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FIITJEE
PHYSICS, CHEMISTRY & MATHEMATICS
Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into one section: Section-A
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for
rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.
(i) Section-A (01 – 08) contains 8 multiple choice questions which have only one correct answer. Each
question carries +3 marks for correct answer and – 1 marks for wrong answer.
Section-A (09 – 14) contains 3 paragraphs. Based upon paragraph, 2 multiple choice questions have to be
answered. Each question has only one correct answer and carries +3 marks for correct answer and – 1 mark
for wrong answer.
Section-A (15 – 20) contains 6 multiple choice questions which have one or more than one correct
answer. Each question carries +4 marks for correct answer. There is no negative marking.
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PART – I : PHYSICS
SECTION – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D)
for its answer, out of which ONLY ONE is correct.
1. ABC is an equilateral prism surrounded by free space. It is desired that any ray incident on
any of its face at any angle of incidence must undergo atleast one TIR before emerging out
from the prism. The minimum required refractive index of the prism is given by. (Incident ray
is assumed parallel to the triangular faces of the prism).
(A) μ > 2 (B)
(C) μ > 1.5 (D) μ > 1.33
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5. Consider the LRC A.C. circuit shown in the figure. It is known that R L C 2R
XL = XC = R. At some instant of time the magnitude of instantaneous
potential drop across the inductor is V. Then:
(A) RMS voltage across the resistor of resistance R is equal to .
V
(B) RMS voltage across the resistor of resistance 2R is .
(C) RMS voltage across the resistor of resistance R cannot be less
than .
(D) RMS voltage across the resistor of resistance R cannot be
greater than .
6. A beam of intensity I strikes a surface normally. The surface absorbs a fraction and reflects
the rest. The pressure exerted on the surface by the beam is:
(A) (B)
(C) (D)
7. In an endoergic reaction a projectile P is used to hit a stationary target T and after the
reaction, two products are formed. Then for the reaction to happen: (Q is the Q value of the
reaction)
(A) The kinetic energy of the projectile in the ground frame must be atleast equal to –Q.
(B) The kinetic energy of P must be atleast equal to –Q in the centre of mass frame of P and
T.
(C) Kinetic energy of P + kinetic energy of T must be atleast equal to –Q in the centre of mass
frame of P and T.
(D) None of the above.
8. A and B are two radio stations antenna radiating electromagnetic radiation of wavelength , d
is the separation between A and B and O is the mid-point of AB. If we move in a full circle of
radius R (> > d) around O, we record a total of 6 maxima, then possibly:
(A) d = 1.5 (B) d = 3
(C) d = 2 (D) d =
Comprehension Type
This section contains 3 groups of questions. Each group has 2 multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE
is correct.
Intensity of a radiation beam is defined as power crossing per unit cross-section area perpendicular
to the direction of propagation of the beam. Whenever an electromagnetic beam strikes a surface it
imparts force to the surface due to the momentum of colliding photons.
9. If a parallel beam of intensity I strikes a perfectly reflecting stationary lamina at an angle θ with
the normal then the pressure exerted on the surface is given by:
(A) (B)
(C) (D)
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10. If instead of being a perfectly reflecting surface, the lamina of previous question were perfectly
absorbing then the net force exerted by the beam per unit area of the lamina is given by:
(A) (B)
(C) (D)
Interference pattern can be observed on a screen using an arrangement known as Fresnel biprism
arrangement as shown in the following figure:
A
S1
Screen
S
a
S2
Here S is a source of light and S 1 and S2 are its virtual images formed due to refraction from two thin
prisms having vertex angle A each. S1 and S2 now serve as two virtual sources for interference
pattern on the screen. The incidence of light on the prism can be assumed to be at small angles.
11. If ‘a’ is the distance of the source of light from the prisms and μ is the refraction index of the
prism material then, separation between S1 and S2 is given by:
(A) a(μ – 1)A (B) 2a(μ – 1)A
(C) μaA (D)
In a hydrogen atom, the transition of an electron from a higher orbital to first orbital corresponds to
Lyman series while a transition to the second orbital from a higher orbital corresponds to Balmer
series.
13. Which of the following transitions has same wavelength as that of the highest possible
wavelength in the Lyman series?
(A) n = 4 to n = 2 for He+ species
(B) n = 4 to n = 1 for Li2+ species
(C) A Balmer series transition from n = 8
(D) n = 4 to n = 2 for Li++ species
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14. Consider a mixture of hydrogen atoms and He+ species with all hydrogen atoms excited to 2nd
orbital and all Helium ions excited to 4th orbital. How many spectral lines will be observed in
the emission spectrum of the mixture?
(A) 7 (B) 5
(C) 6 (D) 8
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D)
for its answer, out of which ONE OR MORE is/are correct.
