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FIITJEE

PHYSICS, CHEMISTRY & MATHEMATICS


BATCHES – PANINI921-G1 & PANINI921-XI1-XI2

CPT3 - 2 CODE: 127930 PAPER - 2

Time Allotted: 3 Hours Maximum Marks: 186

▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.

1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & C in the OMR. Part-B of OMR to be left
unused.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Two Part.


(i) PART–A (01–08) contains 8 Multiple Choice Questions which have One or More Correct answer.
For each question in the group Q. 01 – 08 of PART – A you will be awarded
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: −1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will result
in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in −1
marks, as a wrong option is also darkened.
(ii) Part-A (09-12) – This section contains Two (02) List-Match Sets, each List-Match set has Two (02) Multiple
Choice Questions. Each List-Match set has two lists: List-I and List-II. FOUR options are given in each
Multiple Choice Question based On List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question. Each question carries +3 Marks for correct combination
chosen and -1 marks for wrong options chosen.
(iii) Part-C (01-06) contains Six (06) Numerical based questions with single digit integer as answer, ranging
from 0 to 9 (both inclusive) and each question carries +3 marks for correct answer. There is no negative
marking.

Name of the Candidate: ____________________________________________

Batch: ____________________ Date of Examination: ___________________

Enrolment Number: _______________________________________________

FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
PANINI921-G1,PANINI921-XI1-XI2_PT3 PAPER-2 (PCM)

S
SEEC
CTTIIO
ONN –– II :: P
PHHY
YSSIIC
CSS
PART – A
(Multiple Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D), out
of which ONE OR MORE THAN ONE is/are correct.

1. A coin is placed on a horizontal platform, which undergoes vertical simple harmonic motion
of angular frequency . The amplitude of oscillation is gradually increased. The coin will
leave contact with the platform for the first time
(A) at the highest position of the platform (B) at the mean position of the platform
(C) for an amplitude of g/ 2
(D) for an amplitude g / 

2. The driver of a car travelling with speed 30 m/sec towards a hill sounds a horn of frequency
600 Hz. If the velocity of sound in air is 330 m/sec, the frequency of reflected sound as heard
by driver is
(A) 500 Hz (B) 550 Hz
(C) 555.5 Hz (D) 720 Hz

3. Cv and Cp denote the molar specific heat capacities of a gas at constant volume and
constant pressure respectively. Then
(A) CP – CV is larger for a diatomic ideal gas than for a monatomic ideal gas
(B) CP + CV is larger for a diatomic ideal gas than for a monatomic ideal gas
(C) CP /CV is larger for a diatomic ideal gas than for a monatomic ideal gas
(D) CP .CV is larger for a diatomic ideal gas than for a monatomic ideal gas

4. A binary star system consists of two stars A and B which have time periods TA and TB, radii
RA and RB and masses MA and MB. Then:
(A) if TA > TB then RA > RB (B) if TA > TB then MA > MB
2 3
(C)  A  =  A 
T R
(D) TA = TB
 B 
T  RB 

5. If ,  and  are coefficients of linear superficial and volume expansion respectively, then
 1  2  3  
(A) = (B) = (C) = (D) =
 2  3  1  

6. The speed of a wave on a string is 150 m/s when the tension is 120 N. The percentage
increase in the tension in order to raise the wave speed by 20% is:
(A) 44% (B) 40%
(C) 20% (D) 10%
Space for rough work

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7. A ball of mass m is attached to the lower end of light vertical spring of force constant k. The
upper end of the spring is fixed. The ball is released form rest with the spring at its normal
(un- stretched) length, and comes to rest again after descending through a distance x. Then,
(A) x = mg/k
(B) x = 2mg/k
(C) The ball will have no acceleration at the position where it has descended through x/2.
(D) The ball will have an upward acceleration equal to g at its lowermost position

8. A constant force F is applied on a spring block k


F
system as shown in figure. The mass of the block m
is m and spring constant is k. The block is placed
over a smooth surface. Initially the spring was
unstretched. Choose the correct alternative (s)
(A) the block will execute SHM
(B) amplitude of oscillation is F/2k
m
(C) time period of oscillation is 2
k
2Fx − kx 2
(D) the maximum speed of block is
m
(here x = F/k)
(Only One Correct Answer Type)
Matching list type questions (9 – 12)

Answer Q. 9 and Q. 10 by appropriately matching the lists based on the information given in
the paragraph.

