Adv (20.09.2021) Paper-1

FIITJEE - MOCK TEST
(JEE ADVANCED 2021)

PAPER - 1
(20.09.2021)
Time Allotted: 3 Hours Maximum Marks: 183
 Do not open this Test Booklet until you are asked to do so.
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
A. General Instructions
1. Attempt ALL the questions.

2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each Part is further divided into Two Sections: Section-A & B.
5. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with blue / black ball point pen only for each character
of your Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
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JEEA-MT-PAPER-1 - P2
PART – I [PHYSICS]
SECTION – A
Straight Objective Type
This section contains 7 questions. Each question has four options (A), (B), (C) and (D). ONE OR MORE
THAN ONE of these four options is (are) correct. For each question, you will be awarded 4 marks if you
darken ALL the bubble(s) corresponding to the correct answer(s). You will be awarded 1 mark for darkening
a bubble corresponding to each correct option, provided NO incorrect option is darkened and zero mark if no
bubble is darkened. In all other cases, minus two (–2) marks will be awarded.
1. A cylinder and a variable mass M are arranged on a fixed wedge using a light string and a massless
pulley. There is enough friction between cylinder and the wedge to prevent any slipping
Mass less pulley
Cylinder
M
Fixed Wedge
(A) Only one value of M is possible for which cylinder can remain in equilibrium.
(B) There is a range of value of M for which cylinder can remain in equilibrium.
(C) For a certain value of M, the cylinder starts to roll up the plane. In this situation, magnitude of
friction force on the cylinder by the wedge will be greater than tension in the string
(D) For a certain value of M, the cylinder starts to roll down the plane. In this situation, magnitude
of friction force on the cylinder by the wedge will be greater than tension in the string
2. A rod AC of length ℓ and mass m is kept on a horizontal smooth plane. It is free to rotate and move. A
particle of same mass m moving on the plane with velocity v strikes rod at point B making angle 370
with the rod. The collision is elastic. After collision:
B ℓ/4
A 37° C
V
72 v
(A) The angular velocity of the rod will be
55 ℓ
πℓ
(B) The centre of the rod will travel a distance in the time in which it makes half rotation
3
24mv
(C) Impulse of the impact force is
55
(D) None of these
3. A smooth sphere A of mass m collides elastically with an identical sphere B at rest. The velocity of A
before collision is 8 m/s in a direction making 60º with the line joining the centres at the time of
impact. Which of the following is/are possible?
(A) the sphere A comes to rest after collision

(B) the sphere B will move with a speed of 8 m/ after collision
(C) the directions of motion of A and B after collision are at right angles
(D) the speed of B after collision is 4 m/s.
4. An insect of mass m, starts moving on a rough inclined surface from point A. As the surface is very
sticky, the coefficient of friction between the insect and the incline is µ = 1. Assume that it can move
in any direction ; up the incline or down the incline then
A
µ=1
θ=37°
(A) The maximum possible acceleration of the insect can be 14 m/sec2

(B) The maximum possible acceleration of the insect can be 2 m/sec2
(C) The insect can move with a constant velocity
(D) The insect can not move with a constant velocity
5. The figure above shows an energy level diagram for the hydrogen atom. Several transitions are
marked as Ι, ΙΙ, ΙΙΙ, _______ . The diagram is only indicative and not to scale.
∞
Principal Quantum
4
ΙΙΙ
3
Number
ΙΙ IV V VI
2
Ι
1
(A) The transition in which a Balmer series photon absorbed is VI.
(B) The wavelength of the radiation involved in transition ΙΙ is 486 nm.
(C) IV transition will occur when a hydrogen atom is irradiated with radiation of wavelength 103nm.
(D) IV transition will emit the longest wavelength line in the visible portion of the hydrogen spectrum.
6. A simple pendulum is kept suspended vertically in a stationary bus. The bus starts moving with an
acceleration a towards left. As observed inside the bus: (Neglect frictional forces on pendulum and
assume size of the ball to be very small.)
ℓ
(A) time period of oscillation of the pendulum will be 2π for any value of a.
a + g2
2
ℓ
(B) time period of oscillation of the pendulum will be 2π only when a << g.
a + g2
2
a
(C) angular amplitude of oscillation will be tan−1   for any value of a < g.
g
a
(D) angular amplitude of oscillation will be tan−1   only when a << g.
g
7. For a certain transverse standing wave on a long string, an antinode is formed at x = 0 and next to it,
a node is formed at x = 0.10 m. the displacement y(t) of the string particle at x = 0 is shown in figure.
4
y(cm) t(s)
0.05 0.1 0.15 0.2
-4
(A) Transverse displacement of the particle at x = 0.05m and t = 0.05 s is – 2√2 cm.
(B) Transverse displacement of the particle at x = 0.04 m and t = 0.025 s is – 2√2 cm.
(C) Speed of the travelling waves that interfere to produce this standing wave is 2 m/s.
(D) The transverse velocity of the string particle at x = 1/15 m and t = 0.1 s is 20 π cm/s
SECTION – A
This section contains 6 questions of matching type. The section contains 2 tables (each having 3 columns
and 4 rows). Based on each table, there are 3 questions. Each question has four options (A), (B), (C) and
(D). ONLY ONE of these four options is correct. For each question, you will be awarded 3 marks if you
have darkened only the bubble corresponding to the correct answer and zero mark if no bubble is darkened.
In all other cases, minus one (–1) mark will be awarded.
The system consists of three blocks of mass 2 kg, 3 kg and m. µ s = 0.3 .

