Phase 3 Fiitjee Paper 1

FIITJEE –Phase Test (JEE-Advanced)
PHYSICS, CHEMISTRY & MATHEMATICS

PHASE - III CODE: 101037.3 PAPER - 1
Time Allotted: 3 Hours Maximum Marks: 183
BATCH–SANKALP2325A, O, B, HA1, RAH & WAH-PH-III
 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. SECTION–I is Physics, SECTION–II is Chemistry and SECTION–III is Mathematics.
4. Each part is further divided into two parts: Part – A & C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Two Parts.

(i) Part–A (01 – 07) contains 07 multiple choice questions which have one or more than one correct
answer. Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Part–A (08 – 13) contains 06 Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
(ii) PART–C (01-05) contains (05) Numerical based questions with single digit integer as answer, ranging from
0 to 9 (both inclusive) and each question carries +3 marks for correct answer. There is no negative
marking.
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
SANKALP 2325A, O, B, HA1, RAH & WAH-Ph-III-Paper-1-PCM(101037.3)-2
SECTION – I : PHYSICS
PART – A: (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
1. A tank, which is open at the top, contains a liquid up to a

height H. A small hole is made in the side of the tank at a
distance y below the liquid surface. The liquid emerging from y
the hole lands at a distance x from the tank
(A) if y is increased from zero to H, x will first increase and
then decrease. H
(B) x is maximum for y = H/2
(C) the maximum value of x is H.
(D) the maximum value of x will depend on the density of the
liquid. x
2. Water is being poured into a vessel at a constant rate m3/s. There is a small aperture of cross
sectional area a at the bottom of the vessel. The maximum level of water in the vessel is proportional
to
(A) 2 (B) 
(C) 1/a (D) 1/a2
3. One mole of a monatomic ideal gas goes through a V

thermodynamic cycle, as shown in the volume
versus temperature (V – T) diagram. The correct 3
statement(s) is/are: 2V0 2
[R is the gas constant]
V0 4 1
T
T0/2 T0 3T0/2 2T0
1
(A) Work done in this thermodynamic cycle (1  2  3  4  1) is W  RT0
2
Q12 5
(B) The ratio of heat transfer during processes 1  2 and 2  3 is 
Q2 3 3
(C) The above thermodynamic cycle exhibits only isochoric and adiabatic processes.
Q12 1
(D) The ratio of heat transfer during processes 1  2 and 3  4 is 
Q3 4 2
Space for rough work
4. A large wooden plate of area 10 m2 floating on the surface of a river is made to move horizontally with
a speed of 2 m/s by applying a tangential force. River is 1 m deep and the water in contact with the
–3 2
bed is stationary. Then choose correct statements. (Coefficient of viscosity of water = 10 N-s/m )
–1
(A) velocity gradient is 2s .
(B) velocity gradient is 1s–1
(C) force required to keep the plate moving with constant speed is 0.02 N
(D) force required to keep the plate moving with constant speed is 0.01 N
5. A wave is represented by the equation y = A sin (10x + 15t + /3) where x is in meters and t is in
seconds. The expression represents
(A) a wave travelling in the positive x-direction with a velocity 1.5m/s.
(B) a wave travelling in the negative x-direction with a velocity 1.5m/s.
(C) a wave travelling in the negative x-direction having a wavelength 0.2m.
(D) a wave travelling in the positive x-direction having a wavelength 0.2m.
6. Two solid spheres A and B of equal volumes but of different

densities dA and dB are connected by a string. They are fully
A
immersed in a fluid of density dF. They get arranged into an
equilibrium state as shown in the figure with a tension in the string.
The arrangement is possible only if
(A) dA < dF B
(B) dB > dF
(C) dA > dF
(D) dA + dB = 2dF
7. The equation of two sound waves in medium at x =0 are given by

y1 = 3 sin 100t
y2 = 4 sin 150 t
then
(A) the ratio of intensities of sound waves in the medium is 1 : 4
(B) the ratio of maximum intensities of waves in medium is 9 : 16
(C) the waves when superposed appropriately can produce interference
(D) the waves when superposed appropriately can produce 25 beats/seconds.
PART – A: (Single Correct Answer Type)
of which ONLY ONE is correct.
2
8. An ideal gas is expanding such that PT = constant. The coefficient of volume expansion of the gas is
1 2
(A) (B)
T T
3 4
(C) (D)
T T
cp
9. Each molecule of a gas has f degrees of freedom. The ratio   for the gas is
cv
f 1
(A) 1  (B) 1 
2 f
2 (f  1)
(C) 1  (D) 1 
f 3
10. Two communicating vessels contain a liquid. The diameter of one

