FIITJEE Mock Test Paper 2 Physics Chemistry Maths Sept 2021

FIITJEE - MOCK TEST
(JEE ADVANCED 2021)

PAPER - 2
(20.09.2021)
Time Allotted: 3 Hours Maximum Marks: 231
 Do not open this Test Booklet until you are asked to do so.
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
A. General Instructions
1. Attempt ALL the questions.

2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each Part is further divided into Three Sections: Section-A, B & C
5. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.
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JEEA-MT-PAPER-2 - P2
PART – I [PHYSICS]
SECTION – A
Straight Objective Type
This section contains 3 questions. Each question has four options (A), (B), (C) and (D). ONLY ONE of these
four options is correct. For each question, you will be awarded 3 marks if you have darkened only the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus one (–
1) mark will be awarded.
1. Electrons in a sample of gas containing hydrogen like atom (Z=3) are in fourth excited state. When
photons emitted only due to transition from third excited state to second excited state are incident on a
metal plate photoelectrons are ejected. The stopping potential for these photoelectrons is 3.95 eV. Now,
if only photons emitted due to transition from fourth excited state to third excited state are incident on
the same metal plate, the stopping potential for the emitted photoelectrons will be approximately equal
to
(A) 0.85 eV (B) 0.75 eV
(C) 0.65 eV (D) None of these
2. A uniform magnetic field B increasing with time exists in a cylindrical region of centre O and radius R.
The direction of magnetic field is inwards the paper as shown. The work done by external agent in
taking a unit positive charge slowly from A to C via paths APC, AOC and AQC be WAPC, WAOC and
WAQC respectively. Then
(A) WAPC =WAOC = WAQC (B) WAPC > WAOC> WAQC

(C) WAPC <WAOC< WAQC (D) WAPC = WAQC< WAOC
3. An induction coil is connected to a source that delivers current varying with time. Variation of the current
with time that passes through the coil is shown in the graph. Four moments are marked as t1, t2, t3 and
t4 in the graph. The moment at which self-induced emf is maximum, is:
O t1 t2 t3 t4 t
(A) t1 (B) t2
(C) t3 (D) t4
SECTION – A
This section contains 5 questions. Each question has four options (A), (B), (C) and (D). ONE OR MORE
THAN ONE of these four options is (are) correct. For each question, you will be awarded 4 marks if you
darken ALL the bubble(s) corresponding to the correct answer(s). You will be awarded 1 mark for darkening a
bubble corresponding to each correct option, provided NO incorrect option is darkened and zero mark if no
bubble is darkened. In all other cases, minus two (–2) marks will be awarded.
4. In the figure shown an observer O1 floats (static) on water surface with ears in air while another
observer O2 is moving upwards with constant velocity V1 = V/5 in water. The source moves down with
constant velocity Vs = V/5 and emits sound of frequency 'f'. The velocity of sound in air is V and that in
water is 4V. For the situation shown in figure:
S
Vs= V
5
O1
V1= V
5
O2
4V
(A) The wavelength of the sound received by O1 is
5f
(B) The wavelength of the sound received by O1 is V/f
21f
(C) The frequency of the sound received by O2 is
16
16V
(D) The wavelength of the sound received by O2 is
5f
5. An ideal gas undergoes a thermodynamic cycle as shown in figure.:
Which of the following graphs represents the same cycle?
(A) (B)
(C) (D)
6. Number of collisions of molecules of a gas on the wall of a container per m2will :

(A) Increase if temperature and volume both are doubled.
(B) Increase if temperature and volume both are halved.
(C) Increase if pressure and temperature both are doubled.
(D)Increase if pressure and temperature both are halved.
7. If one of the slits of a standard Young's double slit experiment is covered by a thin parallel sided glass
slab so that it transmits only one half the light intensity of the other, then:
(A) The fringe pattern will get shifted towards the covered slit
(B) The fringe pattern will get shifted away from the covered slit
(C) The bright fringes will become less bright and the dark ones will become more bright
(D) The fringe width will remain unchanged
8. If two balls of given masses and charges are released, which of the following is incorrect arrangement
in equilibrium?
(A) (B)
α2 > α1
θ θ α2
α1
+2q
+q +3q
+q m
(C) m m (D) 2m
SECTION – A
Paragraph Type
This section contains 1 paragraph. Based on the paragraph, there are two questions. Each question has 4
options (A), (B), (C) and (D). ONLY ONE of these four options is correct. For each question, you will be
awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero mark if no
bubble is darkened. No negative marks will be awarded for incorrect answers in this section.
Comprehension:
A uniform and constant magnetic field Tesla exists in space. A charged particle with charge to mass ratio
3
 q  10
  =
 m  19
(
C/kg enters this region at time t = 0 with a velocity V = 20iˆ + 50 ˆj + 30kˆ m/s. Assume that the )
charged particle always remains in space having the given magnetic field. (Use 2 = 1.4)
9. During the further motion of the particle in the magnetic field, the angle between the magnetic field and
velocity of the particle
(A) remains constant (B) increases
(C) decreases (D) may increase or decrease.
10. The pitch of the helical path of the motion of the particle will be
π π
(A) m (B) m
100 125
π π
(C) m (D) m
215 250
SECTION – B
Integer Answer Type
This section contains 10 questions. The answer to each of the questions is a single-digit integer, ranging
from 0 to 9. For each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to
the correct answer and zero mark if no bubble is darkened. No negative marks will be awarded for incorrect
answers in this section.
11. At time t1, an electron is sent along the positive direction of x-axis,
2
through both an electric field E and a magnetic field B , with E
Fnet,y(10–19N)
1 V(m/s)
directed parallel to the y-axis. Graph gives the y-component Fnet,y of
the net force on the electron due to the two fields, as a function of the 0
50 100
-1
electron’s speed V at time t1. Assuming Bx = 0, magnitude of electric
-2
field E in N/C, then find the value of 4E. (Use e = 1.6 x 10–19 C)
12. A uniform triangular plate ABC of moment of inertia I (about an axis

