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FIITJEE Phase Test (JEE-Advanced)

PHYSICS, CHEMISTRY & MATHEMATICS


PHASE-I DATE: 18.09.2022 Paper – 2

Time Allotted: 3 Hours Maximum Marks: 180

1. Please read the instructions carefully. You are allotted 5 minutes


specifically for this purpose.
2.
Batch: LKITN224B02,C06 (PINNACLE - XI)

You are not allowed to leave the Examination Hall before the end of the
test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
1. This question paper contains Three Sections.
1. Section-I is Physics, Section -II is Chemistry and Section -III is Mathematics.
1. Each section is further divided into Two Parts: Part-A & Part-C.
1. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
1. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with a blue / black ball point pen for each character of
your Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Sections.


(i) Part-A (1 – 4) contains Four (04) Multiple Choice Questions which have four (4) options each and only one
correct option. Each question carries +3 marks for correct answer and –1 mark for incorrect answer.
Part-A (5 – 10) contains Six (06) Multiple Choice Questions which have one or more than one correct
answer. Each question carries +4 marks for correct answer and –2 marks for wrong answer.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is
a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 In all other cases.
(ii) Part-C (1 – 8) contains Eight (08) Numerical based questions with single digit integer as answer, ranging
from 0 to 9 (both inclusive). Each question carries +3 marks for correct answer and –1 mark for wrong
answer.

Name of the Candidate :____________________________________________


Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________

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LKITN224B02,C06-PH-I-ADV.(PAPER-2)

USEFUL DATA
PHYSICS CHEMISTRY
Acceleration due to gravity : g = 10 m/s2 −1 −1
Gas Constant R = 8.314 J K mol
−34
Planck constant : h = 6.6  10 J − s = 0.0821 Lit atm
−19 −1 −1
Charge of electron : e = 1.6  10 C K mol
Mass of electron : me = 9.1  10
−31
kg
= 1.987  2 Cal
−1 −1
−12 2 2 K mol
Permittivity of free space :  0 = 8.85  10 C /N −m
Avogadro’s Number Na = 6.023  10 23
Density of water :  water 3
= 10 kg / m
3
−34
5 2 Planck’s constant h = 6.625 10 J .s
Atmospheric pressure : Pa = 10 N / m −27
Gas constant : R = 8.314 J = 6.625 10 erg .s
1 Faraday = 96500 coulomb
K −1 mol −1 1 calorie = 4.2 joule
−27
1 amu = 1.66 10 kg
−19
1 eV = 1.6  10 J
Atomic No: H = 1, He = 2, Li = 3, Be = 4, B = 5, C = 6, N = 7, O = 8, F = 9, Ne = 10, Na = 11,
Mg = 12, Si = 14, Al = 13, P = 15, S = 16, Cl = 17, Ar = 18, K = 19, Ca = 20,
Cr = 24, Mn = 25, Fe = 26, Co = 27, Ni = 28, Cu = 29, Zn = 30, As = 33, Br = 35,
Ag = 47, Sn = 50, I = 53, Xe = 54, Ba = 56, Pb = 82, U = 92.

Atomic masses: H = 1, He = 4, Li = 7, Be = 9, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23,


Mg = 24, Si = 28, Al = 27, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52,
Mn = 55, Fe = 56, Co= 59, Ni = 58.7, Cu = 63.5, Zn = 65.4, As = 75, Br = 80,
Ag = 108, Sn = 118.7, I = 127, Xe = 131, Ba = 137, Pb = 207, U = 238.

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LKITN224B02,C06-PH-I-ADV.(PAPER-2)

Section – I (Physics)
PART – A
(Single Correct Answer Type)
This part contains 4 Multiple Choice Questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

→ → →
1. There are two vectors A = 2î + ˆj + k̂ and B = î + 2ˆj – 2k̂ , then vector component of A along

B is -

(A)
(
2 ˆi + 2ˆj – 2kˆ ) (B)
2
( 2î + ˆj + k̂ ) (C)
2
( î + 2ˆj – 2k̂ ) (D) None of these
9 3 3

2. At t = 0 a particle leaves the origin with a velocity of 6 m/s in the positive y direction. Its
acceleration is given by a = 2iˆ − 3 ˆj m/s2. The x and y coordinates of the particle at the instant
the particle reaches maximum y coordinate are
(A) 2m, 3m (B) 4m, 6m (C) 1m, 3m (D) 2m, 6m