Water
vessel is two times larger than the diameter of the other. A column h
of water of height h = 40 cm is poured into the left vessel. The rise A B
liquid
in the liquid level in the right-hand vessel is {s = 2 (relative density
of liquid) and  = density of water}
(A) 4 cm (B) 6 cm
(C) 8 cm (D) 10 cm
1
11. A Carnot engine operating between temperatures T1 and T2 has efficiency . When T2 is lowered by
6
1
62 K, its efficiency increases to . Then T1 and T2 are, respectively :
3
(A) 372 K and 330 K (B) 330 K and 268 K
(C) 310 K and 248 K (D) 372 K and 310 K
12. A stationary source emits sound waves of frequency 500 Hz. Two observers moving along a line
passing through the source detect sound to be of frequencies 480 Hz and 530 Hz. Their respective
speeds are, in ms–1 (Given speed of sound = 300 m/s)
(A) 16, 14 (B) 12, 16
(C) 8, 18 (D) 12, 18
13. A train moves towards a stationary observer with speed 34 m/s. The train sounds a whistle and its
frequency registered by the observer is f 1. If the speed of the train is reduced to 17 m/s, the frequency
registered is f 2. If speed of sound is 340 m/s, then the ratio f1/f 2 is:
(A) 18/17 (B) 19/18
(C) 20/19 (D) 21/20
PART – C: (Integer Answer Type)

This section contains 05 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the OMR is to be bubbled.
1. Two waves having the intensities in the ratio of 9 : 1 produce interference. The ratio of maximum to
minimum amplitude is K : 1. Find the value of K.
2. One mole of a monoatomic ideal gas is mixed with one mole of a diatomic ideal gas. The molar
specific heat (in calories) of the mixture at constant volume is ……………..
3. A container of large uniform cross–sectional area A resting on a horizontal

surface, holds two immiscible, non – viscous and incompressible liquids of H/2
d
densities d and 2d, each of height H/2 as shown in figure. The lower
density liquid is opened to the atmosphere having pressure P0. A tiny hole
H/2 2d
of area s(sA) is punched on the vertical side of the container at a height h
h(h<H/2). The speed with which liquid will come out of the hole is Kg m/s. x
Then, find the value of K. (Take H = 4 m, h = 1 m)
4 The equation for the vibration of a string, fixed at both ends vibrating in its third harmonic, is given by
y  (0.4 cm) sin[(0.314cm 1 )x] cos[(600 s 1 )t]
The frequency of vibration is (300K) Hz. Then find the value of K.
5. A rigid diatomic ideal gas undergoes an adiabatic process at room temperature. The relation between
temperature and volume for the process is TVx = constant, then x is P/Q. The value of (P+Q) is
SECTION – II : CHEMISTRY
1. Which of the following molecules contains only primary hydrogen atoms?

(A) Neopentane (B) Neohexane
(C) 2, 2, 3, 3Tetramethylbutane (D) 2, 2, 3-Trimethylpentane
2. Acid rain is due to

(A) formation of oxides of sulphur (B) formation of oxides of nitrogen
(C) formation of oxides of chlorine (D) HClO4
3. Stability order of carbocations is

+
+
(I) (II)
+ +
(III) (IV)
(A) I < II (B) II < III

(C) III < IV (D) IV < III
4. What are the products obtained upon the ozonolysis of 2-pentene?

(A) CH3CH2CHO (B) CH3CHO
(C) CH3COCH3 (D) CH3COCH2CH3
5.
1 equiv. Br2
CH2   Product
FeBr3 / 
O 2N
Product is
(A) (B) Br
Br CH2
CH2
O 2N
O 2N
(C) (D) Br
CH 2 Br
CH2
O 2N
O 2N
6. Which reagent(s) distinguish(es) ethylene from acetylene?

(A) Aqueous alkaline KMnO4 (B) Br2 dissolved in CCl4
(C) Ammoniacal Cu2Cl2 (D) Ammoniacal AgNO3
7. Which of the following reactions are yielding correct product as mentioned?

