d

FIITJEE – JEE (Main)

Physics, Chemistry & Mathematics
BATCHES –Two Yr CRP(2224)-ABC-lot-PT-5

QP Code:

Time Allotted: 3 Hours Maximum Marks: 300

▪ Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.

Important Instructions
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log
tables, slide rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card
inside the examination hall / room.

B. Filling of OMR Sheet:

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.

C. Marking Scheme for All Two Parts:

(i) Part-A (01-20) – Contains twenty (20) multiple choice objective questions which have four (4) options each
and only one correct option. Each question carries +4 marks which will be awarded for every correct
answer and -1 mark will be deducted for every incorrect answer.

(ii) Part-B (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or negative
numbers or decimals and round off the value to Two decimal places. (e.g., 6.25, 7.00, -0.33, -.30, 30.27, -
127.30) and each question carries +4 marks for correct answer and there will be no negative marking.

Name of the Candidate :_______________________________________________

Batch :_______________________ Date of Examination :____________________

Enrolment Number :___________________________________________________

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
PT-V-(Mains)
2

Physics
PART – A
Straight Objective Type
This part contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.

1. The circuit shown below contains two ideal diodes, each D1 150 
with a forward resistance of 50  . If the battery voltage is
6V, the current through the 100  resistance (in ampere) 75 
is
(A) 0.27 (B) 0.020 D2
100 
(C) 0.030 (D) 0.036

6V

2. The network shown in Figure is part of a complete I

circuit. If at a certain instant the current (I) is 5A, and A 35 mH B
5 10 V
is decreasing at a rate of 103 A/s, then VB – VA =
(A) 10 V (B) −10 V
(C) Zero (D) −13 V

E1 R1
3. In the circuit shown here, E1 = E2 = E3 = 2 V and R1 = R2 = 4 . The
current flowing between points A and B through battery E2 is E2
A• •B
(A) zero (B) 2 A from a to B
(C) 2 A from B to A (D) none of the above R2
E3

4. In a radioactive reaction an unstable nucleus A

dis-integrates into a stable nucleus B. But A is generated at a
constant rate of q nucleus per second. Then at steady state
number of nucleus of A will be –1 
q (sec ) A B
q (Parent (Daughter
(A) q (B) Nucleus) Nucleus)


(C) q –  (D)
q

5. Imagine a Young’s double slit interference experiment performed with wave associated with
fast moving electrons produced from an electron gun. The distance between successive
maxima will decrease maximum if
(A) the accelerating potential in the electron gun is decreased.
(B) the accelerating potential is increased and the distance of screen from slit is decreased.
(C) the distance of the screen fro the slit is increased.
(D) the distance between the slits is decreased.

D1
5
6. In the figure shown below, chose the correct answer.
(A) Voltage across D2 is 20 Volt.
(B) Voltage across D1 is 20 Volt. D2
(C) Current through diode D1 is 4A. + −
(D) Current through diode D1 is 0 A.
20V

______________________________________________________________________________________________________________________

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
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PT-V-(Mains)
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7. A hydrogen atom and a Li + + ions are both in the second excited state. If  H and  Li are their
respective electronic angular momenta, and E H and E Li their respective energies, then
(A)  H   Li and EH  ELi (B)  H =  Li and EH  ELi
(C)  H =  Li and EH  ELi (D)  H   Li and EH  ELi

8. A point object O is placed at a distance of 0.3 m from a convex L1

2  0.05cm
O• •
lens (focal length 0.2 m) cut into two halves each of which is
L2
displaced by 0.0005 m as shown in figure. Find the distance
between the images (in mm) 30cm
f=20cm
(A) 1 (B) 2
(C) 3 (D) 4

B
9. The figure shows a semi-circular conducting ring of radius a, P
which is rotated with constant angular velocity  about an axis
passing through O and parallel to field B as shown. Identify the
correct value of potential difference O Q


1
(A) VP − VQ = Ba 2
2
(B) VQ − VO = 2Ba 2
1
(C) VP − VO = Ba 2
4
a 2 B
(D) The maximum value of VP − VO =
2

10. The combination of gates shown in given figure yields: A

(A) NAND gate
(B) OR gate X
(C) NOT gate B
(D) XOR gate

11. The error in the measurement of the radius of a sphere is 1%. Then error in the measurement
of volume is
(A) 1% (B) 5%
(C) 3% (D) 8%s