A a B
passing through A and perpendicular to plane of the plate) can
rotate freely in the vertical plane about point A as shown in figure.
The plate is released from the position shown in the figure. Line a a
AB is horizontal. The acceleration of centre of mass just after the
mga2
release of plate is found to be . Find the value of n.
n 3I C
13. A 2 2 cm needle is placed at an angle of 45o, with its centre 5 cm above the optical axis and 15 cm
from a lens of 12 cm focal length as shown in figure. O is the origin and C is the centre of the needle.
y
B
C 450
A 5cm
x
15cm
x
The x co-ordinate of image of point A in cm is x. Find the value of .
6
14. In the figure shown, S1 and S2 are two coherent sources emitting P y
light of wavelength λ and having no initial phase difference. S1
S1
and S2 oscillate simple harmonically with amplitude ‘a’ each and
2a
frequency ‘f’ each on the line PQ which is perpendicular to the x-
axis. The initial position and initial direction of motion of S1 and S2
Q
+x
are shown in the figure. S1 and S2 are at their mean position at t = 2a D
0 sec. The y-coordinate of 3rd maxima at time t is found to be
nλD S2
. Find the value of n. Assume that λ << a and
2a ( 2 − sin ωt ) Q
a << D .
15. A point source of light of power P is kept on the axis of a disc of radius R. Distance of the source from
the centre is 2R. Assume that the disc absorbs all the light falling on it. The force on the disc due to
P
this light is found to be , where c is speed of light and n is an integer. Find the value of n.
n (10c )
16. Two identical small balls each have a mass m and charge q.
When placed in a hemispherical bowl of radius R with frictionless, R R
nonconductive walls, the beads move, and at equilibrium the line
joining the balls is horizontal and the distance between them is R m m
(shown in figure). Neglect any induced charge on the R
hemispherical bowl. Then the charge on each bead is found to be
1
 mg  2  1 
R  . Find the value of n.  here K = 
K n   4 πε 0 
17. Six charges are placed at the vertices of a regular hexagon as +Q -Q

shown in the figure. The electric field on the line passing through
point O and perpendicular to the plane of the figure as a function of
Qa
distance x from point O is found to be . Find the value of n.
nπε 0 x 3 +Q -Q
(assume x >> a )
+Q Q
a
18. A and C are concentric conducting spherical shells of radius a and c
c
respectively. A is surrounded by a concentric dielectric medium of inner
c
radius a, outer radius b and dielectric constant k. If sphere A is given a
charge Q, the potential at the outer surface of the dielectric is found to be C
Q a B
. Find the value of n.
nπε0b A
19. A parallel plate capacitor is to be designed which is to be connected across 1 kV potential difference.
The dielectric material which is to be filled between the plates has dielectric constant K = 6π and
dielectric strength 107 V/m. For safely the electric field is never to exceed 10% of the dielectric strength.
With such specifications, if we want a capacitor of capacitance 50 pF, what minimum area of plates is
1
required for safe working? Express your answer in multiples of 100 mm2. (use ε0 = × 10 −9 in MKS)
36π
20. In the figure shown ABCDEFA is a square loop of side ℓ , but is folded in two equal parts so that half of
it lies in xz plane and the other half lies in the yz plane. The origin O is centre of the frame also. The
2µ0i ˆ ˆ
loop carries current i. The magnetic field at the centre is found to be
nπℓ
( )
i + j . Find the value of n.
y D
C
B
E
O x
z F A
SECTION – C
Numerical Answer Type
This section contains 3 questions. The answer to each of the questions can be any positive number up to
99999.99. For each question, you will be awarded 4 marks if you have darkened the bubbles corresponding to
21. Two separate cylinders of masses m (= 1 kg) & 4m and radii R (= 10 cm) &
2R rotating in clockwise direction with ω1 = 100 rad/sec and ω2 = 200
rad/sec respectively. Now they are held in contact with each other as in
figure. Find the velocity (in m/s) of point of contact when slipping between
cylinders stops.
22. A beam of light has a power of 144 W equally distributed among three wavelengths of 410 nm, 496 nm
and 620 nm. The beam is incident at an angle of incidence of 60o on an area of 1 cm2 of a clean
sodium surface, having a work function of 2.3 eV. Assuming that there is no loss of light by reflection
and that each energetically capable photon ejects a photoelectron, find the saturation photocurrent (in
o
mA). (Take hc/e = 12400 eV A )
23. Water at 50oC is filled in a cubical container of side 1 m. The thickness of the walls of the container is 1
mm. The container is surrounded by large amount of ice at 0oC. The temperature of the water
becomes 25oC in 10ln 2 seconds. Find the ice melted (in kilograms) in that time. [Given, specific heat
of water = 1 cal/gm degree, latent heat of fusion of ice = 80 cal/gm, density of water = 1 gm/cm3, heat
capacity of the container ≅ 0 ]
PART – II [CHEMISTRY]
SECTION – A
1. Which of the following “iminic” compound is least stable?

NH NH
NH
(A) (B)
NH
NH
NH
(C) (D)
HN NH
NH
2. For the reaction,

OH
HO

H (excess)
→A
OH
What is the product A?
(A) (B)
(C) (D)
3. The van der Waal’s constant “b” for gases A, B, C and D are 3 × 10–4, 4 × 10–3, 5 × 10–2 and 3 × 10–5 in
dm3/mole respectively, then which of the following is the correct decreasing order of compressibility.
(A) D > A > B > C (B) A > D > B > C
(C) D > A > C > B (D) B > D > A > C
SECTION – A
4. Which is/are one true statements?

