Advance Paper-Set-A

FIITJEE JEE(ADV.
)
PHYSICS, CHEMISTRY & MATHEMATICS
BATCHES – 1719 CRP ABC LOT RT - 1
CPT1 - 1 CODE: 108071 SET - A PER - 1
Time Allotted: 3 Hours Maximum Marks: 210
 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Section.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each part is further divided into two parts: PART-A & C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Two Parts.

(i) Part-A (01 – 10) contains 10 multiple choice questions which have one or more than one correct
answer. Each question carries +4 marks and – 2 mark for wrong answer.
(ii) Part-C (01 – 10) contains 10 Numerical based questions with single digit integer as answer, ranging
from 0 to 9 (both inclusive) and each question carries +3 marks for correct answer and – 1 mark for
wrong answer.
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4080700. Ph: 9871091470.www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, 0120-4754800/804/805/811.
FIITJEE Greater Noida, Courtesy -Pragyan School, Sector Gamma – I, Greater Noida, Ph : 9871113448
CRP 1719 ABC LOT –RT-1 – (Paper-1)-CMP-IITJEE/19 2
Useful Data Chemistry:

Gas Constant R = 8.314 J K1 mol1
= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56, Mn=55,
Pb=207, Au=197, Ag=108, F=19, H=2, Cl=35.5, Sn=118.6
Useful Data Physics:
Acceleration due to gravity g = 10 m / s2
SECTION– I (PHYSICS)
PART – A
Multi Correct Type
r r
1. Which of the following is/are correct regarding vectors A = î + ˆj and B = 2iˆ  3ˆj
r r
(A) Angle between A and B is acute
r r r
(B) Angle between A + B and A is acute
r
(C) k̂ is a unit vector perpendicular to A
(D)
2
(
1 ˆ ˆ
) r
i  j is a unit vector perpendicular to B.
2. The x  t graphs for two children A and B returning from their

school ‘O’ to their homes P & Q respectively, along straight line
(taken as x - axis) are shown. Choose correct options
(A) A lives closer to school than B.
(B) B starts from the school earlier than A
(C) A and B have equal average velocities
(D) B overtakes A on the way
3. A man pushes against a rigid, immovable wall while standing on rough ground. Which of the following
is/are correct
(A) The man can never exert a force on the wall, which exceeds his weight
(B) If man pushes the wall with a force of 200 N, we can be sure that wall is pushing back with a force of
200 N on him.
(C) Since the wall can not move, it can not exert any force on him.
(D) The man cannot be in equilibrium, since he is exerting a net force on the wall.
4. A block of mass ‘M’ slides with uniform angular speed 'w ' on a
horizontal circular rough track of radius ‘R’ with coefficient of friction
m . String remains horizontal. Then correct options are
(A) Work done by string in one revolution is zero.
(B) Work done by hand on string does not depend on angle 'q '
(C) Work done by hand on string is negative of work done by
friction.
(D) Work done by friction on block is (  m Mg2p R ) .
space for rough work
5. Particles P and Q are in motion under gravity. Then

(A) Their relative acceleration is constant but not zero.
(B) Their relative velocity is constant
(C) Their centre of mass has constant velocity
(D) Their centre of mass has constant acceleration
6. Two horizontal discs of different radii are free to rotate about their
central vertical axes. One is given some angular velocity, and the
other is stationary. Their rims are now brought in contact. There is
friction between the rims.
(A) Friction between rims will disappear when they rotate with
equal angular speed.
(B) Friction between them will disappear when points on the rim have same linear speeds.
(C) Angular momentum of the system remains conserved
(D) Rotational kinetic energy of system will not be conserved
7. A solid sphere of mass m is suspended through a string in a liquid

as shown. The string has some tension. Magnitude of net force due
to liquid on upper hemi-sphere and that on lower hemisphere are F A
and FB, respectively. Then
(A) Density of material of sphere is greater than density of liquid.
(B) FB - FA is independent of atmospheric pressure
(C) FB - FA = mg
(D) FB - FA < mg
8. Two blocks of masses ‘m’ and ‘4m’ lie on a smooth horizontal

