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FIITJEE –Phase Test (JEE-Advanced)


PHYSICS, CHEMISTRY & MATHEMATICS
BATCH – ABC LOT NAO PAPER-2123 (PHASE5)

Pattern - CPT-2 QP CODE: PAPER - 2


Time Allotted: 3 Hours Maximum Marks: 186

 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.

1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Two Part.


(i) PART–A (01–08) contains (8) Multiple Choice Questions which have One or More Correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: 1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will result
in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in 1
marks, as a wrong option is also darkened.
(ii) Part-A (09-12) – This section contains Two (02) List-Match Sets, each List-Match set has Two (02) Multiple
Choice Questions. Each List-Match set has two lists: List-I and List-II. FOUR options are given in each
Multiple Choice Question based On List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question. Each question carries +3 Marks for correct combination
chosen and 1 marks for wrong options chosen.
(iii) Part-B (01-06) contains six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +3
marks for correct answer. There is no negative marking.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-2

SECTION – I : PHYSICS
PART – A: (Multiple Correct Answers Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

1. 10C of charge is given to a conducting spherical shell and another– 3C point charge is placed inside
the shell. For this arrangement mark out the correct statement(s).
(A) The charge on the inner surface of the shell will be +3C and it can be distributed uniformly or non
uniformly
(B) The charge on the inner surface of the shell will be +3C and its distribution would be uniform
(C) The net charge on outer surface of the shell will be +7 C and its distribution can be uniform or non
uniform
(D) The net charge on outer surface of the shell will be +7C and its distribution would be uniform

2. Nine similar resistors of resistance R are connected across edge of


triangular pyramid as shown in the figure. A
3
(A) Equivalent resistance between points A and B is R
5
4
(B) Equivalent resistance between points A and B is R B
3
9
(C) Equivalent resistance between points B and C is R
5
C
8
(D) Equivalent resistance between points B and C is R
15

3. Electric charge +q is uniformly distributed over the entire length of a ring of radius r rotating with
constant angular velocity  about its own axis. Assuming mass of ring to be m, its magnetic moment
to be M and angular momentum to be L.
q r 2 2qr 2
(A) M ý (B) M ý
2 5
M q M 2q
(C) ý (D) ý
L 2m L m

Space for rough work


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CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-3

4. In the L–R circuit shown in the figure, the key K is closed at time t = 0. L
(A) the current through R1 decreases with time, t
(B) the drop across L increases with t
R1 R2
1 E2 E
(C) the magnetic energy stored, in the steady state, equals L 2
2 R2 K

E E
(D) the total current through the battery is, in the steady state, 
R1 R 2

5. A point object O is moving with velocity 20ö2 m/s and a plane mirror is 10 m/s
also moving with a velocity 10 m/s as shown in the figure. Then 20ö2
(A) the separation between the image and the mirror increases
(B) the separation between the image and the mirror decreases
(C) the velocity of image with respect to ground is 20 m/s and parallel to 45Ā
the mirror. O
(D) the velocity of image with respect to ground is 40 m/s and parallel to the mirror.

6. In the Young9s double slit experiment, the interference pattern is found to have an intensity ratio
between the bright and dark fringes as 9. This implies that
(A) the intensities at the screen due to the two slits are 5 units and 4 units respectively.
(B) the intensities at the screen due to the two slits are 4 units and 1 unit respectively.
(C) the amplitude ratio is 3.
(D) the amplitude ratio is 2.

7. In a photoelectric experiment anode potential is plotted against plate I


current. Then which of the following is INCORRECT. C B
(A) A and B will have different intensities while B and C will have different A
frequencies.
V
(B) B and C will have different intensities while A and C will have different
frequencies.
(C) A and B will have different intensities while A and C will have equal frequencies.
(D) A and B will have equal intensities while B and C will have different frequencies

8. If the accelerating potential in an X-ray tube is increased, then the wavelengths of the characteristic
X-rays may changes. Then which of the following is INCORRECT.
(A) first increases then decreases. (B) will increases
(C) will decreases (D) remains constant

Space for rough work


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-4

PART – A: (Matrix-Match Type)


This section contains TWO (02) List-Match Sets. Each List-Match set has TWO (02) Multiple Choice
Questions. Each List-Match set has two lists: List-I and List-II. List-I has Four entries (I), (II), (III) and (IV)
and List-II has Six entries (P), (Q), (R), (S), (T) and (U). FOUR options are given in each Multiple Choice
Question based On List-I and List-II and ONLY ONE of these four options satisfies the condition asked in the
Multiple Choice Question.