(A) diamond is unaffected by conc. acids but graphite reacts with hot conc. HNO3 forming millitic acid
C6(COOH)6.
(B) CO is toxic because it forms a complex with haemoglobin in the blood.
(C) C3O2 carbon suboxide, is a foul-smelling gas.
(D) ZrSiO4 is used as a gemstone.
5. 2 mole of Xn+ is oxidized by 5.6 moles of MnO2 into Xm+, 12 moles of Xn+ is reduced into Xm- by 8.4 mole
of H2S in acidic medium (when H2S is oxidize into SO2.) among the given values of m and n which are
correct.
(A) m = 4.9 and x = -0.7 (B) m = 5 and n = 2
(C) m = 10 and n = 4 (D) m = 7 and x = -1
6. The compound x was boiled under reflux for some time with a solution of sodium hydroxide. The
solution was cooled, acidified with dilute nitric acid and then silver nitrate solution was added : a thick
white precipitate formed. The complex x could have been
(A) CH3COCl (B) C6H5CH2Cl
(C) CH2ClCOOH (D) C6H5Cl
7. The data given below is used to find the type of cubic lattice to which the crystal belong.
Ag Al Cu
a (pm) 407.7 405 361
ρ (g cm-3) 10.5 2.7 8.92
At. mass (gm) 108 27 63.5
Which of the above crystallizes in FCC unit cell?
(A) Ag (B) Al
(C) Cu (D) none of these
Ph CN
8. LiAlH 4 HNO 2
C (B) HIO 4
(C) (X) + (Y)
CH 3 OH
+
H HCN
(A)
(Z) (A)
Correct statements are
(A) X gives yellow precipitate with I2 in presence of NaOH.
(B) Y is reduced by Fehling solution
(C) Z gives silver mirror with [Ag(NH3)2]+
(D) X reduces Tollen’s reagent
SECTION – A
Paragraph Type
Comprehension:
Titration is a method of finding out the strength of an unknown solution by reacting with a known solution using a
suitable indicator. The choice of the indicator depends on the nature of the reaction. The method is carried out
by taking a definite volume of solution of unknown strength in the beaker, indicator is added and then from the
burette the known solution is added till the indicator changes the colour which indicates the reaction is complete.
At this point the number of equivalence of the solution in the beaker is equal to the number of equivalence of the
solution added from the burette.
9. A solution containing x m mole of H2SO4, y millimole of H2C2O4 requires A ml 1M Ca(OH)2 for complete
neutralisation. B ml of 0.1M Mg(MnO4)2 is required for complete oxidation of the same solution. x and y
can be expressed as
2B − A A 2A − B B
(A) , (B) ,
2 2 2 2
A−B A A − 2B B
(C) , (D) ,
2 2 2 2
10. The volume of 2M H4P2O7 needed to neutralise 2cc 2M Ca(OH)2 is

(A) 2cc (B) 1cc
(C) 4cc (D) 1.5cc
SECTION – B
Integer Answer Type
11. A definite amount of solid NH4HS is placed in a flask already containing ammonia gas at a certain
temperature and 0.1 atm pressure. NH4HS decomposes to give NH3 and H2S and at equilibrium total
pressure in flask is 1.1 atm. If the equilibrium constant Kp for reaction
NH4HS (s) ↽ ⇀ NH3 (g) + H2S (g)
is represented as z × 10 −1 , then find the value of z.
12. A spherical balloon of volume 5 litre is to be filled up with H2 at NTP from a cylinder of 6 litre volume
containing the gas at 6 atm and 0oC. The number of balloons that can be filled up are
13. How many grams of a non volatile solute must be dissolved in 114 gm octane so that the vapour
pressure is reduced to 80%? (Molecular weight of solute = 36)
14. The solubility of AgCN in a buffer solution is 1.58 x 10–5 mol lit–1. Given Ksp of AgCN = 1.2 x 10–16 and
Ka (HCN) = 4.8 x 10–10. The pH of buffer is
I O
15. I C C CH2 CH2 I 

Aq. NaOH
→ Product + yellow ppt.
I
Total number of iodine atoms replaced by OH – in the ‘Product’ will be
OCH3
OH
16.

excess HI
→ Final product
OH
The number of HI moles consumed after the end of the reaction will be
17. EMnO− Mn2+ , H+

differs by 0.48 volts if pH of system changed from x to y, keeping the concentration of all
4
other species equal. What is the numerical difference between x and y?
18. 0.01 moles of FeSn [Iron (II) sulphide] requires 0.06 moles of AO34− for complete oxidation. The
species formed are FeO, SO2 and A+2. What should be the value of n?
19. The extent of adsorption (x/m) at a pressure of 1 atm from the following graph is
x 45o
log
m
0.6020
logP
20. The number of compounds having enol percentage greater than their keto percentage are
O
O O
H3C C CH3 , Ph C CH3 , Ph CHO , ,
O O O
Ph C Ph , Et C Ph CH3
SECTION – C
21. For the following parallel chain reaction
4B
-1
-3 s
1 0
= 2x
K1
A 3C
 [B]t 16 
what will be the value of overall half-life of A in minutes? Given that = 
 [C]t 9
22. One mole of a gas with angular triatomic molecules follows gas equation PV–1 = constant. The change
in the entropy of the gas when it is heated from 300 K to 600 K will be ……… cal K–1 .
23. An intimate mixture of Fe2O3 and Al is used as solid rocket fuel. Calculate fuel value (in cal) per cc of
mixture. Heat of formation and densities are as follows:
∆ f H ( Al2 O3 ) = 399 × 103 cal mol−1
∆ f H ( Fe 2O3 ) = 199 × 103 cal mol−1
density (Fe2 O3 ) = 5.2 gm/cc
density ( Al ) = 2.7 gm/cc
PART – III [MATHEMATICS]

