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Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Sections.
Section – I is “Chemistry”, Section – II is “Mathematics” and Section – III is “Physics”.
Each Section is further divided into two Parts: Part – A & Part – B.
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
(i) PART-A (01 – 08) contains 8 Multiple Choice Questions which have Only One Correct answer. Each
question carries +4 marks for correct answer and –2 marks for wrong answer.
PART-A (09 – 16) contains 4 Paragraphs. Based upon each paragraph, 2 Multiple Choice Questions have to
be answered. Each question has Only One Correct answer and carries +3 marks for the correct answer and
–1 mark for a wrong answer.
(ii) PART-B(01 – 04) contains 4 Matrix Match Type Question which have statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. There may be
One or More Than One Correct choices. Each question carries +12 marks for all correct answer however
for each correct row +3 marks will be awarded and –1 mark for each row matched incorrectly.
Name of Candidate :
Enrolment Number :
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Ai TS – 1 ( XI ) | SET – A | APT – 4 | Page |1
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Ai TS – 1 ( XI ) | SET – A | APT – 4 | Page |2
SECTION – I (CHEMISTRY)
PART - A
Single Correct Type
2. One mole of a monoatomic real gas satisfied the equation P V b RT , where b is a constant. The
relationship of interatomic potential V r and interatomic distance r for the gas is given by:
O r O r O r O r
3. Wave function of an orbital is plotted against the distance from nucleus. The graphical representation is of:
+ +
O –
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Ai TS – 1 ( XI ) | SET – A | APT – 4 | Page |3
5. Consider the following six electronic configurations (remaining inner orbitals are completely filled) and mark
the incorrect option.
3s 3p 3s 3p 4s 3d
(I) (II) (III)
4s 3d 4s 4p 4s 3d
(IV) (V) (VI)
8. A mixture of nitrogen and water vapour is admitted to a flask at 760 torr which contains a sufficient solid drying
agent. After long time the pressure reached a steady value of 722 torr. If the experiment is done at 27°C and
drying agent increases in weight by 0.9 gram, what is the volume of the flask? Neglect any possible vapour
pressure of drying agent and volume occupied by drying agent.
(A) 443.34 l (B) 246.3 l (C) 12.315 l (D) 24.63 l
Comprehension Type
Paragraph for question Nos. 09 to 10
Ionisation potential is the minimum amount of energy needed to remove the outermost electron from the gaseous
isolated atom. Its unit is eV/atom or kJ/mole. Successive ionisation energy is the amount of energy needed to remove
electron successively from a gaseous ion, it may be termed as IE2 ,IE3 ,.... . The difference in the values of IE1 ,IE2 ,....
helps to determine electronic configuration of the elements.
10. The order of ionic mobility in aqueous solution of the following ions will be (If R,S belong to same group)
(A) R2 aq S2 aq (B) S2 aq R2 aq
(C) S2 aq R2 aq (D) can not be co-related
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Ai TS – 1 ( XI ) | SET – A | APT – 4 | Page |4
Ascorbic acid, C6H8O6, also known as Vitamin C is a dibasic acid and it is readily oxidized to dehydroascorbic acid as:
O O
HO OH
HO HO +
+ 2H + 2e
HO H O
O O
O O
(C 6H8O 6) (C 6H6O6)
The estimation of ascorbic acid in a sample is made by titrating its solution with KIO 3 solution which acts as an
intermediate and in presence of 1 M HCl solution, the first excess of iodate gives blue colour with starch due to the
redox change given below:
C6 H8O6 IO31 C6 H6O6 I H2O
IO31 I 6H
I 2 H2O
However, if 5 M HCl is used, the redox change occurring is:
C6 H6O6 ICl 2H2O
C6 H8O6 IO31 H Cl
The acid is heat and light sensitive and deactivated at higher temperature and thus placed in cold and dark place. It is
found in fruit juice, green vegetables and its deficiency in human body develops scurvy, brittling of bone, teething
trouble etc.
