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Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Sections.
Section – I is “Chemistry”, Section – II is “Mathematics” and Section – III is “Physics”.
Each Section is further divided into two Parts: Part – A & Part – B.
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
(i) PART-A (01 – 08) contains 8 Multiple Choice Questions which have Only One Correct answer. Each
question carries +4 marks for correct answer and –2 marks for wrong answer.
PART-A (09 – 16) contains 4 Paragraphs. Based upon each paragraph, 2 Multiple Choice Questions have to
be answered. Each question has Only One Correct answer and carries +3 marks for the correct answer and
–1 mark for a wrong answer.
(ii) PART-B (01 – 04) contains 4 Matrix Match Type Question which have statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. There may be
One or More Than One Correct choices. Each question carries +12 marks for all correct answer however
for each correct row +3 marks will be awarded and –1 mark for each row matched incorrectly.
Name of Candidate :
Enrolment Number :
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | Page |2
Section – I (CHEMISTRY)
PART – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
1. How many mL of 0.5 M H2SO4 are needed to dissolve 0.5 g of Cu(II) carbonate?
(A) 6.01 (B) 4.5
(C) 8.1 (D) 11.1
2. At which of the four conditions, the density of nitrogen will be the largest?
(A) STP (B) 273 K and 2 atm
(C) 546 K and 1 atm (D) 546 K and 2 atm
4. Which of the following property of the most electronegative element of the periodic table, is correct?
(A) It’s electron gain affinity is higher than that of chlorine.
(B) It is the smallest atom of it’s period.
(C) It can form compounds in which it’s oxidation number is +2.
(D) It is a s-block element
CH3
6. Phenol is heated with chloroform and alcoholic KOH when salicyladehyde is produced. This
reaction is known as
(A) Friedel-crafts reaction (B) Reimer-Tiemann reaction
(C) Rosenmund reaction (D) Sommelet reaction
7. The compound that will not give iodoform on treatment with alkali and iodine is
(A) acetone (B) ethanol
(C) diethyl ketone (D) isopropyl alcohol
8. Which of the following reagent forms optical isomers as products when treated with CH3CHO?
(A) NaCN/HCN (B) NH2OH
(C) LiAlH4 (D) C6H5NHNH2
Space for rough work
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | Page |3
Paragraph
(Single Correct Choice Type)
Paragraph ( 9 – 10)
The valency of carbon is generally 4, but its oxidation state may be -4, -2, 0, +2, +1 etc. In the compounds
containing C, H and O, the oxidation number of carbon is calculated as:
2nO nH
Oxidation number of carbon = where no, nH and nC are the number of oxygen, hydrogen and
nC
carbon atoms respectively.
10. In which of the following compounds is the oxidation state of carbon is zero?
(A) CH4 (B) CH3OH
(C) HCOOH (D) C6H12O6
Paragraph ( 11 – 12)
n=3
1 3
n=2
2
n=1
In the above figure, the first three orbits of hydrogen atoms are given with their respective principal
quantum numbers. The energy of the orbits increases from n = 1 to n = 3. The energy of the orbits with n
=1, 2 and 3 are E1, E2 & E3 respectively when an electron jumps from the third orbit(n = 3) to the first orbit
(n = 1), three photons are emitted with their wavelengths mentioned in the figure.
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | Page |4
Paragraph ( 13 – 14)
Cyclobutyl bromide when refluxed with magnesium in dry ether formed a compound(A). Which on treatment
with ethanal followed by acidification with dil. HCl gives another compound(B). Compound(B) has refluxed
with an equivalent amount of HBr to form compound(C).
Br Br CH3
(C) CH3 (D)
Paragraph ( 15 – 16)
In the following reaction sequence, the compound J is an intermediate.
CH3CO2 O i H2 , Pd/C
I
CH3COONa
J
ii SOCl2 K
iii Anhy.AlCl3
J(C9H8O2) gives effervescence on treatment with NaHCO3 and a positive Baeyer’s test.
(A) (B)
COCH 3 CH = CH 2
(C) (D)
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | Page |5
(A) (B)
O O
(C) (D) O
PART – B
(Matrix Match Type)
2. Match the characteristics of gases mentioned in column-I with their dependent factors mentioned in
column-II.
