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Sankalp2224 S & T
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. SECTION–I is Physics, SECTION–II is Chemistry and SECTION–III is Mathematics.
4. Each part is further divided into one part: Part – A
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment No.
and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All One Part.
Part–A (01 – 07) contains 07 multiple choice questions which have one or more than one correct answer.
Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Part–A (08 – 14) contains 07 Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Part–A (15 – 18) contains 2 Paragraphs. Based upon each paragraph, 2 Multiple Choice Questions have to
be answered. Each question has Only One Correct answer and carries +3 marks for the correct answer
and 0 mark for a wrong answer.
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-2
SECTION – I : PHYSICS
PART – A: (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
1. Consider a wire carrying a steady current, I placed in a uniform magnetic field B perpendicular to its
length. Consider the charges inside the wire. It is known that magnetic forces do no work. This
implies that,
(A) motion of charges inside the conductor is unaffected by B since they do not absorb energy.
(B) some charges inside the wire move to the surface as a result of B.
(C) If the wire moves under the influence of B, no work is done by the force.
(D) if the wire moves under the influence of B, no work is done by the magnetic forces on the ions,
assumed fixed within the wire.
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-3
B-2
(A) The potential difference across both the battery will be equal.
(B) Rate of heat dissipation in both batteries is equal.
(C) One battery will charge the other battery.
(D) Rate of loss in chemical energy of one battery is more than the rate of gain in chemical energy of
the other.
4. Consider a region where both uniform electric and magnetic fields E and B are present both along the
z-axis. A positively charged particle of charge q and mass m is released from the origin with initial
velocity v 0 ˆi . Which of the following option(s) are correct?
M 2mv
(A) The y coordinate of the particle at time t = is
qB qB
(B) The distance between two consecutive point on the z-axis where the particle touches the z-axis is
an odd multiple of a constant distance.
(C) The distance between two consecutive point on the z-axis where the particle touches the z-axis is
an even multiple of a constant distance.
2m
(D) The time after which the particle touches the z-axis is .
qB
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-4
5. An ammeter has a resistance of 50 and a full scale deflection current of 50 A. It can be used as a
voltmeter or as a higher range ammeter provided that a resistance is added to it. Choose the correct
range and resistance combinations from the following.
(A) 20 V range with approximately 400 k resistance in series.
6
(B) 100 V range with approximately 2 10 resistance in series.
(C) 1 mA range with 50 resistance in parallel.
(D) 0.1 mA range with 50 resistance in parallel.
A B
6. Three charges are placed at points A, B and P. The
magnitudes of these three charges are q1, q2 and q.
Resultant force on the charge at P due to others.
q PA 3
(A) will pass through the centre of AB if 1 P
q2 PB3
q1 PA 2
(B) will pass through the centre of AB if
q2 PB2
(C) will pass through the centre of AB if PA = PB and q1 = q2
(D) will pass through the centre of AB if PA = PB, for all values of q1 and q2.
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-5
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
8. In a certain region of space, there exists a uniform and constant electric field of strength E along x-
axis and uniform and constant magnetic field of induction B along z-axis. A charged particle having
charge q and mass m is projected with speed v parallel to x-axis from a point (a, b, 0). When the
b
particle reaches a point (2a, , 0) its speed becomes 2v. Find the value of electric field strength in
2
terms of, m, v and co-ordinates.
3 mv 2 mv 2
(A) (B)
2 qa qB
2mv 2 3
(C) vB (D)
qBa 2
9. In a certain region of space electric field is given by E 2iˆ 3ˆj 4kˆ . The change in potential observed
by a man who moves from point (1, 0, 5) to the point (4, 2, 6) is. (Electric field is in N/C and co-
ordinates are in meter).
(A) 4V (B) 4V
1 53
(C) (D) V
3 18
10. A point charge Q is kept at a point (0, 0, a/2) as shown in the figure. z
Find the electrostatic flux through surface OABO.