Answer the following by appropriately matching the list based on the information given in the
paragraph
Four YDSE experiment 1, 2, 3 and 4 are performed using single monochromatic light of wavelength 
with separation between the slits d, 2d, 3d and 4d respectively. The separation between the slits and
screen is varying from D and 24 D. It is found that in experiment-I. Separation between slits is d,
separation between slits and screen is D, fringe width is ò and intensity at point P on the screen at
D
distance of x ý from central maxima is I0. Wavelength of light () and position of point P(x) from
d
central maxima in every experiment are same. List-I gives separation between slits while List-II lists
the magnitude of some quantity.
List – I List – II
(I) YDSE-1(d) (P) 1
(II) YDSE-2(2d) (Q) 1/4
(III) YDSE-3(3d) (R) 1/3
(IV) YDSE-4(4d) (S) 1/2
(T) 3/4
(U) 2/3

9. If the separation between slit and screen is D, then correct match for fringe width in terms of ò is
Options
(A) I þ P, II þ S, III þ R, IV þ Q
(B) I þ P, II þ R, III þ S, IV þ T
(C) I þ P, II þ R, III þ Q, IV þ T
(D) I þ P, II þ R, III þ S, IV þ U

10. If the separation between slits and screen for experiment 1,2, 3 and 4 are kept fixed at D, 6D, 12D
and 24D respectively. Intensity at P on screen at a distance x from central maxima in terms of I 0 is
Options
(A) I þ P, II þ Q, III þ S, IV þ U
(B) I þ P, II þ U, III þ S, IV þ T
(C) I þ P, II þ Q, III þ T, IV þ S
(D) I þ P, II þ Q, III þ S, IV þ T

Space for rough work


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-5

Answer the following by appropriately matching the list based on the information given in the
paragraph
E1, E2, E3, E4, E5 are five circuit elements such that E1, E2, E3
E1
and E4 are of same nature (resistive or capacitive) and E2 = nE1
corresponding E5 is capacitive or resistive respectively for a E5
given experiment. Four value of n(= 1, 2, 3, 4) give rise to four E3 = nE4 E4 n: positive
possible circuits: Circuit-1 (n = 1), circuit -2(n = 2), circuit -3(n = integer
3) and circuit -4 (n = 4). List I gives the possible four circuit and
List II gives some numbers.
V0
.
List-I List-II
4
(I) Circuit-1 (P)
3
3
(II) Circuit-2 (Q)
2
(III) Circuit-3 (R) 1
5
(IV) Circuit-4 (S)
2
8
(T)
5
(U) 2

11. If E1 = E4 = R0 (resistive) and E5 = C0(capacitive), then the correct match for the time constant of the
voltage acorss the capacitor, as a factor of R0C0, is:
Options
(A) I þ R, II þ Q, III þ T, IV þ P
(B) I þ S, II þ P, III þ R, IV þ T
(C) I þ P, II þ Q, III þ R, IV þ S
(D) I þ R, II þ P, III þ Q, IV þ T

12. If E1 = E4 = C0 (capacitive) and E5 = R0 (resistive), then the correct match for the time constant of the
voltage across the resistor, as a factor of R0C0, is:
Options
(A) I þ R, II þ Q, III þ U, IV þ S
(B) I þ S, II þ P, III þ R, IV þ U
(C) I þ R, II þ P, III þ Q, IV þ T
(D) I þ P, II þ Q, III þ R, IV þ S

Space for rough work


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-6

PART – B: (Integer Answer Type)


This section contains 06 questions. Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4
marks for correct answer and there will be no negative marking.

1. Find the potential difference (in Volts) between points A


and B shown in the circuit.

2. There is an infinite long straight surface having width 8a9. A point charge q is õ
3
placed at a perpendicular distance a from the surface symmetrically as
2
shown in the figure. If the flux linked with this infinitely long surface due to a
q
charge q is . Then find the value of k.
kõ0
q

3
a
2

Space for rough work


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CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-7

3. ø ù
A charged particle is projected in a magnetic field B ý xiˆ  4jˆ 102 T . The acceleration of the particle

ö 8 ˆ ˆö
is found to be a a ý ÷ i  2j ÷ m / s2 . Find the value of x.
ø3 ø

4. A cylindrical uniform rod of mass 0.72 kg and radius 6 cm rests on two B


parallel rails, that are d = 50 cm apart. The rod caries a current I = 48A L
(In the direction shown) and rolls along the rails without slipping. If it
d
starts from rest due to applications of uniform magnetic field of i
magnitudes 0.25 T (directed perpendicular to the rod and the rail), then L
the friction force(In N) between rod and rails is

5. An electromagnetic wave with intensity 5 W/m2 is absorbed by a surface of area A. If the force on the
surface is 107 N, then A is (in m2) ………………..

6. If the peak value of current through inductor (L), capacitor (C) and resistor (R) in parallel A.C. circuit
are 2mA, 3 mA and 5 mA respectively. The peak value of current delivered by the source in the same
circuit is 13k mA. Find the value of K.

