Lktyr235a01 PH I Main

FIITJEE – JEE (Main)
Physics, Chemistry & Mathematics

DATE: 09.09.2023 PHASE - I
Time Allotted: 3 Hours Maximum Marks: 300
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
BATCH: LKTYR235A01
Important Instructions
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1.Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2.This question paper contains Three Sections.
3.Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4.Each Section is further divided into Two Parts: Part-A & C in the OMR.
5.Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for rough work.
6.No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log tables, slide rule, calculator,
cellular phones, pagers and electronic devices ext. except the Admit Card inside the examination hall / room.
B. Filling of OMR Sheet:

1.Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR sheet.
2.On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3.OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.
C. Marking Scheme for All Two Parts:

(i) Part-A (01-20) contains Twenty (20) multiple choice objective questions which have four (4) options each and only one correct
option. Each question carries +4 marks which will be awarded for every correct answer and -1 mark will be deducted for every
incorrect answer.
(ii) Part-C (01-05) contains five (05) Numerical based questions, the answer of which is a single digit integer, ranging from 0 to 9 (both
inclusive) and each question carries +4 marks for correct answer and there will be no negative marking.
Name of the Candidate :___________________________________________________________________
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Enrolment Number :_______________________________________________________________________
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SECTION – I
PHYSICS
Single Choice Correct Type
1. If A, B and C represent unit vectors in each case, which vector combination(s) results in a unit
vector?
(1) (2) (3) (4)
(A) 1, 2, 3 (B) 1, 3 (C) 1, 2, 4 (D) 4
2. A swimmer crosses a river of width d flowing at velocity v. While swimming, he keeps himself always
at an angle of 120° with the river flow and on reaching the other end he finds a drift of d/2 in the
direction of flow of river. The speed of the swimmer with respect to the river is

(A) 2  3 v  (B) 2 2  3 v  
(C) 4 2  3 v 
(D) 2  3 v   
3. For a given initial speed, a projectile has the same range R for two angles of projection. If t1 and t2 are
the times of flight in the two cases then
1 1
(A) t1t2  R 2 (B) t1t2  R (C) t1t2  (D) t1t2  2
R R
4. In the figure, the block of mass M is at rest on the floor. The acceleration
with which a monkey of mass m should climb up along the rope of
negligible mass so as to lift the block from the floor is
M  M 
(A)   1 g (B)    1 g
m  m 
M M
(C) g (D)  g
m m
5. In the pulley – block system shown, find the accelerations of A, B

and C. Assume the friction to be negligible and the string to be light
and inextensible. The masses of the blocks are m, 2m and 3m
respectively
9g g 7g 7g g 7g
(A) a1  , a2  , a3  (B) a1  , a2  , a3 
10 10 10 10 10 10
9g 9g 7g 9g g g
(C) a1  , a2  , a3  (D) a1  , a2  , a3 
10 10 10 10 10 10
6. A particle of mass m is projected with velocity u at an angle  with horizontal. During the period when
the particle descends from highest point to the position where its velocity vector makes an angle /2
with horizontal, work done by the gravity force is
1   1
(A)   mu 2 tan 2   (B)    mu 2 tan 2 
2 2 2
1   1  
(C)   mu 2 cos 2  tan 2   (D)    mu 2 cos 2   sin 2 
2 2 2 2
7. A body starts from rest on a long inclined plane of slope 45°. The coefficient of friction between the
body and the plane varies as  = 0.3x, where x is the distance travelled down the plane. The body will
have maximum speed (for g = 10 m/s2) when x =
(A) 9.8 m (B) 12 m (C) 1.2 m (D) 3.33 m
8. A time dependent force F = 6t acts on a particle of mass 1 kg. If the particle stars from rest, the work
done by the force during the first 1 sec. will be:
(A) 18 J (B) 4.5 J (C) 22 J (D) 9 J
9. A uniform chain of length 2 m is kept on a table such that a length of 60 cm hangs freely from the edge
of the table. The total mass of the chain is 4 kg. What is the work done is pulling the entire chain on
the table?
(A) 7.2 J (B) 3.6 J (C) 120 J (D) 1200 J
10. The length of second’s hand in watch is 1 cm. The change in velocity of its tip in 15 seconds is
   2
(A) Zero (B) cm / sec (C) cm / sec (D) cm / sec
30 2 30 30
11. A particle travels with speed 50 m/s from the point (3 m, – 7 m) in a direction 7iˆ  24 ˆj . Find its
position vector after 3 seconds.