12. There is a uniform time varying magnetic field in a

x x B = Bot
circular region as shown in the figure. Find out the
potential difference across 2 point along an elliptical path x x x
as shown in figure. x x x x
R2 R2 A
x x x x
B
(A) Bo (B) Bo
2 2 x
Rx
R/2 x
Elliptical
R2 R2 x x
path
(C) Bo (D) Bo
4 5

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Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
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PT-V-(Mains)
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13. A ray incident at an angle 53° on prism emerges at an angle

37°
37° as shown in the figure. If the angle of incidence is made 53°

50°, which of the following is a possible value of angle of

emergence
(A) 35° (B) 42°
(C) 40° (D) 38°

14. A parallel beam of light 500 nm is incident at an angle 30°

with the normal to the slit plane in a Young’s Double Slit
Experiment. The intensity due to each slit is Io. Point O is A
equidistant from S1 and S2. The distance between slits is O
1 mm then 30° D = 3m

d
B
(A) the intensity at O is 4Io.
(B) the intensity at O is zero.
(C) the intensity at a point on the screen 4 mm from O is 4Io. Screen
(D) the intensity at a point on the screen 4 mm from O is zero.

15. Photoelectric effect experiments are performed using three different metal plates p, q and r
having work functions p = 2.0 eV, q = 2.5 eV and r = 3.0 eV, respectively. A light beam
containing wavelengths of 550 nm, 450 nm and 350 nm with equal intensities illuminates
each of the plates. The correct I-V graph for the experiment is
(A) I P (B) I

r
p q

r
V V

(C) I r (D) I

q
p

r q

p
V V

16. The given figure shows a YDSE apparatus are

2
incident on slits S1andS2 ( S1S2 = mm ) at an
3
angle 30o with the horizontal. The medium on
left side of the slits in water (  w = 4 / 3 ) . To S1

0
30 P
obtain the central maxima at point P, a glass
slab ( )
g = 3 / 2, inside water is introduced in
S2
front of slit S1. The thickness of the glass slab D
required for this purpose is
(A) 2mm (B) 4/3 mm
(C) 4 mm (D) 8/3 mm

______________________________________________________________________________________________________________________

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
PT-V-(Mains)
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17. A medium bounded by the planes x = 0, x = a, y = b, y = –b, z = c and z = 0 has refractive

index m( x, z ) = Az3 - Bx + 2 . A ray of light travelling along positive z-axis enters the
æ1 ö
medium at point P çç , 0 ÷
÷, then the optical path introduced by the medium (when the light ray
÷
èB ø
emerges out) will be
Ac 4 Ba2
(A) (B) 4Ac 4 (C) 2c (D)
4 2

18. Figure shows the variation of photocurrent with anode

Photo current
potential for a photosensitive surface for three
different radiations. Let Ia,Ib and Ic be the intensities
and fa,fb and fc be the frequencies for the curves a, b
and c respectively. Which of the following facts is
correct? c
a
(A) fa = fb and Ia  lb b

(B) fa = fc and Ia = lc
(C) fa = fb and Ia = lb
Anode potential
(D) fb = fc and Ib = lc

19. An equiconvex lens made up of material of refractive index 1.5 has focal length of 10 cm.
when placed in air, as shown in the figure. One side of medium is replaced by a medium of
refractive index 1.3. If x, y are the image distance when object is placed at a distance of
20 cm from pole in medium with refractive index 1 and refractive index 1.3 respectively, then
fair=10cm fair=10cm

=1 =1
=1.3 =1.3
O l l O

20cm x y 20cm

=1.5 =1.5
(A) x > 1.3 y (B) x < 1.3 y
(C) x = 1.3 y (D) cannot determine

20. The curve of angle of incidence versus angle of deviation

shown has been plotted for prism. The value of refractive
index of the prism used is:
(A) 3 (B) 2
3 2
(C) (D)
2 3

______________________________________________________________________________________________________________________

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
PT-V-(Mains)
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PART-B
Numerical Type

