Fiitjee: Physics, Chemistry & Mathematics

FIITJEE
PHYSICS, CHEMISTRY & MATHEMATICS
CPT-1 CODE: 120204 PAPER - 2

Time Allotted: 3 Hours Maximum Marks: 201
 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
BATCHES – All 1719
2. This question paper contains Three Sections.

3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.

(i) Part-A (01 – 06) contains 6 Multiple Choice Questions which have Only One Correct answer. Each
question carries +3 marks for correct answer and –1 mark for wrong answer.
Part-A (07 – 09) contains 3 Assertion-Reasoning Questions (MCQs) which have Only One Correct
answer. Each question carries +3 marks for correct answer and – 1 mark for wrong answer.
Part-A (10 – 15) contains 2 Paragraphs. Based upon each paragraph, 3 Multiple Choice Questions
have to be answered. Each question has Only One Correct answer and carries +4 marks for the
correct answer and –1 mark for a wrong answer.
(ii) Part-B (01 – 02) contains 2 Matrix Match Type Questions which have statements given in 2
columns. Statements in the first column have to be matched with statements in the second column.
There may be One or More Than One Correct choices. Each question carries +8 marks for all
correct answer however for each correct row +2 marks will be awarded and –1 mark for each row
matched incorrectly.
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
JEE Adv. Test-1(1719) (Paper-2)–PCM-2
S
SEEC
CTTIIO
ONN–– 1
1:: P
PHHY
YSSIIC
CSS
PART – A
(Single Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
1. An opaque sphere of radius R lies on a horizontal plane.

On the perpendicular line through the point of contact, there R
is a point source of light at a distance R above the sphere.
The area of the shadow on the plane is
(A) R2 (B) 2R2
(C) 3R2 (D) 4R2 R
2. The x-z plane separates two media A and B of refractive indices 1 = 1.5 and 2 =2. A ray of light
travels from A to B. Its directions in the two media are given by unit vectors u1  aiˆ  bjˆ and
u2  ciˆ  djˆ . Then
ad 4 ad 3 bc 4 bc 3
(A)  (B)  (C)  (D) 
cb 3 cb 4 ad 3 ad 4
3. A thin sheet of mass m, radius R and charge Q uniformly distributed

over it rotates with an angular speed .
0 QR
(A) The magnetic induction at the center of the sheet is
2
Q
(B) The electric field at the centre of the disc is
40R2 + + Q + 
+
 QR
(C) The magnetic dipole moment of the disc if 0
3
(D) The ratio of magnetic of dipole moment and angular momentum
Q
of the disc is
2m
4. An electroststic field line leaves at angle  from point change q1
and connects with point charge –q2 at angle ;  *(see in fig.(11)).  
Then the reflection between  and  is +q1
-q2
(A) q1 sin2   q2 sin2 
Figure 11:
(B) q1 tan   q2 tan 
 
(C) q1 sin
2
 q2 sin2
2 2
 
(D) q1 cos  q2 cos
2 2
space for rough work
JEE ADV PAPER – 2– PCM-3
5. A long flexible inextensible rope of uniform linear mass

density  is being pulled on a rough floor with horizontal F
force f in such a way that its lower part is at rest and
upper part moves with constant speed v see given figure
the magnitude of f will be
(A) 2v 2 (B) v 2

(C) v 2 / 2 (D) some function of time and not constant.
0
30
6. Two blocks with masses m 1 and m2 of 10 kg and 20 kg respectively are
placed as shown in the figure , s = 0.2 between all surfaces, then the
tension in string and acceleration of m 2 block will be
(A) 250 N, 3 m/s2 (B) 200 N, 6 m/s2
(C) 306 N, 4.7 m/s 2 (D) 400 N, 6.5 m/s2 m1 m2
PART – A
Assertion – Reason Type
This section contains 3 questions numbered 7 to 9. Each question contains STATEMENT-1 (Assertion) and
STATEMENT – 2 (Reason). Each question has 4 choices (a), (b), (c) and (d) out of which ONLY ONE is
correct.
7. Statement-1:
When charges are shared between two bodies, there occurs no loss of charge but there may occur a
loss of energy.
Statement-2:
In case of sharing of charges, conservation of energy fails.
(A) Statement-1 is true, Statement-2 is true, Statement-2 is a correct explanation for Statement-1
(B) Statement-1 is true, Statement-2 is true, Statement-2 is not a correct explanation for Statement-1.
(C) Statement-1 is true, Statement-2 is false.
(D) Statement-1 is false, Statement-2 is true.
8. Statement-1:
In a standing wave formed in a stretched wire, the energy of each element of the wire remains constant.
Statement-2:
The net energy transfer in a standing wave is zero.
9. Statement-1:
Dispersion can be observed by using a prism only and not by a glass slab.
Statement-2:
The process of dispersion can be explained by cauchy’s formula.
(Paragraph Type)
This section contains 2 paragraphs. Based upon the paragraphs 3 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Paragraph for Question no. 10 to 12
A cylinder fitted with a piston which without friction contains