15. The edge of a cube is represented as 3.00 cm. Accordingly choose the correct statement from
the following (based on correct number of significant figures)
(A) Its total surface area should be reported as 54.00 cm 2 (Assuming we calculate the area of
one face and multiply it by 6).
(B) Its total surface area should be reported as 54.0 cm2 (Assuming after finding area of one
face we multiply it by 6).
(C) Its surface area should be reported as 50 cm2 (Assuming that after finding surface area of
one face we multiply it by 6).
(D) Its volume should be reported as 27.00 cm3.
17. Two resistances 100 ± 2 Ω and 200 ± 5 Ω are connected in parallel, then:
(A) Error in the effective resistance ΔR ≈ ± 1.45 Ω
(B) Effective resistance is
(C) Error in parallel combination’s resistance is ± 2 Ω
(D) Error is parallel combination’s effective resistance is ± 1 Ω.
18. Consider the circuit shown in the figure, at t = 0, the charge on Q0 Q0
capacitor is Q0 and the current in the circuit is i0 as shown. Then:
(A) Then max current through the circuit during the subsequent C
L
oscillations is
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19. An A.C. circuit is operating at resonance. If now both the inductance and capacitance are
doubled:
(A) Current in the circuit will reduce.
(B) Impedance of the circuit will increase.
(C) Current in the circuit will remain the same.
(D) Impedance of the circuit will remain the same.
PART – II : CHEMISTRY
SECTION – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct.
3. The amount of ice that will separate on cooling a solution containing 50 g of ethylene glycol
(Molar mass = 62 g mol-1) in 200 gm water at –9.3°C (Kf = 1.86 K kgmol-1) is
(A) 42 g (B) 38.7 g
(C) 40.6 g (D) 34.8 g
4. The ionic conductance of a trivalent metal (M 3+) ion is 100 ohm-1 cm2 mol-1 and that of a
divalent (A2-) anion is 60 ohm-1 cm2 equi-1. The conductance of 0.2 M solution of the electrolyte
formed by M3+ and A2- is 3.36 × 10-2 ohm-1cm-1. The % dissociation of the electrolyte in its 0.2
M solution is?
(A) 10 (B) 15
(C) 76.3 (D) 30
5. A plot of against log p is a straight line inclined at an angle of 45° and intercept equal to
1. Calculate the amount of adsorbate per gram adsorbent when the pressure is 2 atm.
(A) 2 (B) 20
(C) 40 (D) 4
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7. In face centred cubic (fcc) crystal lattice, edge length of the unit cell is 400 pm. The diameter
(pm) of the greatest sphere which can be fitted into the interstitial void without the distortion of
lattice is
(A) 80.9 (B) 100.5
(C) 129.3 (D) 117.1
8. In a mineral three orthosilicate units are joined in a such way that one corner of the
tetrahedron is shared between any two. The mineral also consists of Sc3+, Ba2+ and water
molecules. The molar ratio of Ba2+ to H2O is 1 : 2. Thus formula of the mineral will be
(A) Sc2BaSi3O10 . 2H2O (B) ScBa2Si3O10 . 4H2O
(C) ScBaSi3O7 . 2H2O (D) ScBa3Si3O11 . 6H2O
(Paragraph Type)
This section contains 3 paragraphs based upon paragraph 2 multiple choice questions have to be
answered. Each of these questions has four choices (A), (B), (C) and (D) out of WHICH ONLY ONE
is correct.
The absorption of infrared radiation causes excitation of the molecule from one vibrational level of
lower energy to same other vibrational level of higher energy ‘ Needless to say, like electronic energy,
vibrational energy of a molecule is quantized. A free C—O bond in carbonmonoxide molecules has a
bond order of 3. . It absorbs an IR radiation of a wave no. 2143.2 cm-1. When CO molecule
donates e- pair to any transition metal, the metal also donates e- pair of its d-orbital to the metal called
back bonding. This inturn reduces the total bond order of C—O bond from 3 to some smaller number
to insure tetravalency of ‘c’ atom. The vibrational frequency of the CO stretch must therefore
decrease. It has actually been found. Reduction of charge from –ve to zero to +ve, exerts decrease in
the tendency of back donation by metal.
10. According to MOT, the back bonding between a transition metal and carbon atom of CO
molecule occurs by which one of the following overlaps?
(A) P - d (B) P - P
(C) d - * (D) d -
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The Ellingham diagram for the reduction of haematite and that of cuprous oxide given below;
4Cu O2 2Cu2O
100
300
2CO O2 2CO2
500
4Fe 3O2 2Fe2O3
700
2C O2 2CO
900
0
500K 1073K Temperature inK
On the basis of the above plot, answer the following two questions:
(C) Below 1073 K ΔG° of formation of CO 2 from CO is more negative than ΔG° of formation of
Fe2O3.