In the thermodynamic process on an ideal monatomic gas, the infinitesimal heat absorbed
by the gas is given by TX. where T is temperature of the system and X is the infinitesimal
change in a thermodynamic quantity X of the system. For a mole of monatomic ideal gas
3  T   V 
X = R ln   + R ln   . Here R is gas constant. V is volume of gas. TA and VA are
2  TA   VA 
constants.
The List-I below gives some quantities involved in a process and List-II gives some possible
values of these quantities.
List – I List – II
(I) Work done by the system in process 1→2→3 (P) 1
RT0 ln 2
3
(II) Change in internal energy in process 1→2→3 (Q) 1
RT0
3
(III) Heat absorbed by the system in process 1→2→3 (R) RT0
(IV) Heat absorbed by the system in process 1→2 (S) 4
RT0
3
(T) 1
RT0 ( 3 + ln 2 )
3
(U) 5
RT0
6
Space for rough work

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PANINI921-G1,PANINI921-XI1-XI2_PT3 PAPER-2 (PCM)

9. If the process carried out on one mole of monatomic ideal gas is as shown in figure in the
1
PV-diagram with P0 V0 = RT0 , the correct match is.
3

(A) I→Q, II→R, III→S, IV→U (B) I→Q, II→S, III→R, IV→U
(C) I→Q, II→R, III→P, IV→U (D) I→S, II→R, III→Q, IV→T

10. If the process carried out on one mole of monatomic ideal gas is as shown in figure in the
1
PV-diagram with P0 V0 = RT0 , the correct match is.
3

(A) I→P, II→T, III→Q, IV→T (B) I→S, II→T, III→Q, IV→U
(C) I→P, II→R, III→T, IV→S (D) I→P, II→R, III→T, IV→P

Answer Q. 11 and Q. 12 by appropriately matching the lists based on the information given in
the paragraph.

A musical instrument is made using four different metal strings, 1, 2, 3 and 4 with mass per
unit length , 2, 3 and 4 respectively. The instrument is played by vibrating the strings by
varying the free length in between the range L0 and 2L0. It is found that in string-1.() at free
length L0 and tension T0 the fundamental mode frequency is f0.
List-I gives the above four strings while List-II lists the magnitude of some quantity.

List – I List – II
(I) String-1 () (P) 1
(II) String-2 (2) (Q) 1/ 2
(III) String-3 (3) (R) 1/ 2
(IV) String-4 (4) (S) 1/ 3
(T) 3 / 16
(U) 1/ 16
Space for rough work

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11. If the tension in each string is T0 the correct match for the highest fundamental frequency in
f0 units will be.
(A) I→P, II→R, III→S, IV→Q (B) I→Q, II→S, III→R, IV→P
(C) I→P, II→Q, III→T, IV→S (D) I→Q, II→P, III→R, IV→T

3L0 5L0 7L
12. The length of the strings 1, 2, 3 and 4 are kept fixed at L0, , and 0 , respectively.
2 4 4
Strings 1, 2, 3 and 4 are vibrated at their 1st, 3rd, 5th and 4th harmonies, respectively such that
all the strings have same frequency. The correct match for the tension in the four strings in
the units of T0 will be.
(A) I→P, II→Q, III→T, IV→U (B) I→P, II→Q, III→R, IV→T
(C) I→P, II→R, III→T, IV→U (D) I→T, II→Q, III→R, IV→U

PART−C
Integer Answer Type
This section contains 6 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).

1. An ideal gas is expanding such that PT2 = constant. The coefficient of volume expansion of
the gas is A/T where T is temperature in kelvin. Find the value of A.

2. 2 kg of ice at –22.50C is mixed with 2.5 kg of water at 250C in an insulating container. If the
specific heat of ice and water are 0.5 cal/gm°C and 1 cal/gm°C respectively. Latent heat of
fusion of ice = 80 cal/gm. Find the amount of water present in the container (In kg).

3. The maximum acceleration and maximum velocity of simple harmonically oscillating system
are 8 m/sec2 and 8 m/s respectively. What is the angular frequency?

4. The power radiated by a black body is P, and it radiates maximum energy around the
wavelength 0. If the temperature of black body is now changed so that it radiates maximum
3 64 P
energy around a wavelength 0 , the new power radiated by it is  n , then find the
4 81
value of ‘n’.

5. A string is stretched along the X axis. A disturbance given by the equation y(x,t) =
 x 
4 sin   cos (10t ) . Where X is in cm and t is in seconds. Distance between two adjacent
 3 
nodes is n cm, then n = ?

6. An organ pipe P1 closed at one end vibrating in its first overtone and another pipe P2 open at
the both ends vibrating in its third overtone are in resonance with a given tuning fork. The
3
ratio of the length of P1 to that of P2 is then n = ?
n
Space for rough work

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PANINI921-G1,PANINI921-XI1-XI2_PT3 PAPER-2 (PCM)

S
SEEC
CTTIIO
ONN –– IIII :: C
CHHE
EMMIIS
STTR
RYY
PART – A
(Multiple Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D), out
of which ONE OR MORE THAN ONE is/are correct.

