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FIITJEE – (JEE-Advanced)

PHYSICS, CHEMISTRY & MATHEMATICS

QP Code: 100027 RIT – 2


Time Allotted: 3 Hours Maximum Marks: 180

▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
BATCHES – C – XII

3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.


4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.
(i) PART – A (01 –06): This section contains SIX (06) questions. Each question has FOUR
options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: −2 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these
three will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening
(A) and (B) will result in −2 marks, as a wrong option is also darkened.
PART – A (07 –10): This section contains TWO (02) paragraphs. Based on each paragraph,
there are TWO (02) questions. Each question has FOUR options (A), (B), (C) and (D). ONLY
ONE of these four options is the correct answer. Each question carries +3 marks for correct
answer and -1 marks for wrong answer.
(ii) PART – B (01 – 03): This section contains THREE (03) questions. The answer to each question is a
NON-NEGATIVE INTEGER. Each question carries +4 marks for correct answer and there will
be no negative marking.
(iii) PART – B (07 – 12): This section contains SIX (06) questions stems. There are TWO (02) questions
corresponding to each question stem. The answer to each question is a NUMERICAL VALUE. If
the numerical value has more than two decimal places, truncate/round -off the value to TWO decimal
places. Each question carries +2 marks for correct answer and there will be no negative
marking.
Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
IT−2023 (RIT-1)-(PCM) 2

S
SEEC
CTTIIO
ONN –– II :: P
PHHY
YSSIIC
CSS
PART – A (Maximum Marks: 24)
This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four option(s) is (are) correct answer(s).

1. A curve between force and displacement is drawn for a


force
particle moving in x axis only conservative forces are
acting on particle
(A) At x1 & x3 particle in stable equilibrium x1 x2 x3 x4
(B) At x1 & x3 particle in unstable equilibrium
(C) At x2 & x4 particle in stable equilibrium
(D) At x2 & x4 particle in unstable equilibrium
150 N
2. For the situation shown in figure, choose the correct option(s)
(take g = 10 m/s2 downward)
5
(A) the acceleration of pulley is m/s2 upward.
6
5
(B) the acceleration of pulley is m/s2 upward.
12 6 kg
(C) the acceleration of pulley is 0.
(D) tension in the string which connects the masses is 75 N. 9 kg

3. A body of mass M was slowly hauled up the rough hill by a


force F which at each point was directed along a tangent to
the hill. Work done by the force
(A) is independent of shape of trajectory.
(B) depends upon vertical component of displacement but
independent of horizontal component.
(C) depends upon both horizontal and vertical components of
displacement from A to B.
(D) does not depend upon coefficient of friction.

4. An automobile of mass m accelerates, starting from rest, while the engine supplies
constant power P
1/ 2
(A) The velocity is given as a function of time by v 2Pt / m
1/ 2 3 / 2
(B) The position is given as a function of time by s 8P / 9m t
1/ 2
(C) The velocity is given as a function of time by v Pt / m
1/ 2 3 / 2
(D) The position is given as a function of time by s 4P / 9m t

Space For Rough Work

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5. Two men of unequal masses hold on to the two sections of


a light rope passing over a smooth light pulley. Which of
the following are possible
(A) The lighter man is stationary while the heavier man
slides with some acceleration
(B) The heavier man is stationary while the lighter man
climbs with some acceleration
(C) The two men slide with the same acceleration in the
same direction
(D) The two men slide with acceleration of the same
magnitude in opposite direction

m1 m2

6. Three blocks a, b, and c of masses 10 kg, 10 kg and 20 kg are


arranged as shown in figure. All the surfaces are frictionless b
and string is inextensible. Pulleys are light. A constant force c a F
F = 20 N is applied on block a as shown. Pulleys and string are
light. Part of the string connecting both pulleys is vertical and
part of the strings connecting pulleys with blocks a and b are
horizontal.
(A) Acceleration of blocks a, b and c is 0.5 m/s2.
(B) Acceleration of block b is 1.
(C) Tension in the string is 10 N.
(D) Acceleration of block c is 0.5

PART – A (Maximum Marks: 12)


This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.