Q Q Charge +Q (0, 0, a/2)
(A) (B)
60 120
Q Q (0, a/2, 0)
(C) (D) O
240 480 B y
(a/2, 0, 0)
A
x
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-6
11. Two point charges of magnitude q & 3q are located at a distance of 'a' from each other within an
infinite dielectric medium of dielectric constant k. The force by the larger charge 3q, on the dielectric
equals
1 1 3q2
(A) zero (B) 1 2
0 k a
1 3q2
(C) (k 1) 2 (D) none of the above
40 a
R
(A) The potential at point P is
20
R
(B) The potential at point A is
40
q0 R
(C) Word done by electrostatic force if a charge ‘q0’ is moved from P to A is
40
q0 R
(D) Word done by electrostatic force if a charge ‘q0’ is moved from P to A is
40
13. A capacitor of capacitance 2 F is charged to a potential 2F
difference of 5V. Now the charging battery is disconnected and
the capacitor is connected in parallel to a resistor of 5 and
another resistor of unknown resistance R as shown in figure. If
the total heat produced in 5 resistance is 10 J then the 5
unknown resistance R is equal to
(A) 10
(B) 15 R
(C) (10/3)
(D) 7.5
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-7
This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Question Stem
In the circuit shown, the switch ‘S’ is closed at t = 0. The charges on C1=2F 4
the capacitors C1 and C2 in the steady state are q1 C and q2 C
respectively.
2 5
C2=3F
6 2
S
5
E=32V
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-8
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-9
O
(i) N3H, H H2O/ O H
1. PhCOOH A (ii)
(B) (C)
int ermediate
Which of the following statements is/are correct about the reaction ?
(A) The compounds (B) and (C), respectively, are Ph — N C O and PhNH2
O
(B) The compounds (B) and (C), respectively, are PhN C and PhNHMe
(C) the reaction is known as Curtius rearrangement reaction
(D) the reaction is known as Schmidt rearrangement reaction
2. The structure of AZT (azidothymine) is given below. It is used to treat AIDS patients. It fights and
AIDS infection but does not cure it
O
NH
O N O
HO
N N N (AZT)
Which of the following statement(s) is/are correct about AZT ?
(A) It shows acidic property
(B) It undergoes tautomerisation
(C) It gives white precipitate with with (ZnCl2 + HCl) (Lucas ragent)
(D) Azide ion (NO
3 ) cannot be replaced by Br
O
via SN2 reaction
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-10
(I) (II)
(C) NH
N
H
N NH
(I) (II) (III)
(D)
N N
H H
4. D-Glucose and D-fructose both form the same osazone. Which statement(s) is/are correct about the
above reaction ?
(A) Glucose and fructose are epimers
(B) Glucose and fructose are anomers
(C) The configuratiosn of the OH group at C-3 and C-4 in glucose and fructose are same
(D) The configurations of the OH group at C-4 and C-5 in glucose and fructose are same
5. Which of the following statement(s) is/are correct about the given below intramolecular Cannizzaro
reaction?
O O
|| ||
OH
Ph C C H
(A) OH attacks at C-1 of aldehyde group (B) OH attacks at C-2 of ketone group
(C) H transfer takes place from C-1 to C-2 (D) Phenyl ion migrate from C–2 to C–1
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-11
X
NO2
7. when treated with H N Where X = F, Cl, Br, I
NO2
O O
OH
8. P (dicarbonyl compound)
(A) (B)
(C) (D)
