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Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
You are not allowed to leave the Examinat ion Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
BATCHES – 57
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Section.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each section is further divided into three part: Part-A , Part-B & Part-C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.
Part -A (09 – 12) contains 4 multiple choice questions which have one or more than one correct
answer. Each question carries +4 marks for correct answer. There is no negative marking.
(ii) Part -B (01 – 02) contains 2 Matrix Match Type questions containing statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. Each question
carries +8 marks for all correct answer. For each correct row +2 marks will be awarded and –1 mark for
each row matched incorrectly.
(iii) Part -C (01 – 06) contains 6 Numerical based questions with single digit integer as answer, ranging from 0
to 9 and each question carries +4 marks for correct answer and – 1 mark for wrong answer.
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SECTION – I: PHYSICS
PART – A: (Single Correct Answer Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
2. A long straight wire, carrying a current I is bent at its mid point to form R
0
an angle of 60 . AT a point P, distance R from the point of bending the
P 600
magnetic field is
(A)
2 1 0i
(B)
2 1 0i
4R 4R
0i i
(C) (D) 0
4 3 R 8R
3. A particle charge q and mass m is projected with a velocity v0 towards Magnetic field
passes through O is
qBR qBR
(A) (B)
m sin 2m sin
2qBR 3qBR
(C) (D)
m sin 2m sin
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2
(C) (D) none of these
8R
S
r B
(B)
3
2r
(C)
3
(D) none of these
space for rough work
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V2
(B) Power delivered by V2 is less than V2 R2
3 eR
V
(C) Current through V1 is greater than
2Re
e 1
V2
(D) Power delivered by V2 is greater than
3 eR
+ + ++
10. H , He and O ions having same kinetic energy pass through a region of space filled with uniform
+ +
magnetic field B directed perpendicular to the velocity of ions. The masses of the ions H , He and
++
O are respectively in the ratio 1 : 4 : 16. As a result
+ ++
(A) H ions will be deflected most (B) only O ions will be deflected least
+ ++
(C) He and O ions will suffer same deflection (D) All ions will suffer the same deflection
11. A microammeter has a resistance of 100 and a full scale range of 50A. It can be used as a
voltmeter or as a higher range ammeter provided a resistance is added to it. Pick the correct range
and resistance combinations
(A) 50 V range with 10 k resistance in series (B) 10 V range with 200 k resistance in series
(C) 5 mA range with 1 resistance in parallel (D) 10 mA range with 1 resistance in parallel
12. Two very long coaxial solenoids 1 and 2 of the are set so that one is inside the other. The number of
turns per unit length are n1 and n2. The currents i1 and i2 are flowing in opposite directions. The
magnetic field at the axis of coils is zero. This is possible when
(A) i1 i2 and n1 n2 (B) i1 i2 and n1 n2
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R2
Column I Column II
(T) 2
2.
(B) A charge particle is moving in uniform (Q) Path of particle may be straight line.
electric magnetic and gravitational field.
(C) A charge particle is moving in uniform (R) Path of particle may be circular.
magnetic and gravitational field (where
electric field is zero)
(D) A charge particle is moving in only uniform (S) Path of particle may be helical.
electric field
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2
1 2 1V
4 1
1 1V
4. Calculate the ratio of magnitude of current in 3 2
1
resistance is to magnitude of current in 4 resistance 1V
1V 2
1 1
3
1V 1V
space for rough work
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60
30
10 + - K
12 V
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1. O H
1.HO CH2 2 OH,H
X
2.Excess MeMgBr, then H3O
3.H , H O
MeO O 2
The compound X is
(A) O OH (B) O
MeO Me MeO Me
(C) O O (D) OH O
MeO Me Me H
Me
2.