SECTION – A
1. In a triangle ABC the angle bisector of vertex A is 5x + y + 4 = 0 if the vertices B and C are ( −4,3 ) and
(1,4 ) respectively then vertex A is
(A) ( 1, 1) (B) (- 1 , 1)
(C) ( 1, - 1) (D) ( - 1, - 1)
2. The largest value of λ for which the circle x 2 + y 2 = λ 2 falls totally in the interior of the parabola
y 2 = 4 ( x + 4 ) is
(A) 4 3 (B) 4
6
(C) 4 (D) 2 3
7
3. Let f ( 3 ) = 4 and f ' ( 3 ) = 5 . Then, lim  f ( x )  , where [.] denotes the greatest integer function is
x →3
(A) 3 (B) 4
(C) 5 (D) Does not exist
SECTION – A
A C 1
4. In a triangle ABC if tan tan = , then
2 2 3
a+c B A C 2
(A) is always greater than or equal to 2 (B) tan  tan + tan  =
ac 2 2 2 3
B A C 4
(C) tan  tan + tan  = (D) a, b, c are in G.P.
2 2 2 3
5. If M is the skew symmetric matrix of order n × n , then

(A) det (M − I) = det (M + I) (B) det (M − I) = − det (M + I) if n is odd
(C) det (M − I) = det (M + I) if n is even (D) det (I − M)(I + M) = 1 ( det (I + M) ≠ 0 )
−1
6. Let f ( x) = x3 − x 2 − x + 1, g ( x) = a 2 − 2 (where a is real parameter) and f ( x) = g ( x) has three

real and distinct roots then f ( x ) = [a ] has real root having the integral part ( where [.] is G. I. F) which
2
is less than
(A) 0 (B) 1
(C) 2 (D) 3
7. Let n = x1 x2 x3 …… x9 is formed using the digit 1, 2… 9 . Each digit is being used once only. If n1 is
number of possible n for which 1 <| x3 − x4 |< 5 and n2 is number of possible n for which | x3 − x4 |= 1 ,
 n1 
then   is less than (where [.] is G. I. F)
 n2 
(A) 2 (B) 3
(C) 4 (D) 5
a p
8.

If A = b q  , then A. AT is not always

 c r 
(A) Singular matrix (B) idempotent
(C) involutary (D) Orthogonal
SECTION – A
Paragraph Type
Comprehension:
 (t )
x
Let g(x) = 2
+ t + 1 dt, f(x) is a decreasing function ∀x ≥ 0 and A = f(x)iˆ + g(x)j,
ˆ B = g(x)iˆ + f(x)jˆ makes
0
obtuse angle with each other ∀x > 0 then
9. Which of the following is true for x ≥ 0 ?

(A) f(x) < 0, g(x) > 0 (B) f(x) > 0, g(x) < 0
(C) f(x) < 0, g(x) < 0 (D) None of these.
10. Value of lim f(x). g(x), is

x →∞
(A) ∞ (B) - ∞
(C) 0 (D) does not exist.
SECTION – B
Integer Answer Type
11. Let A be a square matrix of order 3 such that transpose of inverse of A is A itself, then | adj(adjA) | is
equal to
12. If p = sin4 α + cos4 α + 1 and q = cos6 β + sin6 β + 1 ( α, β ∈ R ) , then value of ( p + q )max  + ( p + q)min  is
(where [.] is G.I.F)
13. The number of solutions of [cos x ] + sin x = 1 in [ π, 3π] is ([ ] denotes greatest integer function)
 cos x + f ( x ) 
14. Let f ( x ) be a continuous function whose range is [2, 6.5]. If h ( x ) =   , λ ∈ N be
 λ 
continuous, where [.] denotes the greatest integer function, then find the least value of λ .
xn
15. Let y = 3x 2 + 2x + 1 and In =  y
dx . If a1I10 + a2I9 + a3I8 = x 9 y , then find the value of a1 − 3a3 .
α 1 α 1
16. If β > 0 and α < 0 such that α + β + = and ( α + β) = − , then find the maximum value of
β 2 β 2
cos β x + sin 2αx + β  .
 
17. If equation f(x).g(x) + (g(x) – f(x))e-|x| = 1 has at most n solution, then n is
18. Let z be a complex number satisfying | z − 1|= 2 and w and w are complex cube root of unity. If z1 is
value of z for which | z − w | maximum and z2 is value of z for which | z − w | − | z − w | is maximum. It
is given that Im( z2 ) > 0 , then find the integral part of | z − w | maximum.
x n r
19. Let x > m, y > n, z > r , then m y r = 0 (where x, y, z > 0). Then find the greatest value of
m n z
 27 xyz 
 .
 ( x − m)( y − n)( z − r ) 
∞
n2 + n − 1

1
20. If = S , then find .
n =1 ( n 2
+ 3n + 2) 2
S
SECTION – C
2π 2π
( )( ) ( )
i i
21. If α = e 13 and β = e 15 , then 1 − α 2 1 − α 4 ....... 1 − α 24 is
22. Let x, y, z are selected from the set of natural numbers, If the probability that x 2 + y 2 + z 2 is divisible by
p
5 is (where p, q are coprime) then p + q equals to
q
23. Let z is a complex number satisfying | z − 1| + z + 2i + β = 0 when β ∈ [1, ∞) . If α is value of z for

α
which |z| is maximum, then value of | i | (where [.] is G.I.F) is
FIITJEE - MOCK TEST