(A) Br Br (B) O
Br NHCOCH3 NHCCH3
Br2 ,FeBr3
 NO2
HNO3 ,H2SO 4
(Major product) 
(Minor product)
(C) CH3 CH3 (D) SO 3H SO 3H
NO2
HNO 3 ,H2SO4
HNO3 ,H2SO4  
  Temp.
NO 2
CH3 CH3
C(CH3)3 C(CH3)3 (Major product)
(Major product)

8. Number of geometrical isomers for 1,8-dichloro-octa-1,3,5,7-tetraene are

(A) 10 (B) 6
(C) 16 (D) 12
9. Which is not aromatic?
(A) (B)
+
(C) (D) N
10. The smog is essentially caused by presence of

(A) O2 and O3 (B) O3 and N2
(C) oxides of sulphur and nitrogen (D) O2 and N2
11. Which of the following are aromatic in nature
(1) (2) (3) (4)

(A) 1 & 2 (B) 2, 3 & 4
(C) 3 & 4 (D) 2 & 4
12. In the reaction given below, the major product formed is:
O
2 
Br 1 mole
N Fe
 Product
(A) O (B) O
Br
N N
Br
(C) O (D) O
N N Br
Br
13. If given reaction occurs then which of the following will be the major product?

H /H2 O
 
(A) (B)
OH OH
(C) (D)
OH OH
Part – C (Integer Answer Type)

9. The correct digit below the question number in the ORS is to be bubbled.
1. How many of the following species is/are electrophiles?

 
CCl4 ; CO2 ; CS 2 ; COCl2 ; CH3 ; NH4 ; NH3 ; PPh3 ; Cl ; SO3
2. How many of the following statement are correct?

(i) Ethene reacts faster than ethyne with H – Cl
(ii) Ethyne reacts faster than ethene withH2/Ni
(iii) Formic acid is stronger acid than acetic acid
(iv) Aniline is stronger base than ethylamine
3. What is the number of moles of CH4 formed in the given reaction?

O NH2
C CH
CH MgBr

3
excess
 Number of moles of CH4
HS
C OH
4. How many stereoisomers are possible for 1,3-dichloro cyclopentane.
5. How many degrees of unsaturation does the following structure have?
S
SEEC
CTTIIO
ONN –– IIIIII :: M
MAAT
THHE
EMMA
ATTIIC
CSS
n
1. The value of the expression Co2  C12  C22  ........   1 Cn2 is (Here Ck = nCk)
(A) 0, if n is odd (B) (1)n, if n is odd
n/2 n-1
(C) (1) Cn/2, if n is even (D) (1) Cn-1, if n is even
1
2. If z   2 then the true statements among the following are
z
(A) Maximum value of | z | is 2 1 (B) Minimum value of | z | is 2 1
(C) Maximum value of | z | is 5 2 (D) Minimum value of | z | is 5 2
z2
3. If is always real, then z can lie on
 z  1
(A) the real axis (B) the imaginary axis
(C) a circle (D) a parabola
n
4. 
Let 1  2   xn  yn 2 , where xn, yn are integers, then
n
(A) xn2  2yn2   1 (B) xn  2yn  xn1  0
(C) xn2  2yn2 1 (D) yn1  xn  yn
1 x2 y2
5. If a tangent of slope of the ellipse 2  2  1 (a > b) is normal to the circle x 2  y2  2x  2y  1  0
3 a b
then
2  2 
(A) maximum value of ab is (B) a  ,2 
3  5 
 
2 
(C) a  ,2  (D) maximum value of ab is 1
3 
6. If n > 1, then (1 + x)n  nx  1 is divisible by

(A) x (B) x2
(C) x3 (D) x4
n 1
7. If Cr  (k 2  3)  nCr 1 then k may lie in the region
(A) (, 2) (B) [ 2,  3)
(C)   3,0  (D) ( 3, 2]
8. If a, b, c be three natural numbers in A.P. and a + b + c = 30, then the possible number of values of
(a, b, c) is
(A) 19 (B) 24
(C) 30 (D) 36
9. Coefficient of x2009 in (1 + x + x2 + x3 + x4)1001 (1 - x)1002 is

(A) 0 (B) 4. 1001C501
(C) 2009 (D) none of these
10. The equation 2 sin2x – (p + 3) sin x + 2p – 2 = 0 possesses a real solution if

(A) 0  p  1 (B)  1  p  3
(C) 4  p  6 (D) p  6
11. Total number of four digit odd numbers that can be formed by using 0, 1, 2, 3, 5, 7 are
(A) 216 (B) 375
(C) 400 (D) 720
x2 y2
12. If P be a variable point on the ellipse   1 with foci F1 and F2 . If A is the area of the triangle
a2 b2
PF1F2 , then the maximum value of A is
(A) 2 abe (B) abe
(C) 3 abe (D) a2b2 e2
x2 y 2 x2 y2
13. From any point on the hyperbola   1 tangents are drawn to the hyperbola   2 . The
a2 b2 a2 b2
area cut off by the chord of contact on the asymptotes is equal to
(A) ab/2 (B) ab
(C) 2ab (D) 4ab
Part – C (Integer Answer Type)