(A) 45iˆ  125 ˆj m  
(B) 45iˆ  151 ˆj m 
(C) 45iˆ  125 ˆj m 
(D) 35iˆ  115 ˆj m   
12. The graph to the right is a plot of position versus time. For which
labeled region is the velocity positive and the acceleration negative?
(A) a
(B) b
(C) c
(D) d
13. As shown in the figure, two blocks with masses m and M (M > m) are pushed by a force F in both
Case I and Case II. The surface on which blocks lie, is horizontal and frictionless. Let RI be the force
that m exerts on M in case I and RII be the force that m exerts on M incase II. Which of the following
statements is true?
(A) RI = RII and is not equal to zero or F (B) RI = RII = F

(C) RI < RII (D) RI > RII
14. Two blocks A and B of masses 2m and m, respectively, are connected by a

massless and inextensible string. The whole system is suspended by a
massless spring as shown in the figure. The magnitudes of acceleration of A
and B immediately after the string is cut, are respectively:
g g
(A) g , (B) , g
2 2
g g
(C) g, g (D) ,
2 2
15. Two blocks A and B are as shown in figure. The minimum horizontal
force F applied on block B for which slipping begins between B and
ground is:
(A) 100 N (B) 120 N
(C) 50 N (D) 140 N
16 The maximum and minimum tension in the string whirling in a vertical circle of radius 2.5 m with
constant velocity are in the ratio 5 : 3 then its velocity is
(A) 10 m/s (B) 7 m/s (C) 15 m/s (D) 5 m/s
17.  
A force F   K yi  xj (where K is a positive constant) acts on a particle moving in the xy-plane.
Starting from the origin, the particle is taken along the positive x-axis to the point (a, 0) and then
parallel to the y-axis to the point (a, a). The total work done by the force F on the particles is:
(A) 2Ka 2 (B) 2Ka 2 (C)  Ka 2 (D) Ka 2
18. A particle of mass m is moving in a horizontal circle of radius r under a conservative centripetal force
K
equal to  2 , where K is a constant. The total energy of the particle is
r
K K K K
(A) (B)  (C)  (D)
2r 2r r r
19. A ball weighing 1.0 kg is tied to a string 15 cm long. Initially

the ball is held in position such that the string is horizontal.
The ball is now released. A nail N is situated vertically below
the support at a distance L. The minimum value of L such that
the string will be wound round the nail is
(A) 15 cm
(B) 4 cm
(C) 9 cm
(D) None of these
20. A block of mass m is attached with a massless spring of force

constant k. The block is placed over a rough inclined surface for
3
which the coefficient of friction is   . The minimum value of
4
M required to move the block up the plane is (neglect mass of
string and pulley and friction on pulley)
3 4
(A) m (B) m
5 5
3
(C) 2 m (D) m
2
Numerical Based Type
1. A point P moves in counter-clockwise direction on a circular path as
shown in the figure. The movement of ‘P’ is such that it sweeps out a
length s  t 3  5 , where s is in metres and t is in seconds. The radius
of the path is 20 m. The acceleration of ‘P’ = 2K, then the value [K]
is ___________ m/s2 (when t = 2 s) (where [K] is greatest integer
function)
2. A stone is dropped from the top of a tower. When it has fallen by 5 m from the top, another stone is
dropped from a point 25 m below the top. If both stones reach the ground at the same moment, and
height of the tower is 5k, then the value of [k] is _________ m. (take g = 10m/s)
(where [k] is greatest integer function)
3. A railway track runs parallel to a road until a turn brings the road to railway crossing. A cyclist rides
along the road every day at a constant speed 20 km/hr. He normally meets a train that travels in same
direction at the crossing. One day he was late by 25 minutes and met the train 10 km before the railway
crossing. The speed of the train is 20k, then the value of [k] is ________ kmh–1.
4. A particle P is projected from a point on the surface of smooth inclined plane

(see figure). Simultaneously another particle Q is released on the smooth
inclined plane from the same position. P and Q collide after t = 4 second. The
speed of projection of P is 5k, then the value of [k] is __________ m/s.
5. A rod AB is shown in figure. End A of the rod is fixed on

the ground. Block is moving with velocity 3 m / s
towards right. The velocity of end B of rod when rod
makes an angle of 60° with the ground is ________ m/s.
SECTION – II
CHEMISTRY
1. An unknown amino acid has 0.032% sulphur. If each molecule has one S-atom, then 1 g of this amino
acid has molecules
(A) 6.02 × 1018 (B) 6.02 × 1019 (C) 6.02 × 1021 (D) 6.02 × 1023
2. In the following reaction, MnO2  4 HCl 