2 kg
µ s = 0.3
3 kg m
Answer Q.8, Q.9 and Q.10 by appropriately matching the information given in the three columns of the
following table:
Column I Column II Column III

(Mass of block m) (Friction on 2 kg block) (Acceleration of system)
(I) 2 kg (i) 5N (P) 0 m/s2
4
(II) 2.5 kg (ii) 6N (Q) m/s2
7
4
(III) 2.6 kg (iii) 4N (R) m/s2
9
4
(IV) 4 kg (iv) 3N (S) m/s2
3
8. Which of the following is correct?

(A) (I) – (ii) – (S) (B) (I) – (i) – (Q)
(C) (IV) – (ii) – (R) (D) (III) – (iii) – (Q)
9. Which of the following is incorrect?

(A) (I) – (ii) – (Q) (B) (III) – (iii) – (P)
(C) (IV) – (ii) – (R) (D) (II) – (i) – (S)

(A) (I) – (iv) – (Q) (B) (III) – (iii) – (P)
(C) (IV) – (ii) – (P) (D) (II) – (i) – (Q)
A wedge and block is placed. All surfaces are smooth. F is the external applied force on the wedge in
horizontal direction.
N
wedge
F M
θ = 37o
following table:
Column I (Force applied F) Column II (Normal reaction N) Column III (Acceleration of

block w.r.t. wedge)
(I) (M + m ) gtan θ (i) Greater than mgcos θ (P) Downward
3 Less than mgcos θ
(II) (M + m ) gtan θ (ii) (Q) Zero
2
(III) Zero (iii) mgcos θ (R) Upward
(IV) (M + m ) g (iv) Zero (S) Cannot be determined

(A) (II) – (i) – (Q) (B) (I) – (i) – (Q)
(C) (III) – (iii) – (P) (D) (IV) – (ii) – (R)
12. Which of the following is incorrect?

(A) (II) – (i) – (R) (B) (III) – (ii) – (P)
(C) (IV) – (i) – (Q) (D) (I) – (i) – (Q)

