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Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
BATCH: LKTYR235A01
attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1.Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2.This question paper contains Three Sections.
3.Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4.Each section is further divided into Two Parts: Part-A & C in the OMR.
5.Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for rough work.
6.Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in any form, are not
allowed.
(ii) Part-A (05-10) – Contains six (06) multiple choice questions with partial marking, which have ONE or
MORE THEN ONE correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: 1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will result in +4 marks; darkening
only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in 1 marks, as a wrong option is also darkened.
(iii) Part-C (01-08) contains eight (08) Numerical based questions with Single Digit Integer, as answer, (Ranging from 0 to 9 both
inclusive). Each question carries +3 marks for correct answer and -1 marks for wrong answer.
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SECTION I
PHYSICS
Single Correct Type
This section contains four (04) multiple choice questions which have ONLY ONE CORRECT answer
(A) (B)
(C) (D)
(A) 35 g
(B) 17.5 g
(C) 70 g
(D) 14 g
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4. Two weights of mass are M and M connected by thread passing
2
over massless pulley. A small weight of mass m placed on mass M .
2
Reaction force on m is
4Mmg 4mg ( M m)
(A) (B)
(3M 2m) (3M 2m)
mg ( M m) 3mg ( M m)
(C) (D)
(3M 2m) (3M 2m)
6. If A vector is given by ɵi ɵj ɵ
k then
1
(A) angle of the vector with x-axis is cos 1
3
(B) projection on x-y plane is 2ɵi 3ɵj 4ɵ
k
2
(C) angel with ɵi ɵj is cos 1
3
(D) magnitude of the vector A is 3 unit
7. Two projectile are thrown simultaneously from same point at angle 1 & 2 from horizontal then
(A) The trajectory of one with respect to two is straight
(B) The trajectory of one with respect to two is parabola
(C) If v1 cos 1 v2 cos 2 then the particle may remain exactly bellow or above the other particle and
trajectory vertical straight line
(D) If v1 sin 1 v2 sin 2 the time of flight of both will be same
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9. A ball starts falling freely from a height h above a point on the inclined
plane forming an angle α with the horizontal as shown. After collision
with the incline it rebounds elastically off the plane. Then it again strikes
the incline at
8h
(A) t after it strikes the inclined at A.
g
2h
(B) t after it strikes the inclined at A.
g
(C) a distance 4h sin from A along the incline.
(D) a distance 8h sin from A along the incline.
PART – C
(Numerical Based)
This section contains eight (08) integer type questions. The answer to each question is a single digit integer,
ranging from 0 to 9 (both inclusive)
3. A particle moved along the x-axis from x = 0 to x = 1 m under the influence of a force given by
F 7 2 x 3 x 2 . Work done in the process is k J. Find the value of k.
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4. A block tied between two springs is in equilibrium. If upper spring is cut
then the acceleration of the block just after cut is 6 m/s2 downwards. Now,
if instead of upper spring, lower spring is being cut then the acceleration of
the block just after the cut will be ________ m/s2.
6. A peculiar force acting upon an object has the equation F cx3 where x is the displacement of the
object from some origin and c = 1N/m3. What is the magnitude of the work done by this force on the
object as the object moves from x 2m to x 2m ?
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SECTION II
CHEMISTRY
Single Correct Type
This section contains four (04) multiple choice questions which have ONLY ONE CORRECT answer
1. The percentage of copper in a copper (II) salt can be determined by using a thiosulphate titration.
0.254 gm of a copper (II) salt was dissolved in water and added to an excess of potassium iodide
solution liberating iodine according to the following equation
2Cu 2 (aq) 4I (aq) ⇌ 2CuI(s) I2 (aq)
The iodine liberated required 20 cm3 of a 0.100 mole dm 3 solution of sodium thiosulphate
2S2 O32 (aq) I2 (aq) 2I (aq) S4 O26 (aq) the percentage of copper, by mass in the copper (II) salt
is. [Atomic mass of copper = 63.5]
(A) 75 (B) 50 (C) 45 (D) 25
3. The system shown in diagram is at equilibrium at 27°C and volume of the bulb is 150 mL. At this
temperature the vapour pressure of water is 28 mm of Hg. If the bulb contains 0.001 mol of O2(g),
volume of liquid water is approximately: (R = 0.0821 L.atm.mole–1)
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One or More Than One Correct Type
This section contains six (06) multiple choice questions which have One or More correct answer
5. 100 g sample of clay (containing 19% H2O, 40% silica, and inert impurities as rest) is partially dried so
as to contain 10% H2O.