one mole of an ideal gas. The wall of the cylinder and piston
c=2mF
are adiabatic. The cylinder contains a resistor of resistance R =
2 k  which is connected to a capacitor of capacity C=75 mF.
R=2K 
 640 
Initially potential difference across capacitor is  3  V and
  S
switch is open .When switch is closed for(2.5 In 4) min, the gas
expands isobarically and its temperature increases by 72 K.
Heat loss though the wires is negligible (R = 8.3 J mole-1 k-1)
10. Work done by the gas is approximately

(A) 0.2kJ (B) 0.4kJ (C) 0.6kJ (D) 0.8kJ
11. Increment in internal energy of gas is

(A) 1 kJ (B) 2kJ (C) 3kJ (D) 4 kJ
12. The value of adiabatic exponent  for gas is

(A) 1.1 (B) 1.3 (C) 1.6 (D) 2.5

a0
An object is thrown from a point A on horizontal Breeze
ground as shown Air blows from right to left so that u0
it imparts a constant acceleration “a0” to object

towards left. Answer the following
A g
13. The value of “a0” such that projectile follows a straight line path is
(A) g tan (B) g cot (C) g sin (D) g cos
14. If condition in above case is satisfied maximum vertical height attained by object above horizontal
ground is
u02 sin2  u02 sin2  2u02 sin2 
(A) (B) (C) (D) None of these
g 2g g
15. It follow straight path up, then down back to fall to same point A. A small object of mass m is suspended
by a thread of length and released when thread is horizontal. Find out velocity of the object when its
vertical component is maximum
2 3 2
(A) g (B) g (C) g (D) g
3 2 3
PART - B
Matrix-Match Type
This section contains 2 questions. Each question contains statements given in two columns which have
to be matched. Statements (a, b, c, d) in Column I have to be matched with statements (p, q, r, s) in
Column II. The answer to these questions have to be appropriately bubbled as illustrated in the
following example. If the correct matches are a-p, a-s, b-q, b-r, c-p, c-q and d-s, then the correctly
bubbled 4 × 4 matrix should be as follows :
p q r s
(a) p q r s
(b) p q r s
(c) p q r s
(d) p q r s
1. In the experimental setup shown S is a point source

of monochromatic light placed at a distance ‘d’ from d
a photocell. The potential difference across the
photocell ‘V’ is sufficient to attract all the A Anode
photoelectrons emitted by the cathode. Under initial Photocell
conditions photoelectrons are emitted. Match the
Cathode
changes given in Column-I with the results given n
Column-II.
Column-I Column-II
(A) The distance ‘d’ is decreased. (P) The photoelectric current increases.
(B) Te frequency of the source is (Q) The photoelectric current may become zero.
decreased (but is non-zero) keeping
intensity constant.
(C) The intensity of the source is (R) The kinetic energy of fastest electron
decreased (but is non-zero) keeping decreases.
frequency constant.
(D) The work function of the photometal in (S) The stopping potential does not change.
the cathode is increased.
2. Average speed of a bus is measured by six different students is given as follows:
Student number 1st 2nd 3rd 4th 5th 6th

Speed (m/s) 12.5 m/s 12.3 m/s 11.8 m/s 12.4 m/s 12.2 m/s 12.6 m/s
Column-I Column-II
(A) Mean absolute error (P)  0.2
(B) Mean value (Q) 12.3 m/s
(C) Relative error (R)  0.0163
(D) Percentage error (S)  1.63%
S
SEEC
CTTIIO
ONN--2
2:: C
CHHE
EMMIIS
STTR
RYY
PART – A
1. The complex with the most intence colour among the following is
(A) [FeF6]3– (B) [MnCl4]2– (C) [CoCl4]2– (D) [CoF6]3–
2. The average value of C – C bond order in graphite is