Space for rough work


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-8

S
SEEC
CTTIIO
ONN –– IIII :: C
CHHE
EMMIIS
STTR
RYY
PART – A: (Multiple Correct Answers Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

1. Which of the following compounds have the oxidation number of the metals as +1?
(A) CuSCN (B) K3[Cu(CN)4]
(C) [Fe(H2O)5NO]SO4 (D) Cu2O

2. Which of the following will undergo aldol condensation?


(A) acetaldehyde (B) propanaldehyde
(C) benzaldehyde (D) trideutro acetaldehyde

3. For the reduction of NO3 ion in an aqueous solution, E0 is +0.96 V. Values of E0 for some metal ions
are given below
V2+ øaqù + 2e- þ V E0 = -1.19 V ; Fe3+ øaqù + 3e- þ Fe E0 = -0.04 V
Au3+ øaqù + 3e- þ Au E0 = +1.40 V ; Hg2+ øaqù + 2e- þ Hg E0 = +0.86 V
The pair(s) of metals that is(are) oxidized by NO3 in aqueous solution is(are)
(A) V and Hg (B) Hg and Fe
(C) Fe and Au (D) Fe and V

4. The correct statement(s) regarding defects in solids is(are)


(A) Frenkel defect is usually favoured by a very small difference in the sizes of cation and anion
(B) Frenkel defect is a dislocation defect
(C) Trapping of an electron in the lattice leads to the formation of F-center
(D)Schottky defects have no effect on the physical properties of solids

5. Extraction of copper from copper pyrite (CuFeS2) involves


(A) crushing followed by concentration of the ore by froth flotation
(B) removal of iron as slag
(C) self-reduction step to produce 8blister copper9 following evolution of SO2
(D)refining of 8blister copper9 by carbon reduction

6. Mixture (s) showing positive deviation from Raoult9s law at 35ĀC is (are)
(A) carbon tetrachloride + methanol (B) carbon disulphide + acetone
(C) benzene + toluene (D) phenol + aniline

7. The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are)
(A) Adsorption is always exothermic
(B) Physisorption may transform into chemisorption at high temperature
(C) Physiosorption increases with increasing temperature but chemisorption decreases with
increasing temperature
(D)Chemisorption is more exothermic than physisorption, however it is very slow due to higher energy
of activation

8. Which one of the following is NOT employed as a tranquilizer?


(A) Naproxen (B) Tetracycline
(C) Chlorpheniramine (D) Equanil

Space for rough work


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-9

PART – A: (Matrix-Match Type)


This section contains TWO (02) List-Match Sets. Each List-Match set has TWO (02) Multiple Choice
Questions. Each List-Match set has two lists: List-I and List-II. List-I has Four entries (I), (II), (III) and (IV)
and List-II has Six entries (P), (Q), (R), (S), (T) and (U). FOUR options are given in each Multiple Choice
Question based On List-I and List-II and ONLY ONE of these four options satisfies the condition asked in the
Multiple Choice Question.

Answer the following by appropriately matching the lists based on the information given in the
paragraph

List-I includes starting materials and reagents of selected chemical reactions. List-II gives structures of
compounds that may be formed as intermediate products and/or final products from the reactions of List-I.

LIST–I LIST–II
(I) (P)
CN CHO
i)DIBAL  H
O þ ii) dil. HCl
iii) NaBH 4
iv) conc. H 2SO 4 CO 2 H
O
(II) (Q) OH
i) O3
þ
ii) Zn, H 2 O
iii) NaBH 4
iv) conc. H 2SO4 OH
CO 2 H
(III) (R)
Cl i) KCN
ii) H3O , 
þ
iii) LiAlH 4
iv) conc. H 2SO4 O
CO 2 CH 3
(IV) CO 2Me (S) OH
þi) LiAlH 4
ii) conc. H 2SO 4
CO 2Me
CO 2 H
(T)
CO 2 H

CO 2 H
(U)

9. Which of the following options has the correct combination considering List-I and List-II?
Options
(A) (II), (P), (S), (T) (B) (II), (P), (S), (U)
(C) (I), (S), (Q), (R) (D) (I), (Q), (T), (U)

10. Which of the following options has the correct combination considering List-I and List-II?
Options
(A) (IV), (Q), (U) (B) (IV), (Q), (R)
(C) (III), (S), (R) (D) (III), (T), (U)

Space for rough work


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-10

Answer the following by appropriately matching the lists based on the information given in the
paragraph

Match the correct oxidation state(s) with the underlined element in the given compounds.
List – I List – II
(Compound) (Oxidation State)
(I) CrO5 (P) 2
(II) H2SO5 (Q) +6
(III) Na2S2O3 (R) 0
(IV) CaOCl2 (S) +1
(T) +10
(U) 1

11. Which of the following options has the correct combination considering List-I and List-II?
Options
(A) (IV), (S), (U) (B) (II), (P), (S)
(C) (I), (S), (Q) (D) (I), (Q), (T)

12. Which of the following options has the correct combination considering List-I and List-II?
Options
(A) (IV), (Q), (U) (B) (IV), (Q), (R)
(C) (III), (P), (Q) (D) (III), (T), (U)

PART – B: (Integer Answer Type)


This section contains 06 questions. Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4
marks for correct answer and there will be no negative marking.