11. A given 1 litre solution of KIO3 of unknown molarity is titrated by taking its 50 ml solution against KI solution in
strong acid medium of excess HCl. The equivalence point was detected when 10 ml of 0.1 M KI was
consumed. The molarity of KIO3 solution:
–3 –3 –3 –2
(A) 4 × 10 M (B) 2 × 10 M (C) 8 × 10 M (D) 10 M
12. The 250 ml sample of fruit juice collected by crushing a fruit is supposed to have only one ingredient (which
can react with KIO3) is taken in 500 ml measuring flask and 250 ml of 1 M HCl is added. A 50 ml solution is
now pipette out and titrated against KIO3 of concentration as reported in above problem. It was found that 1 ml
KIO3 were used. The molarity of ascorbic acid is:
–4 –4 –4
(A) 4.8 × 10 M (B) 9.6 × 10 M (C) 2.4 × 10 M (D) None of these
Paragraph for question Nos. 13 to 14
Consider the adjacent diagram. Initially, flask ‘A’ contained oxygen gas at 27°C and 950 mm of Hg and flask B
contained neon gas at 27°C and 900 mm Hg. Finally, two flask were joined by means of a narrow tube of negligible
volume equipped with a stop cock and gases were allowed to mix up freely. The final pressure in the combined
system was found to be 910 mm of Hg.
A B
O2 Ne
13. What is the correct relationship between volumes of the two flasks?
(A) VB 2VA (B) VB 4VA (C) VB 5VA (D) VB 5.5VA
14. If flask ‘B’ were heated to 127°C, maintaining flask ‘A’ at constant temperature of 27°C, final pressure (in mm
Hg) in the combined system would have been
(A) 1007 (B) 1250 (C) 1137.5 (D) 1990
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Ai TS – 1 ( XI ) | SET – A | APT – 4 | Page |5
Air sample from an industrial area of Delhi, which is heavily polluted by CO 2, was collected and analysed. One such
sample of 224 L of air measured at STP was passed through a 500 mL of 0.1 M KOH solution, where CO 2(g) was
absorbed completely. 50 ml of the above solution was then treated with excess of BaCl 2 solution where all the
carbonate was precipitated as BaCO3(s). The solution was filtered off and the filtrate required 30 ml of 0.1 M HCl
solution for neutralization.
6
15. ppm strength of CO2(g) volume by volume (ml CO2 per 10 ml of air) is :
(A) 224 (B) 2240 (C) 100 (D) 1000
16. Calculate the weight of the precipitate of BaCO3 (s) obtained from 50 ml of the above test solution (M.Wt : Ba
= 137, C = 12, O = 16, BaCO3 = 197)
(A) 3.94 g (B) 0.394 g (C) 1.97 g (D) 0.197 g
PART - B
Matrix Match Type
1. Match the Matrix
Column-I Column-II
(A) Exothermic change P. O g O g
2.
Column-I Column-II
(A) Radial probability distribution graph P.
for 1s orbital
T.
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Ai TS – 1 ( XI ) | SET – A | APT – 4 | Page |6
3.
Column-I Column-II
(Equivalent weight of reactant)
(A) M.Wt P. When CrI 3 oxidises into Cr2O72 and IO41
Eq. Wt. =
33
M.Wt When Fe SCN 2 oxidises into Fe , SO42 ,
(B) Q. +3
Eq. Wt. =
27 CO32 and NO31
(C) M.Wt R. When NH4SCN oxidizes into SO42 , CO32 and
Eq. Wt. =
28 NO31
–1
(D) M.Wt S. When As2S3 oxidises into AsO3 and SO42
Eq. Wt. =
24
T. When CrCl3 oxidises into CrO42 and ClO41
4. Match the correct column from List-1 to List-2 on the basis of following Andrews isotherm of real gas
E G
F T3
P C
T2
T1
D B
A
V
Column-I Column-II
(A) Substance exist in both liquid and P. At AB part
gas state
(B) Only liquid state exist Q. At BD part
(C) Substance exist in gas state only R. At DE part
(D) Highest temperature region in the S. At point C
given plot
T. At GF curve
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Ai TS – 1 ( XI ) | SET – A | APT – 4 | Page |7
SECTION – II (MATHEMATICS)
PART – A
Single Correct Choice Type
sin A 3 cos A 5
1. If and , 0 A, B then tan A tanB is equal to
sin B 2 cos B 2 2
3 5 5 3
(A) (B) (C) 1 (D)
5 3 5
2. If tan cos ec sin then sec 2 =
2 2
(A) 5 1 (B) 5 1 (C) 5 2 (D) 5 2
3.