(A) (II) – (iii) – (R) (B) (III) – (iii) – (P)
(C) (III) – (ii) – (P) (D) (IV) – (i) – (S)
SECTION – C
Integer Answer Type
This section contains 5 questions. The answer to each of the questions is a single-digit integer, ranging
from 0 to 9. For each question you will be awarded 3 marks if you darken ONLY the bubble corresponding
to the correct answer and zero mark if no bubble is darkened. No negative marks will be awarded for
incorrect answers in this section.
14. Figure shows a conducting horizontal rod of resistance r is made to oscillate simple harmonically with
a fixed amplitude in a uniform and constant magnetic field B, directed inwards. The ends of rod
always touch two parallel fixed vertical conducting rails. The ends of rails are joined by an inductor
1 1
and a capacitor having self inductance and capacitance Henry and Farad respectively. The
π π
amplitude of current in the circuit depends on the frequency of oscillation of rod. Find the time period
(in sec) of rod when amplitude of the current will be maximum: (do not consider self inductance
anywhere other than in the inductor)
15. A block of mass m1 is placed on a wedge of an angle θ, as shown. The block is moving over the
inclined surface of the wedge. Friction coefficient between the block and the wedge is µ1, where as it
1
is µ2 between the wedge and the horizontal surface. If µ1 = , θ = 45°, m1 = 4 kg, m2 = 5kg and g =
2
10 m/s2, find minimum value of µ2 so that the wedge remains stationary on the surface. Express your
answer in multiple of 25X10–3.
µ1 m1
m2
θ
µ2
16. A particle is projected from point A, that is at a distance 4R from the centre of the earth, with speed
V1 in a direction making 30° with the line joining the centre of the earth and point A, as shown. Find
the speed V1 if particle passes grazing the surface of the earth. Consider gravitational interaction only
GM X
between these two. (use = 6.4 × 107 m2/s2). Express your answer in the form × 1000 m/s
R 2
and fill value of X.
V1
30°
4R
R
V2
17. In the figure shown AB, BC and PQ are thin, smooth, rigid wires. AB and AC are joined at A and fixed
in vertical plane. ∠BAC = 2θ = 90°and line AD is angle bisector of angle BAC. A liquid of surface
tension T = 0.205 N/m forms a thin film in the triangle formed by intersection of the wires AB, AC and
PQ. In the figure shown the uniform wire PQ of mass 1 gm is horizontal and in equilibrium under the
action of surface tension and gravitational force. Find the time period of SHM of PQ in vertical plane
for small displacement from its mean position, in the form s and fill value of X.
18. A pendulum of length L and bob of mass M has a spring of force constant k connected horizontally to
it at a distance h below its point of suspension. The rod is in equilibrium in vertical position. The rod of
length L used for vertical suspension is rigid and massless. The frequency of vibration of the system
1  nkh2 
for small values of θ is found to be gL +   , where n is an integer. Find the value of n.
2πL  m 
PART – II [CHEMISTRY]
SECTION – A
1. The four general synthetic routes of the synthesis of anhydrous salt are given below.
Method I : By evaporating the reaction mixture of metal hydroxide plus the hydrohalic acid.
Method II : The salt precipitates in anhydrous form upon mixing solutions containing cation and anion.
Method III: Hydrated halide can be dehydrated by appropriate dehydrating agent.
Method IV : Strictly anhydrous method of synthesis (halogen exchange or redox) is required.
For each of the halides listed, select the most appropriate method.
(A) CF4 – Method IV, AgI-Method-III, KF-Method I, SiCl4-Method - III
(B) CF4 – Method IV, AgI-Method-II, KF-Method I, SiCl4-Method - III
(C) CF4 – Method IV, AgI-Method-I, KF-Method IV, SiCl4-Method -VI
(D) CF4 – Method IV, AgI-Method-II, KF-Method I, SiCl4-Method – IV
2. You are about to undertake kinetic comparisions of rates and intimate mechanism of fluoride ion
exchanges of SF6 and free F− versus SeF6 and free F−, in a suitable inert solvent. Which of the
following statements are likely to be correct?
(A) SF6 is more likely to react by dissociative mechanism.
(B) SeF6 is more likely to react by associative mechanism
(C) Both react by dissociative mechanism
(D) SeF6 is more likely to react rapidly
3. Titration of 664 mg of a pure organic carboxylic acid, H2A, showed a rapid change in pH at 40 ml. and
at 80 ml of 0.1 M NaOH titrant. When 40 ml. of NaOH was added, the pH was 5.85 and at 60 ml of
NaOH the pH was 8.08. Which of the following statements are correct?
(A) the molecular weight of acid is 166
(B) the molecular weight of acid 664
(C) the pka1 of acid is 3.62
(D) the pka1 of acid is 5.85
4. The relative rate of extraction of H and D is 2.6 : 1. The percentage yield of the product A and B in
the following reaction is:
uv
C2 H 2 D 4 + Cl2  → C2 HD 4 Cl + C2 H 2 D3Cl
(A) (B)
(A) 27.8%, 72.2% (B) 72.2%, 27.8%
(C) 56.52%, 43.48% (D) 43.48%, 56.52%
5. Which of the following compounds give the same carbocation on ionization?

Br Br
Br
Br
1 2 3 4
(A) 1 (B) 4
(C) 2 (D) 3
6. Pick out the correct statement(s).

(A) Co-ordination no. of an atom at a lattice point in simple cubic arrangement is 6.
(B) Co-ordination no. of an atom at octahedral site is 8
(C) Co-ordination no. of an atom at a lattice point in hcp arrangement is 4
(D) Co-ordination no. of an atom at octahedral site is 6.
7. Which of the following statements are true?

(A) CH 2 - CH 2 - COOH on heating is converted into CH2 = CHCOH
|
NH2
O
(B) CH 2 - CH 2 - CH 2 - COOH on heating is converted into O
|
OH
OH
CH 2 - CH 2 - COOH O O
(C) | on heating converted into
OH HO
(D) CH 2 - COOH form zwitter ion which move towards cathode at pH = 4.
|
NH2
SECTION – A
following table:
Column I (Process) Column II (Used in) Column III (Reagent used)

(I) Van-Arkel process (i) Purification (P) Pine oil and stabilizers
(II) Mond’s process (ii) Concentration (Q) Carbon monoxide
(III) Froth-floatation (iii) Refining (R) Iodine vapours
(IV) Hydrometallurgy (iv) Cementation (S) Sodium cyanide
8. Set of processes used in the metallurgy of cobalt will be

(A) (I) – (i) – (Q) (B) (II) – (iii) – (Q)
(C) (IV) – (ii) – (S) (D) (III) – (ii) – (P)
9. Set of processes used in the metallurgy of copper is

(A) (III) – (ii) – (P) (B) (IV) – (iv) – (P)
(C) (II) – (ii) – (S) (D) (III) – (ii) – (P)
10. Correct set of combinations used in the metallurgy of zirconium will be

(A) (I) – (iii) – (R) (B) (I) – (iv) – (R)
(C) (II) – (iii) – (S) (D) (I) – (ii) – (Q)
following table:

(I) Simple cubic (i) 68% (P) a = 2 2R
2
(II) BCC (ii) 52% (Q) a = R
3
(III) FCC (iii) 74% (R) a = 2R
4
(IV) HCP (iv) 77% (S) a = R
3
11. Correct combination for NaCl will be

(A) (III) – (iii) – (P) (B) (III) – (iii) – (S)
(C) (II) – (i) – (P) (D) (III) – (iv) – (Q)
12. Choose correct combination for CsCl among the following:

