1.

The number of moles of that will be needed to react completely with

one mole of ferrous oxalate in acidic solution is

a) b) c) d) 1
KEY: A

HINT: oxides both and

(or)
2 Which of the following is not formed as product in the reaction ?

A) BN B) B O C) NaCl D) B N H
2 3 3 3 6
KEY:D

HINT:

3. In which of the following sulpher atoms carries different oxidation states

A) H 2S2 O3 B) H 2S2O 7 C) H 2S2O 6 D)
H 2S 2 O 4
KEY:A

4 An acid – base indicator has a Ka of . The acid form of the indicator is

red and the basic form is blue. The change in concentration in order to
change the indicator from 75% red to 75% blue.

a) b) c) d)

KEY: B

HINT:

Acidic basic

Red Blue
 Red from 75% blue from 25%

When 75% blue and 25% red, then

change is

5 It is possible to liquefy a gas

1) at a temperature above critical temperature and at a

pressure above critical pressure.

2) at a temperature equal to critical temperature and at a

pressure lower than critical pressure.

3) at critical temperature and at a pressure equal to critical

pressure

4) at a temperature above critical temperature and pressure

below critical pressure.

6 Dimethyl terephthalate reacts with ethylene glycol under high
temperature and pressure to give a polymer called ‘Dacron’.
Identify the correct statements out of the following

(I) Dacron is polyethylene terphthalate

(II) Dacron is formed by step growth condensation

polymerizations.

(III) Dacron is a polyester

(IV) Methanol molecules are removed during the

polymerization process

1) Only (I) and (II) 2) Only (II), (III) and (IV)

3) Only (III) 4) All of the above

6

7. Carbon cannot reduce Fe2O3 to Fe at a temperature below

983k because
1) Free energy change for the formation of CO more negative
than that of Fe2O3
2) CO is thermodynamically more stable than Fe2O3
 3) Carbon has higher affinity towards oxygen than iron
4) Iron has higher affinity towards oxygen than carbon

7. in this reaction as there is no change in

entropy, at lower temperatures carbon have less affinity
towards oxygen than iron.
8. A first order reaction is 50% completed in20 minutes at 27 0C
and in 5 minutes at 470C. The energy of activation of the
reaction is :

1) 43.85 kJ/mol 2) 55.14 kJ/mol

3) 11.97 kJ/mol 4) 6.65 kJ/mol

8.

9. Which of the following pairs is expected to exhibit the same

colour

1) 2)

3) 4)

10. The crystals of ferrous sulphate on heating give

 1) 2)

3) 4)

10.

11. Which of the following has an optical isomer

1) 2)

3) 4)

In has all (en) in position and hence, shows

11.
optical isomerism

12. Which of following is the correct statement

1) BaCO3 < SrCO3 < CaCO3 < MgCO3 [ Thermal stability]

2) CaF2 > MgF2 > BaF2 > BeF2 [ Solubility in water ]

3) BaSO4 > SrSO4 > CaSO4 > MgSO4 [ Solubility ]

4) Ba( OH)2 > Ca (OH)2 > Mg(OH)2 > Be(OH)2 [ Thermal

stability]
13. Among the following the surfactant that will form micelles in
aqueous solution at the lowest molar concentration at
ambient conditions is

1) 2)

3) 4)

14. For the reaction occurring at two

different pressures respectively. The ratio of two

pressures is 1:3. If the degree of dissociation of X and Z are
equal then the ratio of equilibrium constants (Kp) is

1)1:36 2)4:3 3)1:9 4)2:3

14.

15.

Major product is:

 1) 2) 3)

4)

16. In Dumas’ method for estimation of nitrogen, 0.3g of an

organic compound gave 50mL of nitrogen collected at 300K
temperature and 715mm pressure. Calculate the percentage
composition of nitrogen in the compound. (Aqueous tension
at 300K=15 mm).

1) 17.46% 2) 34.46% 3)64.46% 4) 8.46%

17. Which of the following pair gives the same osazone?

1) glucose, sucrose 2) glucose, lactose

3) lactose, sucrose 4) glucose, fructose

18. In the reaction of iodide ion with , what

is the order of decreasing reactivity for the following X

substituents?

I) II) III) IV)

1) I > II > III > IV 2) IV > III > II > I

 3) III > II > IV > I 4) III > IV > II > I

18. Best leaving group order follows

III > IV > II > I

19. No. of hybridized atoms in acrylonitrile respectively

are

1) 2, 3 2) 2, 2 3) 3, 2 4) 4, 2

20. Which of the following compounds give on heating?

I) II) III) IV)

V)

1) I, IV 2) II, IV 3) I & II 4) IV & V

integer answer
questions
1 number of iodoform molecules
produced per molecule.

ans is 1

2. reacts with to give a single product. The number of

molecules required to react with one mole of in the
balanced reaction is

2.hint ans is 6

3. A metal crystallizes in f.c.c. Then, the ratio of number of its

first nearest neighbours to the second nearest neighbours is

……………..

ans is 2

hint. First nearest neighbours is 12 Second nearest neighbours is

4. How many of the following reduce Fehlings solution?

 Formic acid, formaldehyde, benzalde hyde, sucrose, Fructose,

glucose, acetone

ans is 4

hint. Formic acid, Formaldehyde, fructose, glucose

5. How many of the following compounds undergo

decarboxylation on simple heating,?

Malonic acid, Succinic acid, But – 2 enoic acid, 3-keto

butanoic acid ,

Pent-3-enoic acid, nitro propanoic acid. Oxalic acid,

Pyruvic acid.

ans is 5

5hint . Malonic acid,

32. The acid – base indicator (Hln) shows a colour change at pH = 6.4
when 20% of it is ionized. The dissociation constant of the

indicator is approximately what is the value of X? 7

25. The degree of hardness of a sample of water containing 6 mg of

magnesium

sulphate (other salts are absent) per kilogram of water is 5

16. Among Cu,Hg,Pb,Zn,Au,Ag the number of metals extracted by self

reduction is.3

39. What is the oxidation no. of carbon in ethylene ozonide zero

36. How many of the following are black coloured compounds
Ag2S , PbS ,HgS , CuS , FeS , CoS ,NiS , ZnS , CdS , Sb2S3 , MnS seven