Paragraph for Question Nos. 07 and 08

O A

One end of a light string of length L is connected to a
ball and the other end is connected to a fixed point O. 90–
The ball is released from rest at t = 0 with string
horizontal and just taut. The ball then moves in
vertical circular path as shown. Let the velocity of ball B
at B is v B and at C is vC respectively.
C
7. If v C = 2 vB then the value of  as shown is:
1 1 1 1
(A) cos−1 (B) sin−1 (C) cos−1 (D) sin−1
4 4 2 2

8. If v C = 2 vB then tension in the string at point B is:


3mg
(A) (B) mg
4
mg
(C) (D) none of these
2
Space For Rough Work

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Paragraph for Question Nos. 09 and 10

A ball of mass m = 1 kg is hung vertically by a thread of


length  = 1.50 m. Upper end of the thread is attached to the
ceiling of a trolley of mass M = 4 kg. Initially, the trolley is m
m M
stationary and it is free to move along horizontal rails without 0
friction.
A shell of mass m = 1 kg, moving horizontally with velocity
v0 = 6 m/s, collides with the ball and gets stuck with it. As a
result, the thread starts to defect towards right.

9. The velocity of the combined body (ball + shell) just after collision is
(A) 2 m/s (B) 3 m/s
(C) 1 m/s (D) 4 m/s

10. The maximum deflection of the thread with the vertical is


4 3
(A) cos−1   (B) cos−1  
5 5
2 3
(C) cos−1   (D) cos−1  
3 4

PART – B (Maximum Marks: 12)


This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER.

1. A uniform chain of length  and mass m overhangs a smooth table with its two third part
lying on the table. If the kinetic energy of the chain as it completely slips off the table is
8
mgl , then find the value of ‘x’.
x

x3 9x 2
2. Potential energy of a particle moving along x-axis is given by U = − + 20x . Find out
3 2
position of stable equilibrium state.

3. A block of mass 3 kg is resting on a horizontal plane (coefficient F

of static friction  = 1 2 3 ). A force F is applied to the block as 60

shown in the figure. The minimum magnitude of F (in Newton) for m=3kg

which the block begins to slide is _________. (Take: g = 10 m/s2 )

Space For Rough Work

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IT−2023 (RIT-1)-(PCM) 5

PART – B (Maximum Marks: 12)


This section contains THREE (03) question stems. There are TWO (02) questions corresponding to each
question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places.

Question Stem for Question Nos. 07 and 08

Two small balls ‘A’ and ‘B’ of masses 0.3 kg and 0.6 kg
respectively are rigidly attached to the ends of a light
R
rigid rod of length R 2 and placed inside a fixed smooth
spherical cavity of radius R = 0.5 m with the ball ‘B’ is A
located at the lowest point of cavity as shown in the R
R 2
figure. Immediately after the rod is released from rest.
The normal force on the ball ‘A’ due to surface of cavity
is X newton and the normal force on the ball ‘B’ due to B
surface of cavity is Y newton. (Take g= 10 m/s2)

7. The value of X is _________.

8. The value of Y is _________

Question Stem for Question Nos. 09 and 10

B
A bead B of mass m = 0.5 kg which can slide along a 
smooth horizontal rod is attached to one end of a light
inextensible string of length  = 1 m shown. The other end

‘A’ of the string is pulled with a constant speed v0 = 2 m/s
always directed along the length of the string. Then A
answer the following question.
v0
9. The velocity of the bead (in m/s) at  = 60° is _________.