1. If the transistor is figure, have high value of  and a

VBE of 0.65 volt, the current I (mA), flowing through the
2K  resistance will be

2. A time verifying magnetic field B = krt (where k is a constant r is

the radial distance from ‘O’) is existing in a circular region of
radius ‘R’ as shown, If induced electric field at r = R/2 is E1 and
at r = 2R is E2 then the ratio E2/E1 is

3. A free particle mass ‘m’ is confined to a region of length L.

The de-Broglie wave associated with the particle is
sinusoidal in nature as given in figure. The energy of the
n2h
particle is ,n = ?
8 mL2

4. An open organ pipe containing air resonates in fundamental mode due to a tuning fork. The
measured value of length l (in cm) of the pipe and radius r (in cm) of the pipe
are 1 = 94  0.1, r = 5  0.05 . The velocity of the sound in air is accurately known. The
maximum percentage error in the measurement of the frequency of that tuning fork by this
experiment, will be?

3
2
4 3 4
5. The lens combination having refractive indices & 3
O
3 2
as shown in the figure, is silvered. The velocity of vo = −5 ˆi

image is n ˆi . The value of ‘n’ is R = 20 cm

40 cm

______________________________________________________________________________________________________________________

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
PT-V-(Mains)
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Chemistry
PART – A
Straight Objective Type
This part contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.

1. How many total number of lattice point(s) is/are present in F.C.C unit cell?
(A) 6 (B) 8
(C) 14 (D) 15

2. 2 moles of a non-volatile solute was dissolved in 8 moles of a solvent. If Po is the vapour

pressure of the pure solvent and PS is the vapour pressure of the solution, then the correct
relationship is
8 Po 5
(A) Po − PS = (B) =
10 PS 4
4 10
(C) Po + PS = (D) Po  PS =
5 8

3. Which of the following transition element cannot form complex by using the 3d orbital?
(A) Co (B) Mn
(C) Zn (D) Fe

4. Which of the following electrolyte of identical molarity, has the highest value of molar
conductance?
(A) NaCl (B) HCl
(C) KCl (D) CH3COOH

5. Which of the following compound on heating produces the lightest nitrogen containing gas?
(A) NH4NO3 (B) NH4NO2
(C) NH4Cl (D) (NH4)2Cr2O7

6. Which of the following is a temporary bleaching agent?

(A) Cl2 (B) O3
(C) H2O2 (D) SO2

7. Which of the following compound can separate a mixture containing HF and HCl?
(A) NaCl (B) NaF
(C) NaOH (D) Na2CO3

8. Which of the following metallurgical process is not used in the extraction of Zn from ZnS?
(A) Roasting (B) Calcination
(C) Smelting (D) Distillation

______________________________________________________________________________________________________________________

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PT-V-(Mains)
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9. Which of the following is the structure of an antioxidant?

Cl OH HO Cl
CO
(A) NH (B) S
SO 2
Cl Cl
OH
NHCOCHCl 2
(H3C) 3C C(CH 3)3
(C) O2N CH - CH - CH 2OH (D)
OH
CH3

10. Which of the following compound will not produce any gas upon treatment with dil. HCl?
(A) Na2CO3 (B) Na2S
(C) Na2SO4 (D Na2SO3

11. If all the ions from the corners of the NaCl unit cell are removed, how much resultant charge
will the defected unit cell carry?
(A) One unit positive charge (B) One unit negative charge
(C) Two unit positive charge (D) Two unit negative charge

12. What will be the electrode potential of the following hydrogen electrode?
Pt | H2(1 atm) | HCl(pH = 4)
(A) 0.014 V (B) -0.2364 V
(C) -0.014 V (D) 0.2364 V

13. Which of the following complex of iron is most paramagnetic?

(A) K4[Fe(CN)6] (B) K3[Fe(CN)6]
(C) Na4[FeF6] (D) Na3[FeF6]

14. Which of the following solution does not form metal sulphide, when treated with H2S gas?
(A) FeCl3 (B) CdCl2
(C) ZnCl2 (D) BiCl3

15. Which of the following can absorb the highest amount of oxygen?
(A) NO (B) N2O
(C) N2O3 (D) N2O5

16. In which of the following acid, sulphur shows the highest oxidation state?
(A) H2SO4 (B) H2S2O7
(C) H2S2O8 (D) All are correct