(JEE ADVANCED 2021)
PAPER - 2
(20.09.2021)
HINTS & SOLUTIONS

PHYSICS
1. B
1 1
hv = 13.6 (3)2  2 − 2  = 2.75 eV
 4 5 
for n = 4 to n = 3
1 1
hv = (13.6) × (3)2  2 − 2  = 5.95 eV
 3 4 
for shorter wavelength
3.95 = 5.95 –φ  φ = 2eV
for longer wavelength eVs = 2.75 – 2 = 0.75 eV
2. C
Because of increase in magnetic field with time, electric field is induced in the circular region and
represented by lines of forces as shown in figure. The signs of minimum work done by external agent in
taking unit positive charge from A to C via path APC, AOC and AQC are
WAPC = – ve, WAOC = 0, WAQC = + ve

∴ (C) is the correct choice. .
3. B
di
E = –L
dt
di
Thus induced emf is maximum when is maximum. It is maximum at moment t2.
dt
4. A, C, D
V − Vs V − V 5 4V
For observer O1, λ1 = = =
f f 5f
For O2, there is change of medium hence at the surface of water, keeping frequency unchanged
V 4V
=
λa λ w
5. A, C
(A) (C)
6. B, C
1
Number of collisions per unit area ∝
time between two collision × area
•
n Vrms
 ∝ Vrms ∝ T
A distance between walls × A
distance between walls × A = volume
• 1
n T2
So ∝
A V
•
n
if both T and V are halved, increases.
A
7. A, C, D
2
 I
( )
2
Imax = I1 + I2 =  I1 +  < 41
 2 

2
 I
Imin =  I1 −  >0
 2 

8. A, B
K ( q )( 3q)
(C) Charges are unequal, but repulsion force will be for both the spheres. As weight of both
r2
balls are same, so both will deflect equally.
(A,D) → If the ball is heavier, it will deflect less.
9. A
The component of velocity of charged particle along the magnetic field does not change. The
component of velocity of charged particle normal to magnetic field only changes in direction but always
remains normal to magnetic field. Hence angle between velocity and magnetic field remains same.
10. D
Pitch = T.V||
1 V.B π 38.400 4π π
= . = 4 = 3 m= m
f B 10 . 3800 10 250
11. 5
y
E
When V = 50 m/s qVB = qE  B =
50 qVB
When V = 100 m/s qVB − qE = 2 × 10 −19 x
E = 1.25 N/C
qE
12. 2
Torque about A: a/2
a A⊗ B
mg = Iα
2
mga a/2√3
α=
2I
a mga2
 accelearation = α= a/√3 a a
3 2 3I
C
13. 8
Coordinates of points A and B are A (–16 cm, 4 cm) and B (–14 cm, 6 cm)
For image of A
1 1 1
− =
v A −16 12
12 × 16
 vA =
16 − 12
∴ x1 = 48 cm
v 48
Magnification, m = + = = −3
u −16
∴ height of point A above x-axis
= −3 × 4
y1 = −12 cm
Similarly for B
12 × 14
vB = = 84
14 − 12
x 2 = 84 cm
84
m= = −6
−14
y 2 = −6 × 6 = −36 cm
A ' ( 48 cm, − 12 cm ) , B' ( 84 cm, − 36 cm )
14. 3
3λ D
y-coordinate of 3rd order maxima = , S1 P 3n maxima
d x
3λ 2
y=
d
d=4a-2x 4a
x
S2
where d is the distance between both the sources at any time t.

d = 4a − 2x = 4a − 2a sin ωt = 2a ( 2 − sin ωt )
3λD
∴y =
2a ( 2 − sin ωt )
15. 2
Consider a ring of radius x and thickness dx. Power incident on it
P PxdxR
= 2πxdx cos θ = = dP
4π 4R + x
2
( 2
) 4R + x
2
3
2 2
( )
X
dx
R
P
2R
0
dP.λ
Number of photons falling in this area per unit time dn = . By symmetry it is easy to see that the
hc
resultant force will be horizontally towards left. Force on the ring is
h PxdxR λ h 2R
dF = ( dn ) cos θ, Fres =  dF = 
λ 3
hc λ 1
4R2 + x 2 2 ( )
4R 2 + x 2 2 ( )
R 2
2PR xdx
Fres =  .
( )
2
x =0 c 4R2 + x 2
R
−PR2  1  −PR2  1 1  P
=  2 2 
=  5R 2 − 4R 2  = 20c
c  4R + x 0 c  
16. 3
Two bowl, exerts a normal force N on each bead, directed along the radius line or at 60o above the
horizontal. Consider the free-body diagram of the bead on the left with the electric force Fe applied.
mg y
 Fy = Nsin 60o − mg = 0  N = sin60o
Kq2 mg mg Fx 600
 Fx = −Fe + Ncos60o = 0  R2 = Ncos 60o = tan60o = 3 x
1 mg
K=
4πε0
1
 mg  2
Thus, q = R 
 K 3 
 e 
17. 1
Two opposite charges situated at opposite vertices from a dipole and point lies on bisector line of dipole
for one dipole E
−KP x
E= 3
x +Q -Q
2a
Direction of field due to these three dipoles is in a horizontal plane at distance E

x from plane of hexagon and parallel to it, mutually having angle 60o with each
other. 600
Q ( 2a )
E
Qa 600
Net E0 = E + E = 2E = 2 =
4 πε0 x 3 πε0 x3
E
18. 4
Charge on outer surface of C = –charge on inner surface of C
Hence potential at B due to charge a conductor C = 0
Charge on outer surface of dielectric = –charge on inner surface of dielectric
∴ Potential at B due to charge on dielectric = 0
Q
Potential at B due to charge on A =
4πε0b
Q
∴ Net potential at B =
4πε0b
19. 3
103
E < 106  < 106
d
kε A
d > 10 −3 m C= 0
2
d
kε0 A
d= > 10 −3
C
10 −3 × C 10 −3 × 50 × 10 −12
A> A> = 300 mm2
kε0
( 6π ) ×  
1
× 10 −9 
 36π 
20. 1
Due to FABC the magnetic field at O is along y-axis and due to CDEF the magnetic field is along x-axis.
Hence the field will be of the form A  ˆi + ˆj 
Calculating field due to FABC:
Due to AB:
µ0i µi
B AB =
ℓ
( )
sin 45o + sin 45o ˆj = 2 0 ˆj
2πℓ
4π   C B
2
Due to BC:
µ0i µ0i ˆ π/4
BBC =
 