10. The tension in the string (in Newton) at  = 60° is _________.

Question Stem for Question Nos. 11 and 12

A particle is moving in a conservative field and its potential energy is given as U = (6x –
8y)J, where x and y co-ordinates are in meters. Particle has initial velocity 2iˆ − 3ˆj m/s at ( )
 M 
origin. At t = 1 sec, the angel between velocity and acceleration of particle is cos−1  
5 2
 3
and when the particle crosses x axis, x =  −  m (Given: mass of the particle is 2 kg)
 N

11. The value of M is _________.

12. The value of N is _________.

Space For Rough Work

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IT−2023 (RIT-1)-(PCM) 6

S
SEEC
CTTIIO
ONN –– IIII :: C
CHHE
EMMIIS
STTR
RYY
PART – A (Maximum Marks: 24)
This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four option(s) is (are) correct answer(s).

1. Choose correct statement(s) regarding the characteristics of SF6?


(A) Sulphur undergoes sp3d2 hybridisation
(B) It’s dipole moment is zero
(C) In solid state it exists as [SF5]+ and [SF7]– ions
(D) The central atom contains two lone pairs

2. Choose correct statements regarding the characteristics of second period elements?


(A) Their properties(both physical and chemical) are quite different from their other group
members.
(B) The most electronegative element of the period has the smallest covalent radius.
(C) They form predominantly covalent compounds with hydrogen as compared to their
remaining group members
(D) Their atomic size increases from left to right along the period

3. Which of the properties of the s-block elements and their compounds is/are given in
correct order?
(A) Solubility in H2O: BeSO4 > MgSO4 > CaSO4 > SrSO4 > BaSO4
(B) Thermal stability of carbonates: BeCO3 < MgCO3 < CaCO3 < SrCO3 < BaCO3
(C) Basic strength of oxides: BeO < MgO < CaO < SrO < BaO
(D) Sum of I.E1 and I.E2:
I.E1 = First ionization energy
I.E2 = Second ionization energy
Be > Mg > Ca > Sr > Ba

4. Which of the following compound(s) are oxidized with H2O2 in acidic medium or neutral
medium?
(A) KI (B) PbS
(C) KNO3 (D) NaNO2

5. In which option, the left side species is easily formed(by supplying less energy) than the
right side species from neutral molecules or atoms?
(A) O2 , O (B) N, N2
(C) Li , Li2 (D) He2 , He

6. In which molecules, the electronegativity of sulphur will be higher than that in H2S?
(A) SO2 (B) SO3
(C) SF4 (D) SF2
Space For Rough Work

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PART – A (Maximum Marks: 12)


This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.

Paragraph for Question Nos. 07 and 08

BCl3 is a Lewis acid and ( CH3 )3 N is a Lewis base. When these two molecules combine with each
other an addition compound is formed, the structure of the product formed is
H3C Cl
H3C N B Cl
H3C Cl

Answer the following questions on the basis of above write up.

7. Which changes regarding the bond angle is correct?


(A) In the product the ClBCl bond angle is larger than that in the unreacted BCl3
molecule.
(B) In the product the CNC bond angle is larger than that in unreacted ( CH3 )3 N
molecule.
(C) Both the angles ClBCl and CNC are greater than that of their unreacted molecules.
(D) Both the angles ClBCl and CNC are smaller than that of their unreacted molecule.

8. The hybridization of which atom changes in the product from that was in the reactant?
(A) Carbon (B) Nitrogen
(C) Boron (D) Chlorine
Space For Rough Work

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Paragraph for Question Nos. 09 and 10

1:1) Product(s) 1
olar ratio =
CO 2(m )
r ratio = 2:1 Product(s) 2
CO 2(mola
NaOH Cl2
Product(s) 3
Al
P Product(s) 4
4

Product(s) 5

Answer the following questions on the basis of above reaction.

9. Which product(s) contain anhydrous sodium carbonate?


(A) Product(s)-1 (B) Product(s)-2
(C) Product(s)-3 (D) Product(s)-4

10. Which product(s) contain hydrogen gas?


(A) Product(s)-3 (B) Product(s)-4
(C) Product(s)-5 (D) Product(s)-2

PART – B (Maximum Marks: 12)


This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER.