1. What will be the oxidation state of Cr in complex [Cr(C6H6)2]?

2.

ø excessù þ ø x ù 
ø excessù þ ø y ùunstable 

NBS KOH/H2 O
þ z.

The sp2-hybridised carbon atoms present in one molecule of the end product z is:

3. How many equivalents of HCHO are formed by oxidative cleavage of one equivalent of
D-glucose by excess of HIO4 in water?

Space for rough work


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CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-11

4. The number of hydroxyl group (s) is Q is

þ ø P ù  þ øQù

H 
H

aq. dilute
KMnO ø excess ù , 00 C
4

HO
H3C CH3

5. A compound AB has a rock salt structure with A : B = 1 : 1. The formula weight of AB is


6.023 Y amu. And the closest distance between A and B is Y1/3 nm. The observed density of the
lattice in kg/m³ is:

6. What is the molality of solution consisting of 33.0 mL of benzene (C6H6;d = 0.877g mL– 1) in
187 mL of hexane (C6H14; d = 0.660 g ml – 1)?

Space for rough work


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-12

S
SEEC
CTTIIO
ONN –– IIIIII :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A: (Multi Correct Answer Type)

This section contains 08 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

1. If AB = A and BA = B, then
(A) A2 = A (B) B2 = B
(C) A = I (D) B = I

ü1 , i j ý1
ÿ
2. Let Rn ý bij be a determinant such that bij ý ý3 , i  j ý 0 , then n  N
nôn
ÿ0 , otherwise
þ
(A) R2019 + R2017 = 3R2018 (B) R2019 + R2017 = 9R2018
(C) The value of R4 is 54 (D) R5 is multiple of 9

3. The area bounded between the curves x 2 = y and y2 = x is equal to


(A) area of the region {x, y): x 2 ó y ó |x|} (B) 1/3
1

ø ù
(C) 2 x  x 2 dx (D) none of these
0

dy 6x 2
4. Given the differential equation ý ; y(1) = ð and the following statements
dx 2y  cos y
(A) solution is y2 – siny = – 2x3 + c (B) solution is y2 + siny = 2x 3 + c
(C) c = ð – 2
2
(D) c = ð2 + 2

Space for rough work


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CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-13

5. If a, b, c are non-coplanar unit vectors also b, c are non-collinear and 2a ô ø b ô c ù ý b  c , then


(A) angle between a and c is 60Ā (B) angle between b and c is 30Ā
(C) angle between a and b is 120Ā (D) b is perpendicular to c

x  2 y  2 z  k2  1 x y z
6. If the line ý ý is one of the angle bisector of the lines ý ý and
1 1 4 1 2 3
x y z
ý ý , then the value of k is / are
2 3 1
(A) – 3 (B) 2
(C) 3 (D) – 2

1 1 2
7. Let X and Y be two events such that P(X) = , P(X|Y) = and P(Y|X) = . Then
3 2 5
1 1
(A) P(Xò|Y) = (B) P(X ÷ Y) =
2 5
2 4
(C) P(X ø Y) = (D) P(Y) =
5 15

98 k 1
k 1
8. If I = õ x ø x  1ù
dx , then
k ý1 k
(A) I > loge99 (B) I < loge99
49 49
(C) I < (D) I >
50 50

Space for rough work


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-14

PART – A: (Matrix-Match Type)


This section contains TWO (02) List-Match Sets. Each List-Match set has TWO (02) Multiple Choice
Questions. Each List-Match set has two lists: List-I and List-II. List-I has Four entries (I), (II), (III) and (IV)
and List-II has Six entries (P), (Q), (R), (S), (T) and (U). FOUR options are given in each Multiple Choice
Question based On List-I and List-II and ONLY ONE of these four options satisfies the condition asked in the
Multiple Choice Question.