 MnCl2  2 H 2O  Cl2
2 moles MnO2 react with 4 moles of HCl to form 11.2 L Cl2 at STP. Thus, percent yield of Cl2 is
(A) 25% (B) 50% (C) 100% (D) 75%
3. For the reaction, Fe2O3  3CO   2 Fe  3CO2 , the volume of carbon monoxide required at STP to
reduce one mole of ferric oxide is
(A) 22.4 dm3 (B) 44.8 dm3 (C) 67.2 dm3 (D) 11.2 dm3
4. To prepare a solution that is 0.50 M KCl starting with 100 mL of 0.40 M KCl, what should be done?
(A) add 0.75 g KCl (B) add 20 mL of water (C) add 0.10 mol KCl (D) evaporate 10 mL water
5. Sulphur atoms are of two environments in S 4O62 , difference in oxidation states of two types of sulphur is
(A) 5 (B) 6 (C) 7 (D) 10
6. Magnetic moments of V(Z = 23), Cr(Z = 24) and Mn(Z = 25) are x, y, z. Hence,
(A) x = y = z (B) x < y < z (C) x < z < y (D) z < y < x
7. If the shortest wavelength of H atom in Lyman series is x, then longest wavelength in Balmer series of
He+ is
9x 36 x x 5x
(A) (B) (C) (D)
5 5 4 9
8. Which of the following sets of quantum numbers represents the highest energy of an atom?
(A) n = 3, l = 1, m = 1, s = + 1/2 (B) n = 3, l = 2, m = 1, s = + 1/2
(C) n = 4, l = 0, m = 0, s = + 1/2 (D) n = 3, l = 0, m = 0, s = + 1/2
9. The de-Broglie wavelength of the electron in the ground state of hydrogen atom is:
(KE = 13.6 eV); 1 eV = 1.6 × 10–19 J
(A) 33.29 nm (B) 3.329 nm (C) 332.9 nm (D) 0.0332 nm
10. The amount of energy required to remove the electron from a Li2+ ion its ground state is how many times
greater than the amount of energy needed to remove th electron from an H atom in its ground state?
(A) 2 (B) 9 (C) 4 (D) 6
11. Geometrical configuration of BF3 and NF3 molecules is

(A) the same because of same convalency of the central atom
(B) different because BF3 is polar and NF3 is non-polar
(C) different because BF3 is non-polar and NF3 is polar
(D) None of these
12. Which species has the same shape as the NO3 ion?
(A) SO3 (B) SO32  (C) CIF3 (D) ClO3
13. In which pair or pairs is the stronger bond found in the first species?
I. O22  , O2 II. N 2 , N 2 III. NO  , NO 
(A) I only (B) II only (C) I and III only (D) II and III only
14. The hybridization scheme for the central atom includes a d-orbital contribution in
(A) I 3 (B) PCl3 (C) NO3 (D) H 2 Se
15. Which of the following will have maximum electron affinity?

(A) 1s 2 2 s 2 2 p 5 (B) 1s 2 2 s 2 2 p 6 (C) 1s 2 2 s 2 2 p 6 3s 2 3 p 5 (D) 1s 2 2 s 2 2 p 6 3s 2 3 p 6
16. The relative thermal stabilities of alkali metal halides are such that
(A) CsCl > RbCl > KCl > NaCl > LiCl (B) LiCl > NaCl > KCl > RbCl > CsCl
(C) CsCl > RbCl > KCl > NaCl > LiCl (D) CsCl < RbCl > KCl < NaCl > LiCl
17. Following are the values of the electron affinities (in kJ mol–1) of the formation of O  and O 2  from O
(A) – 142, – 702 (B) – 142, 702 (C) 142, 702 (D) – 142, – 142
18. If Aufbau rule is not followed, K-19 will be placed in __________ block.
(A) s (B) p (C) d (D) f
19. Which has maximum ionization potential?

(A) N (B) O (C) O+ (D) Na
20. Following are the ionization potential values of

 I1  899 kJ mol 1 ,  I 2 1757 kJ mol 1 ,  I3 15000 kJ mol 1 , hence the unknown atom will be
(A) Na (B) K (C) Be (D) Ne

1. When LiNO3 is heated, change in oxidation number of N will be ___________.
2. In O3, central oxygen atom is hypervalent. Hence the number of electron pairs shared by central
oxygen will be ___________.
3. Out of CH 2Cl2 , CH 4 , CCl4 , H 2O, CHCl3 , p-dichlorobenzene, o-cresol, p-xylene, SCl2, BF3, IBr and
CH2O, non-zero value of dipole moment will be ___________.
4. 100 mL of 1 MH 2 SO4 solution is mixed with 200 mL of 2MCa  OH  2 solution. What is the molarity
of excel reagent left in the solution.
5. 1.2 g of Mg is treated with 100 ml of 1M H2SO4. If the molar concentration of the H2SO4 solution after
completion of reaction is x, then 10x will be __________.
SECTION – III
MATHEMATICS
1. In a triangle ABC, coordinates of A are (1, 2) and the equations of the medians through B and C are
x + y = 5 and x = 4 respectively. Then area of ABC (in sq. units) is
(A) 5 (B) 9 (C) 12 (D) 4
2. The set of all possible values of  in the interval  0,   for which the points 1, 2  and  sin ,cos   lie
on the same side of the line x + y = 1 is :
    3   3   
(A)  0,  (B)  ,  (C)  0,  (D)  0, 
 2 4 4   4   4
3. For t   0, 2  , if ABC is an equilateral triangle with vertices A  sin t,  cos t  , B  cos t,sin t  C  a, b 
 1
such that its orthocenter lies on a circle with centre 1,  , then  a 2  b 2  is equal to :
 3
8 77 80
(A) (B) 8 (C) (D)
3 9 9
4. 
Let A   x1 , y1  3x1  4y1  3  0 and B   x 2 , y 2   x 2  3   y 2  4   0
2 2