(A) The percentage of silica in it is 44.4%
(B) The mass of partially dried clay is 90.0 g
(C) The percentage of inert impurity in it is 45.6%
(D) The mass of water evaporated is 10 g
6. A gas obeys P(V - b) = RT. Which of the following is/are correct about this gas?
R
(A) Isochoric curves have slope =
V b
R
(B) Isobaric curves have slope and intercept ‘b’
P
Pb
(C) For the gas compressibility factor = 1
RT
(D) The repulsive forces are overcome by attractive forces
8. On dissolving moderate amount of alkali metal in liquid NH3 at low temperature. Which one of the
following does occur?
(A) Blue coloured solution is obtained
(B) Solvated electrons and solvated metal ions are formed
(C) Liquid NH3 becomes good conductor of electricity
(D) Liquid NH3 solution acts as oxidizing agent
10. Which of the following is/are correct, for the property written along with?
(A) Si < P < C < N : electronegativity
(B) S2– > Cl– > K+ > Ca2+ : ionic radius
(C) Na < Al < Si < Mg : first ionisation potential
(D) Cl2O7 > SO3 > P4O10 : acidic strength
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PART – C
(Numerical Based)
This section contains eight (08) integer type questions. The answer to each question is a single digit integer,
ranging from 0 to 9 (both inclusive)
1. The mole fraction of a solute in a solution is 0.2. At 298 K molarity of this solution is same as its
molality. Density of this solution at 298 K is 2 g/mL. The ratio of molecular weight of solute and
solvent MWsolute / MWsolvent is ____________.
2. RH2 (cation exchange resin) can replace Ca2+ in a sample of hard water as RH 2 Ca 2 RCa 2H
1L of such a hard water sample is passed through a cation exchange resin bed and the resultant
solution requires 20ml of 0.5 (M) NaOH solution for complete neutralization. Hardness of water is
102 ppm w.r.t. Ca2+, what is the value of ?
3. Among the triatomic molecules/ions, BeCl2 , N 3 , N 2O, NO2 , O3 , SCl2 , ICl2 , I 3 and XeF2 , the total
number of linear molecule(s)/ion(s) where the hybridization of the central atom does not have
contribution from the d-orbital(s) is _________ (Atomic number: S = 16, Cl = 17, I = 53 and Xe = 54)
4. An evacuated glass vessel weighs 50.0 gm when empty, 148.0 gm when filled with a liquid of density
0.98 g/ml and 50.5 g when filled with an ideal gas at 1 atm of ‘T K’. The molecular weight of gas is
found to be “XRT gm”. Find the value of X. [Where R is universal gas constant.]
5. Ratio of frequency of revolution of electron in second excited state of He+ and second state of H is
2x
x y is ___________.
3y
6. The magnitude of potential energy of electron in nth excited of He+ ion is 8/81 times the kinetic energy
of electron in the first excited state of Li 2 ion Find ‘n’.
7. Among the following compounds, the number of compounds that are thermally most stable than
MgCO3 are P, then the value of P is __________.