surface connected with a spring in its natural length. Mass ‘m’ is
given velocity v0 through an impulse as shown. Which of following
is/are true about subsequent motion
(A) Kinetic energy of system is maximum simultaneously in COM frame and ground frame
(B) Values of maximum kinetic energy and minimum kinetic energy are same in COM frame and ground
frame.
(C) Minimum kinetic energy is zero in COM frame but non - zero in ground frame
1 2
(D) Maximum and minimum kinetic energies of mass ‘m’ in ground frame are mv0 and zero
2
respectively.
9. A source of sound of frequency f 0 is approaching an observer which is moving away from the source. Air
is at rest and speed of sound in air is v0 . Then choose the correct alternative
(A) observer may hear a frequency of f 0
v0
(B) The wavelength of wavetrain in air may be greater than
f0
v0
(C) The wavelength received by observer must be less than
f0
(D) The velocity of wavetrain in air equal to v0
10. A gas is trapped in a cylinder closed by a frictionless movable piston having some mass ‘m’. Then in
equilibrium
(A) The pressure of the gas will be equal to that of the surroundings, if axis of cylinder is horizontal.
(B) The pressure of the gas cannot be less than that of the surroundings, if axis of the cylinder is not
horizontal.
(C) The pressure of the gas may be equal to that of surrounding, if axis of cylinder is not horizontal
(D) The pressure of the gas may be less that that of surroundings, if axis of the cylinder is not horizontal.
PART – C
Integer Type
1. If energy (E), density ( r ) and power (P) form a fundamental system of units and dimension formula for
momentum can be written as E r P , then find l + m + n.
l m n
r
2. A point moves in x  y plane according to r = 3cos 4t î + 3 ( 1  sin 4t ) ˆj. Find the distance travelled by the
particle in 0.5 seconds.
3. A bead of mass ‘m’ can slide on a thin vertical rod, with sliding friction coefficient m = 0.4. The rod is
translated horizontally with a constant acceleration ‘a’. For what value of ‘a’ will an observer on earth see
equal horizontal and vertical components of acceleration of bead. (g = 9.8 m/s 2)
4. Two blocks with different masses are attached to either end of a light inextensible string that passes over
light frictionless pulley suspended from ceiling. The masses are released from rest. After the heavy block
has descended 1.2 m, its speed is 4 m/s. What is the mass of lighter block, if total mass of two blocks is
12 kg. (g = 10 m/s2)
5. A frictionless pulley has the shape of a uniform disc of mass 2.5 kg and
radius 20 cm. A 1.5 kg block is attached to a wire that is wrapped around
the rim of pulley and system is released from rest. If the fraction of total
kinetic energy, that pulley has after the block has fallen through a distance
K
of 10 m is , then find the value of K.
11
6. A weight w is supported by attaching it to a vertical uniform pole by

a thin cord passing over an ideal fixed pulley. The cord is attached
35 cm below the top. The pole is pivoted about a hinge at its base
and is 1.75 m tall. A thin wire connects the top of the pole to wall.
The nail that holds this wire to wall will come out if an outward force
greater than 24 N acts on it. Find the maximum mass of weight w,
that can be supported.
7. A rectangular tank is filled up to a height of 10 m with water and

25
placed near the bottom of an incline of angle 300. For x = m, the
n
stream of water coming out from hole strikes the inclined plane
normally. Find ‘n’
8. A satellite revolving in a circular equatorial orbit from west to east appears over a certain point on equator
after every 8 hr. Find time period of revolution of satellite.
9. A wire frame in the shape of an equilateral triangle is hinged at one vertex so that it can swing freely in a
1
vertical plane, with the plane of triangle always remaining vertical. The side of the frame is m. If time
3
p
period of small oscillations is seconds, then find n . (g = 10 m/s2)
n
10. One mole of a diatomic gas undergoes the cyclic process as

n
shown. If the efficiency of the process is , find n.
19
SECTION – II (CHEMISTRY)
PART – A
Multi Correct Type
1. To a 10 ml, 1M aqueous solution of Br2, excess of NaOH is added so that all Br2 is disproportionated to Br–
and BrO3–. The resulting solution is made free of Br – by extraction and excess of OH– is neutralised by
acidifying the solution. The resulting solution is sufficient to react with 2g of impure CaC 2O4 (M = 128
g/mole) sample. Which of the following is/are not the correct % purity of oxalate sample:
(A) 85.3% (B) 12.5% (C) 90% (D) 64%
2. ‘P’ is the probability of finding the 1s electron of hydrogen atom in a spherical shell of infinitesimal
thickness, dr, at a distance ‘r’ from the nucleus. The volume of this shell is 4 pr2dr. The qualitative sketch of
the dependance of ‘P’ on ‘r’ cannot be represented by which of the following graph/s
P P P P
(A) (B) (C) (D)
O r O r O r O r
3. Consider the following molecule