(D) Above 1073 K ΔG° for the formation of CO is less negative than that of Fe2O3.
E0 = 0.70
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Hydroquione is a very weak acid. The electrode is set up by dissolving about 1 gram of quinhydrone
in 100 mL water and inserting a clean Pt-wire in to it. Quinhydrone dissociates to give an equimole
cular mixture of quinone and hydroquinone which form a redox system.
is 0.3396 v at 25C. The pH of the acid solution in the right hand half cell is nearly equal to
(A) 2.0 (B) 3.0
(C) 4.0 (D) 1
14. The reduction potential of quinhydrone electrode dipped into an acid buffer mixture formed by
mixing equal volumes of 0.1 M HA (Ka = 10–5) and 0.01 M NaA is nearly equal to
(A) 0.283 V (B) 0.464 V
(C) 0.6918 V (D) 0.1835 V
15. A binary salt mixture upon treatment with dil.HCl gives off a pungent smelling gas that turns
lime water milky and acidified dichromate solution transparent green. The salt mixture upon
heating with NaOH solution (excess) gives off gas that turns Neester’s reagent black. When
the evolution this gas ceases to occur, the same begins to evolve if the reaction mixture is
gives a white precipitate with dil.H2SO4. Hence the salt mixture may contain
(A) Ba(NO3)2 and (NH4)2CO3 (B) BaS and NH4NO3
(C) (NH4)2CO3 and Ba(NO3)2 (D) NH4NO3 and CaSO3
17. A gas “X” is passed through water to form a saturated solution which reacts with magnesium
ribbon to give a gas “Y”. Hence X and Y are, respectively
(A) CO2 and H2 (B) CO2, Cl2
(C) Cl2 and H2 (D) Cl2 and CO2
18. The correct chemical equation(s) for thermal decomposition of nitrates is/are
(A)
(B)
(C)
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(D)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct.
2. Two numbers X and Y are chosen at random (without replacement) from the set {1, 2, ...5N}.
The probability that X4 – Y4 is divisible by 5 is
(A) (B) (C) (D) None of these
3. Each unit square a 3-by-3 unit square grid is to be coloured either blue or red. For each
square either colour is equally likely. The probability of obtaining a grid that does not have a 2-
by-2 red square is equal to
(A) (B) (C) (D)
4. The differential equation of all parabola having their axis of symmetry as x-axis is
(A) (B)
5. A fair coin is tossed ‘n’ number of times. The probability that head will turn up an even number
of times, is equal to
(A) (B) (C) (D)
6. Let A be a 2 × 2 matrix, with real entries and det(A) = d ≠ 0, such that det (A + d. (adj.(A))) = 0.
Then det (A – d. (adj.(A))) is equal to
(A) 2 (B) 4
(C) 7 (D) 8
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is
(A) pa + qb + rc (B) 1
(C) 0 (D) 2
8. A bag contains 12 pairs of socks, 4 socks are picked up at random. The probability that there
is at least one pair is
(A) 41/161 (B) 40/161
(C) 8/25 (D) 7/25
(Paragraph Type)
This section contains 3 paragraphs based upon paragraph 2 multiple choice questions have to be
answered. Each of these questions has four choices (A), (B), (C) and (D) out of WHICH ONLY ONE
is correct.
A given ABC is equilateral, and a point P is a variable point such that PB = PA + PC, P traces a
curve, S = 0, (side of is equal to q).
the interval
(A) (2, 7) (B) (9, 14)
(C) (15, 20) (D) (1, 3)
10. If the region enclosed by S = 0 and the ABC have area ‘r’, then , ([x] is greatest integer)
Consider the experiment of distribution of balls among urns. Suppose we are given M urns,
numbered 1 to M, among which we are to distribute n balls (n < M). Let P(A) denote the
probability that each of the urns numbered 1 to n will contain exactly one ball. Then answer
the following questions.
11. If the balls are identical and any number of balls can go to any urn, then P(A) equals
12. If the balls are identical but atmost one ball can be put in any box, then P(A) is equal to
Let be a position vector of a variable point in OXY plane such that and
, and .
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13. p2 is
(A) 9 (B) (C) (D)
14. p1 + p2 is
(A) 2 (B) 10 (C) 18 (D) 5
16. A positive integer is chosen at random. Let p denote the probability of the event, that the sum
of the digits of its square is 33, then
(A) p < 1/2 (B) p < 1/3
(C) p < 1/7 (D) p < 1/11
17. , and are 3 non-zero non-coplanar vectors with fixed magnitudes. Angles between any
of the vector with the normal of the plane containing other two is . Volume of the
parallellopiped is V and it’s surface area is S. Which of the following is/are true?
(A)
(B)
(C) , and are equally inclined to each other.
(D) If angle between and is θ, then angle between and plane of × is 90° - θ.