17. The white precipitate, Al(OH)3 is not soluble in

(A) NaOH (B) NH4OH
(C) HCl (D) H2SO4

______________________________________________________________________________________________________________________

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PT-V-(Mains)
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0.4 M 0.3 M
18. NaCl FeCl3

In the above aqueous solutions, which are separated by a semipermeable membrane, the
flow of which species takes place through the membrane?
[Assume complete dissociation of electrolytes]
(A) Na+ (B) Fe3+
(C) H2O from NaCl side to FeCl3 side (D) H2O from FeCl3 side to NaCl side

19. Which of the following is the strongest pi-acid ligand (forms back bonding with metals or
metal ions)?
(A) CO (B) CN–
(C) NO+ (D) Ph3P

20. Which of the following electrolyte (fused salt) needs the highest amount of electricity in order
to deposit one mole of metal at the cathode?
(A) AlCl3 (B) AgCl
(C) CaCl2 (D) NaCl

PART-B
Numerical Type

Cr2 ( SO4 )3 ⎯⎯⎯⎯ → (P ) ⎯⎯⎯ (Q)

HO
1. NaOH 2 2
→
Yellow solution
If the oxidation number of chromium in Q is +x, x is

2 What is the sum of the number of fluorine and iodine atoms present in the largest compound
formed by them?

3. The mole ratio of the two gases NO2 and O2 obtained on heating copper nitrate is x : y. The

value of
( x + y ) is
10

4. The depression in freezing point of water becomes 2.232oC when an aqueous solution of
CaCl2( =1) is cooled. What is the molality of the solution?
[Kf of H2O = 1.86 K Kg mol–1]

5. Consider the carbonyl Fe2(CO)9

If x = Number of bridging CO groups
y = Number of -bonds present in ligands

z = Number of Fe – O bonds, then the sum

( x + y + z) is
10

______________________________________________________________________________________________________________________

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
PT-V-(Mains)
10

M a th e m a ti c s
PART – A
Straight Objective Type
This part contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.

1. The probabilities of two events are 0.25 and 0.50. The total probability of both happening
together is 0.14. Which of the following is the probability of none of the events happening?
(A) 0.39 (B) 0.25
(C) 0.11 (D) none of these

2. The equation of a plane passing through (1, 2, -3), (0, 0, 0) and perpendicular to the plane 3x
-5 y +2z = 11, is
5
(A) 3x + y + z = 0 (B) 4x + y + 2z = 0
3
z
(C) 3x − y + = 0 (D) x + y + z = 0
3
Thus plane is x + y + z = 0

3. The image of the point ( −1, 3, 4) in the plane x − 2y = 0 is

 −17 −19 
(A)  , ,4 (B) (15, 11, 4)
 3 3 
 −17 −19   9 −13 
(C)  , ,1 (D)  , ,4
 3 3  5 5 

4. A fair coin is tossed ‘n’ times. If the probability of getting 7 heads is equal to probability of
getting 9 heads, then n =
(A) 12 (B) 14
(C) 16 (D) 20

x +1 y −1 z − 2
5. The angle between the line = = and the plane 2x + y − 3z + 4 = 0 , is
3 2 4
 k 
sin−1  −  , then k is
 100k + 6 
(A) 7 (B) 6
(C) 5 (D) 4

6. The locus represented by xy + yz = 0 is

(A) A pair of perpendicular lines (B) A pair of parallel lines
(C) A pair of parallel planes (D) A pair of perpendicular planes

 dy 
7. If y = y ( x ) is the solution of the differential equation, e y  − 1 = e x such that y ( 0 ) = 0 ,
 dx 
then y (1) is equal to:
(A) 1 + loge 2 (B) 2e
(C) loge 2 (D) 2 + loge 2

______________________________________________________________________________________________________________________

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
PT-V-(Mains)
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dy
8. The solutions of the differential equation 2x − y = 3 represents the curve, is
dx
(A) Straight Line (B) Circles
(C) Parabola (D) Ellipses

1 1 1 1
9. Four persons can hit a target correctly with probabilities , , and respectively. If all hit at
2 3 4 8
the target independently, then the probability that the target would be hit, is:
25 25
(A) (B)
32 192
7 1
(C) (D)
32 192