1.CH3CO3H
2.LiAlH , then H O
X
4 3
3.Na, Mel
The compound X is
OMe
(A) (B)
OMe
O
OMe
(C) (D)
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3. O O
Me
O Me
1.NaBH4 , MeOH
2.TsCl, Pyridine
X
3.NaBr
The compound X is
O Br Br Br
Me
(A) O Me (B) Me Me
O OT s
Br O
Me
O Me
(C) Me Me (D)
Br
4. O
Br
O 1.Mg,Ether
2.EtOH
3.Catalytic H ,H O
X
2
The compound X is
(A) H (B) OH
OEt OEt
O O
(C) O (D) H
OH
O O
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5. CH3CO2H 1.SOCl2
2. 3 Methylaniline
X
3. LiAlH4 then H3O
The compound X is
H3C NH2 H3C NH2
O OH
H H
H3C N H3C N CH3
(C) CH3 (D)
6. H3C OH
O
X
1.HO CH CH OH,Catalytic H
2 2
2.Mg,THF then H C O then H O
2 3
3.H3O , heat
The compound X is
O
Br
H
(A) CH3 (B)
Br O
H
Br
(C) O (D)
O
Br
7. O O
X Catalytic H
Heat
The compound X is
(A) O (B) OH
HO OH O O
(C) O (D) O
HO HO
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8. OH
O
X
1.LiAlH4 then H3 O
2. aq.H SO
2 4
3. PDC
H
The compound X is
(A) EtO (B) EtO
O O
(C) EtO (D) O
OEt
O
O
PART – A: (Multi Correct Choice Type)
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
9. For the benzoin condensation, cyanide ion is used as selective catalyst, this is because
(A) cyanide ion is a good nucleophile
(B) cyanide ion is an effective leaving group
(C) its electron-withdrawing effect makes aldehyde hydrogen more acidic
(D) cyanide ion is a strong base
10. Ester can be reduced by
(A) DIBAL-H (B) Na – C2H5OH (C) NaBH4 (D) CH3MgX
11. Which of the following involves a free radical path?
(A) R X Mg ether
R MgX
(B) R CHO
air
R COOH
OH
Fenton' s H
(C)
reagent
OH O
OH O
3
(D) Fe CN6 /OH
O
12. Ethyl phenyl ketone was treated with 1 equivalent of Br2 / OH . The analysis of reaction mixture after
reaction revealed that
(A) All the ketone was converted into -bromoketone
(B) Only half of the ketone had been consumed
(C) Practically no PhCOCHBrCH3 was present
(D) The sole product is PhCOCHBr2CH3
space for rough work
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Me Me
(B) O (Q) Tollen’s reagent test
H OH
(C) O (R) I2 + NaOH(Iodoform test)
Cl C- H
2.
i CH CuCl1.eq
O3
Zn/H2O
L
OH
M
3 2
ii NH4Cl
N
(K)
Match the following:
Column – I Column – II
(Pairs) (Can be distinguished by)
(A) K and L (P) Ammonical AgNO3
(B) L and N (Q) NaOI
(C) K and M (R) 2, 4-DNP
(D) N and K (S) Br2/H2O
(T) NaHSO3
HOOC COOH
COOH
HOOC
space for rough work
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2. ‘X’ is the sum of localized lone pair and number of nitrogen in melamine. Find the value of X.
OH OH
4. O
X Y Z
H3C C H
SeO
Conc.KOH H /H2O
2
5. CH H
H2O2 /OH
H2C
X
O
How many oxygen atom(s) is/are in the compound[X]?
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1. If the function f x 2x3 9ax2 12a2 x 1 has a local maximum at x x1 and a local
minimum at x x2 such that x 2 x12 , then a is equal to
1
(A) 0 (B)
4
(C) 2 (D) none of these
xn x n
If f x lim n
xf x ln x 1 x 2 dx is equal to
2.
n x x n
, x 1, then 1 x2
(A) ln x 1 x 2 x c (B)
1 2
2
x ln x 1 x 2 x 2 c
(C) x ln x 1 x 2 ln x 1 x 2 c (D) none of these
ex 1 e 2ex 1 e
(A) (B)
2 e 1 e 3e 3e
ex 2e x
(C) (D)
2e 3e
x x
If l1 ezx e z dz and I2 e z /4 dz, then
2 2
4.