Cl F
1 2 3
C C C
H H
If p-electron cloud of C1 – C2 is present in the plane of paper then which of the following is/are correct:
(A) fluorine is perpendicular to the plane of paper.
(B) chlorine is present in the plane of paper
(C) -bond of C2-C3 is perpendicular to the plane of paper.
(D) p-electron cloud of C2 – C3 bond and Cl is present in same plane.
4. Predict the major product/s of the given reaction
( )
HCl 1 equivalent
 major product
Cl
(A) (B)
Cl
Cl Cl
(C) (D)
5. Three closed rigid vessel, A, B and C (without energy transfer with surroundings) initially contain three
different gases at different temperatures. These vessels are connected by tube of negligible volume. The
vessel ‘A’ contain 2 mole Ne gas at 300 K, vessel ‘B’ contain 2 mole SO 2 gas at 400 K and vessel ‘C’
contain 3 mole CO2 gas at temperature 500 K. If the final pressure (in atm) attained by gases is ‘P’ and
the final temperature is ‘T’ when all valves of connecting three vessels are opened and additional 15.6 K
cal heat is supplied to vessel through valve. The volume of A, B and C vessel is 2, 2 and 3 litre
respectively. Which of the following is/are correct? [Use : R = 2 cal/mol-K; C v(Ne) = 3R/2; Cv(CO2) = 5R/2
and CV(SO2)=3R]
CO2
Ne SO2
(A) P = 73.89 atm (B) P = 67.31 atm (C) T = 900 K (D) T = 400 K
For the equilibrium: LiCl.3NH 3 ( s ) ��LiCl.NH 3 ( s ) + 2 NH 3 ( g ) ; K p = 9 atm at 37°C. A 5 L vessel

�� 2
6.
contains 0.1 mole of LiCl.NH 3. How many mole of NH 3 should be added to the flask at this temperature to
derive the backward reaction for completion? [use : R = 0.082 atm-L/mol K]
(A) 0.2 (B) 0.59 (C) 0.69 (D) 0.79
7. Air is trapped in a horizontal glass tube by a mercury column as shown below:

36 cm
(1 atm) Hg
If the tube is held vertical keeping the open end up, length of air column shrink to 19 cm. if the length (in
cm) by which the mercury column shifts down is ‘x’ then which of the following cannot be its value?
(A) 28 cm (B) 19 cm (C) 9 cm (D) 47 cm
8. P-V plot for two gases (assuming ideal) during adiabatic process are given in the figure. Plot ‘A’ and plot
‘B’ should correspond respectively to:

P A
B
V
(A) He and H2 (B) H2 and He (C) He and Ne (D) H2 and Cl2
9. Which of the following molecules have non-zero dipole moments?

(I) gauche conformation of 1,2-dibromoethane
(II) anti conformation of 1,2-dibromoethane
(III) trans-1,4-dibromocyclohexane
(IV) cis-1,2-dibromocyclohexane
(V) Tetrabromomethane
(VI) 1,1-dibromocyclohexane
(A) I and II (B) I and IV (C) II and V (D) IV and VI
10. Consider the ionisation energy trends for the elements P, Q, R and S.
Element I.E.1 I.E.2 I.E.3
(K.cal/mol) (K.cal/mol) (K.cal/mol)
P 497 947 1500
Q 98 735 1100
R 176 347 1850
S 296 530 2050
The order of ionic mobility in aqueous solution of the following ions will not be (If R, S belong to same
group)
(A) R+2 (aq) > S+2 (aq)
(B) S+2 (aq) > R+2 (aq)
(C) S+2 (aq) = R+2 (aq)
(D) S+2 (aq)  R+2 (aq)
PART – C
Integer Type
1. The total number of stereoisomers that can exist for ‘M’ is

H C CH3
3
H3C
2. Find the total number of non-linear molecules:

I 3 , BeCl2 , NH 2 , H 2 O, XeF2 , N 2 O, SO2 , SF2
10
CRP 1719 ABC LOT –RT-1 – (Paper-1)-CMP-IITJEE/19
3. A perfect gas undergoes a reversible adiabatic expansion from (300 K, 200 atm) to (90 K, 10 atm). Find
the atomicity of gas.
4. Find number of substance/s which produce H2 gas when reacted with cold water.
Ca, CaH2, Mg, MgCl2, Ba, BaO2, NaHCO3, Ca3N2
5. How many of the following addition reactions are syn addition reaction?
H3C CH3 H3C CH3