10. The area bounded by the x – axis, part of the curve y = 1 + x −2 and the ordinates x = 1 and
3+ p
x = 2 is divided into equal parts by the ordinate at x = a such that a = , then the value
8
of p is
(A) 70 (B) 71
(C) 72 (D) 73

11. Find the area common to the parabola 5 x 2 − y = 0 and 2 x 2 − y + 9 = 0 .

(A) 12 sq. units (B) 12 3 sq. units
(C) 10 3 sq. units (D) None of these

12. The area (in sq. units) of the region A = {(x, y): x2  y  x + 2} is:
31 13
(A) (B)
6 6
9 10
(C) (D)
2 3

 0 2x 2x 
13. The total number of matrices A = 2y y − y  ; ( x, y  R, x  y ) for which A T A = 3I3
 1 −1 1 
(A) 6 (B) 2
(C) 3 (D) 4

14. The equation of a plane containing the line of intersection of the planes 2x − y − 4 = 0 and
y + 2z − 4 = 0 and passing through the point (1, 1, 0) is:
(A) x + 3y + z = 4 (B) 2x − z = 2
(C) x − 3y − 2z = −2 (D) x − y − z = 0

15. Let y = y ( x ) be the solution curve of the differential equation, y 2 − x ( ) dy

dx
= 1, satisfying

y ( 0 ) = 1. This curve intersects the x – axis at a point whose abscissa is:

(A) 2 + e (B) –e
(C) 2 (D) 2 – e

______________________________________________________________________________________________________________________

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
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Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
PT-V-(Mains)
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16. Let y = y ( x ) be a function of x satisfying y 1 − x 2 = k − x 1 − y 2 where k is a constant and

 1 1 dy 1
y   = − . Then at x = , is equal to:
2 4 dx 2
5 5
(A) − (B) −
4 2
2 5
(C) (D)
5 2

17. The sum of the real roots of the equation

x −6 −1
2 −3x x − 3 = 0 is equal to
−3 2x x+2
(A) 7 (B) 6
(C) 3 (D) 0

18. The distance of the point having position vector − ˆi + 2ˆj + 6kˆ from the straight line passing
through the point (2, 3, -4) and parallel to the vector 6iˆ + 3ˆj − 4kˆ is
(A) 7 (B) 6
(C) 3 (D) 2

 5 2 1 
19. If B =  0 2 1  is the inverse of a 3  3 matrix A, then the sum of all values of  for which
 3 −1
det (A) + 1 = 0, is :
(A) 7 (B) 6
(C) 3 (D) 1

p
20. Three dice are rolled. If the probability of getting different numbers on the three dice is ,
q
where p and q are co – prime, then q – p is equal to
(A) 4 (B) 3
(C) 1 (D) 2

PART-B
Numerical Type

1. The SQUARE of magnitude of the projection of the vector 2iˆ + 3 ˆj + kˆ on the vector
perpendicular to the plane containing the vectors ˆi + ˆj + kˆ and ˆi + 2ˆj + 3kˆ , is:

2. Letters of the word “MOTIVATION” are arranged randomly. If the probability of these such
1
words contains the word “IIT” always is ‘p’, then is equal to
p

3. Centorid of the tetrahedron OABC, where A  ( a,2,3 ) ,B = (1,b,2 ) ,C  ( 2,1,c ) and O is the
origin is (1, 2, 3) . The value of a2 + b2 + c 2 is equal to

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PT-V-(Mains)
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4. Let F = 2i + 2j + 5k and A = (1,2,5 ) , B = ( −1, − 2, − 3 ) and BA  F = 4i + 6j + 2k, then the

value of  is

5 The curve y = x2 –7x +10 intersect the x-axis at the points A and B then the area bounded
by the curve and the line AB is

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PT-V-(Mains)
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ANSWER KEY:- JEE (Main)