1. In the vapour phase the Na – Cl distance of NaCl molecule is 2  10–10 m. What is it’s
dipole moment in Debye unit(Assume 1D = 3.2  10–30 C m)

2. AB is a covalent molecule. The covalent radii of A in A2 and that of B in B2 are respectively


12 and 14 pm. The electronegative difference between A and B is 2. What is the value of
A-B bond length in pm unit?

Cl2 (P) + (Q) + H2O


Cold
3. NaOH
Cl2
Hot (P) + (R) + H2O

If the molar mass of (Q) is expressed as (X – 5.5) g mol–1, what is (X)?

Space For Rough Work

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PART – B (Maximum Marks: 12)


This section contains THREE (03) question stems. There are TWO (02) questions corresponding to each
question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places.

Question Stem for Question Nos. 07 and 08

The atomic number of an atom is x. The colour of it’s diatomic molecule is due to electronic
transition between the highest occupied molecular orbital(HOMO) to the lowest unoccupied
molecular orbital(LUMO). The transition is * → * . If the  * orbital is completely filled and it’s
principal quantum number is 2, then y number of electrons are present in its all type of antibonding
molecular orbitals.

7. The value of x is

8. The value of y is

Question Stem for Question Nos. 09 and 10

Reaction of magnesium with air (O2 and N2)produces a solid residue containing x number of
compounds of magnesium. Reaction of the solid residue with water produces Mg(OH)2 and a gas
which molar mass is y g mol–1. The gas forms white fumes with HCl.

9. The value of x is

10. The value of y is

Question Stem for Question Nos. 11 and 12

Consider a part of period table that contains only normal elements. The properties of the elements
varies in regular manner along the period as well as the group.

A B C D E
P Q R S T
U V W X Y
M N O F G

T is an inert-gas. The element S has to lose x number of electrons in order to be isoelectronic with
the element Q. If the element of first row(A….E) belong to second period, the number of electrons
present in the outermost orbit of B is ‘y’

11. The value of x is

12. The value of y is

Space For Rough Work

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S
SEEC
CTTIIO
ONN –– IIIIII :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A (Maximum Marks: 24)
This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four option(s) is (are) correct answer(s).

If perpendicular tangents can be drawn from (5, k) to x + y − 2x − 4y − 5 = 0 then


2 2
1.
value of k is
(A) 6 (B) 4
(C) 0 (D) –2

2. The equation 2 x 2 − 3xy − py 2 + x + qy − 1 = 0 represents two mutually perpendicular lines if


(A) p = 2 (B) p = 3
(C) q = 2 (D) q = 3

 8ax 
3. It is given that x = 9 is a solution of the equation n x2 + 15a2 − n ( a − 2) = n 
a −2
(
, )
then
3
(A) a = 3 (B) a =
5
(C) other solution is x = 3 / 5 (D) other solution is x = 15

A line y = mx + 1 intersects the circle ( x + 3 ) + ( y + 2) = 25 at the point P and Q. If the


2 2
4.
3
midpoint of the line segment PQ has x – coordinate − , then which one of the following
5
options is correct?
(A) m = 1 (B) m = 2
(C) m = 3 (D) 6  m  8

5. If 24a−b = log7 ( 2401) and log4 ( 98a + 138b) = 5, then find the value of the product
(ab).
(A) a = 2 (B) a = 6
(C) ab = 12 (D) ab = 36

6. The equation of lines passing through point (2, 3) and having an intercept of length 2 units
between the lines 2x + y = 3 and 2x + y = 5 are
(A) y = 3 (B) x = 2
(C) y = x + 1 (D) 4y + 3x = 18
Space For Rough Work

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PART – A (Maximum Marks: 12)


This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.