ℓ
(
sin0o + sin 45o ˆj =) 2 2πℓ
j O
π/4
X
4π  
2 Z
Similarly due to FA:
F A
µ0 i ˆi
BFA =
2 2πℓ
µ0i  1 1 2ˆ
Hence, BFABC =  + + i
πℓ  2 2 2 2 2 
2µ0i ˆ
BFABC = i
πℓ
Similarly due to CDEF:
2µ0i ˆ
BCDEF =
πℓ
i ()
2µ0i ˆ ˆ
Bnet =
πℓ
i+j( )
21. 30
Final direction of motions are shown by ω1f and ω2f .
ωf1 + ai1 ωi2 + a f2
Now, α1 = α2 =
t t
and FR1 + I1α 2 (torque equation of friction)
FR2 = I2 α 2
ω1 F ω2
R ℓα
Dividing 1 = 1 1 ω2
R2 ℓ 2 α 2 ω1
I1 ωf1 + ωi1 R1
 . =
I2 ωi2 − ωf2 R 2
For point of contact when slipping stops ω1 =100m/s ω1 =200m/s
F
R1ωf1 = R 2 ωf2 R = 0.1m R = 0.2m
2kg 4kg
µ1R12 ℓ 2 ωf1 + ωi1 R
. = 1
µ1R 2 ℓ 2
2
R R2
ωi2 −
R2
µ 2R 2 ωi2 − µ1R1ωi1
 ωf1 =
µ 2R1 + µ1R1
4 × .2 × 200 − 1× .1× 100
= = 300 r/s
.4 + .1
R1ωf1 R
ωf2 = = × 300 = 150 rad/sec
R2 2R
22. 1.76
λ1 = 410 nm, λ 2 = 496 nm, λ 3 = 620 nm
1240 eVnm 1240 eVnm 1240 eVnm
E1 = = 3 eV, E2 = = 2.5 eV, E3 = = 2 eV < φ
410 nm 496 nm 620 nm
Hence only λ1 and λ 2 can cause photoemission.
Number of photons of wavelength λ1 incident on the sodium surface in 1 sec,
144 1
× 10 −4 ×
P 3 IA cos θ 3 3 2 2.4 × 10 −3
n1 = = = =
E1 E1 E1 3e
P 3 2.4 × 10 −3
Similarly, n2 = =
E2 2.5e
Total number of photoelectrons emitted in 1 sec = total number of photons of wavelength λ1 and λ 2
= n1 + n2
∴ Photoelectric current = ( n1 + n2 ) e
1 1  44
= 2.4 × 10−3  + A = mA = 1.76 mA
 3 2.5  25
23. 312.5
Let at any instant temperature of water be T, then heat current,
kA
i= ( T − 0 ) ………… (1)
x
where A = 6a2 = 6m2 , x = thickness = 1 mm = 10–3 m
dQ dT
Rate of heat lost from water, = +ms ……… (2)
dt dt
25o 10ln 2
dT kAT dT kA
So, we get from (1) and (2), −ms = − =  dt
dt x 50o
T mSx 0
kA
 ln ( 2 ) = .10 ( ln 2 )
mSx
kA (10 )
So, =1
mSx
Putting values  k =
mSx
=
( )(
103 kg 4.2 × 103 J/kg o C 10 −3 m )
= k = 70 J/m o C
10A 10 × 6 m3 ( )
 Total heat transferred will be = total heat
kA
Q =  dQ =  Tdt Lost by water.
x
Q = mS∆T = 103 × 4200 × 25 J = (105 gm ) (1 cal )( 25 ) = miceL
 106 × 25  25000
Giving mice =   gm = kg = 312.5 kg
 80  80
Mass of ice melted = 312.5 kg
CHEMISTRY
1. D
The iminic
NH
HN NH
compound will gain the aromaticity and will rapidly convert into
NH2
H2N NH2
2. D
H
+
OH OH +
CH2
H
+
HO 
H
→ HO 
− H2O
→  
ring exp.
→
HO
HO
OH OH OH
HO
−H +
+
←
H / excess
similar repetation

