Fiitjee: Physics, Chemistry & Mathematics

FIITJEE
PHYSICS, CHEMISTRY & MATHEMATICS

CPT3 - 1 Q.P. CODE : 192001107 PAPER - 1
TEMPLATE CODE : OJEAD180C06
BATCH – CTY 191 Re(A, B) to P01, P02,...
Time Allotted: 3 Hours Maximum Marks: 243
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into two section: Section-A & B.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.
(i) PART-A (01 – 09) contains 9 Multiple Choice Questions which have Only One Correct answer.
Each question carries +3 marks for correct answer and –1 mark for wrong answer.
PART-A (10 – 13) contains 4 Assertion-Reasoning Questions (MCQs) which have Only One Correct
answer. Each question carries +3 marks for correct answer and – 1 mark for wrong answer.
PART-A (14 – 19) contains 2 Paragraphs. Based upon each paragraph, 3 Multiple Choice
Questions have to be answered. Each question has Only One Correct answer and carries +4 marks
for the correct answer and –1 mark for a wrong answer.
(ii) PART-B (01 – 03) contains 3 Matrix Match Type Questions which have statements given in 2
columns. Statements in the first column have to be matched with statements in the second column.
There may be One or More Than One Correct choices. Each question carries +6 marks for all
correct answer however for each correct row +1 marks will be awarded and zero mark for each row
matched incorrectly.
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
Limited, Ground Floor, Baba House, Andheri Kurla Road, Below WEH Metro Station, Andheri (E), Mumbai - 400 093
Ph.: (Andheri : 42378100); (Chembur : 42704000); (Navi Mumbai : 9004603450); (Thane : 41617777); (Kandivali : 28541310)
Web: www.fiitjee.com  email: academics.mumbai@fiitjee.com
192001107-Ph3PhT02-OJEAD180C06
SECTION– I: PHYSICS
PART– A : (Single Correct Answer Type)
This section contains 9 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
1. The amplitude of a wave disturbance propagating in the positive y-direction is given by:
1 1
y= at t = 0 and y = at t = 1 sec, where x and y are in m. If the shape of the
1 x 2
[1  ( x  1) 2 ]
wave disturbance does not change during the propagation, what is the velocity of the wave?
(A) 1 (B) 2 (C) 4 (D) 5
2. An earth satellite of mass m orbits along a circular orbit C 1at a height 2R from earth’s surface. It
is to be transferred to a circular orbit C2, of bigger radius, at a height 5R from earth’s surface. The
transfer is followed by an elliptical path as shown in figure. Calculate the change in the energie
required at the transfer from points A to B. [R = radius of earth]
mgR mgR mgR mgR

(A) (B) (C) (D)
12 18 2 9
3. The figure shows a planet in elliptical orbit around the sun S. where is the kinetic energy of the
planet maximum ?
P3
P4 S P2
P1
(A) P1 (B) P2 (C) P3 (D) P4
Space for Rough Work
192001107-Ph3PhT02-OJEAD180C06
4. ABC is an equilateral triangle structure up of a light rigid material. Find the frequency of small
vertical oscillations of mass m along AG. Consider k 1  k 2  k 3  k 4  k.
5k 4k 3k 10k
(A) (B) (C) (D)
2m m 5m 9m
5. A uniform narrow tube 1.95 m long is open at both ends. It resonates at two successive
harmonics of frequency 275 Hz and 330 Hz. The speed of sound in the tube is
(A) 200 m/s (B) 205 m/s (c) 210 m/s (D) 214.5 m/s
6. A person standing between two parallel hills fires a gun. He hears the first echo after 1.5 sec. and
the second after 2.5 sec. If the speed of the sound in air is 332 m/s, calculate the distance between
the hills
(A) 581 m (B) 996 m (C) 448 m (D) 664 m
7. 0.5 mole of an ideal gas at constant temperature 27ºC kept inside a cylinder of length L and
cross-section area A closed by a massless piston.
The cylinder is attached with a conducting rod of length L, cross-section area (1/9)m 2 and thermal
conductivity k, whose other end is maintained at 0 0C . If piston is moved such that rate of heat
flow through the conducting rod is constant then velocity of piston when it is at height L/2 from the
bottom of cylinder is : [neglect any kind of heat loss from system]
k  k   k   k 
(A)  m / sec (B)  m / sec (C)  m / sec (D)  m / sec
R  10R   100R   1000R 
192001107-Ph3PhT02-OJEAD180C06
8. Three moles of an ideal monoatomic gas perform a cycle shown in figure. The gas temperatures
in different states are T1 = 200K, T2=400K,T3=1600K, and T4 = 800K. the work done by the gas
during the cycle is (Take R=25/3 J/mol-K)
(A) 5 kJ (B) 25 kJ (C) 15 kJ (D) 20 kJ
9. A body cools from 91C to 89C in 5 minutes when the room temperature is 20C. Then it will cool
from 71C to 69C in minutes
(A) 5 (B) 7 (C) 8 (D) 9
192001107-Ph3PhT02-OJEAD180C06
PART– A : Reasoning Type