Paragraph for Question Nos. 07 and 08

Circle x + y + 2x + 6y + 1 = 0 and x + y − 4x − 2y − 11 = 0 intersect at Q and R


2 2 2 2

7. Length of chord QR is
12 24
(A) (B)
5 5
6
(C) (D) None
5

8. Equation of circle passing through Q and R and also passing through (2, 1) is
(A) x2 + y2 − x + 2y − 5 = 0 (B) x2 + y2 − 4x − 2y = 0
(C) x2 + y2 − 4x − 2y − 4 = 0 (D) None

Paragraph for Question Nos. 09 and 10

If the lines represented by 2x2 − 5xy + 2y2 = 0 be the two sides of a parallelogram and
the line 5x + 2y = 1 be one of its diagonals.
On the basis of above information, answer the following questions:

9. The equation of the other diagonal is


(A) 10x − 11y = 0 (B) 11x − 10y = 0
(C) 3x − 2y = 0 (D) 2x − 3y = 0

10. The centroid of the parallelogram is


(A)  ,
5 11 
(B)  ,
11 5 
 72 36   72 36 

(C) 
5 11 
(D) 
11 5 
,  , 
 36 72   36 72 
Space For Rough Work

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PART – B (Maximum Marks: 12)


This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER.

3
1. The solution set of the system of equaitons log2 x + log2 y = log2 9 + 1, logx + y ( 27 ) = is (p,
2
q) then pq =

If largest value of x satisfying ( log 2 x )( log3 x ) = log3 x + log 2 x − 6 is p, then


3 2
2. p is

3. Consider the circle x2 + y2 = 9 . Tangents from P (4, 3) meet the circle at Q and R.
Then the mid-point of the chord QR is (a, b) then 25(a + b) =

PART – B (Maximum Marks: 12)


This section contains THREE (03) question stems. There are TWO (02) questions corresponding to each
question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places.

Question Stem for Question Nos. 07 and 08

Let circle C1 : x 2 + ( y − 4 ) = 12 intersects circle C2 : ( x − 3 ) + y 2 = 13 at A and B.


2 2

A quadrilateral ACBD is formed by tangents at A and B to both circles.

7. Find the diameter of circumcircle of quadrilateral ACBD. _________

8. Square of area of quadrilateral ACBD is equal to __________

Question Stem for Question Nos. 09 and 10

Consider the line L1 : 3x − 4y + 1 = 0 and L2  5x −12 y −1 = 0 Image of A  2, 3 


 2
under L1 is B and image of B under L2 is C.

9. If the x -coordinate of circumcenter of ABC is k then |k| = ________

10. Square of radius of circum circle of ABC is ________

Question Stem for Question Nos. 11 and 12

Let x 2 + y 2  4x + 3 = 0 be two circles. A triangle ABC has vertices A (0, 2),

( ) ( )
B 2, 3 + 2 , C −2, 2 3 + 2 . It starts moving downwards (i.e. In the negative direction
of y – axis) and stops when its sides touch the circles (AB at P1 and AC at P2 ) then

11. The ratio in which P1 divides new positions of A and B, is , then a + b = ________

12. The ordinate of the new position of vertex A of the triangle ABC, is , then a + b =
_________

Space For Rough Work

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Batches : C – XII
RIT – 2

QP Code: 100027

ANSWERS
S
SEEC
CTTIIO
ONN--1
1 :: P
PHHY
YSSIIC
CSS
PART – A
1. BC 2. BD 3. AC 4. AB
5. ABD 6. BC 7. B 8. A
9. B 10. A
PART – B
1. 18 2. 5 3. 20

7. 2.00 8. 8.00 9. 4.00 10. 24.00


11. 7.00 12. 8.00

S
SEEC
CTTIIO
ONN –– 2
2 :: C
CHHE
EMMIIS
STTR
RYY
PART – A
1. AB 2. ABC 3. ABCD 4. ABD
5. ABCD 6. ABCD 7. B 8. C
9. B 10. B
PART – B
1. 10 2. 8 3. 80

7. 9.00 8. 8.00 9. 2.00 10. 17.00


11. 2.00 12. 5.00

S
SEEC
CTTIIO
ONN –– 3
3 :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
1. BC 2. AD 3. AD 4. BC
5. AC 6. BD 7. B 8. A
9. B 10. C
PART – B
1. 18.00 2. 3.00 3. 63.00

7. 5.00 8. 156.00 9. 1.00 10. 13.00


11. 7.00 12. 5.00

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