If 1 1 a tan 1 1 a , where a R , then sin 4 is equal to
4. Let a and b be two chords of a circle which subtends angles 360 and 60 0 respectively at the centre of the
circle. A chord of length a b subtends at the centre of the circle an angle.
(A) 80 0 (B) 1080 (C) 1200 (D) 1350
5. The perpendicular bisectors of the sides AB and AC of triangle ABC are x y 5 0 and x 2y 0
respectively. If A is 1, 2 , then equation of BC is
(A) 14x 23y 40 0 (B) 14x 23y 40 0
(C) 14x 23y 40 0 (D) 14x 23y 40 0
6. Equation of the line pair through the origin and perpendicular to the line pair xy 3y 2 y 2x 10 0 is
(A) xy 3y 2 0 (B) xy 3y 2 0 (C) xy 3x 2 0 (D) x 2 y 2 0
8. If two vertices of a ABC are given by A 1, 1 , C 3,6 equation of the internal angle bisector ABC is
x y 4 0 then equation of BC is
(A) x 2y 15 0 (B) x 2y 15 0 (C) x 2y 30 0 (D) None of these
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Ai TS – 1 ( XI ) | SET – A | APT – 4 | Page |8
Comprehension Type
Paragraph for question Nos. 09 to 10
The equation of sides AB,BC,CA of triangle ABC are 2x y 0 , x py q, x y 3 respectively. The point P is
2,3
9. If P is centroid then p q
(A) 47 (B) 50 (C) 65 (D) 74
Let p be the product of the sines of the angles of triangle ABC and q is the product of the cosines of the angles
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Ai TS – 1 ( XI ) | SET – A | APT – 4 | Page |9
PART - B
Matrix Match Type
1.
Column - I Column - II
(A) If for some real x the equation (P) 2
1
x 2cos holds then cos
x
(B) If sin cos ec 2 then sin10 cos ec10 (Q) 1
(C) Maximum value of sin4 cos4 (R) 0
(D) Least value of 2sin2 3cos2 (S) 1
(T) 2
2.
Column - I Column - II
(A) 2 sin 4200 cos 3900 cos 6600 sin 3300 (P) 0
(B) tan 3150 cot 4050 cot 4950 tan 5850 (Q) 1
(C)
The value of
1 tan 8 1 tan 37
0 0 (R) 2
(T) 5
3.
Column - I Column - II
(A) Slope of line bisecting the angle between (P) 1
coordinates axes.
(B) Area of triangle formed by line (Q) 0
3x 4y 12 0 with coordinate axes.
(C) Equation 2x2 2xy y 2 6x 6y c 0 (R) 1
represents a pair of lines then c
(D) If distance between the pair of parallel lines (S) 3
x2 2xy y 2 8ax 8ay 9a2 0 is 25 2
a
then
5
(T) 6
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Ai TS – 1 ( XI ) | SET – A | APT – 4 | P a g e | 10
2. Which of the following representation is incorrect for vector equation R P Q?
(A) R (B) Q
Q
R
P
P
(C) (D)
P P
Q
R Q
R
3. For any two vectors A and B if A B |A B|, the magnitude of C A B is equal to
1/ 2
AB
A
1/ 2
(A) A2 B2 (B) A B (C) A2 B2 (D) 2
B2 2AB
2
4. A body travelling along a straight line traversed one third of the total distance with a velocity 4 m/s. The
remaining part of the distance was covered with a velocity 2 m/s for half the time and with velocity 6 m/s for
the other half of time. The mean velocity averaged over the whole time of motion is
(A) 5 m/s (B) 4 m/s (C) 4.5 m/s (D) 3.5 m/s
5. A particle is projected vertically upwards from a point A on the ground. It takes time t1 to reach a point B, but it
still continues to move up. If it takes further t2 time to reach the ground from point B. Then height of point B
from the ground is
1 1 1
(A) g t1 t2 (C) g t1 t2
2 2
(B) gt1t2 (D) gt1t2
2 8 2
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Ai TS – 1 ( XI ) | SET – A | APT – 4 | P a g e | 11
0
7. A particle is projected from ground at an angle 60 with
horizontal with a speed of 10 3 m / s from point A as shown.