This section contains 4 reasoning type questions. Each question has 4 choices (A), (B), (C) and (D),
10. Assertion (A) : As compared to light, Doppler’s effect in sound is observed frequently and easily
in practice.
Reason (R) : Sound waves have larger wavelengths.
(A) Both A and R are true and R is the correct explanation of A
(B) Both A and R are true but R is not the correct explanation of A
(C) A is true, R is false
(D) A is false, R is true
11. Assertion (A) : Transverse mechanical waves can not propagated in liquids and gases.
Reason (R) : Molecules in liquids and gases are having some finite separation from each other.
12. Assertion (A) : A particle is moving along x-axis. The resulting force F acting on it is given by
F  x  3 . The motion of this particle is not SHM.
Reason (R) : In SHM resultant force must be proportional to the displacement from mean
position.
13. Assertion (A) : The square of the period of revolution of a planet is proportional to the cube of its
mean distance from sun .
Reason (R) : The intensity of the gravitational field of the sun acting on the planet is
proportional to the mass of the sun and inversely proportional to square of its
distance from the sun and towards the sun.
192001107-Ph3PhT02-OJEAD180C06
PART– A : (Paragraph Type)

This section contains 2 paragraphs. Based upon the paragraphs 3 multiple choice questions have to
be answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
Paragraph for Question Nos. 14 to 16
Two identical blocks P and Q have mass m each . They are attached to two identical springs (of
spring constant k) initially upstretched . Both the bocks are initially in contact as shown . Now the
left springs (attached with block P) is compressed by A/2 and the right spring (attached with block
Q) is compressed by A . Both the blocks are then released simultaneously.
14. The speed of clock P just before P and Q are about to collide for the first time is
k A k
(a) (b) A
m 2 m
k
(c) .A (d) none of these
2m
15. The speed of block Q just before P and Q are about to collide for the first time is
k A k
(a) (b) A
m 2 m
k
(c) .A (d) none of these
2m
16. After what time when they were released from rest , shall the blocks collide for the first time
 m m
(a) (b) 
2 k k
 m
(c) (d) none of these
3 k
192001107-Ph3PhT02-OJEAD180C06
Figure shows the variation of the internal energy U with the density  of mole of ideal
monoatomic gas for a thermodynamics cycle ABCA. Here process AB is a part of rectangular
hyperbola
17. The P-V diagram of above process
P P
C B
C
(A) (B)
B A
A
V V
P
C
(C) (D) None of these

A
B
18. The total amount of heat absorbed by the system for system for cyclic process is
 10   10 
(A)  In2.5  2 U0 (B)  In0.4  2 U0 (C) 50U0 (D) None of these
 3   3 
19. The work done in process AB is

(A) -U0 (B) -2U0 (C) - 5U0 (D) None of these
192001107-Ph3PhT02-OJEAD180C06
PART– B (MatrixMatch Type)