(A) C C 

Br2
CCl4 (B) C C 
H 2 , Ni

H H D D
H 2 , Pd  BaSO4
(C) H3C C C CH3   (D) H3C C C CH3 
Na , liq NH 3

(E) 
BH 3 .THF
H O ,OH 
 (F) 
Cold, dil., alk. KMnO4

2 2
CH3
(G) 
1. PhCO3 H
2. H + / H O
 (H) 
Br2
H 2O

2
CH3
6. Find the total number of di-chloro products of the reaction:

CH3
Cl2 , h
H Cl   Product
CH2 CH2 CH2 CH3
S-2-chlorohexane
7. 10 ml of H2A (weak diprotic acid) solution is titrated against 0.1 M NaOH. pH of the solution is plotted
against volume of strong base added and following observation is made.
If pH of the solution at first equivalence point is pH 1 and at second equivalence point is pH 2. Calculate the
value of pH2 – pH1 at 25°C. Given : For H2A, pK a1 = 4.6 and pK a2 = 8 , log 25 = 1.4
pH of solution
20 40
Vol. of strong base(ml)
8. The periodic table consists of 18 groups. An isotope of copper, on bombardment with protons, undergoes
a nuclear reaction yielding element ‘X’ as shown below. To which group, element ‘X’ belongs in the
periodic table?
63
29 Cu +11 H � 610 n + a + 211 H + X
9. Each of the compounds shown below has two aromatic rings, labelled as ‘A’ and ‘B’. Identify number of
compounds in which ring ‘B’ is more reactive than ring ‘A’ for EAS.
O O
(i) B (ii) (iii)
A A C O B A C NH B
O
O
C O
O
(iv) HO A B C OH (v) O 2N A CH2 B (vi)
A B
HN O
CH3
B O
N
(vii) S (viii) A C B CH3 (ix)
A O A B
O
10. In the compound Na2[B4O5(OH)4].8H2O, if the (i) number of B–O–B bonds is ‘x’ (ii) number of B–B bonds is
‘y’ (iii) number of sp2 hybridised B atoms is ‘z’. Calculate the value of x + y + z.
12
SECTION – III (MATHEMATICS)

PART – A
Multi Correct Type
1. Which of the following equation in parametric form can represent a hyperbola, where t is a parameter
a� 1� b � 1� tx y x ty
(A) x = t+ �
� ,y = �
t � (B)  + t = 0, + = 1
2� t � 2� t � a b a b
(C) x = et + e t , y = e t  e t (D) x 2  6 = 2 cos t , y 2 + 2 = 4 cos 2 ( t 2 )
2. If the parabola y = ( a  b ) x 2 + ( b  c ) x + ( c  a ) touches the x-axis in the interval [0, 1] then the line
ax + by + c = 0.
(A) always passes through a fixed point (B) represents the family of parallel lines
(C) data insufficient (D) None of these
3. If y = cos q + cos 2q, then

9 8
(A) ymin = (B) ymax = 2 (C) ymin = (D) y max = 1
8 9
Let P ( x ) = x  8 x + 21 and Q ( y ) = y  6 y + 10 x, y �R . If P ( x ) �
Q ( y ) = 5 then possible value(s) of
4 2 2
4.
( x + y) is(are)
(A) 1 (B) 3 (C) 5 (D) 7
5. If the area of the triangle formed by the pair of lines 8x 2  6xy + y 2 = 0 and the line 2 x + 3 y = a is 7, then a
is equal to
(A) 14 (B) 14 2 (C) 28 (D) none of these
6. Let a triangle is formed whose vertices are the vertices of a cube. The total number of
(A) equilateral  are 8 (B) right angled triangle are 48
(C) scalene triangle are 24 (D) right angled triangle are 24
13
7. Sum the series

1 1 1 1
Sn = + + + ....... +
1�4 2� 5 3�6 ( n + 3)
n�
11 1 2 11 1 � 1 1 1 �
(A) Sn =   (B) S n =  � + + �
18 n + 2 3 ( n + 1) ( n + 2 ) ( n + 3) 18 3 �n + 1 n + 2 n + 3 �
11 11 � 1 1 1 �
(C) S� = (D) Sn = � + + �
18 18 �n + 1 n + 2 n + 3 �
8. If ( 1 + cot 46�) ( 1 + cot 53�) ( 1 + cot 59�) ( 1 + cot 62�) ( 1 + cot 73�) ( 1 + cot 76�) ( 1 + cot 82�) ( 1 + cot 89�)
= e k log e 2 then the value of k is equal to
(A) 5/2 (B) 3 (C) 7/2 (D) 4
9. Let tangents at A(z1) and B(z2) are drawn to the circle z = 2. Then which of the following is/are correct
z z
(A) The equation of tangent at A is given by + =2
z1 z1
2 z1 z2
(B) If tangents at A(z1) and B(z2) intersect at P(zP), then z P =
z1 + z2
1 �z1 + z1 �
(C) Slope of tangents at A(z1) is � �
i �z1  z1 �
p
(D) If point A(z1) and B(z2) on the circle z = 2 are such that z1 + z2 = 0, then tangents intersect at .
2
10. If a is complex constant such that a z 2 + z + a = 0 has a real root, then
(A) a + a = 1 (B) a + a = 0
(C) a + a = 1 (D) The absolute value of the real root is 1
PART– C
Integer Type
20 20 20
20 C1 C2 C3
1. The value of C0  +  +K is p then 42 p is
2 3 4
1 1 1 1 1 1
2. Let S = + + + ... + + . If S = where K ΰ ( 0,90 ) , then K equal to
sin 8� sin16� sin 32� sin 4096� sin 8192� sin K �
3. In any triangle ABC, the least value of