3. A man crosses the river perpendicular to river flow in time t seconds and travels an equal distance
down the stream in T seconds. The ratio of man's speed in still water to the speed of river water
will be :
t2 – T2 T2 – t 2 t2 + T2 T2 + t 2
(A) 2 (B) (C) (D)
t + T2 T2 + t 2 t2 – T2 T2 – t 2

4. In the given figure the wedge is fixed, pulley is frictionless and string is light. Surface AB is
frictionless whereas AC is rough. If the block of mass 3m slides down with constant velocity, then
the coefficient of friction between surface AC and the block is –
A

3m
m

B 45° 45° C
(A) 1/3 (B) 2/3 (C) 1/2 (D) 4/3

PART – A
(Multi Correct Choice Type)
This part contains 6 Multiple Choice Questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

5. If x = 165.75 and y = 13 then according to significant figures -


(A) x + y = 179 (B) x  y = 13 (C) x × y = 2.1 × 102 (D) x − y = 152.75

6. Two bodies P and Q are moving along positive x-axis their position-time graph is shown below if
→ →
VPQ is velocity of P w.r.t. Q and VQP is velocity of Q w.r.t. P, then –
x
P

t
→ →
(A) | VPQ | = | VQP | = constant

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LKITN224B02,C06-PH-I-ADV.(PAPER-2)


(B) VPQ is towards origin

(C) VQP is towards origin
→ →
(D) VPQ and VQP both can be towards origin at same time

7. A particle starts from rest and accelerates as shown in the graph.


a (m/s2)
2

15 20
t
5 10
–3

Which of the following is (are) correct?


(A) The velocity of particle at t = 10 sec is 20m/s
(B) The distance travelled in the first 20 sec is 262 m
(C) The velocity at the t = 20 sec is 20 m/s
(D) The distance travelled at end of 15 sec is 200 m

8. The graph shows position as a function of time for two trains running on parallel tracks. Which one
of the following statement is false?

(A) At time tB, both trains have the same velocity.


(B) Both trains have the same velocity at some time after tB
(C) Both trains have the same velocity at some time before tB.
(D) Somewhere on the graph, both trains have the same acceleration.

9. A block of mass m is placed in contact with one end of a smooth tube of mass M (see figure). A
horizontal force F acts on the tube in each case (i) and (ii). Then mark correct option:
M

F m (i)

F m (ii)

F F
(A) am = 0 and aM = in (i) (B) am = aM = in (i)
M M +m
F mF
(C) am = aM = in (ii) (D) Force on m is in (ii)
M +m M +m

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LKITN224B02,C06-PH-I-ADV.(PAPER-2)

10. A uniform chain of length 1 m is placed on a rough horizontal table with a part of it hanging over
the edge of the table. It is found that if the length of the hanging part is 25 cm or more, the chain
starts sliding downwards. Which of the following is/are correct?
(A) The coefficient of friction between the table and the chain is 1/3
(B) The coefficient of friction between the table and the chain is 1/4
(C) The chain will move with a uniform acceleration
(D) The acceleration of the chain will increase till it loses contact with the table

PART – C
(Numerical Based with Single Digit Integer as Answer)
This part contains 8 questions. The answer to each question is a single digit integer ranging from 0 to 9
(both inclusive).

1. A conveyor belt of width 10 m is moving along x-axis with speed 4 m/s as shown in the figure. Two
points A and B are situated on the conveyor belt. A person wants to move from A to B in least time.
His speed with respect to belt is 2 m/s. The time taken by the person (in second) is:
B

4 m/s
A

2. A particle is moving along the locus: y = kx (k = 2) with a constant speed v = 6 m/s. At t = 0, it is
at the origin and about to enter the first quadrant of x-y axes. At some later time t > 0, vx = vy. At
this moment, the value of |ay – ax| in m/s2 is

3. Figure shows the graph of the x-co-ordinate of a particle going along the x-axis as function of time.
Find the instantaneous speed of particle at t = 12.5 s (in m/s)
x

8m A

4m

O 4s 8s 12s 16s B

4. Two second after projection a projectile is travelling in a direction inclined at 30º with horizontal,
after one more second it is travelling horizontally. Angle of projection (in degree) with horizontal
divided by 10 is

5. A system consisting of man on platform is in equilibrium. Mass of man and platform are equal. If
tension in left string is T1 which is equal to one-fourth of weight of man and that in right string in T2,
then 2T1/T2 is -

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LKITN224B02,C06-PH-I-ADV.(PAPER-2)

6. A particle is moving on a straight line with constant retardation of 1 m/s2. What is the average
speed (in m/s) of the particle on the last two meters betore it stops?