This Section contains 3 questions. Each question has four statements (A, B, C and D) given in Column
I and five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct
matching with ONE or MORE statement(s) given in Column II. For example, if for a given question,
statement B matches with the statements given in q and r, then for the particular question, against
statement B, darken the bubbles corresponding to q and r in the ORS.
20.
Column-I Column-II
(A) Q(r) (P) Q(r) is variation of gravitational potential
for a uniform volumetric spherical
distribution of mass
O r=R r
(B) (Q) Q(r) is variation of gravitational potential
Q(r) for a uniform spherical shell
O r=R r
(C) (R) Q(r) is variation of gravitational field
Q(r) intensity for uniform volumetric
spherical distribution of mass
O r=R r
(D) (S) Q(r) is variation of gravitational field
Q(r) intensity for a uniform spherical
shell
O r=R r
192001107-Ph3PhT02-OJEAD180C06
21. A standing wave, formed in an organ pipe aligned along the x-axis, is given by (displacement) y=(5
× 106m) sin (4x) cos (1320t) where x is in metre and t is in seconds.
Column-I Column-II
(A) Change in pressure is maximum (P) x = 1/4 m
(B) Change in pressure is minimum (Q) x = 1/2 m
(C) Maximum amplitude of vibration (R) x=1m
(D) Minimum amplitude of vibration (S) x = 1/8 m
22. The speed (v) of a particle of mass 1 kg moving along a straight line, when it is at a distance (x)
from a fixed point on the line, is given by, v 2  144  9x2 . Match the following
Column-I Column-II
(A) Motion is simple harmonic with time period (P) 2 / 3 units
(B) Max. displacement from the fixed point is (Q) 27 units
(C) Magnitude of acceleration at a distance 3 units from the fixed (R)
4 units
point is
(D) Potential energy at a distance x = 2 unit from fixed point is (S) 18 units
192001107-Ph3PhT02-OJEAD180C06
SECTION–II: CHEMISTRY
23. The final major product of the given reaction.

CH3

KMnO4
H
 X 
Br2lFe
 Y 
CH3
COOH
COOH
Br
(A) (B) Br (C) (D)
Br CH3 Br
24. Which of the following molecules is are meso
Cl Cl
CH3
(A) (B) H OH
H CH3
Cl Cl OH
CH3
(C) (D) All of these
CH3
192001107-Ph3PhT02-OJEAD180C06
Cl Br

25. 
O3 / Zn

NH2OH | H
excess

the total number of isomeric products (including stereomers) formed at the end of the reaction is
(A) 4 (B) 6 (C) 8 (D) 16
26. Among the following the most stable isomer is

OH
OH OH OH
(A) OH (B) (C) (D)
HO OH HO
27. Identify correct acidic strength order
OH
OH OH
OH
O 2N NO 2
(A) > (B) >
NO 2
NO 2 NO 2
(C) CH  CH < CH2 = CH2 (D) NH3 > CH  CH
28. Identify correct stability order ?
(A) > (B) >
OMe F 3C CF3
MeO
(C) (D) > C
+ > +
MeO CF3
192001107-Ph3PhT02-OJEAD180C06
29. 1-Butene 

HBr /Peroxide
 Product (A) Mwt 193 the no of carbon in product (A) greater than 4
CH 2Br CH 2Br
H3C CH2 CH2 CH2 C H H3C CH2 CH2 C CH3

(A) (B)
Et Et
CH 2Br
H3C CH2 CH2 C CH3

(C) (D) Both (B) and (C)
CH3
O
O
30. CnH2n – 12 
O3 / Zn
H2 O
+ O = CH – (CH2)9 – CH = 0
+
n 1
Value of ?
8
(A) 7 (B) 8 (C) 14 (D) 16
31. Sum of total number of chiral centres (X) and total number of pairs of enantiomers (Y) for following
structure.
Cl
Cl
(A) 2 (B) 3 (C) 4 (D) 8
192001107-Ph3PhT02-OJEAD180C06

OH
32. Assertion (A) : is more basic than .
N
Reason (R) : The l.p.of oxygen in phenol are involved in resonance are delocalization while
that of nitrogen in pyridine are localized, and also N is less electronegative than
O.
33. Assertion (A) : is having higher heat of hydrogenation than .
Reason (R): First compound is having less -H than second.

