Rit - 3

Rankers Academy JEE
FIITJEE – (JEE-Advanced)
PHYSICS, CHEMISTRY & MATHEMATICS
QP Code: 100451 RIT- III
Time Allotted: 3 Hours Maximum Marks: 198
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examination Hall befor e the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
BATCHES – C – XII
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & Part-B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Two Parts.

(i) Part-A (01-06) – Contains seven (06) multiple choice questions which have One or More correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: −2 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B)
will result in −2 marks, as a wrong option is also darkened.
(ii) Part-B (01-06) contains Six (06) Numerical based questions with single digit integer as answer, ranging
from 0 to 9 (both inclusive) and each question carries +3 marks for correct answer and -1 marks for wrong
answer.
(iii) Part-B (07-12) contains Six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals to Two decimal places (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and
each question carries +4 marks for correct answer and there will be no negative marking.
Name of the Candidate: ____________________________________________
Batch: ____________________ Date of Examination: ___________________
Enrolment Number: _______________________________________________
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
For More Material Join: @JEEAdvanced_2024

IT−2024 (RIT-3)-(PCM)
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PART – A
(Multi Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE OR MORE may be correct.
1. A block of mass m is connected to another block of mass M k

by a massless spring of spring constant k. A constant force f m M f
starts acting as shown in figure, then
(A) as observed from ground both blocks will come to
momentarily rest simultaneously
(B) as observed from their centre of mass blocks will come
to monetarily rest simultaneously
2mf
(C) maximum extension in spring will
k ( m + M)
mf
(D) maximum extension in spring will
k ( m + M)
2. Two friends P and Q (each weighing 40 kg) are sitting on a frictionless platform at some
distance d apart. P rolls a ball of mass 4 kg towards Q which Q catches. Then, Q rolls the
ball towards P and P catches it. The ball keeps on moving back and forth between P and
Q. The ball has a fixed speed 5 ms–1 on the platform. Choose the correct option(s).
10
(A) Speed of P after he catches the ball for the first time is ms–1
11
10
(B) Speed of P after he catches the ball for the first time is ms–1
9
(C) The centre of mass of the system remains stationary irrespective of the direction of
motion of the ball.
(D) P can roll the ball only for 6 times.
3. The end B of the rod AB which makes angle  with the floor is y
being pulled with a constant velocity vo as shown. The length of
A
the rod is . At the instant when  = 37o
4
(A) velocity of end A is v o downwards
3  vo
O B x
5 vo
(B) angular velocity of rod is
3
(C) angular velocity of rod is constant
(D) velocity of end A is constant
Space For Rough Work

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4 The moment of inertia of a thin equilateral triangular A 3
plate ABC, of uniform thickness about an axis
2
passing through centre of mass and perpendicular to
its plane
(A) I1 + I2 4
(B) I3 + I4
(C) I1 + I4 C
B
1
(D) I1 + I2 + I3 + I4 
2 1
5. A horizontal disc rotates freely about a vertical axis through its centre. A ring, having the
same mass and radius as the disc, is now gently placed on the disc in such a way that
their axes coincide. After some time, both rotate with a common angular velocity
(A) some friction exists between the disc and the ring.
(B) the angular momentum of the disc plus ring is conserved.
2
(C) the final common angular velocity is rd of the initial angular velocity of the disc.
3
2
(D) rd of the initial kinetic energy changes to heat.
3
6. A uniform rod of mass m and length l is placed in gravity free

A
space and linear impulse J is given to the rod at a distance
x = l / 4 from centre and perpendicular to the rod. Point A is at a x
distance l / 3 from centre as shown in the figure. Then J
J
(A) Speed of centre of rod is (B) Speed of point A is zero
m
J 5 J
(C) Speed of upper end of rod is (D) Speed of lower end of rod is
2m 2m
PART – B
Integer Answer Type
This section contains 6 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9.
1. A disc of radius r and mass m moving on perfectly

15 v
smooth surface at a speed v= m/s undergoes an O
17
elastic collision with an identical stationary disc of mass d
2m. the magnitude of velocity (in m/s) of the first disc O’
8r
after the collision will be( given d= )
5

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2. A long, thin carpet is laid on a floor. One end of the carpet is
bent back and then pulled backwards with constant unit v = 1m/s
velocity. The speed of centre of mass of the moving part, just
above the part of the carpet which is still at rest on the floor, is
u
m /s , then find the value of ‘u’ is
4
3. Two blocks of masses m1 = 2 kg and m2 = 5 kg are

moving in the same direction along a frictionless
surface with speeds 10 m/s and 3 m/s respectively,
m2 being ahead of m1. An ideal spring with k = 1120
N/m is attached to the back side of m2. The maximum
compression of the spring when the blocks collide is
 1
 n  metre .
 