( r1 + r2 + r3 ) is
r
4. If the number of garlands that can be formed using 3 flowers of one - kind and 12 flowers of the 2 nd kind is
two digit number AB. Find the value of A  B .
14
16
5. If p1 , p2 , p3 are the altitudes of a triangle which circumscribes a circle of diameter unit, then the least
3
p1 + p2 + p3
value of must be
3
6. A circle is drawn to pass through the vertex ‘A’ and to touch the sides BC and CD at P & Q resp of a
rectangle ABCD. If the length of the perpendicular drawn from A upon PQ is 13 units, then the area of
rectangle ABCD is 4k + 1 sq units, then the value of k is
7. A person has 6 friends and during a certain vacation he met them during several dinners. The found that
he dined with all the 6-exactly on one day, with every 5 of them on 2 day, with every 4 of them on 3 days
with every 3 on 4 days; with every 2 on 5 days. Furthers every friend was present at 7 dinners and every
friend was absent at 7 dinners. The number of dinner (s) he had alone is equal to K. Find value of K.
G13 + G23
8. If A, be the A.M. and G1 , G2 be two G.Ms between two positive numbers a and b then is equal
G1G2 A1
to
� p 3p �
9. The total number of ordered pair (x, y) satisfying |y| = cos x and y = sin 1 ( sin x ) where, x ��
 , �
�2 2 �
10. ( 2 2 2 2
If x 2 + y 2 = 9, 4 a 2 + 9b 2 = 16, then the maximum value of log 12 4 a x + 9b y  12 abxy is )
15
FIITJEE COMMON
TEST
BATCHES: CRP 1719 ABC LOT
RESHUFFLING TEST – 1 Q.P. Code
SET - A 108071
ANSWER KEY
S.NO PHYSICS C.CODE CHEMISTRY C.CODE MATHEMATICS C.CODE

PART - A
1. B, C P110203 A,B,C C110201 A, C, D M111102
2. A, D P110325 A,B,C C112807 A M110105
3. B P110402 D C113611 A, B M111411
4. B, C, D P110506 B C111707 A, C M110105
5. B, D P110612 A,C C111903 C M110732
6. B, D P110708, D C110403 A, B, C M111209
P110723
7. A, B, D P111014 A,B,D C113503 A, B, C M113208
8. A, C, D P111107 B C111902 D M111409
9. A, B, C, D P111313 B,D C111405 A, C M110316
10. A, D P111208 B,C,D C110703 A, C, D M110405
PART- C
1. 1 P110108 2 C111404 2 M110412
2. 6 P110307 4 C113611 4 M111430
3. 7 P110408 1 C111901 9 M113206
4. 2 P110413 3 C111002 8 M111209
5. 5 P110312 4 C111707 8 M111515
6. 3 P110715 9 C111703 3 M110823
7. 3 P111010 4 C110502 1 M111202
8. 6 P110913 8 C110604 2 M113204
9. 5 P111105 5 C111804 2 M113425
10. 2 P111220 7 C111503 2 M111313
16
HINTS & SOLUTIONS