9. The correct digit below the question number in the ORS is to be bubbled.
1.  
Coefficient of t 24 in (1  t 2 )12  1  t12  (1  t 24 ) is nCr + k, then the value of n  r + k is
m
 1 i 
2. If    1 , then least (+ ve) integral value of m is
 1 i 
x2 y2
3. If the normals at the four points (x1, y1), (x2, y2), (x3, y3) and (x4, y4) on the ellipse   1 are
a2 b2
 1 1 1 1 
concurrent, then the value of (x1 + x2 + x3 + x4) ×      is
x
 1 x 2 x 3 x 4 
x2 y 2
4. Total number of tangents to the hyperbola   1 that are perpendicular to the line
9 4
5x  2y  3  0 is/are
n 3
195 P3
5. The number of positive terms of the sequence  xn  , number xn   ,n  N, is
4  n!   n  1 !
FIITJEE INTERNAL TEST

PHYSICS, CHEMISTRY & MATHEMATICS
CPT–1 PHASE-III CODE: 101037.3 PAPER–1
ANSWERS
PHYSICS (SECTION –I)
1. A, B, C 2. A, D 3. A, B 4. A, C
5. B, C 6. A, B, D 7. B, D 8. C
9. C 10. A 11. D 12. D
13. B 1. 2 2. 2 3. 2
4. 1 5. 7
CHEMISTRY (SECTION–II)
1. A, C 2. A, B 3. A, B, D 4. A, B
5. B, C 6. C, D 7. B, C, D 8. A
9. D 10. C 11. C 12. D
13. C 1. 6 2. 3 3. 4
4. 3 5. 4
MATHEMATICS (SECTION–III)
1. A, C 2. A, B 3. A, C 4. A, B, D
5. A, B 6. A, B 7. B, D 8. A
9. A 10. B 11. D 12. B
13. D 1. 8 2. 4 3. 4
4. 0 5. 4

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FIITJEE –Phase Test (JEE-Advanced)

PHYSICS, CHEMISTRY & MATHEMATICS

C. Marking Scheme For All Two Parts.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

1. A tank, which is open at the top, contains a liquid up to a

3. One mole of a monatomic ideal gas goes through a V

Space for rough work

6. Two solid spheres A and B of equal volumes but of different

7. The equation of two sound waves in medium at x =0 are given by

Space for rough work

PART – A: (Single Correct Answer Type)

10. Two communicating vessels contain a liquid. The diameter of one

Space for rough work

Space for rough work

PART – C: (Integer Answer Type)

3. A container of large uniform cross–sectional area A resting on a horizontal

Space for rough work

1. Which of the following molecules contains only primary hydrogen atoms?

2. Acid rain is due to

3. Stability order of carbocations is

(A) I < II (B) II < III

4. What are the products obtained upon the ozonolysis of 2-pentene?

Space for rough work

6. Which reagent(s) distinguish(es) ethylene from acetylene?

7. Which of the following reactions are yielding correct product as mentioned?

Space for rough work

PART – A: (Single Correct Answer Type)

8. Number of geometrical isomers for 1,8-dichloro-octa-1,3,5,7-tetraene are

9. Which is not aromatic?

10. The smog is essentially caused by presence of

11. Which of the following are aromatic in nature

(1) (2) (3) (4)

Space for rough work

Space for rough work

Part – C (Integer Answer Type)

1. How many of the following species is/are electrophiles?

2. How many of the following statement are correct?

3. What is the number of moles of CH4 formed in the given reaction?

4. How many stereoisomers are possible for 1,3-dichloro cyclopentane.

5. How many degrees of unsaturation does the following structure have?

Space for rough work

6. If n > 1, then (1 + x)n  nx  1 is divisible by

Space for rough work

PART – A: (Single Correct Answer Type)

9. Coefficient of x2009 in (1 + x + x2 + x3 + x4)1001 (1 - x)1002 is

10. The equation 2 sin2x – (p + 3) sin x + 2p – 2 = 0 possesses a real solution if

Space for rough work

Part – C (Integer Answer Type)

Space for rough work

FIITJEE INTERNAL TEST

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Batch :__ Date of Examination :_