4. In situation shown in figure a small body of mass ‘m’ = 1kg

placed over a large mass M = 3 kg, whose surface is
horizontal near the smaller mass and gradually curves to h
become vertical. The smaller mass is pushed on the larger
one at a speed u = 10 m/s towards right. Assume that all the
surfaces are frictionless. The maximum speed of larger mass m
in m/s will be
5. A uniform cube of side  and mass m rests on a rough F

horizontal table. A horizontal force F is applied normal to one of
the faces at a point that is directly above the centre of the face
at a height 3/4 above the base. Assuming that the cube may
tip about an edge without slipping, if the angular acceleration of
3g
the cube when F is equal to mg is then value of ‘N’ is
NL
A
6. Three identical rods are joined and hinged at A as
shown. If the angle made by the rod AB with the D
vertical in equilibrium is  then the value of 10 sin B
will be
C

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PART – B
(Numerical based)
This section contains 6 questions, numerical based questions, (answer of which maybe positive
or negative numbers or decimals to Two decimal places).
7. A small ball is projected from point a on the floor towards a

vertical wall as shown in the figure. It hits the wall when its
velocity is horizontal. Ball reaches point A after one bounce
on the floor. If the coefficient of restitution is the same for
the collisions, find its value. A
8. Two equal discs initially at rest are in contact on a

smooth horizontal table. A third disc of same mass but of
double radius strikes them symmetrically and comes to
rest after impact. the coefficient of restitution is
m 2m
9. Two particles one of mass m and the other of mass 2m are projected
horizontally towards each other from the same level above the 10m/s 5m/s
ground with velocities 10 m/s and 5 m/s respectively. They collide in
air and stick to each other. The distance from A where the combined 60m
mass finally land is B
A
10. A block of mass m is attached to a pulley disc of m V

equal mass m and radius r by means of a slack m
string as shown. The pulley is hinged about its
centre on a horizontal table and the block is
projected with an initial velocity of 5 m/s. Its velocity
when the string becomes taut is ‘x’ m/s. Find the
value of x.
11. A tangential force F acts at the top of a thin spherical shell of mass m and radius R. If it
xF
rolls without slipping then acceleration is given by a = . What is the value of x
m
12. A uniform disc of mass m and radius R is rolling without

slipping up a rough inclined plane which makes an angle 300
with the horizontal. If the coefficient of static: and kinetic
friction are each equal to  and the only force acting on the
disc are gravitational and frictional force then if frictional force
mg 
acting on it is up the incline, find x
x

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PART – A
1. The rate of a complex reaction is given as follows:

−dC kC
Rate = = 1
dt 1 + k 2C
Where C is concentration of the reactant
k1 and k2 = Rate constants of the simple reactions with moderate values
Choose correct statement(s) for the reaction
(A) If the concentration is very high, the half-life of the reaction will be directly proportional
to concentration of reactant.
(B) If the concentration is very high, the reaction will follow first order kinetics.
(C) The rate of the reaction increases by increasing temperature.
(D) The rate constant of the reaction increases by increasing concentration of reactant.
2. Which of the following reversible reaction(s) proceed(s) towards forward direction by

increasing the volume of the reaction container?
(A) N2 ( g) + 3H2 ( g) 2NH3 ( g) (B) 2NH3 ( g) N2 ( g) + 3H2 ( g)
(C) Ba (N3 )2 ( s ) Ba ( s ) + 3N2 ( g ) (D) H2 ( g) + I2 ( g) 2HI ( g)
3.
Energy
C+D
A+B
Progress of reaction
Which of the following statement(s) is/are correct for the reaction
A ( g) + B ( g) ⎯⎯
→ C ( g) + D ( g) . Which energy profile is given above?
(A) It is an exothermic reaction
(B) The reaction proceeds through radical ( A • and B• ) intermediates.
(C) The reaction can be accelerated by using a catalyst
(D) The formation of A and B from C and D is accompanied with evolution of heat energy