HO
HO
3. A
Higher the value of b, lower is the incompressibility.
4. A, B, C, D
Factual.
5. A
Eq. of xn+ = eq. of MnO2
2 × (m – n) = 5.6 × (4 – 2)
m – n = 5.6
in second reaction equivalent of xn+ = equation of H2S
12 × (m + n) = 8.4 × (4 + 2) = 50.4
m + n = 4.2 M = 4.9 n = -0.7
6. A, B, C
In C6H5Cl Cl will not be removed by NaOH hence it will not give ppt. of AgCl with AgNO3.
7. A, B, C
d .a3 N A 10.5 × (4.07 × 10 −8 )3 × 6.023 × 10 23
ZAg = = =4
M 108
(4.05 × 10 −8 )3 × 2.7 × 6.023 × 10 23
ZAl = =4
27
(3.61 × 10 −8 )3 × 8.92 × 6.023 × 10 23
ZCu = =4
63.5
Hence all crystallizes in FCC unit cell.
8. A, C
Ph CN Ph CH2NH2 Ph CH2OH
LiAlH4 Ph
C HNO2 C HIO4
C C O + HCHO
CH3 OH CH3 OH CH3 OH
CH3
H
+ (X) (Y)
H O
Ph C CH
CH3
(Z)
9. B
2x + 2y = A × 1 × 2 = 2A
x+y=A
2y = B × 10 × 0.1
B
y=
2
2A − B
∴ x=
2
10. B
eqv. H4P2O7 = eqv Ca(OH)2
V×2×4=2×2×2
V = 1 cc
11. 3
NH4HS (s) ↽ ⇀ NH3 (g) + H2S (g)
At eq. - (0.1 + P) P
As per given 0.1 + 2P = 1.1, ∴ P = 0.5
K p = PNH3 .PH2S = 0.6 × 0.5 = 0.3 or 3 × 10 −1
Hence, z = 3.
12. 6
Volume of gas at NTP is
P1V1 = P2V2
6x6=1V
V = 36 litre
Outcoming gas = 36 – 6 = 30 litre
30
Number of balloons filled = =6
5
13. 9
Po − P n 2
=
P n1
20 x 114
= ×
80 36 114
x = 9 gm
14. 3
AgCN ↽ ⇀ Ag+ + CN–
s x
– +
CN + H ↽ ⇀ HCN
x [H+] s
K sp = s × x
H+  x
Ka =
s
K a .s2
∴ K sp =
H+ 
Hence, H+  = 10 −3
∴ pH = 3
15. 1
O O
−
I 3C C CH2 CH2 I 
OH aq.
→ O C CH2 CH2 OH + CHI3
Product yellow ppt.
16. 5
OCH3 I I
OH I

→ 4HI
+ CH3-I 
−I2
→ 
HI
→
OH I I I
17. 5
MnO−4 + 8H+ + 5e− 
→ Mn+2 + 4H2O
0.0591 1
E1 = Eo − log 8
5 H+ 
0.0591
or E1 = Eo − 8x
5
0.0591
Similarly, E2 = Eo − 8y
5
On solving, difference between x and y = 5.
18. 4
Eq. of FeSn = eq. of AO34−
6.01( x ) = 0.06 × 3
x = 18
2 
 + 4  n = 18
n 
n=4
19. 4
tan 45o = 1
1
∴ =1
n
Hence n = 1
logk = 0.6020
k=4
1 1
x x
From = kP 4 , = 4 (1) 4 = 4
m m
20. 0
Factual.
21. 3.3
 3 
∴ Koverall = K1 + K2 ∵ K 2 = K1 
 4 
= (2 + 1.5) × 10–3s–1 = 3.5 × 10–3s–1
0.693 693
∴ t1/2 = −3
= minutes = 3.3 minutes
3.5 × 10 3.5×60
22. 4.83
T2
∆S = nCln
T1
 R R 600
= 1× 2.303  +  .log
 0.33 2  30
−1
= 4.83 cal K
23. 3940
3
(I) 2Al +
O2  → Al2O3 ∆H = −399 k cal
2
3
(II) 2Fe + O2  → Fe2 O3 ∆H = −199 k cal
2
Subtracting eqn. (II) from (I) we get
2Al + Fe2O3 → Al2O3 + 2Fe ∆H = −399 − ( −199 ) k cal = –200 k cal
Total weight of mixture = 2 × Al + Fe2O3 = 54 + 160 = 214 gm
Total volume of mixture = VAl + VFe2 O3 = 20 cc + 30.76 cc = 50.76 cc
200000 cal
Fuel value per cc of mixture = = 3940 cal cc −1
50.76 cc
MATHEMATICS
1. B
Mirror image of B and C with respect to the angle bisector of vertex A will lie on the side AC and AB
respectively.
2. D
Solving simultaneously
x2 + 4 ( x + 4 ) = λ2
D = 0 gives λ = ±2 3
Now (0, 0) is interior point of parabola as f ( 0 ) < 0
3. D
lim  f ( 3 − h )  = 3 and lim  f ( 3 + h )  = 4
h →0 h →0
3≠4
4. A, B
a, b, c are in A.P.
a+c
 ≥2 ( A.M. ≥ G.M.)
ac
A B B C C A
Use identity, tan tan + tan tan + tan tan = 1
2 2 2 2 2 2
B A C 2
tan  tan + tan  =
2 2 2 3
5. B, C, D
det (M − I) = det (M − I)
T
= det (MT − I)
det (M + I) , if n is even
= det ( −M − I) = 
 − det (M + I) , if n is odd
6. C, D
x3 − x 2 − x + 1 = ( x + 1)( x − 1)2 , f ( x) = g ( x) have 3 real and distinct roots
 0 < a2 − 2 < 1
 [a 2 ] = 2
Now x − x − x + 1 = 2
3 2
has solution in (1, 2)

 the integral part of root is 1.
7. B, C, D
n1 = 2(7 + 6 + 5) ( 7!) = 36(7!)
n2 = 16(7!)
 n1   36 
 = =2
 n2   16 
8. B, C, D
 a2 + p2 ab + pq ac + pr 
 
AAT =  ab + pq b +q
2 2
bc + qr 
 ac + pr bc + qr c 2 + r 2 

a p 0 q b c
| AA |= b q 0
T
p q r =0
c r 0 0 0 0
So AAT is singular matrix.
9. A
g'(x) = x 2 + x + 1
> 0∀x ∈ R
x≥0
g(x) ≥ g(o) ≥ 0
A ⋅B < 0
f(x) ⋅ g(x) < 0
 f(x) < 0 as g(x) > 0 ∀x > 0
10. B
lim g(x) → +∞
x →∞
So lim f(x) ⋅ g(x) → −∞

x →∞
11. 1
Given that A −1,T = A = (A T )−1 = AA T = I
| A |= ±1
2
Now | adj(adjA) | = | A |2 = 1
12. 4
3  1 
p ∈  ,2  ,q ∈  ,1
2  4 
7
 ≤p+q≤3
4
 ( p + q )max  + ( p + q )min 
= 3 +1= 4
13. 3
As [cos x ] = −1, 0, 1 , it gives sin x = 2, 1 and 0

