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ALL INDIA INTERNAL TEST SERIES

CHEMISTRY, MATHEMATICS & PHYSICS


SET – A
APT - 4 080127.1 Ai2TS-1

Time Allotted : 3 Hours Maximum Marks: 312


INSTRUCTIONS
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.

Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions

 Attempt ALL the questions. Answers have to be marked on the OMR sheets.
 This question paper contains Three Sections.
 Section – I is “Chemistry”, Section – II is “Mathematics” and Section – III is “Physics”.
 Each Section is further divided into two Parts: Part – A & Part – B.
 Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
 Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.

B. Filling of OMR Sheet


CLASS XI

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Three Parts.

(i) PART-A (01 – 08) contains 8 Multiple Choice Questions which have Only One Correct answer. Each
question carries +4 marks for correct answer and –2 marks for wrong answer.
PART-A (09 – 16) contains 4 Paragraphs. Based upon each paragraph, 2 Multiple Choice Questions have to
be answered. Each question has Only One Correct answer and carries +3 marks for the correct answer and
–1 mark for a wrong answer.

(ii) PART-B(01 – 04) contains 4 Matrix Match Type Question which have statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. There may be
One or More Than One Correct choices. Each question carries +12 marks for all correct answer however
for each correct row +3 marks will be awarded and –1 mark for each row matched incorrectly.

Name of Candidate :

Batch ID : Date of Examination : / / 2 0 1

Enrolment Number :
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Useful Data Chemistry:


Gas Constant = 8.314 J K1 mol1
R
= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
= 6.023  10
23
Avogadro's Number Na
= 6.626  10 Js
–34
Planck’s Constant h
-27
= 6.25 x 10 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
-27
1 amu = 1.66 x 10 kg
-19
1 eV = 1.6 x 10 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56, Mn=55, Pb=207,
Au=197, Ag=108, F=19, H=2, Cl=35.5, Sn=118.6
Useful Data Physics:
Acceleration due to gravity g = 10 m / s 2

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SECTION – I (CHEMISTRY)
PART - A
Single Correct Type

1. Which of the followings statements are correct?


T
(I) Larger is the value of C for a gas, larger would be its excluded volume.
PC
(II) Larger is the excluded volume of gas, more will be its critical volume.
 R 
(III) The slope for an isochore obtained for a gas showing P V  b   RT is  
V  b 
(IV) The excluded volume for He is more than H2.
(A) I, II, III only (B) I, II, IV only
(C) II, III, IV only (D) III, IV only

2. One mole of a monoatomic real gas satisfied the equation P V  b   RT , where b is a constant. The
relationship of interatomic potential V  r  and interatomic distance r for the gas is given by:

V(r) V(r) V(r) V(r)


(A) (B) (C) (D)

O r O r O r O r

3. Wave function of an orbital is plotted against the distance from nucleus. The graphical representation is of:



+ +
O –

(A) 1s (B) 2s (C) 3s (D) 2p

4. Dichromate ion in acidic medium oxides stannous ion as:


xSn2  yCr2O72  zH  
 aSn4  bCr 3  cH2O
Identify the correct statement/s and mark the correct option:
(I) The value of x : y is 1 : 3
(II) The value of x  y  z is 18
(III) a : b is 3 : 2
(IV) the value of z  c is 7
(A) I, III (B) I, II, III (C) II, III, IV (D) I, IV

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5. Consider the following six electronic configurations (remaining inner orbitals are completely filled) and mark
the incorrect option.
3s 3p 3s 3p 4s 3d
(I) (II) (III)

4s 3d 4s 4p 4s 3d
(IV) (V) (VI)