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4.
o
45
D
d

D = Initial vapour density of reactant
d = Vapour density of equilibrium mixture
 = Degree of dissociation
Above plot is given for the reaction
1 3
(A) NH3 ( g) N2 ( g) + H2 ( g)
2 2
1
(B) SO3 ( g) SO2 ( g) + O2 ( g)
2
1
(C) N2O5 ( g) 2NO2 ( g) + O2 ( g)
2
(D) (NH4 )2 CO3 ( s ) 2NH3 ( g) + CO2 ( g) + H2O ( )
5. A ( g) + 3B ( g) + 4C ( g) ⎯⎯ →Product
The experimental data for the above reaction is given as follows:
Expt. [A0] in M [B0] in M [C0] in M Initial rate in mol L–1s–1
1. 0.1 0.1 0.1 4  10–4
2. 0.2 0.2 0.1 8  10–4
3. 0.2 0.2 0.2 32  10–4
4. 0.4 0.2 0.2 64  10–4
5. 0.4 0.4 0.4 256  10–4
Which of the following statement(s) is/are correct for the reaction?
(A) The rate expression is: Rate = k[A]0[B][C]2
(B) The overall order of the reaction is 3.
(C) The rate constant(k) is 0.4 mol–2 L2 s–1
(D) The rate of reaction increases by 8 times by reducing the volume of reaction vessel to
half of it’s original value
6. Be ( OH)2 ( aq) Be2+ ( aq ) + 2 OH− ( aq )

Above ionization reaction will proceed towards forward direction by adding
(A) NaOH (B) NH4Cl
(C) KH (D) HCl

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PART – B
Integer Answer Type
1. NH3 ( g) + HCl ( g) NH4Cl ( s )

NH3 and HCl are introduced in a one litre vessel at 80oC and 12 atm in the molar ratio of
1:2 respectively. What will be the equilibrium pressure (in atm) of the system if Kp is
1
atm–2?
12
2. What is the minimum pH required to cause the precipitation of ZnS in a solution which
contains 0.01 M ZnCl2, saturated with 0.1 M H2S. Given Ksp( ZnS) = 10−21 , Ka1(H S) = 10−5 ,
2
−15
Ka2(H S) = 10 at 25 C. o
2
3. The pH of 10–2 M KH2PO4 is [Given Ka1 = 10−5 ,Ka2 = 10−9 and Ka3 = 10−15 at 25oC]
4. A solution contains 0.1 M Cl– and 10–4 M CrO24− . If solid AgNO3 is gradually added to this
solution, the conc. of Cl– when Ag2CrO4 begins to precipitate is [A]. What is –log[A]?
K = 10−10 ,K sp( Ag CrO ) = 10 −12 
 sp( AgCl) 2 4 
5. How many of the following aqueous solution can act as buffer when compounds are mixed
in same concentration & same volume.
(I) Na2HPO4 + NaH2PO4 (II) H2CO3 + KHCO3
(III) H3PO3 + Na2HPO3 (IV) H2S2O8 + CaS2O8
(V) Na2C2O4 + K2C2O4 (VI) CH3COOH + NH4OH
(VII) NaNO3 + HNO3 (VIII) PhCOOH + KOH
6. A weak acid HA after treatment with 12 mL of 0.1 M NaOH has pH = 5. At the end point,
the volume of same base required is 13.2 mL. What is the pKa of HA.

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PART – B
(Numerical based)
7. The solubility product of beryllium hydroxide Be(OH)2 is 4  10–6. How many gram of
Be(OH)2 can be dissolved in water to form 100 mL of saturated solution?
[At. mass of Be = 9]
8. 10 mL of 0.2 M HCl is added to 250 mL of a buffer solution with pH = 6.34. The pH of the
solution becomes 6.32. The buffer capacity of the solution is
9. COCl2 ( g) CO ( g) + Cl2 ( g)
Above reaction contains equal number of moles of COCl2, CO and Cl2 gases at
equilibrium. What is KP in atm unit if the equilibrium state is attained at 1.2 atm and 120 K?
10. What is the pH of mixture of 100 mL 0.1 M CH3COOH and 25 mL 0.1 M Ba(OH)2. (Ka of
CH3COOH = 1.8  105 and pK a = 4.74)
11. Reaction (I) A → Products, follows first-order kinetics and Reaction (II) B → products
follows second-order kinetics. If their half-lives are equal, and initial concentration of A and
B are same. What is ratio of rate of reaction (I) to rate of reaction (II) after the lapse of one
half-life?
12. 2 A ( g) + B ( g) C ( g)
Above reaction attains equilibrium in a one litre vessel. The concentrations of A, B and C
gases at equilibrium are 0.2, 0.5 and 0.4 mol L–1 respectively. How many moles of ‘C’ can
be removed from the system so that the concentration of ‘B’ becomes 0.45 M?