PHYSICS CHEMISTRY MATHEMATICS
Part-A Part-A Part-A
Ans1. B Ans1. C Ans1. A
Ans2. C Ans2. B Ans2. D
Ans3. A Ans3. C Ans3. D
Ans4. B Ans4. B Ans4. C
Ans5. B Ans5. C Ans5. D
Ans6. C Ans6. D Ans6. D
Ans7. B Ans7. B Ans7. A
Ans8. C Ans8. B Ans8. C
Ans9. B Ans9. D Ans9. A
Ans10. B Ans10. C Ans10. D
Ans11. C Ans11. A Ans11. B BD BD
Ans12. C Ans12. D Ans12. C
Ans13. D Ans13. D Ans13. D
Ans14. A Ans14. A Ans14. D
Ans15. A Ans15. B Ans15. D
Ans16. D Ans16. D Ans16. B
Ans17. A Ans17. B Ans17. D
Ans18. A Ans18. C Ans18. A
Ans19. B Ans19. C Ans19. D
Ans20. A Ans20. A Ans20. A
Part-B Part-B Part-B
Ans1. 1 Ans1. 6 Ans1. 1.5
Ans2. 2 Ans2. 8 Ans2. 22.5
Ans3. 3 Ans3. 0.5 Ans3. 75
Ans4. 0.16 Ans4. 0.4 Ans4. 2
Ans5. 1.8 Ans5. 2.1 Ans5. 4.5

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Solution

PHYSICS
Part-A
Sol1. In this circuit, D1 is forward biased and D2 is reversed biased.

D1 150 

75 

D2
Open

100 
6V

Resistance of D1 is 50  .

di
Sol2. VA – VB = i(5) + 10V + L
dt
+3
= 5(5) + 10 + L( −10 )
VA – VB = 35 – 35 × 10–3 × 10+3 = 0.

Sol3. Potential difference between A and B through any parallel path is 2 volt so there is
no current in any circuit element.

Sol4. At steady state.

Rate of generation of A = Rate of decay of A.
q = NA
q
 NA =


Sol5. If V is increased  will decrease and hence fringe width will decrease.

Sol6. Since, D1 will be acting as short circuit, D2 will act as open circuit so,
20
Current through 5 resistance and diode D1 is =4A
5

Sol7. According to Bohr’s atomic model.

Sol8. V = 0.6 m
hI h
 = I = 2  hI = 0.1 cm.
ho 0.05
 Distance between them = 0.3 cm = 3 mm.

1 B
Sol9. VQ – VO = B( )(r 2 ) = (2a)2 = 2Ba2.
2 2
Sol10. Conceptual

Sol11. (C)

d dB R  R 
Sol12. V = = (Area)  = (Bo )
dt dt 2  2 

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PT-V-(Mains)
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R2
VAB = Bo
4

Sol13. By the  vs i graph if i is decreased e will decrease less i.e. it may decrease by (2° or 1°).

Sol14. Path diff. at O = d sin 30°

−3 1
= (1 10 )  = 0.5 × 10–3 = 103 .
2
 At 0 there is max having I = 4Io.

Sol15. As  increases saturation current also increases.

Sol16. Extra path by S2 = (d sin ) w = ( g −  w )t

2 1  4  1
 = t
3 2  3   6 
8
t = mm
3

Sol17. The ray will always be normal, its x and y coordinates remains same
c
Ac 4
D Sextra = ò (m- 1)dz = 4
0

Sol18. fA = fB (same stopping potential)

Ia  Ib

Sol19. For 1st lens:-

(I)
1.3
−
1
=
(  − 1) + (1.3 −  )
x ( −20 ) R1 −R2
1.3 1 (  − 1) (1.3 −  )
(II) − = +
20 − y R1 −R 2

Sol20. 2i – A = min
sin (min + A) / 2
=
A
sin  
2

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Part-B

Sol1. As  is high , so I B is negligible

From KVL ( 6.5 + 1.85 + 1.65) 103 I1 = 10
 I1 = 10−3 A
In lower loop
1.65 103 I1 − VBE − I 103 = 0
 I = 1mA

R dB
Sol2. E= 
2 dt

  h
Sol3. =  
 2mE 
2L
= (from given graph)
3

v
Sol4. f=
2( + e)

Sol5. vI = −m2 v o
9 ˆ = 1.8 ˆi
= −  ( −5i)
25

CHEMISTRY
Part-A
Sol1. The lattice points are 8 corners and 6 face centres.

po − pS 2 2
Sol2. = =
p o
8 + 2 10

Sol3. Zn has the full-filled 3d10 configuration.

Sol4. H+ ion has the highest conductivity value.


