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INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
BATCH – NWCM2125O1S _PT3
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. All the section can be filled in PART-A & B of OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
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2 NWCM2125O1S_PT-3_Paper-1
S
SEEC
CTTIIO
ONN –– IIII :: P
PHHY
YSSIIC
CSS
(PART – A)
(One or More Than One Options Correct Type)
This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.
2. Two waves travelling in opposite directions produce a standing wave. The individual wave
functions are given by y1 = 4 sin(3x – 2t) and y2 = 4 sin(3x + 2t) cm, where x and y are in cm
3
(A) The maximum displacement of the motion at x = cm is 4 cm.
4
(B) The maximum displacement of the motion at t = sec is 4 2 cm .
6
(C) Nodes are formed at x values given by 0, /3, 2/3, , 4/3, ………..
(D) Antinodes are formed at x values given by /6, /2, 5/6, 7/6, ………….
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4. A rain drop of radius 1.5 mm, experiences a drag force F = 2 10−5 v N , while falling ( )
through air from a height 2 km, with a velocity v. The terminal velocity of the rain drop will be
nearly (use g = 10m/s2–)
(A) 200 m/s (B) 80 m/s
(C) 7 m/s (D) 3 m/s
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8. A musical instrument is made using four different metal strings, 1, 2, 3 and 4 with mass per
unit length , 2, 3 and 4 respectively. The instrument is played by vibrating the strings by
varying the free length in between the range L0 and 2L0. It is found that in string-1.() at free
length L0 and tension T0 the fundamental mode frequency is f0.
List-I gives the above four strings while List-II lists the magnitude of some quantity.
List-I List-II
(P) String-1 () (1) 1
(Q) String-2 (2) (2) 1/ 2
(R) String-3 (3) (3) 1/ 2
(S) String-4 (4) (4) 1/ 3
(5) 3 / 16
If the tension in each string is T0 the correct match for the highest fundamental frequency in
f0 units will be.
(A) P → 1 ; Q → 3 ; R → 4 ; S → 2 (B) P → 2 ; Q → 4 ; R → 3 ; S → 1
(C) P → 1 ; Q → 2 ; R → 5 ; S → 4 (D) P → 2 ; Q → 1 ; R → 3 ; S → 5
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9. In the thermodynamic process on an ideal monatomic gas, the infinitesimal heat absorbed
by the gas is given by TX. where T is temperature of the system and X is the infinitesimal
change in a thermodynamic quantity X of the system. For a mole of monatomic ideal gas
3 T V
X = R ln + R ln . Here R is gas constant. V is volume of gas. TA and VA are
2 TA VA
constants.
The List-I below gives some quantities involved in a process and List-II gives some possible
values of these quantities.
List – I List – II
(P) Work done by the system in process 1→2→3 (1) 1
RT0 ln 2
3
(Q) Change in internal energy in process 1→2→3 (2) 1
RT0
3
(R) Heat absorbed by the system in process 1→2→3 (3) RT0
(S) Heat absorbed by the system in process 1→2 (4) 4
RT0
3
(5) 5
RT0
6
If the process carried out on one mole of monatomic ideal gas is as shown in figure in the
1
PV-diagram with P0 V0 = RT0 , the correct match is.
3
(A) P → 2 ; Q → 3 ; R → 4 ; S → 5 (B) P → 2 ; Q → 4 ; R → 3 ; S → 5
(C) P → 2 ; Q → 3 ; R → 1 ; S → 5 (D) P → 4 ; Q → 3 ; R → 2 ; S → 5
Space For Rough Work
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List-I List-II
(P) Amplitude of reflected wave (1) 2.0
(Q) Amplitude of transmitted wave (2) 1.5
(R) Maximum displacement of antinodes in (3) 5
the wire AB
(S) Percentage fraction of power transmitted in (4) 82
the wire BC
(5) 92
List-I List-II
(P) | W1 | (1) 5gh A 2
8
(Q) | W2 | (2) gh2 A
−
4
(R) | W3 | (3) 3gh2 A
4
(S) W3 (4) gh2 A
4
(5) 3gh2 A
−
4
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(PART – B)
(Non – Negative Integer)
1. A string of length 20 cm and linear mass density 0.40 g/cm is fixed
at both ends and is kept under a tension of 16 N. A wave pulse is
produced at t = 0 near an end as shown in figure which travels
towards the other end. The string will have the shape shown in the
figure again after k × 10–2 s, then ‘k’ is
3. Heat is transferred to a heat engine from a furnace at a rate of 80 mW. If the rate of heat
75
rejection is 50 mW, then percentage efficiency of the engine is . Find the value of ‘N’.
N
5. A tuning fork of frequency 340 Hz is vibrated just above a cylindrical tube of length 130 cm.
Water is slowly poured in the tube. If the speed of sound is 340 ms–1 then the minimum
height of water required for resonance is (in cm).