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MAAT
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ATTIIC
CSS
PART – A
1. Let a and b be two distinct roots of the equation x3 + 3x 2 − 1 = 0 . The equation which does
not have (a, b) as its root is equal to:
(A) x 3 − 3x − 1 = 0 (B) x3 − 3x 2 + 1 = 0
(C) x 3 + x 2 − 3x + 1 = 0 (D) x 3 + x 2 + 3x − 1 = 0
2. Let a, b, c be distinct positive numbers such that each of the quadratics

ax2 + bx + c, bx2 + cx + a and cx2 + ax + b is non – negative for all x  R . If
a2 + b2 + c 2
R= , then select the option which do not gives correct interval for R
ab + bc + ca
(A) 1  R  4 (B) 1  R  4
(C) 1  R  4 (D) 1  R  4
n n n n
 ai,nb =  bi, then  ai bi +  ( ai − a ) =

2
3. If bi = 1 − ai , na =
i=1 i=1 i=1 i=1
(A) ( (n 2
) (
− n + 1 − n2 + n + 1 )) ab
2
(B) –nab
(C) nab (D) ( (n 2

) (
+ n + 1 − n2 − n + 1 )) ab
2
4. If a, b, c, d are distinct numbers in G.P., then:

(A) a2 + d2  b2 + c 2
(B) ad + bc  2ab
(C) b2 + d2  a2 + c 2
( )
(D) b2 + c 2 x2 − 2 (bc + cd) x + c 2 + d2 = 0 has equal roots

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1 1
5. If  and  are the roots of the equation x2 + px + 2 = 0 and and are the roots of the
 
 1 1  1  1
equation 2x2 + 2qx + 1 = 0, then   −    −    +    +  is not equal to:
    
(A)
9
4
(
9 − p2 ) (B)
9
4
9 + q2( )
(C)
9
4
(
9 − q2 ) (D)
9
4
(
9 + p2 )
6. Let a, b, c be in arithmetic progression. Let the centroid of the triangle with vertices (a, c),
 10 7 
(2,b) and (a, b) be  ,  . If ,  are the roots of the equation ax2 + bx + 1= 0, then the
 3 3
value of  +  −  is not equal to
2 2
69 69
(A) − (B)
256 256
27 71
(C) (D) −
256 256
PART – B
Integer Answer Type
1. The value of 4+2 3 − 4 − 2 3 is
2. If nine arithmetic means and nine harmonic means are inserted between 2 and 3
6
alternatively, then the value of A + (where A is any of the A.M.’s and H the
H
corresponding H.M.) is
3. The product of all positive real values of x satisfying the equation x

(16(log5 x ) − 68log5 x
3
) = 5−16 is
___
4. If the sum of the first 3n terms is equal to the next n terms of an A.P. whose common
difference is non – zero, then the reciprocal of the ratio of the sum of the first 2n terms to
the next 2n terms is _______

IT−2024 (RIT-3)-(PCM)
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 1 1 1 
5. The value of 6 + log3  4− 4− ....  is
 
23 2 3 2 3 2 
6. Let (a) and (b) be the roots of the equation

( 3 1 +a − 1) x2 + ( 1 + a − 1) x + ( 6 1 + a − 1) = 0 where a>-1. The lima→0  ( a ) and
lima→0+  ( a ) are p and q respectively, then value of pq − (p + q) =
PART – B
(Numerical based)
7. In the sequence 1, 2, 2, 3, 3, 3, 4, 4, 4, 4,……, where n consecutive terms have the value