BaCO3 , CaCO3 , SrCO3 , BeCO3
8. Among H 2 , He2 , Li2 , B2 , C2 , N 2 , O2 and F2 , the number of diamagnetic species is __________
(Atomic numbers: H = 1, He = 2, Li = 3, B = 5, C = 6, N = 7, O = 8, F = 9)
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SECTION III
MATHEMATICS
Single Correct Type
This section contains four (04) multiple choice questions which have ONLY ONE CORRECT answer
1. The maximum value of cos 1 cos 2 ...... cos n , under the restrictions 0 1 , 2 , ........, n
2
and cot 1 cot 2 ....... cot n 1 is
1 1 1
(A) (B) (C) (D) 1
2n /2 2n 2n
3. The equations of the sides AB and AC of ABC, respectively are 2x – y = 0 and x + y = 3 and the
centroid G is (2, 3). Then, the slope of the side B C is
(A) 4 (B) 3 (C) 2 (D) 5
4. The range of values of for which the variable line 3x + 4y – = 0 lies between the circles
x 2 y 2 2 x 2 y 1 0 and x 2 y 2 18 x 2 y 78 0 without intercepting a chord on other circle is
(A) 21 (B) 12 21 (C) 21 (D) 15 25
5. Circle(s) touching x-axis at a distance 3 from the origin and having an intercept of length 2 7 on
y-axis is (are)
(A) x 2 y 2 6 x 8 y 9 0 (B) x 2 y 2 6 x 7 y 9 0
(C) x 2 y 2 6 x 8 y 9 0 (D) x 2 y 2 6 x 7 y 9 0
6. For a positive integer n, let f n tan 1 sec 1 sec 2 1 sec 4 ....... 1 sec 2n . Then
2
(A) f 2 1 (B) f 3 1 (C) f 4 1 (D) f 5 1
16 32 64 128
8. If and are roots of the equation ax 2 bx c 0 and , are roots of ax 2 bx c 0 and the
circle having A , and B , as diametric end points passes through the origin and the point
b b
, , then
a a
(A) ac ac 0 (B) ab ab 0 (C) bc bc 0 (D) a 2b2 a2b 2 0
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9. The combined equation three sides of a triangle is x 2 y 2 2 x 3 y 6 0 . If 2, a is an interior
point and (b, 1) is an exterior point of the triangle, then
10 10 9
(A) 2 a (B) 2 a (C) 1 b (D) 1 b 1
3 3 2
2x 1
10. If s is the set of all real x such that is positive, then s contains
2 x 3x 2 x
3
3 3 1 1 1 1
(A) , (B) , (C) , (D) , 3
2 2 4 4 2 2
PART – C
(Numerical Based)
This section contains eight (08) integer type questions. The answer to each question is a single digit integer,
ranging from 0 to 9 (both inclusive)
1. Two rays in the first quadrant x + y = |a| and ax – y = 1 intersect each other in the interval a a0 , ,
the value of a0 is __________.
2. Number of values of b for which in an acute ABC, if the coordinates of orthocenter H are (4, b),
centroid G are (b, 2b – 8) and circumcentre S are (–4, 8), is ________.
5. The acute angle between the line 3x – 4y = 5 and the circle x 2 y 2 4 x 2 y 4 0 is , then the
value of 9 cos is _________.
/2
4 cos x
6. The value of
0
cos x sin x
dx is ____________.
7. Let A = {1, 2, 3, 4}, B = {2, 4, 6}. Then the number of sets C such that A B C A B is
___________.
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FIITJEE – Phase Test (JEE-Advanced)
PHYSICS, CHEMISTRY & MATHEMATICS
(LKTYR235A01)
ANSWERS
Sl. No. Physics Sl. No. Chemistry Sl. No. Mathematics
1. A 1. B 1. A
2. A 2. B 2. A
3. A 3. B 3. D
4. A 4. C 4. B
5. AC 5. ABCD 5. AC
6. AC 6. ABC 6. ABCD
7. ACD 7. ABD 7. ABCD
8. ABD 8. ABC 8. AD
9. AD 9. ABC 9. AD
10. ABD 10. ABD 10. AD
1. 8 1. 4 1. 1
2. 8 2. 2 2. 0
3. 7 3. 4 3. 8
4. 4 4. 5 4. 6
5. 5 5. 8 5. 3
6. 0 6. 5 6. 1
7. 4 7. 3 7. 8
8. 4 8. 5 8. 6
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CONCEPT CODES
Sl. No. Physics Sl. No. Chemistry Sl. No. Mathematics
1. P110303 1. C111101 1. M111403
2. P110403 2. C111209 2. M111403
3. P110401 3. C111207 3. M110701
4. P110312 4. C110305 4. M110805
5. P110404 5. C110205 5. M110801
6. P110202 6. C111204 6. M111401
7. P110304 7. C110106 7. M110803
8. P110502 8. C110805 8. M110801
9. P110305 9. C111002 9. M110705
10. P110403 10. C110702 10. M110105
1. P110303 1. C110205 1. M110706
2. P110305 2. C111106 2. M110701
3. P110501 3. C110306 3. M110705
4. P110403 4. C111201 4. M110803
5. P110312 5. C110102 5. M110810
6. P110501 6. C110102 6. M120802
7. P110306 7. C110902 7. M120301
8. P110405 8. C110305 8. M110604
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Hints & Solutions
Solutions
Chemistry:
1. (B)
Meq of Cu2+ = Meq of I2 = Meq of Hypo.