(A) Stability order: IV > III


(B) Order of spin multiplicity: IV > III = I > II
(C) V does not violate all the three rules of electronic configuration
+
(D) If VI represents A, then A when kept near a magnet, acts as diamagnetic substance.
1
6. How many electrons in an atom can have n  4 , l  2 , m  2 and s  
2
(A) 1 (B) 2 (C) 5 (D) 10
+ –
7. If the ionic radii of K and F are nearly the same (i.e. 1.34Å) then the atomic radii of K and F respectively are:
(A) 1.34 Å, 1.34Å (B) 0.72Å, 1.96 Å
(C) 1.96 Å, 0.72 Å (D) 1.96 Å, 1.34 Å

8. A mixture of nitrogen and water vapour is admitted to a flask at 760 torr which contains a sufficient solid drying
agent. After long time the pressure reached a steady value of 722 torr. If the experiment is done at 27°C and
drying agent increases in weight by 0.9 gram, what is the volume of the flask? Neglect any possible vapour
pressure of drying agent and volume occupied by drying agent.
(A) 443.34 l (B) 246.3 l (C) 12.315 l (D) 24.63 l

Comprehension Type
Paragraph for question Nos. 09 to 10
Ionisation potential is the minimum amount of energy needed to remove the outermost electron from the gaseous
isolated atom. Its unit is eV/atom or kJ/mole. Successive ionisation energy is the amount of energy needed to remove
electron successively from a gaseous ion, it may be termed as IE2 ,IE3 ,.... . The difference in the values of IE1 ,IE2 ,....
helps to determine electronic configuration of the elements.

Element IE1(Kcal/mole) IE2 (Kcal/mole) IE3(Kcal/mole)


P 497 947 1500
Q 98 735 1100
R 176 347 1850
S 296 530 2050
9. Which of the elements can make MX type compound (X is the halogen)?

(A) P (B) Q (C) R (D) S

10. The order of ionic mobility in aqueous solution of the following ions will be (If R,S belong to same group)
(A) R2  aq   S2  aq  (B) S2  aq   R2  aq 
(C) S2  aq   R2  aq  (D) can not be co-related

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Paragraph for question Nos. 11 to 12

Ascorbic acid, C6H8O6, also known as Vitamin C is a dibasic acid and it is readily oxidized to dehydroascorbic acid as:
O O
HO OH
HO HO +
+ 2H + 2e 
HO H O
O O
O O

(C 6H8O 6) (C 6H6O6)
The estimation of ascorbic acid in a sample is made by titrating its solution with KIO 3 solution which acts as an
intermediate and in presence of 1 M HCl solution, the first excess of iodate gives blue colour with starch due to the
redox change given below:
C6 H8O6  IO31  C6 H6O6  I   H2O
IO31  I   6H  
 I 2  H2O
However, if 5 M HCl is used, the redox change occurring is:
C6 H6O6  ICl  2H2O
C6 H8O6  IO31  H   Cl 
The acid is heat and light sensitive and deactivated at higher temperature and thus placed in cold and dark place. It is
found in fruit juice, green vegetables and its deficiency in human body develops scurvy, brittling of bone, teething
trouble etc.

11. A given 1 litre solution of KIO3 of unknown molarity is titrated by taking its 50 ml solution against KI solution in
strong acid medium of excess HCl. The equivalence point was detected when 10 ml of 0.1 M KI was
consumed. The molarity of KIO3 solution:
–3 –3 –3 –2
(A) 4 × 10 M (B) 2 × 10 M (C) 8 × 10 M (D) 10 M

12. The 250 ml sample of fruit juice collected by crushing a fruit is supposed to have only one ingredient (which
can react with KIO3) is taken in 500 ml measuring flask and 250 ml of 1 M HCl is added. A 50 ml solution is
now pipette out and titrated against KIO3 of concentration as reported in above problem. It was found that 1 ml
KIO3 were used. The molarity of ascorbic acid is:
–4 –4 –4
(A) 4.8 × 10 M (B) 9.6 × 10 M (C) 2.4 × 10 M (D) None of these
Paragraph for question Nos. 13 to 14
Consider the adjacent diagram. Initially, flask ‘A’ contained oxygen gas at 27°C and 950 mm of Hg and flask B
contained neon gas at 27°C and 900 mm Hg. Finally, two flask were joined by means of a narrow tube of negligible
volume equipped with a stop cock and gases were allowed to mix up freely. The final pressure in the combined
system was found to be 910 mm of Hg.
A B
O2 Ne