p
 x1  x 2    y1  y2  is minimum, then  x1 , y1    a, b  , where a  b  , p,q  N , the least
2 2
If
q
value of  p  q  , is
(A) 3 (B) 2 (C) 4 (D) 1
5. Let A  3, 4  , B  0,0  and C  3,0  be vertices of ABC . If P is a point inside ABC , such that
d  P, BC   min  P, AB  ,d  P, AC  , then the maximum value of d  P, BC  is equal to
[Note : d  P, BC  represents distance of P from BC.]
1 3
(A) 1 (B) (C) 2 (D)
2 4
6. If the circles x 2  y 2  2ax  2by  c  0 and x 2  y 2  2bx  2ay  c  0 where c > 0, have exactly one
a  b
2
point in common then the value of is

2c
(A) 1 (B) 2 (C) 2 (D) 1/2
7. The locus of the centres of circles passing through the origin and intersecting the circle
x 2  y 2  5x  3y  1 orthogonally, is
1
(A) circle of radius 1 (B) circle of radius
2
3 5
(C) straight line of slope (D) straight line slope
5 3
8. The equation of the circle whose diameter is the common chord of the circle x 2  y 2  3x  2y  1  0
and x 2  y 2  3x  4y  2  0 is
(A) x 2  y 2  8x  10y  2  0 (B) x 2  y 2  5x  4y  7  0
(C) 2x 2  2y 2  6x  2y  1  0 (D) 2x 2  2y 2  6x  2y  1  0
9. Locus of mid-point of the portion between the axes of x cos   y sin   P, where P is constant is
4 1 1 2 1 1 4
(A) x 2  y 2  2 (B) x 2  y 2  4P 2 (C) 2  2  2 (D) 2  2  2
P x y P x y P
1 x
then 1  x 2 
dy
10. If y  is equal to
1 x dx
1 y
(A) y 2 (B) (C)  y (D)
y x
cos 2x
11.   sin x  cos x  2
dx is equal to
1
(A) c (B) ln  sin x  cos x   c
sin x  cos x
(C) ln  sin x  cos x   c (D) ln  sin x  cos x   c
2
3
12. If   2  , then 2  2  2cos 4 equals to
2
(A) 2cos  (B) 2sin  (C) 2cos  (D) 2sin 
13. Area enclosed by x  y  1 is

1
(A) 1 (B) 2 (C) (D) 4
2
14. The number of value of x satisfying the equation. log 2  log 3  log 2 x    x  8  8  x
(A) 0 (B) 1 (C) 3 (D) 4
 2 2 
15. A 1,3 and C   ,  are the two vertices of a triangle ABC and equation of bisector of ABC IS
 5 5 
x  y  2, then
Equation of side BC is
(A) 7x + 3y – 4 =0 (B) 7x + 3y + 4 = 0 (C) 7x – 3y + 4 = 0 (D) 7x – 3y – 4 = 0
16. If the line y  3x cut the curve x 3  y3  3xy  5x 2  3y 2  4x  5y  1  0 at the points A, B, C then
OA  OB  OC is : (where O is origin)

(A) 4 3 3  1 /13  (B) 3 3  1 
(C) 2 3  21 / 7  (D) none of these
17. A circles passing through point (–1,0) and touching the y – axis at (0. 2) also passes through the point
 3   5   3 5 
(A)   ,0  (B)   ,0  (C)  ,  (D)  4,0 
 2   2   2 2
18. If x + y = z, then cos 2 x  cos 2 y  cos 2 z  2 cos x.cos y cos z is equal to

(A) cos 2 z (B) sin 2 z (C) 0 (D) 1
 2 3 11
19. cos cos cos .......cos 
11 11 11 11
1 1 1 1
(A)  (B) (C) (D) 
32 512 1024 2048
1
20. The range of is
4cos x  3sin x  2
 1 1  1 1   1  1 
(A)   ,  (B)  ,     ,   (C)  3,7  (D)   ,0    ,  
 3 7  3  7   3  7 
1. The number of real solutions of the equation sin  e x   2 x  2 x is _______.
2. The smallest positive of x (in degrees) for which, tan x o  tan  x o  10o  tan  x o  20o  tan  x o  30o  is
_______.
3. Number of integral solution of the equation x  1  x  2  7 is _______.
   9    m  8  
4. Let S     0,  :  sec     m  1  sec   
  2  m1  6 