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-12
13. The pH at which the solubility of the below mentioned compound in water is minimum, is?
+
H3N COOH pK a 4
pK a 11 +
NH3
pK a 9
(A) 6.5 (B) 7.5
(C) 10 (D) 9
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-13
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-14
H2 /Pt [O]
Carboxylic acid (C) (C9H10O 2 )
(A) (C9H8O2 ) Chiral KMnO4
(E)
H2 /Pt [O] (PhCOOH)
Carboxylic acid (D) (C9H10O2 )
(B) (C9H8 O2 ) Achiral
COOH
(A) (B)
Ph
COOH
Ph COOH
(C) (D) Both (A) and (C)
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-15
CH3
(II) conc. HCl
CH3 3 C CH2 OH Q
CH3
(B) (CH 3) 2C CH CH(CH 3) 2 and CH3 3 C CH2 Cl
Cl
(C) (CH3)2C CH(CH3)2 and (CH3)2C CH2CH3
Cl Cl
(D) (CH3)2C CH Cl and (CH3)2C CH 2CH3
CH3 Cl
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-16
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
1. If |f(x)| 1, x R and f(0) = f(0) = 0, then which of the following can’t be true
1 1
(A) f (B) f(2) = – 5
2 5
1 1
(C) f(– 2) = 5 (D) f
2 5
n
2. The maximum number of real roots of the equation x + px + q = 0, (n N), is
(A) 3 if n is odd (B) 2 if n is even
(C) n (D) nothing can be said
1 x 2 2 x 2
4. x cos x sin x 4
dx equals
sinx
2 x 1 dx – sin x dx 0 dx esin2 x 1dx 0
2 2 sin x
(A)
0 1
(B) e
1
0
4 1 4 1
2
(C) sin x 2 3 dx sin x 2 12x 33 dx 0 (D) cos x 2 dx 8 cos 162 x 1 dx 0
5 2 4 0
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-17
1
sin n x
2 dx , n N is
6. The value of x
0 sin
2
(A) independent of n (B) 2n
n
(C) (D)
2
3
7. If f(x) be such that f(x) = max{|2 – x|, 2 – x }, then
(A) f(x) is continuous x R (B) f(x) is differentiable x R
(C) f(x) is non-differentiable at one point only (D) f(x) is non-differentiable at 4 points only
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
8. If f(x) be a positive, continuous and differentiable function on the interval (a, b). If lim f x 1
x a
1
and lim f x 31/ 4 . Also f(x) f3(x) + , then
x b f x
(A) b – a (B) b – a
24 24
(C) b – a = (D) none of these
12
1 1
9. If F(x) = and g(x) = sin–1 (2|x|) then, F(x) = g(x) has
x 2 x 3
(A) no solution (B) less than 2 solutions
(C) at least one solution (D) none of these
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-18
2
10. If f(x) is a twice differentiable function such that f(0) f(2) 3;f (0) f (2) 1 then x f (x)dx is
0
(A) 3 (B) 2
(C) 1 (D) 0
dx
11. If cos 3
A tan1 sin x cos x Bln(f(x)) C , then A is equal to
x sin3 x
2 2
(A) (B)
3 5
2
(C) (D) none of these
3
2
sin2 x
12. The value of x
dx, ([.] denotes the greatest integer function) is
0.5
2
(A) 1 (B) 0
(C) 4 - sin 4 (D) None
13. If f(x) = [x 2] – [x]2 , where [.] denotes the greatest integer function, and
x [ 0, n], n N, then the number of elements in the range of f(x) is
(A) 2n + 1 (B) 4n – 3
(C) 3n – 3 (D) 2n – 1
3
14. If f : , 1,1;f x sin x and g : 0, 1,1;g x cos x also
2 2
f x g1 x ,f 1 x g1 x x 1,1 then
1
7
(A) max 2 3 (B) max 2
2
7
(C) min 2 3 (D) min 2
2
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-19
This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
dn f x n
x d f x
Let f : R R be a function such that
dxn
exists for all n N and lim
n
e
dxn dx = 0 x R, f(x) –
df x d2f x d3 f x d4 f x d5 f x
dx
dx 2
dx3
dx 4
dx5
= x Then, by using ex f x dx e x f x e x f x dx , answer the
following:
1
x
18. e f x dx
0
is equal to
(A) 1 (B) e – 1
(C) e2 – 1 (D) none of these
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-20
ANSWERS
PHYSICS (SECTION –I)
1. B, D 2. A, B, C, D 3. A, C, D 4. A, B, D
5. A, B, D 6. A, C 7. A, B, C 8. A
9. B 10. C 11. B 12. A
13. C 14. B 15. B 16. C
17. B 18. B
1. A, D 2. A, B, D 3. A, B, C 4. C, D
5. A, C 6. A, B, D 7. B, C, D 8. B
9. D 10. C 11. D 12. B
13. C 14. A 15. B 16. A
17. A 18. C
1. A, B, C, D 2. A, B 3. A, B 4. B, C
5. A, D 6. A, C 7. A, D 8. B
9. C 10. B 11. A 12. B
13. D 14. B 15. C 16. C
17. B 18. B
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-21
1. B, D
2. A, B, C, D
3. A, C, D
| E E2 E3 E 4 |
i 1
r1 r2 r3 r4
4. A, B, D
5. A, B, D
For ammeter, RA
A
imax RS R A Imax
i
R
S
I Rs
i = 0.1 mA for Rs = 50 [as RA = 50 and imax = 50 A]
For voltmeter, RA Rv
V = imax (RA + RV) A
Imax
V 10 V for Rv = 200 k
v
6. A, C
7. A, B, C
Using the symmetry of the circuit
2
CAE = F
3
8
CAI = F
7
12
CHI = F
7
6
CHB = F
5
8. A
Change in kinetic energy is only due to work done by electric field.