13. What is the correct relationship between volumes of the two flasks?
(A) VB  2VA (B) VB  4VA (C) VB  5VA (D) VB  5.5VA

14. If flask ‘B’ were heated to 127°C, maintaining flask ‘A’ at constant temperature of 27°C, final pressure (in mm
Hg) in the combined system would have been
(A) 1007 (B) 1250 (C) 1137.5 (D) 1990

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Paragraph for question Nos. 15 to 16

Air sample from an industrial area of Delhi, which is heavily polluted by CO 2, was collected and analysed. One such
sample of 224 L of air measured at STP was passed through a 500 mL of 0.1 M KOH solution, where CO 2(g) was
absorbed completely. 50 ml of the above solution was then treated with excess of BaCl 2 solution where all the
carbonate was precipitated as BaCO3(s). The solution was filtered off and the filtrate required 30 ml of 0.1 M HCl
solution for neutralization.
6
15. ppm strength of CO2(g) volume by volume (ml CO2 per 10 ml of air) is :
(A) 224 (B) 2240 (C) 100 (D) 1000

16. Calculate the weight of the precipitate of BaCO3 (s) obtained from 50 ml of the above test solution (M.Wt : Ba
= 137, C = 12, O = 16, BaCO3 = 197)
(A) 3.94 g (B) 0.394 g (C) 1.97 g (D) 0.197 g

PART - B
Matrix Match Type
1. Match the Matrix

Column-I Column-II
(A) Exothermic change P. O  g   O  g 

(B) Endothermic change Q. O  g   O1  g 


O  g   O2  g 
nd
(C) I.E.2 of oxygen (2 ionization R.
energy)
(D) E.A. of oxygen (Electron affinity) S. O1  g   O2  g 
T. O  g   O2   g 

2.
Column-I Column-II
(A) Radial probability distribution graph P.
for 1s orbital

(B) Radial probability distribution graph Q.


for 2s orbital

(C) Has got one radial node R.

(D) Electron cloud picture for 2s orbital S.

T.

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3.

Column-I Column-II
(Equivalent weight of reactant)
(A) M.Wt P. When CrI 3 oxidises into Cr2O72 and IO41
Eq. Wt. =
33
M.Wt When Fe  SCN 2 oxidises into Fe , SO42 ,
(B) Q. +3
Eq. Wt. =
27 CO32 and NO31
(C) M.Wt R. When NH4SCN oxidizes into SO42 , CO32 and
Eq. Wt. =
28 NO31
–1
(D) M.Wt S. When As2S3 oxidises into AsO3 and SO42
Eq. Wt. =
24
T. When CrCl3 oxidises into CrO42 and ClO41

4. Match the correct column from List-1 to List-2 on the basis of following Andrews isotherm of real gas

E G
 F T3
P C
T2
T1
D B
A

V

Column-I Column-II
(A) Substance exist in both liquid and P. At AB part
gas state
(B) Only liquid state exist Q. At BD part
(C) Substance exist in gas state only R. At DE part
(D) Highest temperature region in the S. At point C
given plot
T. At GF curve

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SECTION – II (MATHEMATICS)
PART – A
Single Correct Choice Type
sin A 3 cos A 5 
1. If  and  , 0  A, B  then tan A  tanB is equal to
sin B 2 cos B 2 2
3 5 5 3
(A) (B) (C) 1 (D)
5 3 5