6  3
&    k then k  ?
S
5. The line x + 2y + 3 = 0 cuts the circle x 2  y 2  4x  4y  1  0 at points P and Q and the line
2x + 3y +  = 0 cuts the circle x 2  y 2  6x  2y  7  0 at points R and S. If P, Q, R and S are
concyclic, then find the value of  .
FIITJEE – JEE (Main)
Physics, Chemistry & Mathematics
(LKTYR235A01)
DATE: 09.09.2023
ANSWERS
Sl. No. Physics Sl. No. Chemistry Sl. No. Mathematics
1. B 1. A 1. B
2. C 2. B 2. A
3. B 3. C 3. B
4. B 4. A 4. C
5. A 5. A 5. A
6. C 6. C 6. A
7. D 7. A 7. D
8. B 8. B 8. C
9. B 9. C 9. D
10. D 10. B 10. C
11. B 11. C 11. B
12. D 12. A 12. D
13. C 13. D 13. B
14. B 14. A 14. B
15. A 15. C 15. B
16. A 16. B 16. A
17. C 17. B 17. D
18. B 18. C 18. D
19. C 19. C 19. C
20. A 20. C 20. B
1. 7 1. 1 1. 0
2. 9 2. 3 2. 5
3. 6 3. 7 3. 2
4. 2 4. 1 4. 2
5. 2 5. 5 5. 4
CONCEPT CODE
Sl. No. Physics Sl. No. Chemistry Sl. No. Mathematics
1. P110201 1. C110202 1. M110703
2. P110309 2. C110202 2. M110705
3. P110304 3. C110202 3. M110801
4. P110403 4. C110205 4. M110705
5. P110403 5. C110203 5. M110701
6. P110502 6. C110111 6. M110808
7. P110305 7. C110103 7. M110810
8. P110501 8. C110106 8. M110807
9. P110504 9. C110102 9. M110702
10. P110306 10. C110102 10. M120501
11. P110203 11. C110305 11. M120701
12. P110303 12. C110305 12. M111401
13. P110403 13. C110306 13. M110605
14. P110406 14. C110304 14. M110202
15. P110406 15. C110703 15. M110707
16. P110409 16. C110802 16. M110704
17. P110501 17. C110703 17. M110807
18. P110501 18. C110110 18. M111401
19. P110502 19. C110702 19. M111405
20. P110503 20. C110702 20. M111403
1. P110307 1. C110203 1. M111403
2. P110301 2. C110302 2. M111401
3. P110308 3. C110304 3.
4. P110305 4. C110205 4. M111401
5. P110408 5. C111102 5. M110808
Hints & Solutions
Physics:
1. (B)
2. (C)
Drift = d/2 = (vr – vs sin 30) d/vs cos 30

 vs  4 2  3 v 
3. (B)
4. (B)
Equation of motion for M:
Since M is stationary,
T – Mg = 0
 T = Mg ……… (1)
Since the monkey moves up with an acceleration ‘a’, T – mg = ma
 T = m(g + a) ……… (2)
Equating (1) and (2), we obtain
Mg = m(g + a)
M 
 a    1 g
m 
M 
That means, if a    1 g , the block M can be lifted from floor.
m 
5. (A)
The FBD of A, B, C are shown in the diagram
T  ma1 ………… (1)
2mg  2T  2ma2 ………… (2)
3mg  T  3ma3 ………… (3)
Constraint relation:
x3  2 x2  x1  0
d 2 x3 d 2 x2 d 2 x1
2 2  2 0
dt 2 dt dt
a3  2a2  a1  0 ………… (4)
Solving the equations
9g g 7g
a1  , a2  , a3 
10 10 10
9
T  mg
10
6. (C)
As horizontal component of velocity does not change,

 
v cos    u cos 
2
u cos 
v
 
cos  
2
1 1 1 
Wgravity  k  mv 2  m  u cos    mu 2ocs 2 tan 2
2
2 2 2 2
7. (D)
tan 45    0.3x
8. (B)
1
From impulse momentum theorem  6tdt  mv
0
 v = 3 m/s
1
1 3  4.5 J
2
So, work done by the force = K.E. =
2
9. (B)
 4   0.60  4  6  10  0.3
Work done =   60   g     3.6 J
 200   2  20
10. (D)
 90  1
v  2v sin    2v sin 45  2v   2v
 2  2
2 2
= 2  r  2  1  cm / s
60 30
11. (B)
Given speed v = 50 m/s in the direction a  7iˆ  24 ˆj
v  vaˆ; aˆ is the unit vector in the direction 7iˆ  24 ˆj
aˆ 
 7iˆ  24 ˆj  
 7iˆ  24 ˆj 
 24    7  25
2 2
 7iˆ  24 ˆj   2 7iˆ  24 ˆj m / s
v  vaˆ  50.
25
 