Sol5. NH4 Cl ⎯⎯ → NH3 + HCl

NH4NO3 ⎯⎯ → N2O

NH4NO2 ⎯⎯ → N2
(NH4 )2 Cr2O7 ⎯⎯

→ N2

Sol6. SO2 bleaches by reduction. Hence the bleached material undergoes oxidation to retain its original
colour. Cl2, O3 and H2O2 bleaches through oxidation.

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Sol7. NaF + HF ⎯⎯
→ NaHF2

Sol8. O2 gas is needed to convert the ore to it’s oxide.

Sol9. It is butylated hydroxytoluene(BHT).

Sol10. SO24− + H+ ⎯⎯
→ HSO −4

Sol11. Cl– at the corners are removed.

No. of Cl– per unit cell of the face centres = 3
No. of Na+ per unit cell = 4
4 Na+ + 3 Cl– → One unit positive charge left.

0.0591
Sol12. ECell = ECell −
o
log H+ 
n
0.0591
=0- log10–4 = -0.0591  -4 = 0.2364 V
1

Sol13. Na3[FeF6] contains five unpaired electrons.

Sol14. 2FeCl3 + H2S ⎯⎯

→ 2FeCl2 + S  +2HCl
Other metal ions are in their stable oxidation states.

Sol15. 2NO + O2 ⎯⎯
→ 2NO2
2N2O + 3 O2 ⎯⎯
→ 4NO2

Sol16. In H2S2O8, the o.s of sulphur is +6 not +7 due to the following structure.
O O

HO - S - O - O - S - OH

O O

Sol17. NH4OH does not form complex with ‘Al’.

Sol18. The vapour pressure at NaOH solution is higher than that in FeCl3 solution.

Sol19. NO+ is the strongest -acid ligand due to its positive charge density.

Sol20. One mole of Al3+ needs three fardays of electricity to be deposited at cathode.

Part-B
Sol1. P is Cr(OH)3, Q = Na2CrO4

Sol2. The compound is IF7.

Sol3. 2Cu (NO3 )2 ⎯⎯


→ 2CuO + 4NO2 + O2

Sol4. Tf = Kfim

or, 2.232 = 1.86  3  m
 m = 0.4

Sol5. Structure of Fe2(CO)9 is

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PT-V-(Mains)
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O
OC CO
C
OC Fe Fe CO

OC CO
C C

O O

Mathematics
Part-A

Sol1. Let P(A) = .25 and P(B) = .50 and P(A  B) = .25 + .50 - .14 = .61
Now P(A’  B’) = 1 – P(A  B)= 0.39

Sol2. Let the required plane be

ax +by + cz =0
We have
3a - 5b +2c = 0 , a + 2b - 3c =0
a b c
 = =
15 − 4 2 + 9 6 + 5
 a : b : c = 11 : 11 : 11
Thus plane is x + y + z = 0

Sol3. For Image

 − ( −1)  − 3  − 4 −2( −1 − 2(3)
= = = 2
1 −2 0 1 + ( −2)2
 9 −13 
therefore, image is  , ,4
5 5 
Sol4. Let n be the number of times.
1 1
p= ,q=
2 2
According to question,
7 n−7 9 n−9
 1  1  1  1
n
C7     = n C9    
2 2 2 2
 n C7 = n C9  n − 7 = 9  n = 16

 6 + 2 − 12  −1  −4 
Sol5.  = sin−1     = sin  .
 14 . 29   406 

Sol6. xy + yz = 0
 x ( y + z) = 0
 x = 0, y + z = 0
Thus it represents a pair of planes
X = 0, y + z = 0
that are clearly mutually perpendicular.

Sol7. ey = t
dy dt
ey =
dx dx

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dt
− t = ex
dx
IF = e
−1.dx
= e− x
( )
t e− x =  ex .e− x dx
ey−x = x + c
Putting x = 0,y = 0,c = 1
ey−x = x + 1
y = x + loge ( x + 1)
at x = 1, y = 1 + loge 2

dy dx
Sol8. =  2 ln(y + 3) = ln X + ln C
y + 3 2x
(y + 3)2
 = c parabola curve
x

Sol9. Let persons be A, B, C, D

P (Hit) = 1 – P (none of them hits)
(
= 1− P A  B  C  D )
= 1 − P ( A ) .P (B ) .P ( C ) .P (D )
1 2 3 7
= 1− . . .
2 3 4 8
25
=
32

a 2
1 1 1
Sol10.  x − = x − 
x1 2 x 1
 1 3
 2a −  =
 a 2
 4a − 3a − 4 = 0
2

3 + 73
a=
8

 ( 2 x 
3
Sol11. Required area = 2
+ 9 ) − 5 x 2 dx
− 3

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Sol12. x 2  y  x + 2
x 2 = y; y = x + 2
x2 = x + 2
x2 − x − 2 = 0
( x − 2 )( x + 1) = 0
x = 2, − 1
2
9
Area =  ( x + 2 ) − x dx = 2
2