3 3 4
(A) 1 (B) (C) (D)
2 4 3
3. The red colour of ruby is due to

(A) d-d transition of Cr3+ ion in Cr2O3 lattice (B) d-d transition of Cr3+ ion in Al2O3 lattice
(C) ligand to metal charge transfer transition (D) metal to metal charge transfer transition
4. The sequence of three steps involved in the following conversion is
(A) (i) Fridel crafts alkylation (ii) Reduction (iii) Friedel crafts acylation
(B) (i) Fridel crafts acylation (ii) Fridel crafts alkylation (iii) Reduction
(C) (i) Fridel crafts acylation (ii) Reduction (iii) Friedel crafts acylation
(D) (i) Fridel crafts alkylation (ii) Friedel crafts acylation (iii) Reduction
5. OEt
NH2
(excess)
O  1 EtONa,then H O 
Y  3
 2 NaOH, then H O , Heat
Z
3
H
NH N
(A) Y= Z=
COOEt
O
O
COOEt
N N
(B)
CO 2Et
Y= Z=
H
NH N
(C) Y= Z=
CO 2Et
O
O
CO 2Et
(D) N
N
CO 2Et
Y= Z=
6. CHO O
o
 H2NCONHNH2 
HCl,100 (Re flux for 4hr )
 Product
( 1 mol) (Major)
( 1 mol) ( 1 mol)
NNHCONH 2 CH = N - NHCONH 2
(A) (B)
NCONHNH 2 CH = NCONHNH 2
(C) (D)
PART – A
correct.
7. Assertion: Sodium phenoxide is more reactive than phenol towards electrophilic substitution reaction
which takes place in a polar solvent.
Reason: Phenoxide ion contains less number of hydrogen atoms than that of phenol.
(A) Statement-1 is True, Statement-2 is true, Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is true, Statement-2 is NOT a correct explanation for Statement-
1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
8. Statement-1: Moist sulphur dioxide is a temporary bleaching agent.

Statement-2: It bleaches colour substance through reduction.
1.
(D) Statement-1 is False, Statement-2 is True.
9. Statement-1: Direct nitration of benzene to trinitrobenzene is practically impossible.

Statement-2:Three nitro groups present on benzene ring produces large steric hindrance.
1.
(D) Statement-1 is False, Statement-2 is True
(Paragraph Type)
Heating a mixture of ammonium chloride and sodium tetrahydridoborate gives one liquid product(X), along with
other product, under ambient condition.
10. Compound X is
(A) NH4[BH4] (B) [(NH3)2BH2][BH4]
(C) N3B3H6 (D) N3B3H12
11. Compound X is an example is

(A) ionic liquid (B) saturated heterocycle
(C) molecular cage (D) unsaturated heterocycle
12. Hydrolysis of ‘X” produce

(A) Bronsted acid (B) Lewis base
(C) Paramagnetic gas (D) Diamagnetic gas with bond order ‘3’

Two flask A and B have equal volumes. A is maintained at 300 K and B at 600 K. While A contains H 2 gas, B
has an equal mass of CH4 gas. (Assuming ideal behaviour for both gases)
13. The ratio of molar kinetic energy of molecules in flask ‘A’ and ‘B’ respectively is
(A) 4 : 1 (B) 1 : 2
(C) 1 : 4 (D) 8 : 1
14. If ZA and ZB are compressibility factors of H2 and CH4 then

(A) ZA = 4 ZB (B) ZA = ZB
(C) 2 ZA = ZB (D) 2 ZA = ZB
15. If A and B are mean free path of molecules in flask A and B respectively then B/A is
(Collision diameter of CH4 may be taken as twice as that of H2)
(A) 4 : 1 (B) 1 : 4
(C) 1 : 2 (D) 2 : 1
PART - B
Matrix-Match Type
p q r s
(a) p q r s
(b) p q r s
(c) p q r s
(d) p q r s
1. Match the following:

Column – I Column – II
(A) FeCl3 (P) Gives precipitate with K4[Fe(CN)6]
(B) CuSO4 (Q) Oxidises KI
(C) KMnO4 (R) Gives precipitate with excess of NH3(aq)
(D) ZnCl2 (S) Gives precipitate with excess of NaOH(aq)
(T) Aqueous solution is coloured due to charge

transfer spectra
2. Match column-I with column-II assuming ideal gas

Column – I Column – II
(A) Free expansion (P) Increase in temperature
(B) Adiabatic expansion (Q) U = 0

(against constant pressure)
(C) Isothermal expansion (reversible) (R) STotal > 0
(D) Adiabatic compression (reversible) (S)

 dw  0 cyclic process
(T) Ssurr = 0
S
SEEC
CTTIIO
ONN--3
3:: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
19
1 1 1
1. Let   r   1    ......  and
2 3 r
  2r  1  r     20    where 
r 1
and  are constants then
   is equal to
(A) 100 (B) 90 (C) 190 (D) 210
2. Let f  x   a6 x 6  a5 x5  a4 x 4  ......  a0 be real polynomial such that a0  R and

a2 a 4 a6
a0     0 . The equation f  x   0
3 5 7
(A) has a real root in  1, 1 (B) has no real roots in (–1, 1)
(C) has no real roots (D) has all the roots equal

nx
3. Value of I  x
0
2
 6x  9
dx
n3 n3 n3 n3
(A) (B) (C) (D)
12 6 2 3
A point is selected at random inside the circle x  y  36 , then the probability that it also lies inside
2 2
4.
two parabolas y  4x and x  4y is
2 2
4 4 4 4
(A) (B) (C) (D)
27 27 9 9
 1

5. The number of roots of the equation 51x101  2323x100  45x  1035  0 in the interval  45100 , 46 
 
is
(A) 0 (B) 1 (C) at most 1 (D) at least 1
Let  and  are non zero complex numbers satisfying     8 and     20 . If equation
2 2 3 3
6.
 
x2  bx  c  0 having roots and , then value of b2  c (where   0,   0,   I )
 
(A) 5 (B) 7 (C) 3 (D) 9
PART – A
correct.
The following questions 7 to 9 consists of two statements each, printed as Assertion and Reason. While
answering these questions you are to choose any one of the following four responses.
(A) If both Assertion and Reason are true and the Reason is correct explanation of the
Assertion.
(B) If both Assertion and Reason are true but Reason is not correct explanation of the
Assertion.
(C) If Assertion is true but the Reason is false.
(D) If Assertion is false but Reason is true
 1  x  dx . Then I
1 n I10 55
7. Statement – 1 : Let In  5

0
11 54
Statement – 2 : If u  x  and v  x  are differentiable functions, that  udv  uv   vdu
 3  1
dx 1
 
1
Statement – 1 : I    tan1   ln
 1  3 4  2
2 1
3
8.
0 3
1 x 3
3  
Statement – 2 : The integrand of the integral I becomes rational by the substitution
x
t
3
1  x3
9. Statement-1 : The set of real values of y for which real x satisfy

yx2 + y2x + 2 = 0 is (, 0]  [2, ).
Statement-2 : If x is real then the discrimnant of quadratic equation px 2 + qx + r = 0 is non- negative,
where p, q, r  R and p  0.
(Paragraph Type)
Let f  xy   x f  y   y f  x   x,y  0 and f 1  0, f ' 1  1
10. f  x  has
(A) maximum (B) minimum
(C) both maximum and minimum (D) neither maximum nor minimum
11. The number of inflectional points on the curve y  f  x  is

(A) 0 (B) 1 (C) 2 (D) 3
12. The minimum value of the function g  x   x f  x  is

1 1 1 1
(A) (B) (C)  (D) 
e 2e e 2e
Consider a plane mirror P1 having equation as z = 0. A ray of light emerging from the point P(1, 2, 3)
x 1 y  2 z  3
and travelled along the line   gets reflected from the plane mirror P1 and reflected
3 2 1
line is denoted by L2.
13. The equation of the line L2, is