(A) (II) – (ii) – (R) (B) (I) – (ii) – (R)
(C) (II) – (i) – (S) (D) (IV) – (iv) – (Q)
13. Which among the following is correct for a solid having two tetrahedral void per unit cell?
(A) (II) – (ii) – (Q) (B) (III) – (iii) – (P)
(C) (IV) – (iv) – (Q) (D) (I) – (ii) – (R)
SECTION – C
Integer Answer Type
14. The rate of decomposition for methyl nitrite and ethyl nitrite can be given in terms of rate constant (in
sec–1) K1 and K2 respectively. The energy of activations for the two reactions are 152.30 kJ mol–1 and
157.7 kJ mol–1 as well as frequency factors are 1013 and 1014 respectively for the decomposition of
methyl and ethyl nitrite. The temperature (0C) at which rate constant for the two reactions become
same will be…
15. A2Ox is oxidised to AO3¯ by MnO4¯ in acidic medium. If 1.5 × 10–3 mole of A2Ox requires 40 ml of
0.03 M-KMnO4 solution in acidic medium. The value of x will be…
16. The number double bond equivalents in the following compound are….
O
C OH
C
C OH
O
(Ninhydrin)
17. If 0.01% of a substance undergoing decomposition is consumed in 1 millisecond when the

concentration is 0.02 M and in 0.25 millisecond when the concentration is 0.04 M, the order of the
reaction will be….
18. A weak acid HA (50.0 ml) was titrated against 0.1 M NaOH. The pH values when 20 ml & 40 ml base
have been added are found to be 4.898 & 5.324 respectively. What will be the pH of the solution at
equivalence point? (Given : log 8/3 = 0.426, log 2 = 0.301, log 15 = 1.176)
PART – III [MATHEMATICS]

SECTION – A
1. There are (n + 1) identical balls on which the numbers nC0, nC1, nC2, ……., nCn are written, each ball
carrying a different number. The total number of ways in which the balls can be arranged in a row so
that the values of numbers on the first and last balls are equal, is
(A) n! when n is even ( )
(B) n2 − 1 . ( n − 2 ) ! when n is odd
1 1
(C) .n! when n is even (D) ( n + 1)(n − 1)! when n is odd
2 2
π
2. P and Q are two points on the curve x 2 + y 2 = a2 , where ∠POQ = , O being the origin. The
2
equation of the tangent to the curve at P is x − 3y + 2a = 0 . The equation of the tangent to the
curve at Q is
(A) x + 3y − 2a = 0 (B) 3x + y − 2a = 0
(C) x + 2y − 2a = 0 (D) 3x + y + 2a = 0
3. If x × b = c × b and x ⊥ a , then x is equal to
(A)
b × (a × c )
(B)
(b × c ) × a
b.c b.a
(C)
(
a× c ×b ) (D) None of these
a.b
π4
 tan
n
4. Let In = x dx, n ∈ N . Then,
0
1
(A) I1 = I3 + 2I5 (B) In + In − 2 =
n
1
(C) In + In− 2 = (D) None of these
n −1
2
5. (
If x1, x2 are roots of equation tan−1 x ) − 3 tan−1 x + 1 = 0 such that x1 > x 2 > 0 and x1x 2 < 1, then
x12 − x 22 tan3
(A) 2 2
is equal to
1 − x1 x 2 tan5
 x − x2 
(B) tan−1  1  is equal to 5 −π
 1 + x 1x 2 
 x + x2 
(C) tan−1  1  is negative
 1 − x1x 2 
 1  1  −1 1
(D) cot −1   1 − cot −1  + cot is equal to 2
x
 1  x 2  x2
2 2 x2 y2
6. If length of latus rectum of ellipse E1 : 4 ( x + y − 1) + 2 ( x − y + 3 ) = 8 and E2 : + =1
P P2
( 0 < P < 1) are equal, then
π
(A) Area of ellipse E2 is sq. unit
2
 −1 2
− 
(B) Area of director circle of E2 is π  2 3 + 2 3  sq. unit
 
2 2
(C) If (x, y) is any point on E1, then maximum value of ( x − 2 ) + ( y − 1) is 2
(D) Area of E1 is 2π sq. unit
1
7. If A1, A2, ……., An are independent events such that P ( A i ) = for i = 1, 2, 3, ………, n and
10i
 
1  bn +1 − b − an 
( ) ( ) (
P A1A 2 .......A n + P A1A 2 .......A n + ........... + P A 1A 2 .......A n ) =
a n( n +1) 
, where a, b and a, c
 b c 
are coprime, then
(A) a + b is a prime
(B) Maximum value of k for which 3k divides ( a + b ) ! is 8
(C) Maximum value of k for which 4k divides ( a + b + c )! is 6
(D) Number of zeros at the end of ( a + b + c )! is 4
SECTION – A
following table:

(I) f ( θ ) = a sin θ + bcos θ + c (i) a = 1, b = −1, c = 3 (P) Has no solution for any
real λ
equals to λ 2
(II) f ( θ ) + f ' ( θ ) equals to λ (ii) a = 2, b = − 7, c = 4 (Q) Have real solution for only
one integral value of λ
(III) π  (iii) a = 2, b = 5, c = 1 (R) Have real solution for five
f ( θ ) + f '  − θ  equals to integral values of λ
2 
2
λ +6
(IV) π  π  (iv) a = 4, b = 5, c = 10 (S) Have real solution for two
f ( θ ) + f '  − θ  + f ''  − θ  positive integral value of
2  2 
λ
equals to λ 2 + 15
8. Which of the following options is correct?