At the same time the sufficient long wedge is made to move 10 3 m/s
with constant velocity of 10 3 towards right as shown in 10 3 m/s
figure. The time in second after which particle will hit the
wedge will be (g = 10 m/s )
2
300 600
(A) 1 sec A
(B) 2 sec
(C) 3 sec
(D) it will never collide on the wedge
Comprehension Type
Paragraph for question Nos. 09 to 10
A mosquito net over a 7 ft 4 ft bed is 3 ft high. The net has a hole at one corner of the bed through which a
mosquito enters the net. Take the hole as origin, the length of the bed as the x-axis, its width as the y-axis and
vertically up as the z-axis. Now answer the following question based on the paragraph.
9. It the mosquito files and sits at the diagonally opposite upper corner of the net, then what is the displacement
of the mosquito?
(A) 7iˆ 3jˆ 4kˆ (B) 7iˆ 4ˆj 3kˆ (C) 3iˆ 7 ˆj 4kˆ (D) 4iˆ 3jˆ 7kˆ
10. What is the unit vector along the plane of the bed, which is directed away from the hole along the diagonal of
the bed?
7i 4 ˆj 4iˆ 7 ˆj
(A) 7iˆ 4ˆj (B) 4iˆ 7 ˆj (C) (D)
65 65
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Ai TS – 1 ( XI ) | SET – A | APT – 4 | P a g e | 12
The coordinates of a particle moving in a plane are given by x t acos pt and y t b sin pt , where
a,b a , and p are positive constants of appropriate dimensions. Then
16. The time of which velocity and acceleration of the particle are normal to each other
(A) (B) (C) (D)
2p 3p 4p 6p
PART - B
Matrix Match Type
1. Some physical quantities are given in column I, and some possible SI units in which these quantities may be
expressed are given in column II. Match the physical quantities in column I with the units in column II.
Column - I Column - II
(A) GMe Ms (P) (volt)(coulomb) (meter)
G universal gravitational constant
M e - mass of the earth
Ms - mass of the sun
3 -2
(B) 3RT (Q) (kilogram) (meter) (second)
M
R universal gas
T absolute temperature
M molar mass
2 -2
(C) F2 (R) (meter) (second)
q 2 B2
F force
q charge
B magnetic field
2 -1
(D) GM e (S) (farad) (volt) (kilogram)
Re
G universal gravitational constant
Me mass of the earth
Re radius of the earth
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Ai TS – 1 ( XI ) | SET – A | APT – 4 | P a g e | 13
2. A particle initially (t = 0) located at x = 0 moves along the positive x direction under the action of a force. The
velocity of the particle varies with x as v k x , where k is a constant. Then
Column - I Column - II
(A) the displacement x varies with time t as (P) k 2T 2
4
(B) the velocity v varies with time t as (Q) kt2
2
(C) the acceleration a varies with the time t as (R) k 2t 2
of the particle is 4
(D) the distance s traveled by the particle in (S) 2
k
time T is 2
3. Given two vectors A xiˆ 4ˆj and B 6iˆ 2jˆ . For value of x match the following
Column - I Column - II
(A) A is perpendicular to B (P) x 12
(B) A is either parallel or antiparallel to B (Q) x2 6
(C)
A B is perpendicular to A B (R)
x
4
3
(D)
A B is parallel to A (S) x 6
4.
Column - I Column - II
(A) A particle is moving in circle (P) The acceleration may be perpendicular to its
velocity
(B) A particle is moving in a straight line (Q) The acceleration may be in the direction of
velocity
(C) A particle is undergoing projectile motion (R) The acceleration may be at some angle
with angle of projection , 0 with the velocity 0
2 2
(D) A particle is moving is space (S) The acceleration may be opposite to its
velocity
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