 
2. If tan  cos ec  sin then sec 2 =
2 2
(A) 5 1 (B) 5 1 (C) 5 2 (D) 5 2

3.  
If 1  1  a tan  1  1  a , where a  R , then sin 4 is equal to

(A) 1 a (B) 1 a (C) a (D) a

4. Let a and b be two chords of a circle which subtends angles 360 and 60 0 respectively at the centre of the
circle. A chord of length a  b subtends at the centre of the circle an angle.
(A) 80 0 (B) 1080 (C) 1200 (D) 1350

5. The perpendicular bisectors of the sides AB and AC of triangle ABC are x  y  5  0 and x  2y  0
respectively. If A is  1, 2 , then equation of BC is
(A) 14x  23y  40  0 (B) 14x  23y  40  0
(C) 14x  23y  40  0 (D) 14x  23y  40  0

6. Equation of the line pair through the origin and perpendicular to the line pair xy  3y 2  y  2x  10  0 is
(A) xy  3y 2  0 (B) xy  3y 2  0 (C) xy  3x 2  0 (D) x 2  y 2  0

7. If the points of intersection of curves C1 :  x 2  4y 2  2xy  9x  3 and C2 : 2x2  3y 2  4xy  3x  1 subtends a


right angle at origin then the value of  is
(A) 19 (B) 9 (C) - 19 (D) - 9

8. If two vertices of a ABC are given by A 1, 1 , C  3,6  equation of the internal angle bisector ABC is
x  y  4  0 then equation of BC is
(A) x  2y  15  0 (B) x  2y  15  0 (C) x  2y  30  0 (D) None of these

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Comprehension Type
Paragraph for question Nos. 09 to 10

The equation of sides AB,BC,CA of triangle ABC are 2x  y  0 , x  py  q, x  y  3 respectively. The point P is
 2,3

9. If P is centroid then p  q 
(A) 47 (B) 50 (C) 65 (D) 74

10. If P is the orthocentre then p  q 


(A) 47 (B) 50 (C) 87 (D) 74

Paragraph for question Nos. 11 to 12


ABC is a triangle right angled at A, AB = 2AC. A  1,2 , B  3,1 . The vertices of the triangles are in anticlockwise
sense. BCEF is a square with vertices in clockwise sense.

11. Area of triangle ACF is


51 51 31 21
(A) (B) (C) (D)
8 4 5 4

12. The abscissa of the centroid of triangle BCE is


1 1 2
(A) - 1 (B)  (C)  (D) 
2 3 3
Paragraph for question Nos. 13 to 14
In a triangle ABC if
cot A  cot B  cotC  cot 

13. cos ec 2 A  cos ec 2B  cos ec 2C is equal to


(A) sin2  (B) cos2  (C) sec 2  (D) cos ec 2

14. The maximum value of  is


(A) 30 0 (B) 45 0 (C) 60 0 (D) 90 0

Paragraph for question Nos. 15 to 16

Let p be the product of the sines of the angles of triangle ABC and q is the product of the cosines of the angles

15. In this triangle tan A  tanB  tanC 


p q
(A) p  q (B) p  q (C) (D)
q p
16. tan AtanB  tanC tanC  tanC tan A 
1 q 1 p
(A) 1  q (B) (C) 1  p (D)
q p

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PART - B
Matrix Match Type
1.
Column - I Column - II
(A) If for some real x the equation (P) 2
1
x   2cos  holds then cos 
x
(B) If sin  cos ec  2 then sin10   cos ec10  (Q) 1
(C) Maximum value of sin4   cos4   (R) 0
(D) Least value of 2sin2   3cos2  (S) 1
(T) 2
2.
Column - I Column - II
(A) 2  sin 4200 cos 3900  cos  6600  sin  3300  (P) 0
(B) tan 3150 cot  4050   cot 4950 tan  5850  (Q) 1
(C)
The value of
1  tan 8 1  tan 37  
0 0 (R) 2