= 20 × 0.1 = 2
Mass of Cu 2 2 10 3 63.5 0.127 g
0.127
% of Cu 2 100 50
0.254
2. (B)
VC 3b
V
b C
3
90
= 30 cc / mole
3
a
PC
27b 2
a PC 27 b 2
= 130 × 27 × (30)2
= 3.159 × 106
= 3.16 × 06 cc2 atm/mole2
3. (B)
Pressure of O2 in bulb = 161 – 28 = 133 mm of Hg
nRT 0.001 0.0821 300 760
volume 0.140 L 140 mL
P 133
volume of liquid H 2O 150 140 10 mL
4. (C)
BeSO4 soluble in H2O
CO+ paramagnetic
Correct
XeF6 has max. L.P. electrons.
5. (ABCD)
100 g sample of clay contains 19% H2O, 40% silica + 41% inert impurity
After partially dried sample contains 10% of water.
Let, now mass of H2O present is x g.
x
100 10
81 x
100 x
10
81 x
x=9g
Total mass = 81 + 9 = 90
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40
% Silica = 100 44.4
90
41
% of inert impurity = 100 45.6
90
The mass of H2O evaporated = 10 g
6. (ABC)
R
For isochoric curve P T
V b
y mx
For isobaric curve P V b RT
RT
V b
P
R
V T b
P
y mx c
7. (ABD)
(A) l = 0 for s-orbital
(B) The no. of peaks in radial distribution graphs = n – l
(C) Orbital angular momentum of 4s = 3s
(D) For ‘H’ atom energy depends on only ‘n’ value
8. (ABC)
(A) Alkali metals in liquid NH3 are dark blue in colour.
(B) Solvated metal ions & solvated electrons are formed.
(C) Solutions of NH3 acts as good conductor due to presence of solvated electrons
(D) Solution of metals in liquid NH3 are powerful reducing agent
9. (ABC)
Saline hydrides are ionic in nature.
10. (ABD)
Na < Al < Mg < Si : first ionization potential
1. (4)
Molality = Molarity
0.2 1000 0.2 1000 2
0.8 MA 0.8MA 0.2MB
MA = Mol. wt of solvent
MB = Mol wt of solute
0.8MA 0.2MB 0.8 MA 2 1.6MA
0.2 MB 1.6 MA 0.8MA
0.2 MB 0.8MA
MB 0.8
4
MA 0.2
2. (2)
Meq of NaOH required = 20 × 0.5 = 10
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Mass of Ca2+ in Milli grams = 10 × 20 = 200
200 mg of Ca2+ Present per litre water
Degree of hardness = 200
=2
3. (4)
BeCl2 – sp linear
N 3 – sp linear
N2O – sp linear
NO2 – sp linear
4. (5)
Mass of liquid = 148 – 50 = 98 g
98
Volume of liquid = 100 mL volume of vessel
0.98
Vessel of 100 mL contain ideal gas at 760 mm of Hg at TK
Mass of gas = 50.5 – 50 = 0.5 g
PV = nRT
760 100 0.5
RT
760 1000 M
M 10 0.5 RT 5 RT
x5
5. (8)
Vn
No. of revolutions =
2 rn
z
Vn
n
n2
rn
z
z z z2
No. of revolution 2 3
n n n
22
No. of revolutions of e in He 3
– 2+
3
2
1
No. of revolutions of e– in H 3
2
2 3 5
2 2 2
Ratio = 3 2 3
3 1 3
x+y=5+3=8
6. (5)
13.6 2 8 13.6
2
z 2 2 z2
n 81 n
13.6 2 8 13.6
2
2 2 2 32
n 81 2
n 36
2
n=6
i.e. 5th excited state.