9. B
dV = E.dr
10. C
11. B
Force on 3q due to all charges is given by coulomb's law in vacuum.
1 3q2
Force on 3q due to all charges (q and dielectric) is ;
k.40 a2
1 3q2 1 1 3q2
Force on 3q due to q is , therefore that due to dielectric is (1 ) .
40 a2 40 k a2
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-22
12. A
kQ R
Potential at ‘C’ =
R 20
Flat surface of hemispherical shell is on equipotential surface.
13. C
14. B
15. B
16. C
15-16. The equivalent circuit is shown in the steady state.
C1=2F 4
32
I 1.6 A
20
Potential drop across the capacitor C1 2 5
V1 I(6 5) 1.6 11 17.6 volt C2=3F
q1 C1V1 2 17.6 35.2 C
Potential drop across the capacitor C2, 6
V2 I(5 4) 1.6 9 14.4 volt I
q2 C2 V2 3 14.4 43.2 C 5
=32V
17. B
18. B
8y
Sol.17-18. i 0 B mg A
i
B
3
37
37
3mg
y0
8iB
y0 = 10 B
If loop is displaced by small y downward. Then,
8
ma mg iB (y y 0 )
3 y0
8iB
a y C
3m
8iB
3m
2
T 2
1. A, B, C, D
– 1 f(x) 1 on integrating it twice with limits 0 and x, we get
x2
|f(x)|
2
1 1
f and |f(2)| 2.
2 8
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-23
2. A, B
f(x) = xn + px + q
n1
f(x) = n x + p
f(x) = 0 have maximum of two or one real roots as n 1 is even or odd
f(x) = 0 can have maximum of three or two real roots as n is odd or even.
3. A, B
In f(x) = (1 – x) ln (1 + x) + (1 + x) ln (1 – x)
x2 x3 x 2 x3
= 1 x x .......... 1 x x ..........
2 3 2 3
1 1 1 1 1
= 2 x 2 1 x 4 x 6 .......... < 0
2 4 3 6 5
0 < f(x) < 1
4. B, C
x cos x + sin x = 1 x 2 cos x cot 1 x
2 x2
I 1 x 2
sec 4 x cot 1 x dx
dt 2 x 2
Put t = x – cot–1 x =
dx 1 x 2
tan3 t
I sec 4 tdt 1 tan t sec tdt
2 2
= tan t
3
c
tan3 x cot 1 x
I tan x cot 1 x c
3
ALITER
Put x = tan t dx = sec2 t dt
x cos x + sin x = sec t sin (x + t)
1 x 2 2 x2 sec 2 t 1 sec 2 t
x cos x sin x dx = sec 4
sec 2 tdt
4
t sin4 x t
1 sec 2 t 4
= sin 4 tan t t
dt = cosec u du u tan t t
cot u 3 3
1 1 x tan x 1 x tan x
= cot u c = c
3 3 x tan x x tan x
5. A, D
b 1
Since f x dx b a f b a x adx ,
a 0
2 1 1
2
sin x 2dx sinx 1 dx sin x 2 2 x 1 dx
1 0 0
4 1
2
cos x 2 dx 8 cos8 x 4 dx
4 0
0
2
= 8 cos 162x 1 dx .
1
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-24
6. A, C
1 3 1
sin n x
sin n x sin n x
2 dx I I 2 2 dx
Let, In x
n 1 n x
0 sin 0 sin
2 2
2
= 2 cos(n 1)xdx = sin n 1 x 0 0
n1
0
I0 = I1 = I2 = ….. = In
Hence, In = I0 =
dx
0
7. A, D
Clearly from the graph, f(x) is
continuous x R but not y=2–x y=x–2
differentiable at – 1, 0, 1, 2 (4 points).