SECTION – I (PHYSICS)
PART – A
1. B, C
r r r
Sol. (
A+B � ) ( )(
A = 3iˆ  2ˆj �î + ˆj = 1 )
� cos q > 0
� q < 90 0
r
A� kˆ = 0
� q = 90 0
2. A, D
Sol. B starts after time to than A and overtakes A where graphs intersect.
3. B
Sol. Their is always a reaction equal and opposite to action force.
4. B, C, D
Sol. Use Work-Energy Theorem
r
N=� f�ds =  f �
l
5. B, D
r r r
Sol. aP = aQ = g
r r r
vrel = vP  vQ
r r r
arel = aP  aQ
r r
r mP vP + mQ vQ
vCM =
mP + mQ
r r
r m P aP + mQ aQ
aCM =
mP + mQ
6. B, D
Sol. Friction will disappear when, relative motion between point of contact stops.
Because of negative work by friction kinetic energy will decrease.
7. A, B, D
Sol. Body sinks, when rb > rl
and Th + T = mg for equilibrium.
8. A, C, D
Sol. Motion of blocks when observed from COM frame will be S.H.M.
9. A, B, C, D
Sol. Conceptual
�v  vobs �
f = f0 � 0 �
�v0  vs �
10. A, D
mg cos q
Sol. Pgas = Psur � , where q is angle of axis of cylinder with vertical.
A
PART – C
1. 1
7 1 3
Sol. momentum = E 5 r 5 P 5
2. 6
Particle will move along circle x 2 + ( y  3 ) = 32 with speed 12 m/s
2
Sol.
s = vt = 6m
3. 7
17
Sol. N = ma
mg  f = ma
g
�a= =7
1+ m
4. 2
20
Sol. v 2 = 2as � a =m / s2
3
20 m1  m2
a= = g � m1  m2 = 8 kg and m1 + m2 = 12
3 m1 + m2
� m2 = 2kg
5. 5
1 1
Sol. mgh = Iw 2 + mv 2
2 2
1 2
Iw
2 M 5
= =
mgh M + 2m 11
6. 3
Sol. Taking torque about hinge
T1 �( 1.75  0.35 ) = T2 sin 37 0 ( 1.75 ) , where T1 = mg
40
T2 = mN
3
For nail
T2 sin 37 0 �24
m �3kg
7. 3
v0
Sol. = tan 30 0 , v0 = 2g ( 10  x )
2g ( x  y )
Equ. of trajectory
g g
y' = 2 x'2 � x  y = 3y 2
2v0 2� 2g ( 10  x )
25
solving we get x = m
3
8. 6
TT 24TS
Sol. t' = E S � 8 =
TE  TS 24  TS
TS = 6 hr
9. 5
2
ma 2 ma 2 �ma 2 � 3a ��
+ + � + m � ��
I 3 3 �12 � 2 ��
Sol. T = 2p = 2p � �
mgd a
3mg
3
2p
=
20
10. 2
Work
Sol. Efficiency ( h ) =
Heat absorbed
18
SECTION – II (CHEMISTRY)
PART – A
1. A,B,C
Sol.
3Br2 + 6OH  ��
� 5 Br  + BrO3 + 3H 2 O
m. mole taken 10
m. mole formed – 10/3
+  2 
6 H + BrO + 3C2O ��
3� Br + 6CO2 + 3H 2O
4
 2
10/3 m mole BrO3 reacts with 10 m. mole C2 O4
Þ mass of CaC2O4 reacted = 10 × 10–3 × 128 = 1.28 g
1.28
% purity = �100 = 64%
2
2. A,B,C
Sol. The probability distribution curve for 1s electron of hydrogen atom is
P
O r
3. D
Sol.
Cl
F
C C2 C3
1
H
H
4. B
Sol. Alkenes are more reactive than alkynes towards electrophilic addition mechanism.
5. A,C
Sol. Total heat received by gas = Total heat provided
3 5
2 � R ( T  300 ) + 2 �3R ( T  400 ) + 3 � R ( T  500 ) = 15600 Þ T = 900 K
2 2
P �7 = 7 �0.0821 �900
Þ P = 73.89 atm
6. D
LiCl.3 NH 3 ( s ) ��LiCl.NH 3 ( s ) + 2 NH 3 ( g )
��
Sol. — 0.1 a
0.1 — a  0.2
K P = 9 = PNH Þ PNH 3 = 3
2
3
Þ 3 �5 = ( a  0.2 ) 0.082 �310

a = 0.79 7. A,B,D
Sol. 1 1 = PV
PV 2 2
� 36 �
1 �A �h1 = �
1+ � �A �19
� 76 �
h1 = 28 cm
So, length (in cm) by which the mercury column shifts down = 28 – 19 = 9 cm
8. B
Sol. For adiabatic process PV g = constant.
So, more is the value of g , more decrease is in pressure.
9. B,D
Sol.
19
Br Br Br
Br
H Br H H Br
H
(I) (II) (III) H (IV) H
H H H H H
H Br Br
m¹0
m¹0 m=0 m=0
Br
CBr4 Br
(V) (VI)
m=0
m¹0
10. B,C,D
Sol. Since IES > IE R � Size of S < Size of R
Hence high charge density cation S+2 will be more hydrated and lesser would be its ionic mobility.
PART – C
1. 2
Sol. Bridging doesn’t allow the trans form.
So, total number of stereoisomers are 2
2. 4
Sol. I 31 sp 3 d ; linear
BeCl2 sp; linear
NH2– sp3; pyramidal
H2O sp3; bent
XeF2 sp3d; linear
N2O sp; linear
SO2 sp2; bent
SF2 sp3; angular
3. 1
Sol. P1g T g = constant
( 200 ) 300g = ( 10 )
1 g 1 g
90g
g
�3 �
( 20 )
1 g
=� �
�10 �
3�
( 1  g ) log 20 = g �
log
� �
� 10 �
Þ g = 1.67
Monoatomic gas.
4. 3
Sol. Ca, CaH2 and Ba produces H2 gas with cold water.
5. 4
Sol. B, C, E, F are syn addition reactions