Answer the following by appropriately matching the lists based on the information given in the
paragraph
Consider lines L1 : y = ax, z = c ; L2 : y = –ax, z = –c and L3 : y = z, ax = –c (where a  b  c). Let L be
a variable line which intersects the given lines.
List-I and List-II contain statements about L and some and certain ordered triplets of numbers.
List – I List – II
(I) Locus of L passes through point P then P is (P) (a , 1, –c2)
2

Locus of L is k1x – y + k2z + k3 = 0, then


2 2 2
(II) (Q) (0, 0, c)
(k1, k2, k3) is
Locus L intersects the xz-plane in locus Lò which
ö 2c ö
(III) is an ellipse with major axis ñ, minor axis ò, (R) ÷ a , 1, 0 ÷
centre as (ñ1, ò1) then (ñ, ò, ñ1 + ò1) is (a2 > 1) ø ø
Locus L intersects the xy-plane in hyperbola with
transverse axis ñò, conjugate is òò, centre as ö 2c ö
(IV) ö c2 ö (S) ÷ 2c, a , 0 ÷
ø ù ø ù
ñ1, ò1 where ñò, òò, ñ1 ò1 is ÷ 2 þ 1÷
' ' ' ' ø ø
ø a ø
öc ö
(T) ÷ a , 0, 0 ÷
ø ø
The locus of L and the xy
(U) plane intersect in a
hyperbola

9. Which of the following is the only CORRECT combination?


A. (I), (Q), (T) B. (II), (P), (T)
C. (III), (S), (R) D. (IV), (Q), (U)

10. Which of the following is the only CORRECT combination?


A. (I), (Q), (R) B. (II), (P), (U)
C. (III), (S), (R) D. (IV), (Q), (R)

Space for rough work


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-15

Answer the following by appropriately matching the lists based on the information given in the
paragraph
Let f(x) = sin(ð cosx) and g(x) = cos(2ð sinx) be two functions defined for x > 0. Define the following
sets whose elements are written in the increasing order:
X = {x : f(x) = 0}, Y = {x : fò(x) = 0},
Z = {x : g(x) = 0}, W = {x : gò(x) = 0}
List – I contains the set X, Y, Z and W. List – II contains some information regarding these sets.
List – I List – II

(I) X 
(P)  ,
ð 3ð
2 2 
, 4ð, 7ð

(II) Y (Q) an arithmetic progression


(III) Z (R) NOT an arithmetic progression

(IV) W  ð 7ð 13ð
(S)  , ,
6 6 6

 
(T)  ,
ð 2ð
3 3

 
(U)  ,
ð 3ð
6 4

11. Which of the following is the only CORRECT combination?


A. (II), (R), (S) B. (I), (Q), (U)
C. (II), (Q), (T) D. (I), (P), (R)

12. Which of the following is the only CORRECT combination?


A. (IV), (P), (R), (S) B. (III), (P), (Q), (U)
C. (IV), (Q), (T) D. (III), (R), (U)

Space for rough work


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-16

PART – B: (Integer Answer Type)


This section contains 06 questions. Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +3
marks for correct answer and there will be no negative marking.

ùO I ù
1. If, z ý ú ú , where O, I are 2 ô 2 null and identity matrix respectively, where p = det(det (z)) then,
û I Oû
|p| is _____

2. Let the unit vectors a, b, c be the position vectors of the vertices of a triangle ABC. If F is the position
vector of the mid point of the line segment joining its orthocentre and centroid then
ø a  F ù2  øb  F ù2  ø c  F ù2 = _________

x 1 y z
3. The lines ý ý and x – y + z – 2 = 0 = x  3z  5 are coplanar for ,
2 1 2
7
then = __________
31

4. A bag contains 4 red and 6 black balls. A ball is drawn at random from the bag, its colour is observed
and this ball along with two additional balls of the same colour are returned to the bag. If now a ball is
drawn at random from the bag, then the probability that this drawn ball is red, is _________

5. Three numbers are chosen at random without replacement from {1, 2, 3, … 8}. The probability that
their minimum is 3, given that their maximum is 6, is _________

öðö
6. Let f : R þ R be a differentiable function such that f (0) = 0, f ÷ ÷ = 3 and f ò(0) = 1. If
ø2ø
ð /2
ö ðù
gø x ù ý  û f ò ø t ù cosec t  cot t cosec t f ø t ùý dt for x  ÷ 0 , ú , then lim g ø x ù is equal to _______
ø 2û x þ0
x

Space for rough work


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-17

FIITJEE INTERNAL TEST


PHYSICS, CHEMISTRY & MATHEMATICS
CPT–2 QP CODE: PAPER–2

ANSWERS
PHYSICS (SECTION –I)
PART– A
1. A, D 2. A, D 3. A, C 4. C, D
5. B, C 6. B, D 7. B, C, D 8. A, B, C
9. A 10. D 11. D 12. A
PART – C
1. 6 2. 6 3. 3 4. 2
5. 6 6. 2

CHEMISTRY (SECTION –II)


PART – A
1. A, B, C, D 2. A, B, D 3. A, B, D 4. B, C
5. A, B, C 6. A, B 7. A, B, D 8. A, B, C
9. B 10. B 11. A 12. C
PARTB
1. 0 2. 8 3. 1 4. 4
5. 5 6. 3

MATHEMATICS (SECTION –III)