n, the 150th term is:
8. If (1) (2010) + (2) (2009) + (3) (2008) + ……..+ (2010) (1) = (335) (2011) (  ) , then the
value of  must be
9. 7 5...5 7 denote the (r + 2) digit number where the first and the last digits are 7 and the
98
remaining r digits are 5. Consider the sum S = 77 + 757 + 7557 + ... + 7 5...5 7 . If
99
7 5...5 7 + m
S= , where m and n are natural numbers less than 3000, then the value of
n
m + n is
10. If a1,a2,a3 ,......,a20 are A.Ms. between 13 and 67, then the maximum value of a1a2a3 ,....a20
is (P ) where P + Q equals to
Q
11. Consider the quadratic equation ( c − 5) x2 − 2cx + (c − 4 ) = 0,c  5. Let S be the set of all
integral values of c for which one root of the equation lies in the interval (0, 2) and its other
root lies in the interval (2, 3). Then the number of elements in S is:
The quadratic polynomial P ( x ) = ax + bx + c has two different zeroes including –2. The
2
12.
quadratic polynomial Q ( x ) = ax + cx + b has two different zeroes including 3. If  and
2

 be the other zeroes of P(x) and Q (x) respectively, then find the value of .


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BATCHES – C-XII
RIT – III
Code : 100451
ANSWERS
S
SEEC
CTTIIO
ONN--1
1 :: P
PHHY
YSSIIC
CSS
PART – A
1. BC 2. ACD 3. AB 4. ABCD
5. ABD 6. ABCD
PART – B
1. 3 2. 3 3. 4 4. 5
5. 8 6. 6 7. 0.50 8. 0.56
9. 40.00 10. 3.33 11. 1.20 12. 6.00
S
SEEC
CTTIIO
ONN –– 2
2 :: C
CHHE
EMMIIS
STTR
RYY
PART – A
1. AC 2. BC 3. CD 4. A
5. BCD 6. BD
PART – B
1. 8 2. 1 3. 7 4. 6
5. 4 6. 4 7. 0.043 (range: 0.04 to 0.05)
8. 0.4 9. 0.4 10. 4.74(range 4.70 to 4.80)
11. 1.38(range 1.38 to 1.39) 12. 0.25 (range 0.23 to 0.27)
S
SEEC
CTTIIO
ONN –– 3
3 :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
1. BCD 2. ABC 3. CD 4. AD
5. BCD 6. ABC
PART – B
1. 2 2. 5 3. 1 4. 5
5. 4 6. 2 7. 17 8. 2012
9. 1219 10. 60 11. 11 12. 11

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Rankers Academy JEE

QP Code: 100451 RIT- III

Time Allotted: 3 Hours Maximum Marks: 198

B. Filling of OMR Sheet

C. Marking Scheme For All Two Parts.

Name of the Candidate: ____________________________________________

Batch: ____________________ Date of Examination: ___________________

Enrolment Number: _______________________________________________

For More Material Join: @JEEAdvanced_2024

1. A block of mass m is connected to another block of mass M k

For More Material Join: @JEEAdvanced_2024

6. A uniform rod of mass m and length l is placed in gravity free

1. A disc of radius r and mass m moving on perfectly

For More Material Join: @JEEAdvanced_2024

3. Two blocks of masses m1 = 2 kg and m2 = 5 kg are

4. In situation shown in figure a small body of mass ‘m’ = 1kg

5. A uniform cube of side  and mass m rests on a rough F

Space For Rough Work

For More Material Join: @JEEAdvanced_2024

7. A small ball is projected from point a on the floor towards a

8. Two equal discs initially at rest are in contact on a

10. A block of mass m is attached to a pulley disc of m V

12. A uniform disc of mass m and radius R is rolling without

For More Material Join: @JEEAdvanced_2024

1. The rate of a complex reaction is given as follows:

2. Which of the following reversible reaction(s) proceed(s) towards forward direction by

For More Material Join: @JEEAdvanced_2024

6. Be ( OH)2 ( aq) Be2+ ( aq ) + 2 OH− ( aq )

For More Material Join: @JEEAdvanced_2024

1. NH3 ( g) + HCl ( g) NH4Cl ( s )

Space For Rough Work

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Space For Rough Work

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2. Let a, b, c be distinct positive numbers such that each of the quadratics

 ai,nb =  bi, then  ai bi +  ( ai − a ) =

(C) nab (D) ( (n 2

4. If a, b, c, d are distinct numbers in G.P., then:

Space For Rough Work

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1. The value of 4+2 3 − 4 − 2 3 is

3. The product of all positive real values of x satisfying the equation x

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6. Let (a) and (b) be the roots of the equation

7. In the sequence 1, 2, 2, 3, 3, 3, 4, 4, 4, 4,……, where n consecutive terms have the value

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