(A) (I) – (ii) – (R) (B) (II) – (ii) – (P)
(C) (I) – (iii) – (P) (D) (I) – (ii) – (S)

(A) (II) – (ii) – (R) (B) (III) – (i) – (R)
(C) (III) – (iii) – (P) (D) (III) – (ii) – (R)
10. Which of the following options is not correct?

(A) (II) – (i) – (R) (B) (IV) – (iv) – (Q)
(C) (I) – (ii) – (R) (D) (III) – (iii) – (P)
following table:

f ( x ) = log2 ( x ( x + 1) ) x2 h ( x ) = ln ( ln x )
g( x) = 2
2x + 1
(I) Domain of f ( x ) is ( −∞, ∞ ) (i) Domain of g( x) is (P) Domain of h ( x ) is [ e, ∞ )
( −∞, ∞ )
(II) Range of f ( x ) is ( −∞, − 2] (ii) Range of g ( x ) is [0, ∞ ) (Q) Range of h ( x ) is [0, ∞ )
(III) Domain of f ( x ) is (0, 1) (iii) Domain of g ( x ) is (1, ∞ ) (R) Domain of h ( x ) is ( 0, ∞ )
(IV) Range of f ( x ) is ( −∞, ∞ ) (iv)  1 (S) Range of h( x) is
Range of g ( x ) is 0, 
 2 ( −∞, ∞ )
(A) (I) – (iv) – (P) (B) (IV) – (i) – (R)
(C) (III) – (ii) – (Q) (D) (III) – (i) – (Q)

(A) (IV) – (ii) – (S) (B) (III) – (iv) – (P)
(C) (II) – (iv) – (S) (D) (IV) – (iv) – (R)
13. Which of the following options is not correct?

(A) (III) – (iv) – (Q) (B) (III) – (i) – (R)
(C) (II) – (iv) – (P) (D) (II) – (i) – (Q)
SECTION – C
Integer Answer Type
14. A coin is tossed n times. The probability of getting atleast one head is greater than that of getting
5
atleast one tail by . Then, find the value of n.
32
15. If the length of common chord of the parabola 2y 2 = 3 ( x + 1) and the circle x 2 + y 2 + 2x = 0 is k 3 ,
then find the value of k.
2 a+b+c
16. ( )
If a = 3, b = 4, c = 5 , a ⊥ b + c , b ⊥ ( c + a ) and c ⊥ a + b , then( ) 5
is …………
n
1 50 1 dx 1
17. If  
e − 1 n =1 ( n + 1) ! − n
|x|
e{ }
1+ e sin x
= 1−
( ab )!
, where a and b are prime, then find  ab  ([.] denotes
 
G.I.F.).
18. Find the maximum value of length of perpendicular from ( cos α ,sin α , 0 ) on the plane which is
parallel to z axis, passing through (1, 2, 0) and perpendicular to x + y = 0.
FIITJEE - MOCK TEST

(JEE ADVANCED 2021)
PAPER - 1
(20.09.2021)
HINTS & SOLUTIONS

PHYSICS
1. A, D
The F.B.D. of cylinder is as shown. In equilibrium  T = Mg = tension in string
In equilibrium, net force on cylinder is zero ∴ Torque is same about any axis.
 Torque on cylinder about any point is zero.
τA = Mg 2R – mg sinθ R = 0
T
mgsinθ
m sin θ
∴ M= , Hence for only one value of M
2
cylinder can remain in equilibrium.  A is true, B is false
When the cylinder rolls up the incline, sense of

rotation of cylinder about center of mass is clockwise. Hence T > f.  C is false.
When the cylinder rolls down the incline, sense of
rotation of cylinder about center of mass is anticlockwise. Hence T < f.  D is True.
2. A, B, C
The ball has V', component of its velocity perpendicular to the length of rod immediately after the
collision. u is velocity of COM of the rod and ω is angular velocity of the rod, just after collision. The
ball strikes the rod with speed vcos53° in perpendicular direction and its component along the length
of the rod after the collision is unchanged.
Using for the point of collision.
u
ω
v'
D
Velocity of separation = Velocity of approach
3V  ωℓ 
 = + u + V ' .... (1)
5  4 
Conserving linear momentum (of rod + particle), in the direction ⊥ to the rod.
mV(3/5). = mu – mV' ....(2)
Conserving angular moment about point 'D' as shown in the figure