19. The players A, B and C, toss a coin cyclically in that order (that is, A, B, C, A, B, C, A, B,....) till
a head shows. Let p be the probability that the coin shows a head. Let , and γ be,
respectively, the probabilities that A, B and C gets the first head. Then
(A) = (1 – p) (B) γ + 2p = (1 + p2)
(C) + + γ = (D) = 1/(3 – 3p + p2)
20. Suppose a1, a2, ............. are real numbers which are in A.P. and a1 ≠ 0, with common
difference non-zero, then
(A) is singular.
(B) System of equations a1x + a2y + a3z = 0, a4x + a5y + a6z = 0, a7x + a8y + a9z = 0 has finite
number of solutions.
(C) If , then trace (B) will not be zero, if r is even natural number.
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(D) For matrix B (given in (C)), trace (B) can never be non-zero, if r is odd natural number.
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PART – I : PHYSICS
1. A
For no emergence:
A > 2θc
or θc < A/2
or θc < 30°
or
or or μ > 2.
2. C
or , at t = 0, q = 0,
qmax = 2C.
3. B
Model the cylinder as a solenoid with increasing current.
4. B
Consider the ray diagram. Upon reversing any ray, it will still pass through S after two
reflections.
5. C
Instantaneous value ≤ peak value.
the VL phasor has a length of atleast V, which must be equal to the phasor length of voltage
phasor for R.
Vrms for R .
6. D
7. C
8. A
9. D
Let A be cross section of beam and Aʹ be the area on the lamina on which the beam falls.
Let n = number of photons following per second.
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Then:
, Aʹ cos θ = A
and
10. A
Net force per unit area of lamina () = Net momentum absorbed per unit time per unit area.
A = Aʹ cos θ
11. B
S = (μ – 1)A
Separation = 2a tan(S) = 2aS
S is small due to near normal incidence on thin prisms.
12. B
13. A
14. C
Hydrogen line will overlap with one of the Helium lines.
15. B
6 has infinite number of significant figures.
16. A, B, C
17. A
18. A, B
and
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19. A, B
20. A, C
PART: III (MATHEMATICS)
1. D
Let D be the origin, and , ,
and so,
=
= 4(Ar(ΔABC)).
2. C
The number of ways of choosing X and Y is 5NC2. Arranging the numbers {1, 2, ...., 5N} in five
rows as follows:
1, 6, 11, ........, 5N – 4.
2, 7, 12, ......., 5N – 3.
3, 8, 13, ......., 5N – 2.
4, 9, 14, ......., 5N – 1.
5, 10, 15, ....., 5N.
We see that X4 – Y4 will be divisible by 5 if both X and Y lie in the last row, or if they lie
anywhere in the first four rows. Thus the number of favorable ways is NC2 + 4NC2, so that the
probability of the required event is
3. D
Using inclusion and exclusion principle, the probability of getting a two by two red square
= .
4. A
Equation is,
y2 = mx + c, m and c are arbitrary.
5. B
Total outcomes = 2n.
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6. B
Let , Adj(A) =
A + d. (Adj(A)) =
det (A + d. (Adj(A))) = 0
(d – 1)2 + (w + x)2 = 0 d = 1, w = - x,
det (A – d.(Adj(A))) = d(d + 1)2 = 4.
7. C
8. A
Total number of choosing 4 socks (in order) out of 12 pairs (or 24 socks) is 24 × 23 × 22 × 21.
The number of ways in which no pair is selected is 24 × 22 × 20 × 18. Thus, the probability of
not getting any pair is
10. A
11. B
Total number of ways = M + n – 1CM-1, number of favorable cases = 1
12. D
Total number of ways = MCn , number of favorable cases = 1
13. D
Square of the minimum distance between a point (–2, 3) and the circle is p2, i.e. .
14. C
Square of maximum distance between a point (–2, 3) and the circle is p1, i.e. .
15. A, C
16. A, B, C, D
Let x be a positive integer such that sum of the digits of its square is 33. Then 3|x2 3|x.
Therefore, 9|x2. But a number is divisible by 9 if and only if sum of its digits is divisible by 9.
Therefore, 9|33, which is not possible. Thus, there is no positive integer such that sum of the
digits of its square is 33. Therefore p = 0 < 1/11 < 1/7 < 1/3 < 1/2.
17. A, B
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18. A, B
d1. d2 < 0 then ‘+’ sign gives bisecting plane containing the origin and a1a2 + b1b2 + c1c2 > 0
in their usual notations.
19. A, B, D
Let q = 1 – p. Then = P(A wins the game)
= P(H or T T T H or T T T T T T H or ....)
also,
and
20. A, C, D
|A| = 0, a1 ≠ 0 and all of diagonal elements are non-negative numbers, the similar logic for
(D) also.
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