34. Assertion (A): All bonds inside the ring in pyridine are of identical length..
Reason (R): Pyridine have two equal contributing resonating structure.
35. Assertion (A): Staggered (anti) is always more stable than Gauche.
Reason (R): Staggered form has minimum steric crowding. .
192001107-Ph3PhT02-OJEAD180C06

correct.
R – X 
Na/ether
R  R
R – X + R’ – X 
Na/ether
 R – R’ + R’ – R’ + R – R + alkene
Na is introduce in ether solution methyl chloride, C2H5Cl & n-propyl chloride
36. Calculate the sum of coupling & disproportion product

(A) 6 (B) 8 (C) 12 (D) 10
37. How many alkenes are obtained in the mixture.

(A) 2 (B) 3 (C) 4 (D) 5
38. In which of the following alkyl Halide not gives alkane on treatment with Na ether
H C CH2 CH2 H2C CH2 CH CH3
(A) 2 (B)
Cl Cl Cl Br
H3C CH CH2
(C) (D) Both (A) and (B)
Br Cl
192001107-Ph3PhT02-OJEAD180C06
CH3 – CH2 – CH2 – OH 

H2SO4
at 180ºC
 CH3 – CH2 – CH2 – O+H2 
 CH3 – CH = CH2 + H2O
39. Find out the total number of 1, 2 shifts in this reaction.
Con H2 SO4 / 
 
(A) 2 (B) 3 (C) 5 (D) 6
Con H2 SO4 / 
40.   Product
HO
No of hyperconjugated bonds in Product
(A) 4 (B) 6 (C) 8 (D) 10
41. no of transition state in above Rxn.

(A) 4 (B) 5 (C) 6 (D) 7
192001107-Ph3PhT02-OJEAD180C06

42. Match the following:
Column-I (Molecules) Column-II (Property)

(A) (P) Chiral atom is present
Cl
Br H
(B) O (Q) Molecule is chiral
O
(C) CH3 (R) Plane of symmetry is present
CH3
(D) (S) Centre of symmetry is present

Cl Cl
192001107-Ph3PhT02-OJEAD180C06
Column-I Column-II
Cl

HNO3


(A) H2 SO4 (P) KH / kD = 1
NO 2
(B) 
Cl2 /Fe (Q) KH / kD > 1
(C) 
con. H2SO4
 (R) Deactivated benzene
CH3
Ortho and para substituted products are
(D) 

C2H5 OH/H
 (S)
major
44. Match the following

Column-I (Molecule) Column-II (Pka of conjugate acid)
(A) (P) 0.8

N O
H
(B) (Q) 5.33

N
Et
(C) (R) 10.65

N
(D) N (S) 10.95

O
192001107-Ph3PhT02-OJEAD180C06
SECTION–II: MATHEMATICS
45. The interval in which x must lie so that the numerically greatest term in the expansion of (1 – x)21
has the greatest coefficient is, (x > 0)
5 6 5 6 6 7 6 7
(A)  ,  (B)  ,  (C)  ,  (D)  , 
6 5 6 5 7 6 7 6
46. The number of real negative terms in the binomial expansion of (1 + ix) 4n-2, n N, x > 0 is
(A) n (B) n + 1 (C) n – 1 (D) 2n
47. The coefficient if x5in the expansion of (x2 – x – 2)5 is

(A) -83 (B) -82 (C) -86 (D) -81
2
48. If |z – 1| = 1 and arg(z)  0, where z  0 and  is acute, then 1  is equal to
z