  
(A) r  8iˆ  4ˆj   3iˆ  2jˆ  kˆ    
(B) r  8iˆ  4ˆj   3iˆ  2jˆ  kˆ 
(C) r   8iˆ  4ˆj     3iˆ  2jˆ  kˆ  (D) r   8iˆ  4ˆj     3iˆ  2jˆ  kˆ 
14. The equation of the plane ‘P2’ containing both the lines L1 and L2, is
(A) 2x – 3y + 4 = 0 (B) 3x – 2y + 4 = 0 (C) 2x + 3y + 4 = 0 (D) 3x + 2y + 4 = 0
15. The equation of the plane P3 passing through the intersection of planes, P1 and P2 and bisecting the
angle between P1 and P2, is
(A) 2x  3y  13z  4  0 (B) 3x  2y  11z  4  0
(C) 2x  3y  11z  4  0 (D) 2x  3y  13z  4  0
PART - B
Matrix-Match Type
p q r s
(a) p q r s
(b) p q r s
(c) p q r s
(d) p q r s
1. Match the following

Column-I Column-II
(A)  1 (P) 2
 for x  1
f x   x is differentiable every where and
ax 2  b for x  1

k  2a  4b, then the value of k is
(B) If 
f  x   sgn x 2  ax  1  has exactly one point of (Q) –2
discontinuity, then the value of a can be

(C) f  x   2  3 n sin x  ,n  N,,x  0,  has exactly 11 points (R) 1
of discontinuity, then the value of n is where [.] = GIF

(D) f  x   x  2  a has exactly three points of non – (S) 5
differentiability, then the value of a is
2. Let A and B are two distinct fixed points and P be a variable point such that distances PA, PB, AB
satisfy PA   3 PB 
1 2
  4 where i  R,i  1,2,3,4, then match the locus of P.
Column-I Column-II
(A) If 1  2 , 3  1, 4  0 (P) Straight line
(B) If 3  0 and  4  0 (Q) Circle
(C) If 1  2 , 3  0, 3  1,  4  0 (R) Ellipse
(D) If 1  2  3  1 and  4  AB (S) Hyperbola

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FIITJEE

PHYSICS, CHEMISTRY & MATHEMATICS

CPT-1 CODE: 120204 PAPER - 2

2. This question paper contains Three Sections.

B. Filling of OMR Sheet

C. Marking Scheme For All Three Parts.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

1. An opaque sphere of radius R lies on a horizontal plane.

3. A thin sheet of mass m, radius R and charge Q uniformly distributed

5. A long flexible inextensible rope of uniform linear mass

(A) 2v 2 (B) v 2

Paragraph for Question no. 10 to 12

A cylinder fitted with a piston which without friction contains

10. Work done by the gas is approximately

11. Increment in internal energy of gas is

12. The value of adiabatic exponent  for gas is

Paragraph for Question no. 13 to 15

1. In the experimental setup shown S is a point source

2. Average speed of a bus is measured by six different students is given as follows:

Student number 1st 2nd 3rd 4th 5th 6th

2. The average value of C – C bond order in graphite is

3. The red colour of ruby is due to

4. The sequence of three steps involved in the following conversion is

space for rough work

8. Statement-1: Moist sulphur dioxide is a temporary bleaching agent.

9. Statement-1: Direct nitration of benzene to trinitrobenzene is practically impossible.

Paragraph for Question no. 10 to 12

11. Compound X is an example is

12. Hydrolysis of ‘X” produce

Paragraph for Question no. 13 to 15

14. If ZA and ZB are compressibility factors of H2 and CH4 then

1. Match the following:

(B) CuSO4 (Q) Oxidises KI

(C) KMnO4 (R) Gives precipitate with excess of NH3(aq)

(D) ZnCl2 (S) Gives precipitate with excess of NaOH(aq)

(T) Aqueous solution is coloured due to charge

2. Match column-I with column-II assuming ideal gas

(B) Adiabatic expansion (Q) U = 0

(D) Adiabatic compression (reversible) (S)

space for rough work

2. Let f  x   a6 x 6  a5 x5  a4 x 4  ......  a0 be real polynomial such that a0  R and

9. Statement-1 : The set of real values of y for which real x satisfy

Paragraph for Question no. 10 to 12

Let f  xy   x f  y   y f  x   x,y  0 and f 1  0, f ' 1  1

11. The number of inflectional points on the curve y  f  x  is

12. The minimum value of the function g  x   x f  x  is

Paragraph for Question no. 13 to 15

13. The equation of the line L2, is

space for rough work

1. Match the following

discontinuity, then the value of a can be

of discontinuity, then the value of n is where [.] = GIF

differentiability, then the value of a is

space for rough work

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