6. A large tank is filled with water to a height H. A small hole is made at the base of the tank.
It takes T1 time to decrease the height of water to H/ 9 and it takes T2 time to take out the
rest of water. Find T1 / T2
Space For Rough Work
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S
SEEC
CTTIIO
ONN –– II :: C
CHHE
EMMIIS
STTR
RYY
(PART – A)
(One or More Than One Options Correct Type)
This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.
1. CH 3CH 2CH = CH 2, CH 3 - C = CH 2
CH3
(I) (II)
(A) Order of heat of hydrogenation : I > II
(B) Heat of combustion: I > II
(C) Heat of atomization: II > I
(D) Enthalpy of HCl (electrophilic) addition: I > II
(hv) Product(s)
NBS ion
titut
S ubs action-I
CH 3CH 2CH = CH 2 e
2. NBS R
/hv
Ad
Rea dition
ctio Product(s)
n-II
3. Reagent −I
CH3 − C C − CH3 ⎯⎯⎯⎯→ ( X)
Reagent-II
H H
H3C CH3
Br Br
(A) Reagent-I may be Na/liquid NH3
(B) Reagent-II may be Br2/CS2
(C) The oxidation product of (X) may be CH3COOH
(D) The end product of the reaction is an optically active compound
Space For Rough Work
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CH3
X Y
6.
and
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8. Match the atoms or group of atoms mentioned in list - I with their electronic effects
mentioned in list - II.
List – I List – II
(P) CH3 (1) Stabilize carbocations by pi-electrons
and destabilize them by sigma electrons
–
(Q) OH (2) Stabilize carbocations only by sigma
electrons
(R) NO2− (3) Destabilise carbocations by both - and
- electrons
(S) Cl– (4) Destabilize carbanions by -electrons
and stabilize carbanions by -electrons
(5) Stabilize carbanions by sigma as well as
pi-electrons
(A) P – 3; Q – 4; R – 1; S – 2 (B) P – 2; Q – 1; R – 3; S – 4
(C) P – 2; Q – 5; R – 4; S – 3 (D) P – 3; Q – 4; R – 5; S – 2
9. Match the hydrocarbons mentioned in list - I with their properties mentioned in list - II.
List – I List – II
(P) CH3CH2CH2CH3 (1) Functional isomer can form salt with
NaNH2
(Q) CH3 – CH = CH – CH3 (2) Temperature dependent addition
products are formed
(R) CH3 – C C – CH3 (3) Two moles of the same product is
formed by ozonolysis reaction
(S) CH2 = CH – CH = CH2 (4) Undergoes no addition reaction
(5) Free radical halogenation form three
monochloro products
(A) P – 5; Q – 2; R – 3; S – 1 (B) P – 4; Q – 3; R – 1; S – 2
(C) P – 2; Q – 3; R – 1; S – 5 (D) P – 3; Q – 2; R – 5; S – 4
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10. Match the reactions mentioned in list - I with the nature of their products mentioned in list - II.
List – I List – II
(P) CH 3 (1) Product after hydrogenation reaction
shows only geometrical isomerism
Cl
Alcoholic KOH (E2 )
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯→
1, 2−elimination
CH3
(Q) CH3 (2) Product after hydrogenation shows both
geometrical and optical isomerism
Cl
Alcoholic KOH (E 2 )
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ →
1, 2−elimination
CH3
(R) CH3 (3) Product before hydrogenation shows
optical isomerism
Cl
Alcoholic KOH (E 2 )
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ →
1, 2−elimination
CH3
(S) CH3 (4) One product is formed in the reaction
CH3
Alcoholic KOH ( E2 )
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ →
1, 2−elimination
Cl
(5) More than one product is formed in the
reaction
(A) P – 4; Q – 3; R – 2; S – 1 (B) P – 3; Q – 4; R – 2; S – 1
(C) P – 2; Q – 1; R – 5; S – 3 (D) P – 2; Q – 4; R – 1; S – 5
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11. Match the benzoid compounds mentioned in list - I with the properties of their EAS products
mentioned in list - II.
List – I List – II
(P) CH 2CH 2CH 2COCl (1) Product reacts with Cl2/hv and
Anhy.AlCl3
⎯⎯⎯⎯⎯⎯⎯ →
Cl2/Fe
( 2 moles)
(R) CH2Cl (3) Major product forms two
Anhy.AlCl3
⎯⎯⎯⎯⎯⎯⎯ → monochloro products upon free
radical chlorination(Consider
optical isomerism)
( 2 moles)
(S) (4) Major product contains one Cl
+ CH3 Cl ( excess )
Anhy.AlCl3
⎯⎯⎯⎯⎯⎯⎯ →
atom
(5)
Forms most stable carbocation
intermediate
(A) P – 2; Q – 4; R – 3; S – 5 (B) P – 2; Q – 3; R – 5; S – 4
(C) P – 2; Q – 4; R – 5; S – 1 (D) P – 2; Q – 3; R – 4; S – 1
(PART – B)
(Non – Negative Integer)
1. CH 3 - CH - CH - CH - CH - C 2H5
Cl Cl Cl Cl
NaNH 2(excess)
( X ) ⎯⎯⎯⎯⎯⎯⎯⎯⎯
Lindlar 's catalyst
Excess
→ (Y)
Br2(excess)/ CCl 4
(Z)
How many structural isomer(s) is/are formed as the end product of above reaction?