(A) tan  (B) i tan  (C) tan (D) tan 2
2
49. If z is a complex number lying in the first quadrant such that Re(z) + lm(z) = 3,then the maximum
value of {Re(z)}2 lm(z) is
(A) 1 (B) 2 (C) 3 (D) 4
192001107-Ph3PhT02-OJEAD180C06
50. If the equation of the perpendicular bisector of the line joining two complex numbers P (z 1) and
Q(z2) are the complex plane is z  z  r  0 then  and r are respectively are
(A) z2 – z1 and | z1 |2 + | z2 |2 (B) z1 – z2 and | z1 |2 – | z2 |2
(C) z2  z1 and | z1 |2 + | z2 |2 (D) z2 – z1 and | z1 |2 – | z2 |2
51. n-similar balls each of weight w when weighed in pairs the sum of the weights of all the possible
pairs is 120 when they are weighed in triplets the sum of the weights comes out to be 480 for all
possible triplets, then n is
(A) 5 (B) 10 (C) 15 (D) 20
52. A rack has 5 different pairs of shoes. The number of ways in which 4 shoes can be chosen from it ,
so that there will be no complete pair is :
(A) 1920 (B) 200 (C) 110 (D) 80
53. A seven digit number made up of all distinct digits 8, 7, 6, 4, 2, x and y is divisible by 3. Then
possible number of order pair (x, y) is
(A) 4 (B) 8 (C) 2 (D) None of these
192001107-Ph3PhT02-OJEAD180C06

54. Assertion (A) : The points z = x + iy on the complex plane satisfying |z + i| < |z – x| < |z – 1| lie
on the same side of the origin of a parabola with vertex on imaginary axis.
Reason (R): |z – x| < |z – 1| is always true.
55. Assertion (A) :  

2 cos-1x = sin-1 2x 1  x 2 is an identity
 1
Reason (R): tan-1   = cot-1x if x > 0.
x
56. Let P(z) be a point on the argand plane such that zz  az  az  b  0 , where a  C and b  R –
{-1} and |a|2 – b > 0
Assertion (A) : This equation represents circle and  a  is centre of this circle.
Reason (R): This equation represents circle whose radius is | a |2 b .

57. Assertion (A) : The coefficient of x3+2 in the expansion of (a + x) (b + x)+1 (c + x)+2    N is
(a + b + c).
Reason (R): The coefficient of xm in the expansion of (a + x)n is nCm an-m.
192001107-Ph3PhT02-OJEAD180C06

correct.
In argand plane |z| represent the distance of a point z from the origin. In general |z 1 – z2| represent
the distance between two points z1 and z2. Also for a general moving point z in argand plane, if
arg(z) = , then z = | z | ei , where ei = cos + i sin 
58. The equation |z – z1| + |z – z2| = 10 if z1 = 3 + 4i and z3 = -3 – 4i represents

(A) point circle (B) ordered pair (0, 0)
(C) ellipse (D) none of these
59. ||z – z1| - |z – z2|| = t, where t is a real positive parameter always represents
(A) ellipse (B) hyperbola
(C) circle (D) none of these
 
60. If z   3  2i   zcos   argz  , then locus of z is
 4 
(A) circle (B) parabola
(C) ellipse (D) hyperbola
192001107-Ph3PhT02-OJEAD180C06
Let ABC be a triangle, from vertices A, B and C altitudes AD, BE and CF are drawn to opposite
sides BC, CA and AB respectively which meet at a point O. Now triangle DEF is completed, also
length OA, OB and OC respectively are p, q and r.
61. Ratio of area of DEF to ABC is

(A) 2cosA cosB cosC (B) 2sinA sinB sinC
(C) 2cosA cosB sinC (D) none of these
62. Radius of the circumcircle of DEF is

R
(A) (B) R
2
R
4
63. Radius of the incircle of DEF is

(A) 2R cosA cosB cosC (B) R cosA cosB cosC
abc cos A cosBcosC
 ABC
192001107-Ph3PhT02-OJEAD180C06