0 0
(A) I1 exI2
2
(B) I1 ex l2
2
(C) I1 ex /2I2 (D) none of these
5. If f ' x x x , where x denotes the fractional part of x, then f x is decreasing in
1 1
(A) , 0 (B) , 2
2 2
1 1
(C) , 2 (D) ,
2 2
space for rough work
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a4
6. The set of all values of a for which the function f x 1 x 5 3x ln5 decreases
1 a
for all real x is
3 21
(A) , (B) 4, 1,
2
27
(C) 3, 5 2, (D) 1,
2
7. The value of m for which the area of the triangle included between the axes and any tangent
to the curve xm y bm is constant, is
1
(A) (B) 1
2
3
(C) (D) 2
2
x 1
2
ex
9. Let f x . Which of the following statements are correct?
1 x
2
2
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The tangent at a point P1 (other than (0, 0)) on the curve ax y b 0 meets the curve again at
3
10.
P2 . The tangent at P2 meets the curve again at P3 and so on. If the abscissae of P1,P2 ,P3 ,...,Pn form
a GP, then (a, b) may be equal to
(A) (1, 0) (B) (2, 7)
(C) (3, 5) (D) (4, 9)
1 1
11. Let f x be a real valued function defined by f x x 2 x 2 t.f t dt x 3 f t dt . Which of the
1 1
following hold good?
1
10 30
(A) t.f t dt 11 (B) f 1 f 1
1
11
1 1
20
(C) t.f t dt f t dt (D) f 1 f 1
1 1
11
cos 2x.cos 2
2
(A) x.cos 23 x.cos 24 x.cos 25 x dx
ln x
1
(B) x 2 1 dx
1
2x 1
1
tan
1
(C) 1 x x 2 dx
0
/2
(D) ln tan x dx
0
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x 1 4 x
(A) 3
3 3
(P) 0
If I x cos x dx, then 50 2 I is
2
equal to
(B) 10 (Q) 100
If J sgn sin x dx, then 10J is equal to
0
(C) 102 (R) 50
If K
0
cot 1 x dx, then [K] is equal to (here [.] denotes
G.I.F.)
(D) 51 (S) 70
x 25 dx L
If L 0
51
, then is equal to (here [.] and {.} denote
2
x 25 dx
0
greatest integer function and fractional part function
respectively)
(T) 20
f x f " x f ' x
2
C is an arbitrary constant.
Column-I Column-II
(A) If f ' n 5040, then n is divisible by (P) 3
(B) If g x , x R is discontinuous at 9 points, then n is divisible (Q) 4
by
(C) If g x 5 has 8 solutions, then n may be equal to (R) 6
(D) If the number of roots of the equation f ' x 0 be (S) 8
(T) 9
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1 x4
1. Let 3
dx f x C1, where f 0 0 and f x dx g x C 2 with g 0 0 . If
1 x 4 2
1 k
g k , find the value of 6 .
2
2
ex e2/ x
2. The value of the definite integral 1 x dx is
n 1
3.
Let n be a positive integer and f x min x 1, x 2 ,..., x n . If f x dx 2, then the value
0
of n is
x3 x 2
4. Let f x
3
2
x 2 and g' x x2 9 x 2 4x 3 x 2 3x 2 x 2 2x 3 . If n1,n2
denote the number of points of local minima and local maxima of the function f g x , then the value
of n1 n2 is
6. Let the function f x ax6 bx5 cx 4 dx3 ex2 fx g a 0 touch the line y g x x p
3
32
at x = 1, 2 and 3, and h x f x g x . If h x dx 105 , then the value of a is
1
space for rough work
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IT-2017-SANKALP-57-XII-PCM-19
PART – A
9. ABD P120216
10. AC P120305
11. BC P120213, P120214
12. CD P120304
PART – B
1. AP BQ CS DR P120206
2. A PQS B PQRS C PQS DQ P120305
PART – C
1. 2 P120309
2. 3 P120213
3. 5 P120305
4. 3 P120207
5. 6 P120216
6. 5 P120306
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CHEMISTRY (SECTION-II)
PART – A
1. D (Concept Code: C121206)
2. A (Concept Code: C121204)
3. A (Concept Code: C121207)
4. D (Concept Code: C121207)