1. Which of the following compound(s) form(s) an aldehyde upon acidic hydrolysis or hydrolysis
in presence of H2SO4/HgSO4?
(A) CH3CH = CH2 (B) HC  CH
(C) CH2 = CH2 (D) CH3 – C  CH

CH3CH = CHCH3 ⎯⎯
→ CH3CH − CHCH3
2.
O
The reagent(s) used in the above change is/are?
(A) CF3COOOH (B) H2O
(C) MCPBA(meta chloro per benzoic acid) (D) KMnO4/OH–/Cold

3. The heat of hydrogenation of which alkene(s) is/are higher than that of CH3CH = CHCH3?
(A) CH2 = CH2 (B) CH3CH = CH2
(C) (CH3)2C = CHCH3 (D) (CH3)2C = C(CH3)2

4. Which of the following pair of compounds cannot be distinguished by ammonical Cu2Cl2


solution?
(A) CH3CH = CHCH3 and CH3 – C  C – CH3
(B) CH3C  CCH3 and CH3CH2CH = CH2
(C) CH3CH2CH2CH3 and CH3CH2C  CH
(D) CH3CH = CHCH3 and CH3CH2CH = CH2

5. CH 3 - CH = CH - C = C - CH 3

CH3 CH3
Which of the following is/are the ozonolysis product(s) of the above compound?
(A) CH3CHO (B) CH3COCH3
(C) CH3CH2CHO (D) CH3 – CO – CHO
Space For Rough Work

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6. OH

Fe
+ Br2 ⎯⎯⎯ → Product

The product(s) of above reaction is/are:


OH
OH
Br
Br
(A) (B)

Br
OH
OBr

(C) (D)

Br

7. The aromatic compound(s) out of the following is/are:

(A) (B)

(C) (D)

OH

8. Which of the following substance(s) is/are more acidic than phenol ?

(A) O2N OH (B) H3C OH

(C) OHC OH (D) F3C OH

Space For Rough Work

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(Only One Correct Answer Type)


Matching list type questions (9 – 12)

Match the compounds mentioned in List-I with their properties mentioned in List-II
List – I List– II
(I) CH4 (P) Undergoes substitution reaction
(II) C2H6 (Q) Undergoes addition reaction
(III) C2H4 (R) Decolourises bromine water
(IV) C2H2 (S) Reacts with ammonical Cu2Cl2 solution
(T) Contains only sigma bonds
(U) Contains sigma and pi-bonds

9. Which is the correct combination according to the above lists.


(A) I → S (B) II → Q
(C) III → P (D) IV → U

Match the compounds mentioned in List-I with their properties mentioned in List-II
List – I List– II
(I) CH4 (P) Undergoes substitution reaction
(II) C2H6 (Q) Undergoes addition reaction
(III) C2H4 (R) Decolourises bromine water
(IV) C2H2 (S) Reacts with ammonical Cu2Cl2 solution
(T) Contains only sigma bonds
(U) Contains sigma and pi-bonds

10. Which combination is correct according to the above lists.


(A) I → U (B) II → T
(C) III → S (D) IV → T

Match the group(s) or atom(s) mentioned in List-I with their electronic effects which they exert if
attached to benzene ring, mentioned in List-II.
List – I List– II
(I) CH3 (P) + I effect
(II) Cl (Q) – I effect
(III) NO2 (R) + R effect
(IV) OH (S) – R effect
(T) Increases acidic strength of aliphatic
monocarboxylic acids
(U) Activates benzene ring towards electrophilic
substitution reaction

11. Which combination is correct according to the above list?


(A) I → Q (B) II → S
(C) III → T (D) IV → P
Space For Rough Work

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Match the group(s) or atom(s) mentioned in List-I with their electronic effects which they exert if
attached to benzene ring, mentioned in List-II.
List – I List– II
(I) CH3 (P) + I effect
(II) Cl (Q) – I effect
(III) NO2 (R) + R effect
(IV) OH (S) – R effect
(T) Increases acidic strength of aliphatic
monocarboxylic acids
(U) Activates benzene ring towards electrophilic
substitution reaction

12. Which combination is correct according to the above list?


(A) I → S (B) II → Q
(C) III → U (D) IV → S

PART−C
Integer Answer Type
This section contains 6 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).

1. The formula of an amine is C4H11N. How many -hydrogen atom(s) is/are present in its most
basic isomer in gaseous state?

2. How many alkene(s) is/are formed by dehydrohalogenation of the following compound?


(Consider stereoisomers)
Cl

CH 3CH 2CCH 2CH 2CH 3

CH3

3. The molecular formula of an alcohol is C4H9OH. How many CH3 group(s) is/are present in its
least acidic isomer?

4. How many maximum number of alkyl nitrate(s) is/are formed by nitration (reaction with
conc.HNO3) of CH3CH2CH3?

5. CH3 CH3

CH3 - CH - CH - CH 3
How many monochloro product(s) is/are formed by the above compound?