 ℓ mℓ 2  ωℓ
0 = 0 + mu − ω  u = .... (3)
 4 12  3
By solving,
24V 72V
u= ,w=
55 55ℓ
ℓ/4  N dt
π
Time taken to rotate by π angle t = .
ω
3. C, D
Sphere A moving with velocity v has a component v/2 along the line joining the centres of the
spheres at the time of collision and another component v√3/2 perpendicular to the previous direction.
After collision the component along the line will interchange i.e. B will move with v/2 velocity i.e. 4 m/s
along the line joining the centres and A moves with v√3/2 velocity at perpendicular direction to B.
4. A, C
mgsinθ + mg cos θ = ma
θ
g sin θ
m os
gc
m mg cosθ
θ=37° mg
a = g sin θ + g cos θ
3 4 
= 10  +  = 14 m/sec2.
5 5 
If fr = mg sinθ
3 3mg
= mg × = < fr max
5 5
fr< fr max
3mg 4mg
<
5 5
nt
n sta
co fr
v=
θ
sin
mg
hence insect can move with constant velocity.
5. A, B, D
For Balmer series, n1 = 2, n2 = 3,4,........
(lower) (higher)
∴ In transition (VΙ), Photon of Balmer series is absorbed.
In transition ΙΙ ΙΙ
E2 = – 3.4 eV, E4 = – 0.85 eV
∆E = 2.55 eV
hc hc
∆E =  λ=
λ ∆E
λ = 486 nm.
Wavelength of radiation = 103 nm = 1030 Å

12400
∴ ∆E = o
1030 A
12.0 eV
So difference of energy should be 12.0 eV (approx)
Hence n1 = 1 and n2 = 3
(–13.6)eV (–1.51)eV
∴ Transition is V.
For longest wavelength, energy difference should be minimum.
So in visible portion of hydrogen atom, minimum energy emitted is in transition ΙV.
6. B, C
–1 a
θ=tan g
egl
extreme
bob will oscillate about equilibrium position

a
with amplitude θ = tan−1   for any value of a.
g
If a << g, motion will be SHM, and then
ℓ
time period will be 2π
a + g2
2
7. A, C, D
Equation of standing wave
y = −4 sin10πt cos5πx , where y is in cm.
∂y
When x = 0.05m and t = 0.05 s is y = – 2√2 cm and for transverse velocity calculate .
∂t
8. C
9. D
10. B
Soln. (8 – 10):
T1 T2
2 kg
µ s = 0.3
3 kg m
Let acceleration of system is ‘a’.
30 − T1 = 3a
T2 − mg = ma
T1 − T2 − f = 2a
11. B
12. C
13. C
Soln. (11 – 13):

ma cos θ N
a1 = w.r.t. wedge
m
ma mgsin θ
wedge
F M a
θ = 37o
For a1 = 0
mgsin θ = ma cos θ
a = g tan θ
F = (M + m ) g tan θ
14. 2
Here oscillating rod is an ac source because emf induced in it is (vBℓ) ; which varies sinusoidally
because v varies sinusoidally.
Maximum current will flow through the circuit under resonance condition. Therefore time period of
oscillation of rod is T = 2π LC = 2 sec.
15. 5
Taking block + wedge as system and applying NLM in horizontal direction
= m1 [g(sin θ – µ1 cos θ)] cos θ ........... (1)
Again applying NLM in vertical direction
(m1 + m2)g – N2 = m1 a sin θ
N2 = (m1 + m2)g – m1 sin θ(g sin θ – µ1g cos θ)
µ1 m1
m2
f2 θ
µ2
N2
For limiting condition f2 = µ2N2 ........... (2)
From (1) and (2)
m1 cos θ ( gsin θ − µ1gcos θ )
µ2 =
( m2 + m2 ) g − m1 sin θ ( gsin θ − µ1gcos θ )
Using values
1
µ2 = = 125 x 10–3
8
16. 8
V2
Conserving angular momentum m.(V1 cos60°). 4R = m.V2.R ; = 2.
V1
Conserving energy of the system
GMm 1 GMm 1
− + mV12 = − + mV22
4R 2 R 2
 1  2  1  2  3  GM
  V2 −   V1 =  
2 2 4 R
or 2
V1 = (1/2)(GM/R)
1 8000
V1 = 64 × 10 6 = m/s
2 2
17. 5
The F.B.D. of wire PQ is
The force due to surface tension = FST = 2T × 2 AD tanθ
For wire to be in equilibrium (Figure (a))