5. D (Concept Code: C121208)
6. A (Concept Code: C121206)
7. A (Concept Code: C121206)
8. A (Concept Code: C121207)
PART – A
9. ABC (Concept Code: C121206)
10. ABD (Concept Code: C121207)
11. ABCD (Concept Code: C121206)
12. BCD (Concept Code: C121206)
PART – B
PART – C
1. 6 (Concept Code: C121207)
2. 9 (Concept Code: C121208)
3. 5 (Concept Code: C121206)
4. 4 (Concept Code: C121206)
5. 2 (Concept Code: C121206)
6. 8 (Concept Code: C121209)
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MATHEMATICS (SECTION-III)
PART – A
1. C M120608
2. D M120701
3. B
4. D M120805
5. A M120605
6. B M120606
7. B M120601
8. C M120602
PART – A
9. AC M120604, M120608
10. ABCD M120601
11. BD
12. ABCD M120802, M120803, M120805, M120806
PART – B
1. A Q M120804
B P M120807
C P M120803
D R M120807
2. A QS M120507
B PT M120508
C ST M120508
D QR
PART – C
1. 2 M120701
2. 0 M120701
3. 5 M120812
4. 4 M120606
5. 9 M120612
6. 2 M120606
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mg
I
RB0
2. C P120302 3 R/2
oI
Sol. B= sin 90 sin( 30 )
o o
4 3 R / 2
–300 600
P
900
oI
=
4 3R
3. B P120305
R
Sol. r
2 sin C r
mv 0 R 2
r
R
qB 2 sin
qBR
v0
2m sin
4. C P120208
12 1r2 r12
Sol. 4
24 r1 r2
5. B P120216
2
Sol. Required value = VC iC max
2 2R 4R
6. A P120306
Sol. Magnetic field at a distance r from the wire will be
B
i
B 0 1 dr
2 r r dl
force on the small element of length dl on semicircular
wire is
dF i2 d l B i2 dl B i2B dr ( dl = dr)
3R
0
F
R
i2 B dr
2
i1i2 ln3 .
7. B P120305
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Sol. The magnetic induction of the solenoid is directed along its axis.
Therefore, the Lorentz force acting on the electron at any instant of time
R B
will lie in the plane perpendicular to the solenoid axis. Since the electron 0
A C
velocity at the initial moment is directed at right angles to the solenoid axis,
the electron trajectory will lie in the plane perpendicular to the solenoid v v'
axis. The Lorentz force can be found from the formula F evB . r
O1
The trajectory of the electron in the solenoid is an arc of the circle whose radius can be deter mined
from the relation evB mv 2 / r.
The trajectory of the electron in shown in figure, where O1 is the centre of the arc AC described by
the electron, v ' is the velocity at which the electron leaves the solenoid. The segments OA and OC
are tangents to the electron trajectory at points A and C. The angle between v and v ' is obviously
AO1C since OAO1 OCO1.
In order to find , let us consider the right triangle OAO1; side OA R and side AO1 r.
Therefore, tan( / 2) R / r eBR / (mv).
eBR
Therefore, 2 tan1
mv
Obviously, the magnitude of the velocity remains unchanged over the entire trajectory since the
Lorentz force is perpendicular to the velocity at any instant. Therefore, the transit time of electron in
the solenoid can be determined from the relation
r m 2m eBR
t tan1 .
v eB eB mv
8. C P120215
I I 2rI 2r
Sol. VAB = IReff = r r , hence Reff is .
3 3 3 3
9. ABD P120216
Sol. q=
CV
3
1 e t/RC
Current through V2
V t /RC
3R
e i2 =
V V 1/RC
Current through V1 i1 = e
2R 6R
V2
at t = RC, power delivered by V2 = Vi2 =
3Re
10. AC P120305
m 1 4 16
Sol. r rH : rHe : r0 : : 1: 2 : 2
q 1 1 2
+
Radius is smallest for H , so it is deflected most
12. CD P120304
Sol. Bnet B1 B2 B1 B2 0 B1 = B2 B ni.