−1

Sol13. A T A = 3I3
 0 2x 2x   0 2y 1  3 0 0 
 2y y − y  2x y −1 = 0 3 0 
 1 −1 1  2x − y 1  0 0 3 
8x 2 0 0  3 0 0
 
  0 6y 2 0  = 0 3 0 
 0 0 3  0 0 3 

3
 8x 2 = 3  x = 
8
1
 6y 2 = 3  y = 
2
4 matrices are possible

Sol14. The required plane is ( 2x − y − 4 ) +  ( y + 2z − 4 ) = 0 it passes through (1, 1, 0)

 ( 2 − 1 − 4 ) +  (1 − 4 ) = 0
 −3 − 3 = 0   = −1
x−y−z=0

dx
Sol15. + x = y2
dy
= e
1dy
I.F. = ey
 x.e y =  y 2 .e y dy
xey = y2ey − 2yey + 2ey + C
y (0) = 1
 C = −e
 xey = y2ey − 2yey + 2ey − e
Put y = 0
x = 0−0+2−e
 x = 2−e

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Sol16. Differentiating
−2x x.2 yy '
y. + 1 − x 2 .y ' = − 1− y2
2 1− x 2
2 1− y 2

1 1 1
Put x = , y = − and x,y = −
2 4 8
− 5
y' =
2
Sol17. By expansion, we get
−5x3 + 30x − 30 + 5x = 0
 −5x3 + 35x − 30 = 0
 x3 − 7x + 6 = 0 , All roots area real
So, sum of roots = 0

P (–1, 2, 6)
AP.n
Sol18. AD = = 61
n

 PD = AP2 − AD2 = 110 − 61 = 7

A (2, 3, –4) D
n = 6iˆ + 3ˆj − 4kˆ

Sol19. B = 5 ( −5 ) − 2 ( − ) − 2
= 22 − 2 − 25
1+ A = 0
2 −  − 12 = 0
Sum = 1

Sol20. Total number of ways = 63 = 216

Favourable outcomes p3 = 120
6

120 5
 Probability = =
216 9
 p = 5, q = 9
 q−p = 4

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Part-B
Sol1. Vector perpendicular to plane containing the vectors ˆi + ˆj + kˆ d ˆi + 2ˆj + 3kˆ is parallel to vector
ˆi ˆj kˆ
= 1 1 1 = ˆi − 2ˆj + kˆ
1 2 3
 Required magnitude of projection

=
( )(
2iˆ + 3ˆj + kˆ . ˆi − 2ˆj + kˆ )
ˆi − 2ˆj + kˆ

2 − 6 +1 3 3
= = =
6 6 2

10!
Sol2. Total words are
2! 2! 2!
8!
The words contain the word “IIT” are
2!
8!
2
 Probability = 2! =
10! 45
2!2!2!

Sol3. We have 4 = a + 1 + 2 + 0,
 a =1,
8 = 2 + b + 1 + 0,
 b=5
12 = 3 + 2 + c +0 ,
 c=7
a2 + b2 + c 2 = 1 + 25 + 49 = 75 .

i j k
Sol4. BA  F = ( 2i + 4j + 8k )  ( 2i + 2j + 5k ) = 2 4 8
2 2 5
4i + 6j − 4k = 4i + 6j + 2k (given).
  = −2

Sol5: The curve y = x2 – 7x +1 0 intersects x-axis at the points (2, 0) and B(5, 0) .
Hence the required area is y
5 5


= – ydx = −  (x − 7x + 10 dx)
2

2 2

 x3 7x 2 5
=– − + 10x  = 4.5
3 2 2 A(2, 0) B(5, 0)
O x

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