4T AD tanθ = mg .... (1)
If the wire PQ is at a distance x below the mean position, the restoring force on the wire is (Figure
(b))
– ma = 4T tanθ (AD + x) – mg = 4T tanθ x
Hence the wire PQ executes SHM
a = – (4T/M) tanθ x
comparing with a = – ω2x we get
ω = (4T/M) tanθ
2
m 1× 10−3 π
or T = 2π = 2π −3
= s
4T tan θ 4 × 25 × 10 5
18. 1
The extension developed in the string due to small values of 'θ' is :
x = h sin θ≅ hθ
Torque about 'O' :
τ0 = (Mg sin θ) L + (kx)h
or, τ0≅ mg θL + kh2θ = (mgL + kh2)θ ...... (1)
Also;
τ0 = I0α = mL2α …… (2)
From (1) and (2) :
mL2α = (mg L + kh2)θ
1 kh2 
or α = 2  gL + θ
L  m 
θ g
Now : T = 2π = 2π
α 1 kh2 
2 
gL + θ
L  m 
1 1  kh2 
υ= =  gL + 
T 2πL  m 
CHEMISTRY
1. D
Conceptual.
2. A, B, D
Since S6+ is smaller and has reached its maximum total coordination number and is therefore unlikely
to associate another F−.
SeF6 is more likely to react by an associate mechanism.
SeF6 is more likely to react rapidly, dissociation of F− from very strongly acidic S6+ or Se6+ is likely to
have high activation energy.
3. A, C
Since 4 mole of NaOH was required to reach first equivalence point, the molecular wt. was
664 mg
= 166
4 m mol
60 ml of NaOH is represented by a point midway to second equivalence point, at which
pH = Pka2 = 8.08
At the first equivalence point,
Pka1 + Pka2
pH = 5.85 =
2
∴ Pka1 = 3.62
4. C
The reaction follows free radical substitution and % yield is governed by reactivity-selectivity principle.
5. A, C
Cleave the bond between carbon and bromine and rearrange it.
6. A, D
C.N. of octahedral void = 6
C.N. of hcp arrangement = 12
7. B, D
O O
|| ||
(A) CH 2 - CH 2 - C 
→ CH 2 = CH − C− OH
| |
NH2 OH
O
CH2 CH2 CH2 C O
o
(B) OH HO
(D) At high concentration cationic charge created hence move towards cathode
8. B
Factual.
9. D
Factual.
10. A
Factual.
11. A
Factual.
12. C
Factual.
13. D
Factual.
14. 9
K = Ae− Ea / RT
13 [ −152300 /(8.314× T )]
For methyl nitrite K 1 = 10 e
14 [ −157700 /(8.314 × T )]
For ethyl nitrite K 2 = 10 e
if K1 = K2 then
1013 e[ −152300 /(8.314×T)] = 1014 e[ −157700 /(8.314 × T)]
10 = e( +157700 − 152300) / (8.314 × T)
157700 − 152300
or 2.303 log 10 =
8.314 × T
∴ T = 282 K
=90C
15. 3
1.5 × 10–3 × (10–2x) = 0.03 × 5 × 40
x=3
16. 7
Conceptual.
17. 3
0.01
0.02 ×
100 = K 0.02n
−3
10
0.01
0.04 ×
100 = K 0.04n
0.25 × 10 −3
2n = 8
n=3
18. 9
4.898 = pka + log 2/(a-2)
5.324 = pka + log 4/(a-4)
 4   a − 2  
0.426 = log  × 
 a − 4   2  
2 (a − 2)
2.66686 =
(a − 4)
8 2 (a − 2)
=
3 a−4
4(a – 4) = 3 (a – 2)
a = 10
4.898 = pka + log2 /8
pka = 5.5
1 10 
pH = 7 +  5.5 + log 
2 150 
= 9 (approx)
MATHEMATICS
1. A, B
If n is even, first and last places can be filled in n ways and rest in (n – 1)! Ways = n.(n – 1)! = n!
ways.
If n is odd, first and last places can be filled in n + 1 ways and rest in ( n − 1) ! ways
( )
= ( n + 1)( n − 1) ! = n2 − 1 ( n − 2 ) ! ways
2. B, D
The tangents will be perpendicular and their intersection lies on x 2 + y 2 = 2a2 (director circle).
3. B, C
(
x×b = c ×b  a× x×b = a× c ×b) ( )
x=
(
a× c ×b ) which is equal to
(b × c ) × a as well.
a.b a.b
4. A, C
Use reduction formula.
5. B, C, D
tan−1 x1.tan−1 x 2 = 1
tan−1 x1 + tan−1 x 2 = 3
x1 + x 2
= tan3
1 − x1x 2
Now, tan−1 x1 − tan−1 x 2 = 9 − 4 = 5
x1 − x 2
= tan 5
1 + x 1x 2
x12 − x 22

1 − x12 x 22
= ( tan3 ) tan 5( )
(
tan−1 tan 5 = 5 − π )
−1
tan ( tan3 ) = 3 − π < 0
6. A, B, C
2 2
 x + y − 1  x −y +3
   
 2   2 
+ =1
12 2
2 ( )
2a2
L.R. = = 2
b
3 1
2P2 1 −
Now, = 2  P2 = P=2 3
P 2
3
π
Area of ellipse E2 is πP 2 =
2
 −2 1
− 
(
Area of director circle of E2 = π P2 + P = π  2 3 + 2 3  )
 
7. A, B, C, D
9
f ( n ) = n(n+1) 1 + 11 + 111 + ...... + 111.....1
 n times 
10 2
n
1 + 11 + 111 + ...... + 111......1 =  100 + 101 + .......10r −1
r =1
=
n (
1 10r − 1 )
1 10 − 1
1
=  10 + 102 + ....... + 10n − n
( )
9
1 10 10 − 1 (  )
n
=  − n
9  10 − 1 
 