PART – A
1. A, B 2. A, D 3. A, B, C 4. B, C
5. A, C 6. A, C 7. A, D 8. B, D
9. A 10. B 11. C 12. A
PART – B
1. 1.00 2. 3.00 3. 1.00 4. 0.40
5. 0.20 6. 2.00
Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-18

SOLUTION
PHYSICS

PART – A

1. 3C inside not at center (not fitted)

2. VP = VQ
R1 Q
Neglect R3 A
VR = VC R3 R4
R2
Neglect R9
R6
(R2, R5, R7) and (R1, R4, R8) sets are in series P R
1 1 1 1 5
ý   ý B R5
Req 3R 3R R 3R R8
R7
3R
R AB ý  C
5

q 2ð
3. Iý T=
T 
q


L = I
L = mr2
M qr 2
ý
L 2mr 2 
M q
ý
L 2m
q qr 2
M = IA = ô ðr 2 ý
2ð 2

i0 L
4. i ý i0 et/  ý t/ 
, tý, iÿ
e
I E E R1 R2
ý  E
R R1 R2
K
2
1 1 ö E ö 1 E2
U ý LI22 ý L ÷ ÷ ý L 2
2 2 ø R2 ø 2 R2

5. Image and mirror have relative velocity (VI = 0, Vm = 10 m/s) 10 m/s


VI = 2Vm  V0) for perpendicular 20 m/s
VI = 2 ô 10  20 = 0
Image only have velocity parallel to mirror

O 20 m/s

2
ö I1 ö
÷  1÷
9 (x  1)2 ÷ I2 ÷
6.
Imax
ý ý  ø ø
Imin 1 (x  1)2
ö I1 ö
2

÷÷  1÷÷
ø I2 ø
I1 x 1
ýx, ý3
I2 x 1
I1
ý 2 , x + 1 = 3x 3
I2
Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-19

I1
ý 4 , 2x = 4  x = 2
I2
I õ A2
Aõ I
A1 2
ý
A2 1

7. If maximum current increases only when intensity increases stopping potential depends on frequency
of liquid.

8. x Ray depends on target material do not depend on v acc.

D
9. Fringe width ò ý
d
D
For YDSE -1; ò1 ý ýò
d
D ò
For YDSE -2; ò2 ý ý
2d 2
D ò
For YDSE -3; ò3 ý ý
3d 3
D ò
For YDSE -4; ò4 ý ý
4d 4

d1
10. For experiment -1, path difference x1 ý x
D1
d D
x1 ý ý
D d

 Phase difference ö1 ý ÷  ý 2ð

ö1
I1 ý I0 cos2 ý I0
2
d2
For experiment -2, path difference x 2 ý x
D2
2d D 
x 2 ý ý
6D d 3
2ð  2ð
 Phase difference ö2 ý ÷ ý
 3 3
ö2 I0
I2 ý I0 cos2 ý
2 4
d3
For experiment -3, path difference x 3 ý x
D3
3d D 
x 3 ý ý
12D d 4
2ð  ð
 Phase difference ö3 ý ÷ ý
 4 2
ö3 I0
I3 ý I0 cos2 ý
2 2
d4
For experiment -4, path difference x 4 ý x
D4
4d D 
x 4 ý ý
24D d 6
2ð  ð
 Phase difference ö4 ý ÷ ý
 6 3
Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-20

ö4 3I0
I4 ý I0 cos2 ý
2 4

11. Find time constant by shorting the battery finding Reff across C0. Then  = Reff ô C0.

12. Find time constant by shorting the battery finding Ceff across R0. Then  = R0 ô Ceff.

PART – B

1. Potential between A and C is fixed


4 10

25
Eeq ý 2 2 ý
1 1 1

2 2
Eeq = 7
ö7ö
VAB ý 6 ô ÷ ÷ ý 6 volt
ø7ø

q
2. ö= , assume a cube around charge q where one face will be long surface.
6õ0

3. B ý (xiˆ  4j)
ˆ ô 102

aý i  2ˆj
3
F ý q(V ô B)
FþB
a ÷B ý 0
8
x  4ô2 ý 0
3
x=3

4. F = iLB
F = 48 ô (0.5) (0.25)
F = 6N i
L

F  f = ma …(i)
mR2
fôR= ñ …(ii)
2
ma
fý …(iii)
2
From (i) and (iii)
F
ma
F ý ma f
2
3ma

2
ma F
fý ý
2 3

P
5. I= ý 5 , F = 107 N
A
P = 5A
F ô V = 3A, V = C = 3 ô 108 m/s
5A = 102 ô 3 ô 108
5A = 30
Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-21

30
A= ý 6 m2
5

I ý ø 3  2 ù  ø 5 ù ý 26 mA
2 2
6.