So, n1i1 n2i2 or n1 n2 and i1 i2
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IT-2017-SANKALP-57-XII-PCM-24
PART – B
PART – C
1. 2 P120309
L
Sol. Force exerted by air on the rod
2R v 2 LRv 2
2
Balancing torque about point O NI R B LRv
2 2 3L
4
3v L
2 2
300IBR
4
L2 v 2
I 0.01A
400BR
Thus, Io is 2.
2. 3 P120213
Sol. RVoltmeter = 6, Rammeter = 0.5
Req = 10
30
I 3A
10
Reading of voltmeter = 1 3 = 3 volt.
3. 5 P120305
dv
Sol. q[v x ˆi v y ˆj] B0kˆ [v x ˆi v y ˆj] m … (i)
dt
1 1
ay qv xB0 v y and ax [qB0 v y v x ] … (iii)
m m
At t = 0, v y v 0 and v x 0 and t = t, v x 0 , vy 0
1 2 x
v0 0
qB x
m qB0
qB0mv 0
x = 10.
2 q2B2
Hence, ‘n’ is 5.
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IT-2017-SANKALP-57-XII-PCM-25
4. 3 P120207 2
Sol. According to Kirchoff’s current rule. Current 1 2 1V
4 1
passing through A towards left = current passing
through B toward right. 1V A
1 2
1
1V
1V 2
1 1
B 3
1V 1V
5. 6 P120216
12
Sol. Current through 30 is A and apply loop rule then charge on the capacitor C2 is 60µC.
40
6. 5 P120306
Blq v 2 B2l2 q2
Sol. Impulse Fdt BIl dt mv Blq v h .
m 2g 2m2 g
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IT-2017-SANKALP-57-XII-PCM-26
Chemistry
PART – A
1. D (Concept Code: C121206)
Sol. Acetal formation, then attack of G.R on ester to give complex and finally acidification leads to
(D).
PART – B
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IT-2017-SANKALP-57-XII-PCM-27
Sol. O
C- H
O
L is formed by reductive ozonolysis
C - CH 3
CH3
PART – C
N N
H2N N NH2
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Mathematics
MCQ Single Correct (01 – 08) (+3, –2)
1. C M120608
1. f ' x 6x2 18ax 12a2 0 (for max or min)
x a, 2a
x2 x12
a cannot be negative.
If a 0, then local minimum occurs at x = 2a and local maximum at x = a. Thus, x1 a and
x2 2a .
2. D M120701
xn x n
2. f x lim , x 1
n x n x n
1 x 2n
lim
n 1 x 2n
1 0
1
1 0
I
x f x ln x 1 x 2 dx
x ln x 1 x 2 dx
1 x2
1 x2
Put ln x 1 x
2
t x 1 x 2 et
dx
e
2
dt and t
x 1 x2
1 x 2
or
1
x et e t
2
1
2
1
I et e t .t dt t et e t et e t
2
c
1 x 2 ln x 1 x 2 x c
3. B
f ' x f x f x
1
3.
0
4. D M120805
x
I1 ezx e z dz e
2 x
z2 zx dz
4.
0 0
x 2 x 2 2
z x
x 2 4 x z
e
dz e x2 /4
e 2
dz
0 0
x/2 1 x2 /4 x z2 /4
e z dz e e
2 2
ex /4
dz
x/2 2 x
x
ex e z
2 2
/4 /4
dz
0
2 4
ex / I2
5. A M120605
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5. f ' x x x y
f ' x 0
x x 0 1
x x
It is clear from the figure that x
–2 –1 1 O 1 2
1
x , 0 . 2
2
6. B M120606
a4
6. f ' x 5 1 x 4 3 0
1 a
a4
1 0
1 a
7. B M120601
7. x y bm
m
dy my
Taking logarithm, .
dx x
my
Equation of tangent at x, y is Y y X x
x
X Y
1
x 1 m y 1 m
m
1
Area of triangle OAB .OA .OB
2 B
1
x 1 m y 1 m
2 m
xy 1 m
2
2m
For m = 1, area is a constant. O A
8. C M120602
1
8. f ' 0
3
2
Replace x by x and then apply LH-rule.