3π 5π
∴x = , , 2π
2 2
14. 8
1 cos x + f ( x ) 7.5
≤ ≤
λ λ λ
 1 7.5 
If  ,  contains any integer, then h ( x ) can not be continuous.
λ λ 
∴ λ = 8, 9, …..
15. 7
dy
2y = 6x + 2
dx
dy
y = 3x + 1
dx
Now, I10 a1 + a2I9 + a3I8 = x 9 y
Differentiate w.r.t. x
( )
a1x10 + a2 x9 + a3 x 8 = 3x 2 + 2x + 1 9x8 + x 4 ( 3x + 1)
 a1 = 30, a 2 = 19, a3 = 9
16. 2
α = −1, β = 2
cos β x + sin 2αx + β
0 ≤ cos 2x − sin 2x + 2 ≤ 2 2
 cos 2x − sin2x + 2  =2
max
17. 2
( f(x) + e )( g(x) − e ) = 0
−|x| −|x|
This equation will have at most two solutions.
18. 2
Integral part of | z − w |max = 2
19. 2
Solving determinant we get
x y z
+ + =2
x−m y−n z −r
Now AM ≥ GM  greatest value = [2 2] = 2
20. 4
n2 + n − 1
an =
(n 2 + 3n + 2) 2
1 −2 n − 3
= 2 + 2
n + 3n + 2 (n + 3n + 2) 2
1 −2 n − 3
= 2 + 2
n + 3n + 2 (n + 3n + 2) 2
1 1 1 1
= − + −
n + 1 n + 2 (n + 2) (n + 1) 2
2
 −1 1  1 1
Sn =  + + −
 n + 2 2  (n + 2) 4
2
1 1 1
S∞ = − =
2 4 4
21. 13
(
x13 − 1 = ( x − 1)( x − α ) x − α 2 ...... x − α12 ) ( )
x = −1
( ) (
−2 = −2 ( −1 − α ) −1 − α 2 ...... −1 − α12 )
 (1 + α ) (1 + α ) ....... (1 + α ) = 1
2 12
Now, (1 − α ) (1 − α ) ....... (1 − α ) = 13
2 12
(1 − α )(1 − α )(1 − α ).......(1 − α ) = 13

2 4 6 24
22. 147
176 22
Required probability = =
10 × 10 ×10 125
So p + q = 147
23. 19
| z − 1| + z + 2i + β = 0
( x − 1)2 + y 2 + x + β + i ( y + 2) = 0
 y = −2
x 2 + 1 − 2 x + 4 = x 2 + β 2 + 2β x
5− β2 (2 β + 2)(−2 β ) − (5 − β 2 )2
f (β ) = x = , f '( x) =
2( β + 1) 4( β + 1) 2
−2 β 2 − 4 β − 10
= <0
4( β + 1) 2
So f ( β ) max = 1
So α = 1 − 2i for which |z| is maximum
π π
i (1− 2 i ) i
iα = e 2 = eπ ⋅ e 2
iα  = eπ  = 19

FIITJEE Mock Test Paper 2 Physics Chemistry Maths Sept 2021

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FIITJEE Mock Test Paper 2 Physics Chemistry Maths Sept 2021

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FIITJEE - MOCK TEST

(JEE ADVANCED 2021)

1. Attempt ALL the questions.

B. Filling of OMR Sheet

Name of the Candidate (in Capital Letters) :_____________________________________

Enrolment Number :_________________________________________________________

Batch :________________________ Date of Examination : ________________________

(A) WAPC =WAOC = WAQC (B) WAPC > WAOC> WAQC

5. An ideal gas undergoes a thermodynamic cycle as shown in figure.:

Which of the following graphs represents the same cycle?

6. Number of collisions of molecules of a gas on the wall of a container per m2will :

12. A uniform triangular plate ABC of moment of inertia I (about an axis

17. Six charges are placed at the vertices of a regular hexagon as +Q -Q

1. Which of the following “iminic” compound is least stable?

2. For the reaction,

4. Which is/are one true statements?

10. The volume of 2M H4P2O7 needed to neutralise 2cc 2M Ca(OH)2 is

15. I C C CH2 CH2 I 

17. EMnO− Mn2+ , H+

other species equal. What is the numerical difference between x and y?

21. For the following parallel chain reaction

PART – III [MATHEMATICS]

5. If M is the skew symmetric matrix of order n × n , then

6. Let f ( x) = x3 − x 2 − x + 1, g ( x) = a 2 − 2 (where a is real parameter) and f ( x) = g ( x) has three

obtuse angle with each other ∀x > 0 then

9. Which of the following is true for x ≥ 0 ?

10. Value of lim f(x). g(x), is

17. If equation f(x).g(x) + (g(x) – f(x))e-|x| = 1 has at most n solution, then n is

23. Let z is a complex number satisfying | z − 1| + z + 2i + β = 0 when β ∈ [1, ∞) . If α is value of z for

FIITJEE - MOCK TEST

HINTS & SOLUTIONS

WAPC = – ve, WAOC = 0, WAQC = + ve

distance between walls × A = volume

where d is the distance between both the sources at any time t.

Direction of field due to these three dipoles is in a horizontal plane at distance E

has solution in (1, 2)

So lim f(x) ⋅ g(x) → −∞

As [cos x ] = −1, 0, 1 , it gives sin x = 2, 1 and 0

This equation will have at most two solutions.

(1 − α )(1 − α )(1 − α ).......(1 − α ) = 13

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Batch : Date of Examination :