CHEMISTRY

PARTA
ù 1 ù 1 1
ù 1 ù 2
1. K 3 úCu ø CN ù4 ú , Cu SCN, Cu 2 O, úû Fe ø H 2 O ù5 NO úû SO 4
û û

2. All carbonyl compounds containing ñ - H or ñ - D undergo aldol condensation. (except benzaldehyde)

3. The species having less reduction potential with respect to NO 3 (E0 = +0.96 V) will be oxidised by
NO3. These species are V, Fe and Hg.

4. Frenkel defects is also known as dislocation defects.

5. Conceptual

6. (a) CCl4 and CH3OH, the extent of H – bonding is decreased. The mixture is more vaporised thus,
positive deviation from Raoult9s law.
(b) Acetone + CS2 shows positive deviations.

7. Conceptual

8. Naproxen is a non – steroidal anti inflammatory drug. Tetracycline is used to treat infection.
Chloropheniramine is an antihistamine, while equanil is a tranquilizer.

9-10. (i) O

CN C H
øù i DIBAL  H ø iii ù NaBH4

ø ii ù dil. HCl þ 
ø iv ù conc. H2SO4 þ
O O
CHO

O
(ii)
CHO
øù 3
þ
i O
ø ù
ø ii ù Zn / H 2 O 
ø iv ù conc. H2SO4 þ
iii NaBH 4

COOH O
COOH

O
(iii)
Cl COOH
øù
 þ
i KCN
ø ù

ø iv ù conc. H 2 SO4 þ
iii LiAlH
ø ii ù H O , 
3
4

CO 2CH 3 O
COOH
(iv) CO 2Me CH 2OH
øù
 þ
i LiAlH
ø ù
4

 þ
ii conc. H SO
2 4
CO 2Me
O
CH 2 CH 2OH

PARTB

1. Benzene is a neutral ligand.


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-22

O
2. HO
Cl Cl OH


þ 
 þ

Cl Cl HO OH
O
(x) (y) (z)

3. It has only one CH2OH group.

þ ø P ù  þ øQù

4. 
H aq. dilute
 KMnO ø excess ù , 00 C
4



H 
H

þ 
1, 2 methyl shift
þ 
 H
þ

HO
H3C CH3 H3C CH3
aq. dilute ø excess ù
KMnO 4 00 C

OH

HO OH
HO

5. A = 2y1/3 nm. M = 6.023 × y × 4 amu


6.023 ô 4 ô 1.66 ô 1027
Density = m/a3 = kg / m³
8y ô 1027
40
ý ý 5 kg / m³
8

6. Mass of benzene = 33 × 0.877 g


28.941
Moles of benzene = = 0.371
78
Mass of hexane = 187 × 0.66
= 123.42 g
0.371ô 1000
m= ý 3.006
123.42

MATHEMATICS

Part  A
1. A, B
We have A = AB = A(BA) = (AB)A = AA = A2
and B = BA = B(AB) = (BA)B = BB = B2

2. A, D
3 1 0 0 ... 1 1 00...
3 1 0...
1 3 10 0... 0 3
1
Rn ý 0 1  Rn ý 3 0 1
0
. 0 . 0
. ø n 1ùôøn 1ù
. . nôn
. . øn1ùôøn1ù
 Rn = 3Rn – 1 – Rn – 2
 Rn + Rn – 2 = 3Rn – 1

3. A, B, C
Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-23

Point of intersection of two curves y = x 2 and y


x = y2 is (1, 1).
Now area bounded by curves is given by
1 1
ö 2 3/2 x 3 ö
A= ø x  x ù dx ý ÷ x 
2
ø3 3 ø0
÷
P(1, 1)
0

1
üA= sq. units. x
3
Also, option (A) represents the same region.

4. B, C
 ø 2y  cos y ù dy ý  6x dx  y2 + siny = 2x3 + c
2

ü y(1) = ð  c = ð2 – 2
ü solution is y2 + siny = 2x 3 + ð2 – 2.

5. A, C

øa ÷ c ù b  øa ÷ bù c ý b  c
2
ö 1ö ö 1ö
b÷a ÷ c  ÷  c ÷a ÷b  ÷ ý 0
ø 2ø ø 2ø
1 1
 a ÷ c ý and a ÷ b ý 
2 2
ð
 ñ1 is and ñ2 = 120Ā
3

6. A, C
Since point of intersection of the given lines is (0, 0, 0). It must lie on the angle bisector so,
0  2 0  2 0  k2  1
ý ý  k = ā 3.
1 1 4

7. A, D
ö X ö Pø X ÷ Yù 1
P÷ ÷ ý ý
øYø PøYù 2
ö Y ö Pø X ÷ Yù 2
P÷ ÷ ý ý
ø Xø P ø Xù 5
2
 P(X ÷ Y) =
15
4 7
P(Y) = also P ( X ø Y) =
15 15
ö Xò ö ö Xö 1 1
P ÷ ÷ ý 1 P ÷ ÷ ý 1 ý
øYø øYø 2 2