6. 9
Sol.
20
CH2Cl CH3 CH3

H Cl Cl C Cl H C Cl
CH2 CH2 CH2 CH3 CH2 CH2 CH2 CH3 Cl CH CH2 CH2 CH3
( d,l )
CH3 CH3 CH3

CH3
H Cl H Cl H Cl
H C Cl CH 2
CH 2 CH2
CH 2
CH2 CH2 CH2
CH Cl CH2
Cl H H Cl
CH2CH3 CH2Cl
CH3 CH3
( d,l )
7. 4

Sol. � HA + H 2 O
At first equivalence point: H 2 A + OH ��
pK a1 + pK a2 12.6
pH1 = = = 6.3
2 2
At second equivalence point
HA + OH  ��
� H 2O + A2
Let N1 is the normality of H2A taken and M1 is the molarity of H2A taken
N1V1 = N 2V2
N1 �10 = 0.1 �40
N1 = 0.4
M 1 = 0.2
Þ Number of moles of H2A = 0.2 × 10 × 10–3 = 2 × 10–3 = number of moles of A–2
2 2 �103 1
� � 50 �103 = 25
�A �=
1 1 1
pH 2 = 7 + pK a , 2 + log C = 7 + 4  ( 1.4 ) = 10.3
2 2 2
Þ pH 2  pH 1 = 4
8. 8
Sol. 29 + 1 = 2 + 2 + Zx
Z x = 26
i.e. Iron
This belongs to group 8 of periodic table.
9. 5
Sol. In (ii), (iii), (v), (vi) and (viii) ring ‘B’ is more activating than ring A.
10. 7
Sol.
21
OH
B
O O
HO B O B OH
O O
B
OH
x = 5, y = 0, z = 2
SECTION – III (MATHEMATICS)
PART - A
1. A, C, D
Sol. 2x 2y �x � y x2  y 2 = 4 x2  y 2 = 6
+ = 2t t � + 1 �=
a b �a � b
2x 2y 2 �x � ty
 =
a b t �  1 �= 
�a � b
2 2
x y y 2
 2 = 1; x2
a 2
b 1=
a2 b2
2. A
Sol. Repeated root at x = 1
( b  c) ca
=2 =1
( a  b) ab
2a + b + c = 0
3. A, B
2
� 1� 9
Sol. y = 2�cosq + � 
� 4� 8
9
ymin = ymax = 2
8
4. A, C
( x 2  4 ) + 5�
Q ( y) = 5 � �
P ( x) �
2
( y  3) + 1�
� 2
Sol. =5
� ��
x 2 = 4, y = 3
5. C
�a a ��a 2 a �
Sol. Vertices of the triangle are (0, 0), � , ��, , �
�8 4 ��14 7 �
6. A, B, C
Sol. Total triangles = 8C 3 = 56
Equilateral triangles = 8 (here all sides are equal to face diagonal)
Right triangles = 48
Scalene triangles = 24 (which are right angled triangle also, here one side is edge, one is face diagonal
and one is body diagonal).
7. A, B, C
( n + 1) ( n + 2 ) 1 2
Sol. Tn = = +
n ( n + 1) ( n + 2 ) ( n + 3) ( n + 1) ( n + 2 ) n ( n + 1) ( n + 2 ) ( n + 3)
11 1 2
Sn =  
18 n + 2 3 ( n + 1) ( n + 2 ) ( n + 3)
22
8. D
Sol. cot ( 46�+ 89�
) = cot ( 135�)
cot 46�cot 89� 1
= 1
cot 46�+ cot 89�
cot 46�cot 89�+ cot 46�+ cot 89�+ 1 = 2
( 1 + cot 46�) ( 1 + cot 89�) = 2
Similar ( 1 + cot 53� ) ( 1 + cot 82�) = 2
k log 2
16 = e e
k = 4.
9. A, C
Sol. (A)
�z  z � p z  z1 z  z1
Arg � 1 �= � ( depending on the diagram ) � + =0
�0  z1 � 2 z1 z1
(C) As equation of tangent at A ( x1 y1 ) is xx1 + yy1 = 4
 x1 2 x1 �z + z �
\ Slope of tangent = = = = i �1 1 �
y1 2 y1 �z1  z1 �
(D) Clearly tangents are parallel lines
10. A, C, D
Sol. Let z = aÎR and a = p + iq
(p + iq)a2 + a + p  iq = 0
pa2 + a + p = 0 a2q  q = 0
a = ±1
a±1+ a =0 |a| = 1
PART - C
1. 2
20 20
C
�r + 1r ( 1)
r
Sol.
r =0
1 20 21 1
�Cr +1 ( 1 ) = ( 1)
r
21 r =0 21
2. 4
1 1 1
Sol. S= + + ....... +
sin 8� sin16� sin 8192�
S = ( cot 4� cot 8�
) + ( cot 8� cot16�) + .....
1
S = ( cot 4� cot 8192�
)=
sin 4�
3. 9
1 1 1 1
Sol. + + =
r1 r2 r2 r
r1 + r2 + r3 3
�
A.M  H.M 3 1 1 1
+ +
r1 r2 r3
23
r1 + r2 + r3
�3r
3
r1 + r2 + r3
�9
r
4. 8
Sol. This is a case equivalent to distributing 12 identical flowers into 3 - identical boxes or x + y + z = 12 , taking
only different combinations of x, y, z.
Case - I
x = y = z � 1  way
Case - II
x = y �z, 2 x + z = 12, x �z
(A) x > z , let x  z = a a �1 then total solutions = 2
(B) x < z then
total solutions = 4
Case - III
x + y + z = 12, x �y �z
taking only different combination of x, y, z
Let x > y > z
total ways = 12
Ans 1 + 2 + 4 + 12 = 19
5. 4
6. 3
Sol. Let (a, ) be the coordinates of A
|a +   a| 2
13 = ,a +  2  2 aa  2 a + a2 = 0
2
a = 13
7. 1
Sol. Let At , t = 1, 2,...., 6 be set of days on which the friend is present at dinner and Bt be set of days on
which the friend is absent at dinner. Then At = Bt = 7
Ai �Aj = 7 Ai �Aj �Ak = 4
Ai �Aj �Ak �Al = 3, Ai �Aj �Ak �Ak �Am = 2
and A1 �A2 �A3 �A4 �A5 �A6 = 1
A1 �A2 �...... �A6 = �Ai  �Ai �Aj
= 6 C1 �7  6 C2 �5 + 6 C3 �4  6 C4 �3.....
= 13
Total number of dinners alone = 14  13 = 1
8. 2
9. 2
10. 2
Sol. Let x = 3 cos q, y = 3 sin q
4
& a = 2 cos f, b = sin f
3
max × value of 144 cos 2 ( q + f ) is 144