2. A saturated hydrocarbon(X) forms more than one dichloro products. The molar mass of one
of the dichloroproduct is 113 g mol–1. How many dichloro product(s) is/are formed by the
hydrocarbon(X)? (Consider stereoisomers)
Space For Rough Work
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3. NO2
CH3COCl,Anhy.AlCl3
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ → Product
C6H6
How many oxygen atoms(s) is/are present in the product of above reaction?
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S
SEEC
CTTIIO
ONN –– IIIIII :: M
MAAT
THHE
EMMA
ATTIIC
CSS
(PART – A)
(One or More Than One Options Correct Type)
This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.
( )
n
2. If 9 + 80 = I + f where I, n are integers and 0 f 1, then
(A) I is an odd integer (B) I is an even integer
(C) (I + f )(1 − f ) = 1 ( )
n
(D) 1 − f = 9 − 80
3. Number of shortest ways in which we can reach from the point (0, 0, 0) to point (3, 7, 11) in
space where the movement is possible only along the x – axis, y – axis and z – axis or
parallel to them and change of axes is permitted only at integral points (an integral point is
one, which has its coordinates as integer) is:
(A) equivalent to number of ways of dividing 21 different objects in three groups of size 3, 7,
11
(B) equivalent to coefficient of y3 z7 in the expansion of (1 + y + z )
21
(C) equivalent to number of ways of distributing 21 different objects in three boxes of size 3,
7, 11
(D) equivalent to number of ways of arranging 21 objects of which 3 are alike of one kind, 7
are alike of second type and 11 are alike of third type
x2 y2 x2 y2 1
5. The foci of the ellipse + 2 = 1 and the hyperbola − = coincide. Then the
16 b 144 81 25
value of b 2 is:
(A) 5 (B) 7
(C) 9 (D) 1
Space For Rough Work
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6. ABCD is a convex quadrilateral and 3, 4, 5 and 6 points are marked on the sides AB, BC,
CD and DA respectively. The number of triangles with vertices on different sides is:
(A) 270 (B) 220
(C) 282 (D) none of these
7. 7 different coloured balls are to be kept in 5 different boxes. A box may contain any
number of balls and no box is empty (order of balls is considered in the boxes). Then
number of such ways are:
(A) 7!. 6C4 (B) 7!.5! 6C2
(C) 7!.5! (D) none of these
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(5) 30
(A) P → 5, Q →1, R →4, S →2 (B) P → 1, Q →3, R →1, S →4
(C) P → 5, Q →1, R →3, S →5 (D) P → 1, Q →2, R →1, S →4
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(PART – B)
(Non – Negative Integer)
1. There are four balls of different colours and four boxes of colours, same as those of the
balls. The number of ways in which the balls, one each in a box, could be placed such that a
ball does not go to a box of its own colour is ____
1 1
2. If the coefficients of x −2 and x −4 in the expansion of x 3 + 1 , ( x 0 ) , are m and n
2x 3
m
respectively, then is equal to
n
3. Let 1 be the area of PQR inscribed in an ellipse and 2 be the area of the P'Q'R'
whose vertices are the points lying on the auxiliary circle corresponding to the points P, Q,
4 3
R, respectively. If the eccentricity of the ellipse is , then the ratio 343 2 must be ___
7 1
4. An isosceles ABC is inscribed in the circle x2 + y2 = 16, A = (0, 4 ) . From points A, B and C
x2 y2
three ordinates are drawn which cut the ellipse + = 1 at the points P, Q and R
16 9
respectively such that A and P are on the opposite sides, Q and B are on the same side and
C and R are on the same side of the major axis. If PQR is right angled at P and is the
smallest angle of the ABC, then find the value of 16 tan2 + 8 tan + 9 .
5. (
Find the number of solutions of equation sin−1 4 sin2 + sin + cos−1 ( −1 + 6 sin ) = ) 2
,
0, 5
5 −1 10 + 2 5
6. If the sum of all values of x 0, satisfying the equation + = 8 is,
2 sin x cos x
k
10 , then find the value of k.
Space For Rough Work
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Chemistry
PART – A
1. ABC 2. AB 3. ABC 4. C
5. C 6. B 7. D 8. B
9. B 10. C 11. D
PART – B
1. 4 2. 5 3. 1 4. 2
5. 4 6. 5
Mathematics
PART – A
1. BC 2. ACD 3. ABD 4. B
5. B 6. D 7. A 8. B
9. D 10. D 11. C
PART – B
1. 9 2. 182 3. 2401 4. 24
5. 6 6. 4
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