Answer is 5
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7. (3)
BaCO3 , CaCO3 , SrCO3 are more stable than MgCO3
8. (5)
H 2 Li2C2 N 2 & F2 are diamagnetic
Mathematics:
1. (A)
n n n n
2. (A)
a sin x b 2 cos x cos d
d 4b 2 cos 2 a 2
d 2 a2
2
cos 2
4b
d 2 a2
cos
2b
3. (D)
Solving 2x – y = 0 and x + y = 3
we get A = (1, 2)
Equation of median through A
23
y2 x 1
1 2
x–y=–1
4. (B)
The given circle S1 : x 2 y 2 2 x 2 y 1 0
5. (AC)
Equation of circle can be written as
x 3 y 2 y 0
2
x2 y 2 6x y 9 0
Now, radius 7 9 16
2
2
9 9 16
4
2 64 8
equation is x 2 y 2 6 x 8 y 9 0
6. (ABCD)
tan
f n 1 sec 1 sec 2 ...... 1 sec 2n
2
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2 cos 2
2 1 sec 2 ........ 1 sec 2n
= tan
2 cos
= tan 1 sec 2 ........ 1 sec 2n
Proceeding in this way, we get, Fn tan 2n
F2 tan 1, F3 tan 1, F4 tan 1, F5 tan 1
16 4 32 4 64 4 128 4
7. (ABCD)
x2 y 2 8x 2 y 8 0
x 2 y 2 2 x 6 y 10 a 2 0
r1 r2 C1C2 r1 r2
C1 4, 1 and C2 1, 3
r1 16 1 8 3
r2 1 9 10 a 2 a
C1C2 9 16 5
3 a 5 3 a
a 2
a , 2 2,
8. (AD)
b c
We have, ;
a a
b c
;
a a
Equation of circle having AB as diameter is
x x y y 0
x 2 x y 2 y 0
b c b c
x2 x y2 y 0
a a a a
aa x 2 y 2 abx aby ac ac 0
b b
∵ It passes through origin is , .
a a
ac ac 0
b 2 b2 b b
and aa 2 2 ab ab 0
a a a a
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a 2 b 2 a 2 b 2 0
9. (AD)
Combined equations of the sides of the triangle is x 2 y 2 2 x 3 y 6 0
Separate equations of sides are
x y 0, x y 0 and 2 x 3 y 6 0
The point (–2, a) moves on the line x = – 2 and (b, 1) moves on the line y = 1
From the figure, the y-coordinates of the points of the intersection of x = –2 with y = –x and 2x + 3y =
6 give the range of values of a.
The x-coordinates of the points of intersection of y = 1 with y = – x and y = x give the range of values
of b.
10. ()
2x 1
0
x 2 x 2 3 x 1
1. (1)
Solving the two equations of ray i.e. x + y = |a| and ax – y = 1
a 1 a 1
We get x 0 and y 0 , when a + 1 > 0; we get a > 1
a 1 a 1
a0 = 1
2. (0)
4 b 1
We know that H.G and S are collinear b 2b 8 1 0
4 8 1
b 4 16 2b b 8 b 4 0
b 8 b 12 0
b = 8 or 12
8 4
But b
3
4
b
3
16 b
And 2b 8
3
b=8
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but no common value of b is possible.
3. (8)
c1 c2 d1 d 2
Area of parallelogram =
m1 m2
2
cd
Area of parallelogram formed by the first set of 4 lines 18 ……… (i)
a b
2
cd
and area of parallelogram formed by the second set of 4 lines 72 ……… (ii)
ab
By equations (i) and (ii),
c d a b 18
2
c d a b 72
2
∵ a, b, c, d N
RHS must be a perfect square for some least value of (a – b) which obviously can be equal to 2
|a – b| = 2
a = 1 and b = 3
c – d = 6 and c + d = 12
c = 9 and d = 3
a + b + c + d = 16
4. (6)
Here point P is the radical centre of these circles, on solving like S1 S 2 0 and S 2 S3 0 we get
point P(0, –3)
Given required circle passes through P and touches x + y = 5 at point (6, –1)
Given x 2 y 2 ax by 2c 0
a = – 7, b = 7
2c = 12 c = 6
a+b+c=6
5. (3)
∵ is the angle between the tangent and the line.
Circle with centre (2, –1) and radius = 3
Perpendicular from centre on 3x – 4y = 5 is
6 45
P 1
5
1
sin 90
3
1
cos
3
1
9 cos 9 3
3
6. (1)
/2
4 cos x
L
0
cos x sin x
/2 cos x /2
4 2 4 sin x
L
dx
0 cos x sin x
dx
0 cos x sin x
2 2
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4
/2
cos x sin x dx 2 L 2
2L =
0
cos x sin x
L=1
7. (8)
C = {2, 4}
C = {2, 4, 1}
C = {2, 4, 3}
C = {2, 4, 6}
C = {2, 4, 1, 3}
C = {2, 4, 1, 6}
C = {2, 4, 3, 6}
C = {2, 4, 1, 3, 6}
8. (6)
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