9. AC M120604, M120608
x 1
2
ex
9. f x
1 x
2
2
x 1 x 3x 5x 1
3 2
f ' x .e x
x 1
3
2
Let g x x3 3x2 5x 1
g' x 3x2 6x 5
Discriminant < 0 so g(x) has only one real root.
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t2 2t1 t2 t1 0
t 2 2t1
Similarly, t 3 2t 2
Abscissae are in G.P. for all values of a and b.
11. BD
We have f x x2 ax2 bx3 , where a t.f t dt and b f t dt .
1 1
11.
1 1
a t a 1 t 2 bt 3 dt
1
Now,
1
2b
a ...(i)
5
f t dt a 1 t
1 1
Again, b 2
bt 3 dt
1 1
2 a 1
b …(ii)
3
4 10
From (i) and (ii), a and b .
11 11
f x is even
I 2 f x dx
0
/2
I 2.2 f x dx
0
/2
I 4 f x dx 4I1
0
/2
Now, I1 f x dx
0
I1 I1
I1 0
I0
Part – B
2 Comprehension Type (+8, –1)
1. A Q M120804
B P M120807
C P M120803
D R M120807
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1.
(A) I1
2
3
x 1 3 3
4 x x cos x dx
4 x x 1 5 x cos 5 x dx
2
3 3 3
4 x x 1 5 x cos x dx
3 3 3
2
2I1 2x 5 cos x dx
3
2
3 3
2I1 2x cos x dx 5cos x dx
2 2
Now, integrate by parts.
2
I1
2
J sgn sin x dx
10
(B)
0
5 1dx 5 1 dx 5 5 0
1 2
0 1
So, K 0
x 25 dx
51
(D) L 0
x 25 dx
51
Nr x 25 dx x x 25 dx
51 51
0 0
51 51
51 x dx 25 51 50 51
1
2 0
x 25 dx
51
Also, Dr
0
51
x dx
51
0 2
2. A QS M120507
B PT M120508
C ST M120508
D QR
2.
(A) In f x ln x 1 ln x 2 ... ln x n
1 1 1
f ' x f x ...
x 1 x 2 x n
f ' x x 2 x 3 ... x n x 1 x 3 ... x n ... x 1 x 2 ... x n 1
f ' n n 1n 2 ...3.2.1 n 1!
5040 n 1! n8
f ' x 1 1 1
(B) gx ... k
f x x 1 x 2 x n
g x is discontinuous at n points. n 9
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y
g(x)
g(x) = 5
x
O 1 2 3 n–1 n
Part – C
Integer Type (01 – 06) (+4, –1)
1. 2 M120701
1
x
1 x4 x3 t 1 x 1
1. dx dx dt C1 C1 (Put 2 x 2 t 2 )
1 x
3/2 3/2 3
4
1 2
t t 1 x 4 x
x2 x
x 1 1 2
Now, dx sin x C2
1 x4 2
1
Hence, g
2 12 k
k 12
2. 0 M120701
2
2. Put y.
x
We get I I I 0
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3. 5 M120812
1
3. Here, the area of each big triangle is and there are 2 of them.
2
y
x
(0, 0) (1, 0) (2, 0) (3, 0) (4, 0) (5, 0) (6, 0)
1
Also, the area of each small triangle is and there are (n – 1) of them.
4
n 1 1 1
So 0 f x dx 2 2 4 n 1
4. 4 M120606
4. f ' x x2 x 1 0 x R
h x f g x
h' x f ' g x g' x
ve
n1 2, n2 2
5. 9 M120612
5. f ' x 2 Graph of f x is concave y
upward on 0, .
(0, 3)
As x , f x and f ' x .
3x 2 3 4f ' x
L lim 2 (0, 2)
x f x
x 1 f x f x
6x 4f " x
lim
x f ' x f ' x
x
6
lim 3
x f " x
L 9
2
6. 2 M120606
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at 1, 2, 3,
h x f x g x has a double root at 1, 2, 3.
h x a x 1 x 2 x 3
2 2 2 Line : g(x)
3
3
32
I a x 1 x 2 x 3 dx
2 2 2
105 2
1
a2 1
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