(0, 2)
–1 1 (2, 0)
3
y=2–x
8. B
1
Since f(x) f 3(x) +
f x
f x f x
f(x) f(x) f 4(x) + 1 1
1 f 4 x
on integrating w.r.t. x from x = a to b
1 b
2
tan1 f 2 x b a
a
1
or b – a lim tan1 f 2 x lim tan1 f 2 x or b – a
.
2 x b x a 24
9. C
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-25
y = f(x)
1 1
, ,
2 2 /2 2 2
1 16 1 16
, ,
2 5 2 5
–2 –1/2 0 1/2 2
y = g(x)
Clearly, 2 solutions
10. B
2 2
11. A
dx
I= cos x sin x 1 sin2x
2
cos x sin x dx
=
1 sin2x 1 sin2x
2
Put cosx + sinx = t
(cosx – sinx)dx = dt
2dt 2 1 1
I=
2 t2 t 2 1 3 t 2 1 t2 2
dt
2 1
= tan1 sin x cos x ln(f(x)) C
3 3 2
12. B
13. D
When x = n –1, f(x) = (n –1)2 – (n –1)2 = 0
When n –1 < x < n, [x] = n –1, (n – 1)2 [x2] n2 – 1
0 [x2] – [x]2 n2 – 1 – (n –1)2
0 f(x) 2n –2.
Since f(x) has to be an integer,
the set of values of f(x) is {0, 1, 2, . . .,2n –2}
14. B
f 1(x) sin1(x) and g1(x) cos1(x)
15. C
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-26
16. C
–1 1
We know that (f )(x) =
f f 1
x
1
(f –1)(3) =
f 0
f f 1 x f 1 x
also, (f –1)(x) = 2
f f 1 x
f f 1 3 2cos sin1 cos1
(f –1)(3) = 3
.
f f 1 3 sin5 sin1
g(x) = x(f –1)(x) + f –1(x) – f(f –1(x)) (f–1)(x)
–1
g(x) = f (x)
1
g(x) = (f –1)(x) = (f–1)(3) = 2
.
sin sin1
17. B
18. B
x
e f x dx = e x f x ex f x dx
(Applying integration by parts on the integral on R.H.S)
e x f x dx ex f x ex f x e x f x dx
(Repeatedly apply integration by parts on the integral in R.H.S)
dnf x
ex f x dx e x f x f x f x f x f x ... + lim e x
dx given to be’0’
n dxn
df x d2 f x d3 f x
ex f x dx e x f x 2
3
... …(1)
dx dx dx
2 3 4 5
df x d f x d f x d f x d f x
consider f(x) – . = x …(2)
dx dx 2 dx3 dx 4 dx5
differentiating both sides 6n times (where n can be any natural number)
d6n 2 3 4 5 6n
f x df x d f x d f x d f x d f x d x = 0
dx6n dx dx 2 dx3 dx 4 dx 5 dx 6n
d6n d6n1 d6n3 f x d6n 3 d6n 4 f x d6n 5 f x
f x 6n1 6n 3 f x = 0 n N …(3)
dx 6n dx dx 6n 2 dx dx6n 4 dx6n 5
Using (2), (3)
df x d2 f x
f(x) – ...
dx dx2
df x d2f x d3 f x d4 f x d5 f x
= f(x) – . +
dx dx 2 dx3 dx 4 dx5
d6n d6n1 d6n3 f x d6n3 d6n 4 f x d6n 5 f x
dx 6n
f x 6n 1
dx dx 6n 2
6n 3 f x
dx dx 6n 4
dx 6n 5
=x+0
df x d2 f x
f(x) – ... = x
dx dx2
Using (1)
x x
e f x dx = xe
differentiating w.r.t x exf(x) = xex + ex f(x) = x + 1
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Sankalp2224 S & T(Ph-4)_Paper-2_PCM(1000764.1)-27
e x f x dx e x dx e 1
0 0
f(x) is clearly increasing, one–one function.
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