1  tan 22 1  tan 23 


0 0

(D) Number of solution of (S) 3


log2  4.3x  6   log2 9x  6   1 is

(T) 5
3.
Column - I Column - II
(A) Slope of line bisecting the angle between (P) 1
coordinates axes.
(B) Area of triangle formed by line (Q) 0
3x  4y  12  0 with coordinate axes.
(C) Equation 2x2  2xy  y 2  6x  6y  c  0 (R) 1
represents a pair of lines then c 
(D) If distance between the pair of parallel lines (S) 3
x2  2xy  y 2  8ax  8ay  9a2  0 is 25 2
a
then 
5
(T) 6

4. Match the following:


Column – I Column – II
(A) 2 4 8 (P) 7
The value of sin  sin  sin is
7 7 7
(B)         (Q) 3
If 4cos = 3cos, then the value of cot   cot   is
 2   2  2
(C) If A + B + C = , then greatest value of cosA + cosB + cosC is (R) 3
3 cos2x sin2x
(D) The minimum value of 9 .27 .81 (S) 7
2
(T) 3

2

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SECTION – III (PHYSICS)


PART – A
Single Correct Choice Type
   
1. The resultant of A and B makes an angle  with A and  with B ,
(A)    (B)    if A < B (C)    if A > B (D)    if A = B

  
2. Which of the following representation is incorrect for vector equation R  P  Q?

 
(A) R (B) Q

Q 
R
 
P 
P
(C)  (D) 
 P P 

Q  
 R Q
R

        
3. For any two vectors A and B if A  B |A  B|, the magnitude of C  A  B is equal to
1/ 2
 AB 
A 
1/ 2
(A) A2  B2 (B) A  B (C)  A2  B2  (D) 2
 B2  2AB
 2 

4. A body travelling along a straight line traversed one third of the total distance with a velocity 4 m/s. The
remaining part of the distance was covered with a velocity 2 m/s for half the time and with velocity 6 m/s for
the other half of time. The mean velocity averaged over the whole time of motion is
(A) 5 m/s (B) 4 m/s (C) 4.5 m/s (D) 3.5 m/s

5. A particle is projected vertically upwards from a point A on the ground. It takes time t1 to reach a point B, but it
still continues to move up. If it takes further t2 time to reach the ground from point B. Then height of point B
from the ground is
1 1 1
(A) g  t1  t2  (C) g  t1  t2 
2 2
(B) gt1t2 (D) gt1t2
2 8 2

6. The acceleration time graph of a particle moving in a straight a(m/s)2


line is as shown in the figure. The velocity of the particle at
time t = 0 is 2 m/s. The velocity after 2 seconds will be 4
(A) 6 m/s
(B) 4 m/s
(C) 2 m/s
(D) 8 m/s t(s)
1 2

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Ai TS – 1 ( XI ) | SET – A | APT – 4 | P a g e | 11
0
7. A particle is projected from ground at an angle 60 with
horizontal with a speed of 10 3 m / s from point A as shown.
At the same time the sufficient long wedge is made to move 10 3 m/s
with constant velocity of 10 3 towards right as shown in 10 3 m/s
figure. The time in second after which particle will hit the
wedge will be (g = 10 m/s )
2
300 600
(A) 1 sec A
(B) 2 sec
(C) 3 sec
(D) it will never collide on the wedge

8. The dimensions of Planck’s constant are


(A)  MLT 1  (B)  ML2T 2  (C)  ML1T 2  (D)  ML2T 1 

Comprehension Type
Paragraph for question Nos. 09 to 10

A mosquito net over a 7 ft  4 ft bed is 3 ft high. The net has a hole at one corner of the bed through which a
mosquito enters the net. Take the hole as origin, the length of the bed as the x-axis, its width as the y-axis and
vertically up as the z-axis. Now answer the following question based on the paragraph.