7. A block of mass 1 kg lies on a horizontal surface in a truck. The coefficient of static friction
between the block and the surface is 0.6. If the acceleration of the truck is 5 m/s2, then what
frictional force acting on the block (in newton)?

8. In the figure, find the minimum value of mass ‘m’ (in kg) of the rod rod
so that the block of mass M =12 kg remains stationary on the
inclined plane (take g = 10 m/s2) assume there is no friction m  = 0.5
 3
between rod and block.  sin37o =  M
 5

0
37

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LKITN224B02,C06-PH-I-ADV.(PAPER-2)

Section – II (Chemistry)
PART – A
(Single Correct Answer Type)
This part contains 4 Multiple Choice Questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

1. How many gram of oxygen is present in 49 gram of sulphuric acid(H2SO4)?


(A) 64 (B) 32 (C) 16 (D) 8

2. Given that the abundances of isotopes 54Fe, 56Fe and 57Fe are 5%, 90% and 5%, respectively. The
atomic mass of Fe is
(A) 55.85 (B) 55.95 (C) 55.75 (D) 56.75

3. Which of the following has maximum number of atoms?


(A) 24 g of C (Mol. Wt. = 12 g mol–1) (B) 23 g of Na (Mol. Wt. = 23 g mol–1)
(C) 48 g of S (Mol. Wt. = 32 g mol–1) (D) 108 g of Ag (Mol. Wt. = 108 g mol–1)

4. The radial wave equation for hydrogen atom is:


3/2
1  1
  (x − 1)(x − 8x + 12) e
−r /2
= 2

16 4  a0 
where x = 2r / a0 ;a0 = radius of first Bohr orbit. The minimum and maximum position of radial
nodes from nucleus are:
a0 a0 a0
(A) a0 ,3a0 (B) ,3a0 (C) ,a0 (D) ,2a0
2 2 2

PART – A
(Multi Correct Choice Type)
This part contains 6 Multiple Choice Questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

5. A solution contains 4 g NaOH. Which of the following solutions can completely neutralize it?
(A) 200 mL of 0.5 M HCl (B) 500 mL of 0.1 M H2SO4
(C) 400 mL of 0.25 M KOH (D) 1000 mL of 0.1 M NaCl

6. Which of the following subshells does not exist for an atom according to quantum theory?
(A) 2d (B) 4f (C) 3f (D) 6f

7. Which of the following quantities are dependent on temperature?


(A) Molarity (B) Normality (C) Molality (D) Mole fraction

8. Find correct statement(s):


(A) Methane : Tetrahedral (B) Ammonia : Pyramidal
(C) Water : Bent (D) BeF2 : Linear

9. Which of the following contain one mole of atoms?


1
(A) mole of H2SO4 (B) 15 gram of NO
7
(C) 5.6 L of SO3 at STP (D) 1g – atom of hydrogen

10. Element corresponding to which of these/this atomic number belongs to p-block in Modern
Periodic Table:
(A) 19 (B) 35 (C) 53 (D) 83

PART – C
(Numerical Based with Single Digit Integer as Answer)

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LKITN224B02,C06-PH-I-ADV.(PAPER-2)

This part contains 8 questions. The answer to each question is a single digit integer ranging from 0 to 9
(both inclusive).

1. Number of moles of atoms present in 18 g H2O is

2. How many maximum number of electron(s) of an atom of nitrogen will have s = +½?
s = spin quantum number

3. Find out ratio of sigma (  ) and pie (  ) bond in ethene.

4. Total number of p − d bonds in SO24− is

5. Number of plane of symmetry in CH2Cl2 is

h
6. is the angular momentum of the electron in the n = _____ orbit of He+ .

7. Identify the group (in Modern Periodic Table) and valency of a hypothetical element having atomic
number 119. If group number is x and valency is y. Give the value of x + y.

8. What will be the maximum number of lines possible for Balmer series when a set of 8 hydrogen
atoms are irradiated with light and all are excited to 6th excited state and spectrum is obtained?