Initially the particle is at r   3iˆ  7 ˆj  m
0
Position of the particle after 3 sec, r  r0  vt

    
 r  3iˆ  7 ˆj  3  2 7iˆ  24 ˆj  45iˆ  151 ˆj m 
12. (D)
In part (D), slope is positive and decreasing, so velocity is positive and decreasing. If velocity is
decreasing, then acceleration is negative.
13. (C)
F
Acceleration of all blocks in both cases is the same and is a 
mM
In case I: required normal reaction R1 is equal to net force on block of mass m
 RI = ma
In case II: required normal reaction RII is equal to net force on block of mass M.
 RII = Ma
Hence, RII > RI
14. (B)
After string is cut, free body diagram of block A gives
mg g
2ma A  3mg  2mg or a A  
2m 2
Free body diagram of block B gives maB  mg or aB  g
15. (A)
The sliding shall start at lower surface first
If F > 0.5 [10 + 10]g
Or F > 100 N
16. (A)
In this problem it is assumed that particle although moving in a vertical loop, its speed remain
constant.
mv 2
Tension at lowest point Tmax   mg
r
mv 2
Tension at highest point Tmin   mg
r
mv 2
Tmax  mg
r 5
 2

Tmin mv 3
 mg
r
By solving we get, v  4 gr  4 10  2.5  10 m / s
17. (C)
While moving from (0, 0) to (a, 0)
Along positive x-axis, y = 0  F   kxjˆ
i.e., force is in negative y-direction while displacement is in positive x-direction.
 W1 = 0
Because force is perpendicular to displacement
Then particle moves from (a, 0) to (a, a) along a line parallel to y-axis (x = +a) during this

F  0k yiˆ  ajˆ 
The first component of force,  kyiˆ will not contribute any work because this component is along
 
negative x-direction iˆ while displacement is in positive y-direction (a, 0) to (a, a). The second
component of force i.e.  kajˆ will perform negative work.
  
 W2   kajˆ ajˆ    ka  a    ka 2
So net work done on the particle W  W1  W2
= 0    ka 2    ka 2
18. (B)
mv 2 K mv 2 K
Here  2   2
r r r r
r r
 K K
U    F  dr      2  dr  


r  r
K K K
Total energy E  KE  PE   
2r r 2r
19. (C)
Velocity of bob at C should be 5gR
5 g  R  L   2 gR
5  R  L   2R
3R  5 L
3 3
L  R   15  9 cm
5 5
20. (A)
3
mg sin   mg
5
 3  4  3
f max   mg cos      mg  mg
 4  5  5
3
f max  mg sin   mg
5
Block will move upwards when
6
kx0  f max  mgkx0  f max  mg sin   mg ………….. (i)
5
From conservation of mechanical energy
1 2
Mgx0  kx0
2
6
mg
kx0 5 3
M   m
2g 2g 5
1. (7)
s  t3  5
ds
v  3t 2
dt
dv
and at   6t
dt
 at t 2  12
v 2  vt  2  12 
2 2
aR   
R R 20
a  at2  aR2  14.994
a  14 m / s 2
14 = 2k
 k = 7 m/s2
2. (9)
Velocity of Ist stone when passing at A
V 2  0  2.10.5  V  10 m / s
and S1  S 2  20 m
 1  1 
 10t  10t 2    10t 2   20
 2  2 
1
At t  2 s, S 2  10  22  20 m
2
Hence, height of the tower, H  S1  S 2  25  20  45 m
45 = 5k
k=9m
3. (6)
Time taken by the cyclist to cover 10 km
10 km 1
tcycle  1
 h  30 min
20 kmh 2
It means the train will take 5 min to cover 10 km.
5
t = 5 min = hr
60
Train running as per schedule.
10 10  60
So Vmin    120 kmh 1
 5 / 60  5
120 = 20k
 k = 6 kmh–1
4. (2)
It can be observed from figure that P and Q shall collide if the initial component of velocity of P along
incline. u|| = 0 that is particle is projected perpendicular to incline.
 Time of flight
2u 2u
T 
g cos  g cos 
gT cos 
 u  10 m / s
2
10 = 5k
 k = 2 m/s
5. (2)
Let AB = l, E = (x, y)
vB  vx iˆ  v y ˆj
vB  3iˆ  v y ˆj …………. (i)
x 2`  y 2  l 2
2 xvx  2 yv y  0
y
 3 vy  0
x
 3   tan 60  v y  0
 v y  1
Hence, from (i) vB  3iˆ  ˆj
Hence, vB  2 m / s
Chemistry:
1. (A)
mass of s
%S   100 amino acid
molar mass
mass of s
 molar mass of amino acid = 100
%s
7  32 ag
=  100  105 g / mole
0.032
1g
Hence number of mole = 5  105 mol
10 g / mol
Hence number of molecules = 10 5  6.02  1023  6.02 1018
2. (B)
Here HCl is limiting reagent
Hence theoretically the moles of Cl2 gas produced
1
= by the reaction of 4 mole of HCl =  4  1 mol of Cl2
4
11.2 L
Actual yield of Cl2   0.5 mole
22.4 L / mol
Actual
Hence % yield of Cl2   100
Theoretical
0.5
=  100  50%
1
3. (C)
The moles of carbon monoxide (CO) to reduce 1 mole Fe2O3  3 mole
Volume of CO at STP = 3 × 22.4 L = 67.2 L
4. (A)
Increase in molar concentration = 0.1 M
Hence milimoles of KCl to be added = 0.1 M × 100 ml = 10 m mole
Hence mass of KCl added = 10 m mol × 74.5 g/mole = 0.745 g = 0.75 g
5. (A)
O O
O   S 5  S o  S 0  S 5  O 1
O O
Hence difference of oxidation states
6. (C)
Magnetic moment  Number of unpaired electrons
XV   Ar  3d 3 4s1 n  3
YCr   Ar  3d 5 4s1 n6
ZMn   Ar  3d 5 4s 2 n5
7. (A)
Refer hydrogen spectrum.
8. (B)
Energy n + l
=3+2=5
9. (C)
n = 2r
n2
2  0.53  Å
2 r z n
    2  0.5  Å
n n z
1
   2  3.141 0.53  Å  3.329 Å  332.9 pm
1
10. (B)
13.6 Z12
IE of Li 2 n12