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FIITJEE JEE(ADV.

Time Allotted: 3 Hours Maximum Marks: 210

B. Filling of OMR Sheet

C. Marking Scheme For All Two Parts.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

Useful Data Chemistry:

2. The x  t graphs for two children A and B returning from their

space for rough work

5. Particles P and Q are in motion under gravity. Then

7. A solid sphere of mass m is suspended through a string in a liquid

8. Two blocks of masses ‘m’ and ‘4m’ lie on a smooth horizontal

space for rough work

space for rough work

6. A weight w is supported by attaching it to a vertical uniform pole by

7. A rectangular tank is filled up to a height of 10 m with water and

10. One mole of a diatomic gas undergoes the cyclic process as

space for rough work

3. Consider the following molecule

4. Predict the major product/s of the given reaction

space for rough work

For the equilibrium: LiCl.3NH 3 ( s ) ���LiCl.NH 3 ( s ) + 2 NH 3 ( g ) ; K p = 9 atm at 37°C. A 5 L vessel

7. Air is trapped in a horizontal glass tube by a mercury column as shown below:

(A) He and H2 (B) H2 and He (C) He and Ne (D) H2 and Cl2

space for rough work

9. Which of the following molecules have non-zero dipole moments?

1. The total number of stereoisomers that can exist for ‘M’ is

2. Find the total number of non-linear molecules:

space for rough work

H3C CH3 H3C CH3

6. Find the total number of di-chloro products of the reaction:

space for rough work

space for rough work

SECTION – III (MATHEMATICS)

3. If y = cos q + cos 2q, then

space for rough work

7. Sum the series

3. In any triangle ABC, the least value of

space for rough work

S.NO PHYSICS C.CODE CHEMISTRY C.CODE MATHEMATICS C.CODE

HINTS & SOLUTIONS

Þ 3 �5 = ( a  0.2 ) 0.082 �310

Sol. B, C, E, F are syn addition reactions

CH2Cl CH3 CH3

CH3 CH3 CH3

(D) Clearly tangents are parallel lines

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Batch :__ Date of Examination :_

For the equilibrium: LiCl.3NH 3 ( s ) ��LiCl.NH 3 ( s ) + 2 NH 3 ( g ) ; K p = 9 atm at 37°C. A 5 L vessel