8. B, D
98 k 1 k 1 k 1
1 98
k 1 98
dx
õ x 1
dx ü õ  x(x  1)
dx ü õ  x
k ý1 k k ý1 k k ý1 k
98 98
õ ø n øk  2ù  n øk  1ù ù ü I ü õ ø n øk  1ù  nk ù
k ý1 k ý1

n 50 ü I ü n 99
49
 ü I ü n99 .
50

9. A
10. B

9-10. Plane through line y = ax, z = c is (y – ax) + 1(z – c) = 0


Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-24

Similarly, (y + ax) + 2(z + c) = 0


 (y + c) + 1(y – c) = 0 and (y – c) + 2(y + c) = 0
y  c 1 y  c
 1 ý , ý ; 12 = 1
y  c 2 y  c
ö y  ax öö y  ax ö
ü Locus is ÷ ÷÷ ÷ ý1
ø z  c øø z  c ø
a2x2 – y2 + z2 – c2 = 0

11. C
12. A

11-12. f(x) = 0  sin(ð cosx) = 0


 ðcosx = n1ð, n1  I
 cosx = – 1, cosx = 0, cosx = 1
n ð
 x ý 2 , n2  I
2

 X= 
ð
2
, ð,

2 
, 2ð......

fò(x) = 0  – cos(ð cosx) ð sinx = 0


 sinx = 0 or cos(ð cosx) = 0
 x = n3ð or ð cosx = (2x4 + 1) ð/2
 cos x = – ½, ½
 x = n5ð ā ð/3
Y= 
ð 2ð 3ð 4ð 5ð 6ð
, ,
3 3 3 3 3 3
, , , 
.....

g(x) = 0  cos(2ð sinx) = 0


ð
 2ð sinx = ø 2n6  1ù
2
2n  1 3 1 1 3
 sin x ý 6 ý , , ,
4 4 4 4 4
ü 1 3 ü
 Z = ý x sin x ý ā , ā , x þ 0 ý
þ 4 4 þ
gò(x) = 0  – 2 ð cosx sin(2ð sinx) = 0
cosx = 0 or sin(2ð sinx) = 0
ð
 x ý ø 2n7  1ù or 2ð sinx = n8ð
2
1 1
 sinx = – 1,  , 0, , 1
2 2
ü 1 ü
W = ý x sin x ý ā1, ā , 0, x þ 0 ý
þ 2 þ
 I – (P), (Q)
II – (Q), (T)
III – (R)
IV – (P), (R), (S)

Part  B

1. 1.00
Det (z) = O ô O – I ô I = O – I = –I
1 0
p = Det (Det (z)) = (–1)2 0 1

 |p| = 1

2. 3.00
Let the circumcentre of the triangle be the origin.
abc
 F = øa  b  c ù
2
 orthocentre is a  b  c and the centroid is
3 3
Yashpatil TG~ @bohring_bot
CTY-2324 ABC LOTNAO-PAPER-2(PH5)_ADVANCED (PCM)-25

 ø a  F ù  øb  F ù  ø c  F ù ý
2 2 2 1ù ø 2
ù 2
ø ù
û a  2 øb  c ù  øb  2 ø a  c ù ù  c  2 ø a  b ù û
2 ù

9
1ø ù
= 27 ý 3 .
9

3. 1.00
The lines should intersect or be parallel
Let ø 2t  1, t,2t ù be any point on the first line
31
Putting it in both the planes we get  ý .
7
There is no  for which both the lines are parallel.

4. 0.40
Initially 4 Red balls and 6-Black balls
4 6 6 4 2
Required probability = ô  ô =
10 12 10 12 5

5. 0.20
Given set of numbers is {1, 2, 3, 4, 5, 6, 7, 8}
We have to select three numbers
Let us assume that
event A þ in selected three numbers minimum is 3
event B þ in selected three numbers maximum is 6
We have to find P(A/B)
P ø A ÷ Bù n ø A ÷ Bù
Now P ø A / B ù ý ý
P øB ù n øB ù
A ÷ B = in selected three numbers, minimum is 3 and maximum is 6
ü The remaining number is either 4 or 5
ü n(A ÷ B) = 2
n(B) = selecting two numbers from 1, 2, 3, 4, 5 (as maximum of numbers is 6)
= 5C2
n ø A ÷ Bù 2 1
ü P ø A / Bù ý ý 5 ý .
n øB ù C2 5
6. 2.00
ð /2
gø xù ý  ùûf ò ø t ù cosec t  cot ø t ù cosec ø t ù f ø t ùùû dt
x

ð /2 f øxù
 g ø x ù ý f ø t ù cosec ø t ù x ý3
sin x
ö f øxù ö
 lim g ø x ù ý lim ÷÷ 3  ÷
x þ0 x þ0
ø sin x ÷ø
= 3 – fò(0) = 2

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