Column – I Column - II
(A) Vapour density of an ideal gas (P) Temperature
(B) R.M.S velocity of an ideal gas (Q) Pressure
(C) Total kinetic energy of an ideal gas (R) Molecular mass
(D) Liquification of a real gas (S) Number of moles
(T) Mass of gas
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | Page |6
CH3
(T) Hoffman product
Space for rough work
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | Page |7
Section – II (MATHEMATICS)
PART – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
3. If f x 2x x ,g x
1
3
2x x and h x f g x , then domain of sin1 h h h x ............ is:
n times
1 1
(A) 1, 1 (B) 1, , 1
2 2
1 1
(C) 1, (D) , 1
2 2
5. A circle passes through the points A(1,0), B(5,0) and touches the y-axis at C(0,h). If ACB is
maximum then
(A) h 3 5 (B) h 2 5
(C) h 5 (D) h 2 10
7. The common tangents to y 2 8x and the curve 3x2 y2 3 meet y 2 8x at P and Q. The length
of PQ is
(A) 0 (B) 1
(C) 2 (D) 4
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | Page |8
Paragraph
(Single Correct Choice Type)
Paragraph ( 9 – 10)
x – [ x ] ; x I
Let ƒ(x) = ; where I is the set of integers & [x] represents greatest integer £ x.
1 ; xI
(f ( x ))2 n – 1
If g(x) = lim , then :
n (f ( x ))2 n 1
Paragraph ( 11 – 12)
Consider the function f x 3x 4 4x3 12x2
Paragraph ( 13 – 14)
If f x x g x , then f f ' f " ..... f n1 0 where f(x) and g(x) are
n
polynomials for a polynomial f(x) with rational coefficients, answer the following questions
14. If f(x) touches x-axis at only one point, then the point of touching is
(A) always a rational number (B) may or may not be a rational number
(C) never a rational number (D) none of these
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | Page |9
Paragraph ( 15 – 16)
L1 : 6x2 xy y2 0, L2 : 3x 2 axy y 2 0, a 0
15. If one of the lines given by L1 coincides with one of the lines given by L 2 , then the value of a is
equal to
7 1
(A) (B)
2 2
(C) 1 (D) 4
16. If L 3 denotes the equation of the pair of other two lines of L1 and L2 :p1,p2 denote the lengths of the
perpendiculars from the point (8, 4) on the lines given by L 3 , then p12 p22 is equal to
(A) 8 (B) 32
(C) 40 (D) none of these
PART – B
(Matrix Match Type)
1.
Column – I Column – II
A. Number of points from where two perpendicular tangents can be drawn
x2 y2 (p) 0
to the hyperbola 2, n, n Z is
cos sec 2
2
C. x2 y2
A normal to the hyperbola 1 , has equal intercepts on positive x
4 1
x2 y2
and y axes if this normal touches the ellipse 2 2 1, then (r) 6
a b
9 2
25
a b2 =
D. x2 y2 x2 y2
y mx c be common tangent to 1 and 1 then
16 9 4 3 (s) 8
m c
2 2
x f x
2. f x is a polynomial function satisfying lim 1 and f 1 1, f 2 2, f 3 3 and f 4 4
x x5 1
Column-I Column-II
(A) f 5 1 (P) 1
6
(B) x f x (Q) 2
lim
x 3 x3
(C) f x x (R) 3
lim
x 2 x 2 2x
(D) f ' 2 (S) 5
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | P a g e | 10
4. Both given functions are identical in the interval : Match the following
Column-I (Functions) : Column-II
(A) 2x
f x tan1 , g x 2 tan1 x
(P) 1, 1
2
1 x
(B) f x sin sin x , g x sin sin1 x
1
(Q) 1, 1
(C) f x logx2 25 , g x logx 5 (R) 1, 1
(D) f x sec 1 x cos ec 1x, , g x sin1 x cos1 x (S) 0, 1
Space for rough work
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | P a g e | 11
1. Force acting on a particle moving in a straight line varies with the velocity of the particle as
K
F = . Here, K is a constant. The work done by this force in time t is:
v
K 2Kt
(A) 2 . t (B) 2Kt (C) Kt (D) 2
v v
2. A spring has a length l1 when tension in it is n1(in N). It has a length l2 when tension is n2 (in N). Find
its spring constant :
(n l – n1l1 ) (n – n2 ) (n – n1 ) (n l – n2l2 )
(A) 2 2 (B) 1 (C) 2 (D) 1 1
(l1 – l2 ) (l1 – l2 ) (l1 – l2 ) (l1 – l2 )
3. If vectors P, Q and R have magnitude 5, 12 and 13 units and P Q R , the angle between Q and
R is
5 5 12 7
(A) cos1 (B) cos1 (C) cos1 (D) cos1
12 13 13 13
4. A simple circuit contains an ideal battery and a resistance R. If a second identical resistor is placed
in parallel with the first,
(A) the potential across R will decrease
(B) the current through R will decreased
(C) the current delivered by the battery will increase
(D) the power dissipated by R will increased
5. A positively charged thin metal ring of radius R is fixed in the xy plane, with its centre at the origin O.
A negatively charged particle P is released from rest at the pint (0, 0, z0), where
z0 >0. Then the motion of P is
(A) non-periodic, for all values of z0 satisfying 0 z0 .