IE of H 13.6 Z 22
n22
IE of Li 2 z12 32
  2  2 9
IE of H z2 1
11. (C)
Refer VSEPR theory
12. (A)
Refer VSEPR theory
13. (D)
Bond strength  Bond order
Refer MOT
14. (A)
Refer VSEPR theory
15. (C)
Chlorine have highest electron affinity
16. (B)
Thermal stability  Lattice energy of alkali halides
17. (B)
 H eg   ve,  H eg   ve
1 2
18. (C)
Fact
19. (C)
I.E  effective nuclear charge
20. (C)
I3 is very high, hence for I3 inner shell electron will be lost.
1. (1)
LiNO35  Li2O  NO24  O2
Difference 5 – 4 = 1
2. (3)
   
 
O O O

3. (7)
Non-zero value of dipole moment
CH 2Cl2 , H 2O, CHCl3 , o  Cresol , SCl2 , IBr , CH 2O
4. (1)
Ca  OH 2  H SO2 4 
 CaSO4  2 H 2O
200 2 m .mol 1001 m.mol
 Limiting reagent 
Here m.mol Ca  OH 2 left = 400 – 100 = 300
5. (5)
1.2 g
Moles of Mg   0.05
24 g / mol
 100 
Moles of H 2 SO4 taken = 1M   L
 1000 
= 0.1 mole
Mg  H 2 SO4   MgSO4  H 2
Moles of H 2 SO4 left = 0.14 – 0.05 = 0.05 mole
0.05mol
Hence, concentration of H2SO4 left =  0.5M
0.1L
Hence, x = 0.5
 10x = 5
Mathematics:
1. (B)
Median through C is x = 4
So the x coordinate of C is 4. Let C   4, y  , then the mid point of A (1,2) and C (4,y) is D which lies
on the median through B.
1 4 2  y 
D   , 
 2 2 
1 4  2  y
Now,  5  y  3.
2
So, C   4,3 .
The centroid of the triangle is the intersection of the medians. Here the medians x = 4 and
x + y = 5 intersect at G (4, 1).
The area of triangle ABC  3  AGC
1
 3  11  3  4  3  2   4  2  1   9.
2
2. (A)
Let f  x, y   x  y  1
Given 1, 2  and  sin ,cos   are lies on same side.
 f 1, 2   f  sin ,cos    0
 2 sin   cos   1  0
  1
 sin   cos   1  sin     
 4 2
   3   
     ,      0, 
4 4 4   2
3. (B)
Let s  sin t , c  cos t
Let orthocenter be  h, k 
Since it if an equilateral triangle hence orthocenter coincides with centroid.
 a  s  c  3h, b  s  c  3k
  3h  a    3k  b    s  c    s  c   2  s 2  c 2   2
2 2 2 2
2 2
 a  b 2
 h     k    ,
 3  3 9
a b
Now circle centre at  , 
 3 3
4. (C)
Point  x2 , y2    8, 4 
Point  x1 , y1  is on the line : 3 x1  4 y1  3  0
min   x  x    y  y   denote min distance of  x , y  from the given line.