6.
( CH )
→ ( X ) ⎯⎯⎯⎯⎯
+
⎯⎯⎯⎯⎯ → Products
3 2 CHClKMnO 4 /H
AlCl3

How many carbon atom(s) is/are present in the final organic product of above reaction?
Space for rough work

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S
SEEC
CTTIIO
ONN –– IIIIII :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
(Multiple Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D), out
of which ONE OR MORE THAN ONE is/are correct.

1. If the complex numbers z1, z2, z3, z4, taken in that order, represent the vertices of a rhombus,
then
(A) z1 + z3 = z2 + z4 (B) |z1 – z2| = |z2 – z3|
z1 − z3
(C) is purely imaginary (D) none of these
z2 − z 4

2 If 100!= 2 35  7 ………,then


1
(A)  = 97 (B)  = (  − 1)
2
1 1
(C)  =  (D)  = 
2 3

3 If sec  − 1 = ( )
2 − 1 tan ,then  =

(A) 2n (B) 2n +
4
 
(C) 2n − (D) 2n +
4 3

4. If  is a complex constant such that z2 + z +  = 0 has a real root, then:


(A)  +  = 1 (B)  +  = 0
(C)  +  = −1 (D) the absolute value of the real root is 1

5. Number of ways in which 200 people can be divided in 100 couples is:
( 200 ) !
(A) 100 (B) 1 3  5.....199
2 (100 ) !
 101  102   200  ( 200 ) !
(C)     .....   (D)
 2  2   2  (100 ) !

If n  1, then (1 + x ) − nx − 1 is divisible by:


n
6.
(A) x 2 (B) x 3
(C) x 4 (D) x 5
Space for rough work

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7. Let zn − 1 = 0, have n roots given by 1,  2 ,......n then:


(A) 1 +  2 + ...... +  n = 0
(B) 1 .  2 ......n = ( −1)
n +1

(C) 1 = 2 = ...... n = 1
(D) 1,  2 ,......n divide a unit circle into a regular polygon of n sides

8. Let us consider all complex numbers satisfying z − 25i  15 . Among all these complex
numbers:
3
(A) complex number with least argument is tan−1  
4
3
(B) complex number with maximum argument is  − tan−1  
4
(C) complex number with least magnitude is 10
(D) complex number with maximum magnitude is 40

(Only One Correct Answer Type)


Matching list type questions (9 – 12)

List – I List – II
(I) The number of subsets of the set 1,2,3,.......9 (P) 4017
containing at least one odd number
(II) The number of ways of choosing at least 3 students (Q) 256
from a class of 12.
(III) The number of solution x1x2 x3 x4 = 210 (R) 496
(IV) The number of five digit numbers in which every digit (S) 125
exceeds the immediately preceding digit

9. Which of the following is the only correct combination?


(A) I →P (B) II →P
(C) III →S (D) IV →R

10. Which of the following is the incorrect combination?


(A) I →Q (B) II →P
(C) III →P (D) IV → S
Space for rough work

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List – I List – II
(I) Area enclosed by real axis, imaginary axis, Re(z)=4 and (P) 9
2Im ( z ) = 3 is
(II) Position number of numerically greatest term for x=1/18 (Q) 8
in the expansion of ( 2 + 9x )
23
is/are
(III) If 14
Cr +1 is the binomial coefficient of 7th term from (R) 7

ending in the expansion of ( 2a + 5b )


14
then r=
(IV) Coefficient of x 7 in the expansion of (1 − x ) −2 is (S) 6
(T) 5
(U) 4

11. Which of the following is the only correct combination?


(A) I → S (B) II → T (C) III → Q (D) IV → U

12. Which of the following has more than one answer in List II?
(A) I (B) II (C) III (D) IV

PART−C
Integer Answer Type
This section contains 6 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).

1. If the ratio of the 7th term from the beginning to the 7th term from the end in the expansion of
n
 1/3 1  1
 2 + 1/3 
is , find n.
 3  6

2. Four times the sum of the roots of the equation sin 2x + 5 sin x + 5 cos x + 1 = 0 in the interval
p
0,50 is p , then 1010 is

3. The sides of a triangle are a − 1, a,a + 1 where a is a natural number and a  1 , its largest
k
angle is twice the smallest. The value of 3a3 + 20a2 + 35a + 1 is equal to k, then
1051
equals

4. The number of ways in which we can choose 5 letters from the word INTERNATIONAL are
 . Then sum of all digits of  is

5. cos 2x + a sin x = 2a − 7 possesses a solution for a  1,  2  . Then ( 1 + 2 ) =

R 16
6. In a ABC, a : b : c = 4 : 5 : 6 . The ratio is . Then K is
r K
Space for rough work

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