9. It the mosquito files and sits at the diagonally opposite upper corner of the net, then what is the displacement
of the mosquito?
(A) 7iˆ  3jˆ  4kˆ (B) 7iˆ  4ˆj  3kˆ (C) 3iˆ  7 ˆj  4kˆ (D) 4iˆ  3jˆ  7kˆ

10. What is the unit vector along the plane of the bed, which is directed away from the hole along the diagonal of
the bed?
7i  4 ˆj 4iˆ  7 ˆj
(A) 7iˆ  4ˆj (B) 4iˆ  7 ˆj (C) (D)
65 65

Paragraph for question Nos. 11 to 12


In a new system of units, let the units of force, energy and velocity be 5 N, 10 J and 100 ms1 respectively. Then in
this system

11. The unit of length is


(A) 1 m (B) 2 m (C) 3 m (D) 4 m

12. The unit of mass is


-1 -2 -3 -4
(A) 10 kg (B) 10 kg (C) 10 kg (D) 10 kg

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Paragraph for question Nos. 13 to 14


y
Using the concept of relative motion, answer the following question.
Velocity of the river with respect to ground is given by 'V0 ' . Width of
the river is ‘d’. A swimmer swims (with respect to water) perpendicular
d V0
to the current with acceleration a  2t (where t is time) starting from
rest form the origin O at t = 0.
O

13. The time of crossing the river is


(A)  d  (B)  2d  (C)  3d 
1/ 3 1/ 3 1/ 3
(D) information is insufficient

14. The drift of the swimmer is


(A) V0  d  (B) V0  2d  (C) V0  3d 
1/ 3 1/ 3 1/ 3
(D) None of these

Paragraph for question Nos. 15 to 16

The coordinates of a particle moving in a plane are given by x  t   acos  pt  and y  t   b sin  pt  , where
a,b   a  , and p are positive constants of appropriate dimensions. Then

15. Shape of the path followed by particle is


(A) Circle (B) Straight line (C) Ellipse (D) Parabola

16. The time of which velocity and acceleration of the particle are normal to each other
   
(A) (B) (C) (D)
2p 3p 4p 6p
PART - B
Matrix Match Type

1. Some physical quantities are given in column I, and some possible SI units in which these quantities may be
expressed are given in column II. Match the physical quantities in column I with the units in column II.

Column - I Column - II
(A) GMe Ms (P) (volt)(coulomb) (meter)
G  universal gravitational constant
M e - mass of the earth
Ms - mass of the sun
3 -2
(B) 3RT (Q) (kilogram) (meter) (second)
M
R  universal gas
T  absolute temperature
M  molar mass
2 -2
(C) F2 (R) (meter) (second)
q 2 B2
F  force
q  charge
B  magnetic field
2 -1
(D) GM e (S) (farad) (volt) (kilogram)
Re
G  universal gravitational constant
Me  mass of the earth
Re radius of the earth

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2. A particle initially (t = 0) located at x = 0 moves along the positive x direction under the action of a force. The
velocity of the particle varies with x as v  k x , where k is a constant. Then
Column - I Column - II
(A) the displacement x varies with time t as (P) k 2T 2
4
(B) the velocity v varies with time t as (Q) kt2

2
(C) the acceleration a varies with the time t as (R) k 2t 2
of the particle is 4
(D) the distance s traveled by the particle in (S) 2
k
time T is 2
 
3. Given two vectors A  xiˆ  4ˆj and B  6iˆ  2jˆ . For value of x match the following

Column - I Column - II
 
(A) A is perpendicular to B (P) x  12
 
(B) A is either parallel or antiparallel to B (Q) x2 6
   
(C)
 
A  B is perpendicular to A  B   (R)
x
4
3
  
(D)
 A  B is parallel to  A  (S) x  6

4.
Column - I Column - II
(A) A particle is moving in circle (P) The acceleration may be perpendicular to its
velocity
(B) A particle is moving in a straight line (Q) The acceleration may be in the direction of
velocity
(C) A particle is undergoing projectile motion (R) The acceleration may be at some angle 
  
with angle of projection  , 0    with the velocity  0    
2  2
(D) A particle is moving is space (S) The acceleration may be opposite to its
velocity

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