 63. (6)
64. (3) 65. (3) 66. (9) 67. (9) 68. (7) 69. (2) 70. (8)
71. (8) 72. (3) 73. (2) 74. (3) 75. (7)
PAGE-7

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PHYSICAL CHEMISTRY

Course : VIJETA (JP) & ANOOP (EP) Date : 14.12.2019

(1) 0.1 M (2) 0.001 M (3) 0.01 M (4) 104 M

8. Mohr's salt is dissolved in dil. H2SO4 instead of distilled water to

9. KMnO4 reacts with oxalic acid according to the equation,

19. The Vander Waal's equation explains the behaviour of

24. Any gas shows maximum deviation from ideal gas at

28. Which is not true in case of an ideal gas

29. Postulate of kinetic theory is

32. Kinetic energy of a gas depends upon its

35. At constant temperature, in a given mass of an ideal gas

36. Air at sea level is dense. This is a practical application of

40. The form of iron having the highest carbon content is

42. The spin magnetic moment of cobalt in the compound Hg[Co(SCN)4 ] is

44. Which of the following is not oxidized by O3

45. Ferrous sulphate on strong heating gives

50. AgCl dissolves in a solution of NH 3 but not in water because

(1) NH 3 is a better solvent than H 2 O (2) Ag  forms a complex ion with NH 3

56. In the redox reaction

64. Number of pairs of ions which are coloured in aqueous solutions ?

65. How many of the following oxides show amphoteric nature?

66. How many of the following aqueous solutions are colored ?

ANSWER KEY OF REVISION DPP No. # 5

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