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LKITN224B02,C06-PH-I-ADV.(PAPER-2)

Section – III (Mathematics)


PART – A
(Single Correct Answer Type)
This part contains 4 Multiple Choice Questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

1. If y = x sinx , then
1 dy 1 dy 1 1 dy 1
(A) = + cot x (B) = + cot x (C) = − cot x (D) None of these
y dx x dx x y dx x

d 2 x
2. (x e sin x ) =
dx
(A) x e x (2 sin x + x sin x + x cos x ) (B) x e x (2 sin x + x sin x − cos x )
(C) x e x (2 sin x + x sin x + cos x ) (D) None of these

cos x − 1
3.  cos x + 1
dx =

x 1 x 1 x x
(A) 2 tan − x + c (B) tan − x + c (C) x − tan + c (D) x − 2 tan +c
2 2 2 2 2 2

4. If (1, 3), (2, 5) and (3, 3) are three elements of A × B and the total number of elements in A  B is 6, then the
remaining elements of A  B are
(A) (1, 5); (2, 3); (3, 5) (B) (5, 1); (3, 2); (5, 3)
(C) (1, 5); (2, 3); (5, 3) (D) None of these
PART – A
(Multi Correct Choice Type)
This part contains 6 Multiple Choice Questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

5. If tan 1° tan 2° ....tan 89° = x2 – 8, then the value of x can be -


(A) – 1 (B) 1 (C) – 3 (D) 3

6. If tan2  = 2 tan2  + 1, then value of cos 2 + sin2  is


(A) 1 (B) 2 (C) 0 (D) independent of 

1
7. Ifsin x + cos x = y + , x  0,  , then
y
(A) x =  / 4 (B) y = 1/ 2
3x
(C) y = 1 (D) x =
4

8. If sin (  cos ) = cos (  sin ) , then sin 2 is equal to


(A) 3/4 (B) – 3/4
(C) 1/4 (D) – 1/4

9. The solution of the equation 7log x – 5log x + 1 = 3.5log x –1 – 13.7log x –1 is


(A) an even number (B) rational number (C) irrational number (D) composite number

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LKITN224B02,C06-PH-I-ADV.(PAPER-2)

2
10. The x-values satisfying the equation | x − 1 |log 3 x −2 log x 9 = (x – 1)7 is/are
1
(A) (B) 1 (C) 2 (D) 81
3

PART – C
(Numerical Based with Single Digit Integer as Answer)
This part contains 8 questions. The answer to each question is a single digit integer ranging from 0 to 9
(both inclusive).

1. The value of 3log5 7 − 7log5 3 = …………

2. For ( (
log 7 log5 x+5 + x )) = 0, x is equal to ___
3  
3. If     , then the expression 4 sin4  + sin2 2 + 4 cos2  −  is equal to:
2 4 2

4. Number of real solutions of the equation x2 + 3 x + 2 = 0 is

sin80o sin 65o sin35o


5. Let P = then the value of 24P is:
sin 20o + sin50o + sin110o

6. The number of solutions of the sin 3 = 4sin  sin ( x +  ) sin ( x −  ) , ( 0     ) in each


quadrant, is ____

1
7. If log(1− x ) 3 − log(1− x ) 2 = , then the value of ( −4x ) is
2
8. If a, b, c are distinct positive numbers, each different from 1, such that (logba logca – logaa) +
(logab logcb – logbb) + (logac logbc – logcc) = 0, then abc =

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LKITN224B02,C06-PH-I-ADV.(PAPER-2)

FIITJEE INTERNAL TEST


Batch: LKITN224B02,C06 (PINNACLE - XI)

IIT-JEE 2024
PHASE – I PAPER – II
ANSWERS
DATE: 18.09.2022
PHYSICS
Part – A
1. A 2. B 3. C 4. B
5. ABC 6. AC 7. ACD 8. ABD
9. ACD 10. AD
Part – C
1. 5 2. 9 3. 2 4. 6
5. 7 6. 1 7. 5 8. 6

CHEMISTRY
Part – A
1. B 2. B 3. A 4. B
5. AB 6. AC 7. AB 8. ABCD
9. ABCD 10. BCD
Part – C
1. 3 2. 5 3. 5 4. 2
5. 2 6. 2 7. 2 8. 5

MATHEMATICS
Part – A
1. A 2. A 3. D 4. A
5. CD 6. CD 7. AC 8. AB
9. ABD 10. CD
Part – C
1. 0 2. 4 3. 2 4. 0
5. 6 6. 1 7. 5 8. 1

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