1 n +1
= 10 − 10 − 9n 
81 
 
1 10n+1 − 10 − 9n 
f (n) =
9 n(n +1) 
 10 2 
8. D
9. C
10. B
Soln. (8 – 10):
a = 2, b = − 7, c = 4
1≤ y ≤ 7  1≤ λ ≤ 7
So, two positive integer λ are possible.
a = 1, b = −1, c = 3
f ( θ ) + f ' ( θ ) = sin θ − cos θ + 3 + cos θ + sin θ
= 2 sin θ + 3
3 − 2 ≤ 2 sin θ + 3 ≤ 2 + 3
π 
f ( θ ) + f '  − θ  = 2a sin θ + c
 2 
a = 2, c = 1
−3 ≤ 4 sin θ + 1 ≤ 5
π  π 
f ( θ ) + f '  − θ  + f ''  − θ  = k
2  2 
= −acos θ + sin θ ( 2a − b ) + c
a = 4, b = 5, c = 10
5 ≤ k ≤ 15
11. D
12. B
13. B
Soln. (11 – 13):
– + –  1 1
f ( x ) = log ( x (1 − x ) )  , 
0 1 2 4
Domain
x (1 − x ) > 0
0 < x <1
Let t = x (1 − x ) 0 1/2 1
So, range is −∞ < f ( x ) ≤ −2
x2
g( x) =
2x 2 + 1
Domain −∞ < x < ∞
1  2x 2 + 1 − 1 
y=  
2  2x 2 + 1 
1 1 
= 1 − 2
2  2x + 1 
2x 2 + 1 ≥ 1
1
0< 2 ≤1
2x + 1
1
1− 1 ≤ 1− 2 < 0 +1
2x + 1
1
0≤y<
2
h ( x ) = ln ( ln x )
ln ( ln x ) ≥ 0
ln x ≥ 1
x ≥ e1
Domain [ e, ∞ )
Let ln x = t
−∞ < t < ∞
y = ln t
y ∈ [ 0, ∞ )
14. 5
1
The probability of getting at least one head = 1 −
2n
1 1
and of getting at least two tails = 1 − − n. n
2n 2
15. 1
1
Solving both we get x = − , − 3
2
1
Put x ≠ −
2
3
x = −3 gives y = ±
2
 1 3  1 3
Length of chord = distance between  − , −  and  − , 
 2 2  2 
  2
16. 2
2 2 2 2
a + b + c = a + b + c = 50
17. 7
n |x|} dx
 e{
−n 1 + e sin x
n |x|
=  e{ } dx.
0
1 x− x
= n e [ ] = n ( e − 1)
0
50
n 1
 (n + 1)! = 1 − (3 × 17 )!
1
So, ab = 51
So,  ab  = 7
 
18. 1
Let equation of plane is
ax + by + d = 0
a + 2b + d = 0
a+b = 0
d =a
x − y +1 = 0
| cos α − sin α |
p=
2
pmax = 1

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FIITJEE - MOCK TEST

(JEE ADVANCED 2021)

1. Attempt ALL the questions.

B. Filling of OMR Sheet

Name of the Candidate (in Capital Letters) :_____________________________________

Enrolment Number :_________________________________________________________

Batch :________________________ Date of Examination : ________________________

(A) the sphere A comes to rest after collision

(A) The maximum possible acceleration of the insect can be 14 m/sec2

The system consists of three blocks of mass 2 kg, 3 kg and m. µ s = 0.3 .

Column I Column II Column III

8. Which of the following is correct?

9. Which of the following is incorrect?

10. Which of the following is correct?

Column I (Force applied F) Column II (Normal reaction N) Column III (Acceleration of

11. Which of the following is correct?

12. Which of the following is incorrect?

13. Which of the following is correct?

5. Which of the following compounds give the same carbocation on ionization?

6. Pick out the correct statement(s).

7. Which of the following statements are true?

Column I (Process) Column II (Used in) Column III (Reagent used)

8. Set of processes used in the metallurgy of cobalt will be

9. Set of processes used in the metallurgy of copper is

10. Correct set of combinations used in the metallurgy of zirconium will be

Column I Column II Column III

11. Correct combination for NaCl will be

12. Choose correct combination for CsCl among the following:

17. If 0.01% of a substance undergoing decomposition is consumed in 1 millisecond when the

PART – III [MATHEMATICS]

3. If x × b = c × b and x ⊥ a , then x is equal to

Column I Column II Column III

8. Which of the following options is correct?

9. Which of the following options is correct?

10. Which of the following options is not correct?

Column I Column II Column III

12. Which of the following options is correct?

13. Which of the following options is not correct?

FIITJEE - MOCK TEST

HINTS & SOLUTIONS

When the cylinder rolls up the incline, sense of

Conserving angular moment about point 'D' as shown in the figure

hence insect can move with constant velocity.

Wavelength of radiation = 103 nm = 1030 Å

bob will oscillate about equilibrium position

Soln. (11 – 13):

For wire to be in equilibrium (Figure (a))

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Batch : Date of Examination :