1 2
2
1 2
2
2 2
So point  x1 , y1  will be foot of perpendicular from  x2 , y2  on the given line
5. (A)
For max d  P, B, C 
Point P is incentre & PA & PB will be angle bisector
6. (A)
C1C2  R1  R2
7. (D)
Let equation of circle be x 2  y 2  2 gx  2 fy  c  0
 c  0  circle pas sin g through  0,0  
Then apply condition of orthogonal circle
2 g1 g 2  2 f1 f 2  C1  C2
8. (C)
Equation of common chord = S1  S 2  2 y  1  0
Equation of family of circles passing then common chord = S1  S 2  0
To find  , centre of circle will lie on 2 y  1  0
9. (D)
10. (C)
11. (B)
12. (D)
1  cos 2  2cos 2 
1  cos 2  2sin 2 
 2  2  2 cos 4
 2  2  2cos 2 2  2  2cos 2
  2  3 / 2  cos 2  0
 2  2cos 2  2 1  cos 2   2  2sin 2 
  3 
 2sin   2sin      
 2 4 
13. (B)
14. (B)
x = 8 is the only point in domain
15. (B)
Mirror image of 1,3 w.r.t x + y = 2
Lies on BC.
x 1 y  3  2
 
1 1 2
x  1  y  3  1
x  0, y  2
16. (A)
17. (D)
Eequation of family of circles.
 x    y  2   x  0
2 2
Passes then  1,0 

1 4    0
5
x2   y  2  5x  0
2
18. (D)
x y  z
cos 2 x  cos 2 y  cos 2 z  2 cos x cos y cos z.
cos 2 x  1  sin 2 y  cos 2 z  2cos x cos y cos z
cos  x  y  cos  x  y   cos 2 z  1  2cos x cos y cos z
cos z cos  x  y   2cos x cos y   cos 2 z  1
 cos z cos  x  y    cos 2 z  1
 cos 2 z  cos 2 z  1  1
19. (C)
2
f 2f 3f 11 f  f 2f 5f 
cos cos cos ......cos   cos cos .....cos 
11 11 11 11  11 11 11 
2
 f 2f 4f 8f 5f 
  cos .cos . .cos .cos 
 11 11 11 11 11 
2 2
 16 f   5f 5f 
 sin 11 5 f   2sin 11 cos 11  1
 f
cos   f  
 16sin 11   32sin  1024
 11   11 
20. (B)
1. (0)
2. (5)
3. (2)
4. (2)

Let      m  1
6

&    m
6

so,    
6
9 9
1
Here,  sec .sec   
m 1 m1 cos .cos 
9
sin      9
 2  2  tan   tan  
m 1 cos .cos  m 1
9
     
 2  tan    m   tan     m  1  
m 1   6  6 
  9   8
 2  tan      tan    2   cot   tan    
  6   3
4
 tan   cot  
3
1
 tan   or 3
3
5. (4)

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FIITJEE – JEE (Main)

Physics, Chemistry & Mathematics

Time Allotted: 3 Hours Maximum Marks: 300

B. Filling of OMR Sheet:

C. Marking Scheme for All Two Parts:

Name of the Candidate :___________________________________________________________________

Batch :__________________________________ Date of Examination :____________________________

Enrolment Number :_______________________________________________________________________

(1) (2) (3) (4)

(A) 1, 2, 3 (B) 1, 3 (C) 1, 2, 4 (D) 4

5. In the pulley – block system shown, find the accelerations of A, B

(A) RI = RII and is not equal to zero or F (B) RI = RII = F

14. Two blocks A and B of masses 2m and m, respectively, are connected by a

19. A ball weighing 1.0 kg is tied to a string 15 cm long. Initially

20. A block of mass m is attached with a massless spring of force

4. A particle P is projected from a point on the surface of smooth inclined plane

5. A rod AB is shown in figure. End A of the rod is fixed on

2. In the following reaction, MnO2  4 HCl 

11. Geometrical configuration of BF3 and NF3 molecules is

15. Which of the following will have maximum electron affinity?

19. Which has maximum ionization potential?

20. Following are the ionization potential values of

Numerical Based Type

point in common then the value of is

13. Area enclosed by x  y  1 is

(A) 7x + 3y – 4 =0 (B) 7x + 3y + 4 = 0 (C) 7x – 3y + 4 = 0 (D) 7x – 3y – 4 = 0

18. If x + y = z, then cos 2 x  cos 2 y  cos 2 z  2 cos x.cos y cos z is equal to

Numerical Based Type

1. The number of real solutions of the equation sin  e x   2 x  2 x is _______.

3. Number of integral solution of the equation x  1  x  2  7 is _______.

As horizontal component of velocity does not change,

Position of the particle after 3 sec, r  r0  vt

min   x  x    y  y   denote min distance of  x , y  from the given line.

So point  x1 , y1  will be foot of perpendicular from  x2 , y2  on the given line

Passes then  1,0 

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Batch :______ Date of Examination :