(B) simple harmonic, for all values of z0 satisfying 0 z0 .
(C) approximately simple harmonic, provided z0 R .
(D) such that P crosses O and continues to move along the negative z-axis towards z = –.
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | P a g e | 12
7. The capacitance of a parallel-plate capacitor is C0 when the region between the plates has air. This
region is now filled with a dielectric slab of dielectric constant K. The capacitor is connected to a cell
of emf , and the slab is taken out, then choose the incorrect option
(A) charge C0(K – 1) flows through the cell.
(B) energy 2C0(K – 1) is absorbed by the cell.
(C) the energy stored in the capacitor is reduced by 2C0(K – 1).
(D) the external agent has to do 1/2 2C0(K – 1) amount of work to take the slab out.
Paragraph
(Single Correct Choice Type)
Paragraph ( 9 – 10)
A potentiometer is a device used for measuring emf and S 30V
internal resistance of a cell. It consists of two circuits one is
main circuit in which there is a cell of given emf and given
resistance R which is connected across a wire of length r =1
100 cm and having resistance r and another circuit having A B
Jockey
unknown emf and galvano-meter. For a given G
potentiometer if = 30V, r = 1 and resistance R varies
with time t given by R = 2t. The jockey can move on wire
with constant velocity 10 cm/sec and switch S is closed at t
=0
9. If Jockey starts moving from A at t = 0 and balancing point found at t = 1 sec, then the value of is
(A) 1 V (B) 2 V (C) 3 C (D) 4 V
10. If Jockey starts moving from A at t = 1 sec, then the balancing point will be obtained at
(A) t = 3 sec (B) t = 5 sec (C) t = 4 sec (D) t = 9 sec
Paragraph ( 11 – 12)
If a man in a boat rows perpendicular to the banks he is drifted to a distance of 120 m in 10 minutes.
If he heads at an angle of from upstream he crosses the river by shortest path in 12.5 minutes.
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | P a g e | 13
Paragraph ( 13 – 14)
A plank of mass m1 = 8 kg with a block (mass m2 = 2 kg) on it 2kg
is placed on a horizontal rough floor. A horizontal force F is
applied on the plank. The co-efficient of friction for all the F 8kg
contact surfaces is 1/5.
Paragraph ( 15 – 16)
Two circular rings A and B each of radius a = 30cm are fixed 10C –20C
coaxially with their axis horizontal in a uniform electric field E 105 N/ C E=105 N/C
directed vertically upward as shown in figure. Distance between centres
of the rings A and B (CA and CB) is 40 cm. Ring A has positive charge CA CB
qA 10μC and B has a negative charge qB = –20C. A particle of mass
m and charge q = 10C is released from rest at the centre of ring A. If
particle moves along CA CB , then (g = 10 m/s2) A B
16. Work done by all electric field, when particle moves from CA to CB is
(A) –1.2 J (B) 1.2 J (C) –3.6 J (D) 3.6 J
Space for rough work
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | P a g e | 14
PART – B
(Matrix Match Type)
1. If a parallel plate capacitor of capacitance C is charged with battery of emf V volt through a
resistance R
Column – I Column – II
(A) The separation between the (P) Charge on the capacitor increases
plates of capacitor is increased,
keeping battery connected
(B) The separation between the (Q) Charge on the capacitor decreases
plates of capacitor is
decreased, keeping battery
connected
(C) The separation between the (R) Electric potential energy between the space
plates of capacitor is increased, of the plates of the capacitor decreases
keeping battery disconnected
(D) The separation between the (S) Electric potential energy between the space
plates of capacitor is of the plates of the capacitor increases
decreased, keeping battery
disconnected
(T) Potential difference between the plates
remains constant
2. A position charge Q is uniformly distributed over the ring of radius R = 1m and potential at infinity is
assumed to be zero.
Column I Column II
(T) KQ 2
7
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | P a g e | 15
E
A3
R2
Column I Column II
(T) 2
x
C
4. The displacement-time (x-t) graph of a body
acted upon by some forces is shown in the A
figure. B
t
O
Column I Column II
(A) For OA, the total work done by all the (P) positive
forces together is
(B) For AB acceleration is (Q) negative
(C) From O to B velocity is (R) first positive then negative
(D) At B acceleration is (S) first negative then positive
(T) zero
Space for rough work
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