Column-I Column-I
(A) The number of permutations of the letters of the (P) 169194
word HINDUSTAN such that the pattern ‘HIN’ nor
‘DUS’ nor ‘TAN’ appears, are
(B) Taking all the letters of word “MATHEMATICS” (Q) 9  9!
how many words can be formed in which either M
2!
or T are together?
(C) The number of ways of distributing 15 identical toys (R) 29C
15 – 15
among some or all of the students in a classroom
consisting of 15 students such that no student gets
all the toys
(D) The total number of eight-digit numbers, the sum of (S) 45 × 106
whose digits is odd, is
Column-I Column-I
(A) x sin x  (P) 1
The number of solution of   in [-, ]
2 cos x 4
(B) The number of solution of equation (Q) 0

  
sin-1 x2  1  cos1 2x 2  5 
2

(C) The number of solution of (R) 3
 
x4 – 2x2 sin2  x   1  0
2 
(D) The number of solution of x2 + 2x + 2sec2 x + (S) 2
tan2x = 0
192001107-Ph3PhT02-OJEAD180C06
Column-I Column-I
(A) If in a triangle sin2A + sin2B = sin(A + B), then the (P) Right angled
triangle must be
(B) bc (Q) Equilateral
If in a triangle ABC  b2  c 2  2bc cos A ,
2cos A
then the triangle must be
(C) A B C (R) Isosceles
If in a triangle ABC tan  tan  tan  3 ,
2 2 2
(D) If in a triangle the sides and the altitude are in A.P., (S) Obtuse angled

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FIITJEE

PHYSICS, CHEMISTRY & MATHEMATICS

Time Allotted: 3 Hours Maximum Marks: 243

B. Filling of OMR Sheet

C. Marking Scheme For All Three Parts.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

mgR mgR mgR mgR

(A) 5 kJ (B) 25 kJ (C) 15 kJ (D) 20 kJ

PART– A : Reasoning Type

PART– A : (Paragraph Type)

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Paragraph for Question Nos. 17 to 19

17. The P-V diagram of above process

(C) (D) None of these

19. The work done in process AB is

PART– B (MatrixMatch Type)

Space for Rough Work

23. The final major product of the given reaction.

(C) (D) All of these

26. Among the following the most stable isomer is

(A) > (B) >

28. Identify correct stability order ?

(A) > (B) >

29. 1-Butene 

H3C CH2 CH2 CH2 C H H3C CH2 CH2 C CH3

H3C CH2 CH2 C CH3

PART– A : Reasoning Type

33. Assertion (A) : is having higher heat of hydrogenation than .

Reason (R): First compound is having less -H than second.

PART– A : (Paragraph Type)

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36. Calculate the sum of coupling & disproportion product

37. How many alkenes are obtained in the mixture.

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CH3 – CH2 – CH2 – OH 

(A) 2 (B) 3 (C) 5 (D) 6

41. no of transition state in above Rxn.

PART– B (MatrixMatch Type)

42. Match the following:

Column-I (Molecules) Column-II (Property)

(D) (S) Centre of symmetry is present

43. Match the following:

44. Match the following

(A) (P) 0.8

(B) (Q) 5.33

(C) (R) 10.65

(D) N (S) 10.95

47. The coefficient if x5in the expansion of (x2 – x – 2)5 is

PART– A : Reasoning Type

55. Assertion (A) :  

Reason (R): This equation represents circle whose radius is | a |2 b .

PART– A : (Paragraph Type)

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58. The equation |z – z1| + |z – z2| = 10 if z1 = 3 + 4i and z3 = -3 – 4i represents

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61. Ratio of area of DEF to ABC is

62. Radius of the circumcircle of DEF is

63. Radius of the incircle of DEF is

PART– B (MatrixMatch Type)

64. Match the following:

66. Match the following:

Batch :__ Date of Examination :_