Lkitn224b02, C06-Ph-1-Adv-1 (PCDK, CPN, MPK) (Cbse)

FIITJEE Phase Test (JEE-Advanced)
PHYSICS, CHEMISTRY & MATHEMATICS

PHASE-I DATE: 18.09.2022 Paper – 1
Time Allotted: 3 Hours Maximum Marks: 180
Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
You are not allowed to leave the Examination Hall before the end of the test.
Batch: LKITN224B02,C06 (PINNACLE - XI)
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Sections.
Section-I is Physics, Section -II is Chemistry and Section -III is Mathematics.
Each section is further divided into Two Parts: Part-A & Part-C.
Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for
rough work.
Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with a blue / black ball point pen for each character of
your Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Sections.

(i) Part-A (1 – 6) contains Six (06) Multiple Choice Questions which have one or more than one correct
answer. Each question carries +4 marks for correct answer and –2 marks for wrong answer.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is
a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 In all other cases.
Part-A (7 – 10) contains Four (04) Matching List type questions. Each question has 4 statements in List-I
and 4 or 5 statements in List-II. The codes for Lists have four options (A), (B), (C), (D) out of which only
one is correct. Each question carries +3 Marks for correct answer and -1 mark for wrong answer.
(ii) Part-C (1 – 8) contains Eight (08) Numerical based questions with single digit integer as answer, ranging
from 0 to 9 (both inclusive). Each question carries +3 marks for correct answer. There is no negative
marking.
Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
FIITJEE Ltd., FIITJEE Kathauta Chauraha, Vinamra Khand, Gomti Nagar, Lucknow – 226010. Ph: 0522-2724960, 2724961.
FIITJEE Ltd., Near M.G. Convent School, Sector - G, LDA Colony, Kanpur Road, Aashiana, Lucknow - 226012. Ph: 0522-4114644, 4114645.
FIITJEE Ltd., Near Four Season House, A-1/3, Sector - C, Aliganj, Lucknow - 226024. Ph: 0522-4976464, 4976465.
2
LKITN224B02,C06-PH-I-ADV.(PAPER-1)
USEFUL DATA
PHYSICS CHEMISTRY
Acceleration due to gravity : g = 10 m/s2 −1 −1
Gas Constant R = 8.314 J K mol
−34
Planck constant : h = 6.6  10 J − s = 0.0821 Lit atm
−19 −1 −1
Charge of electron : e = 1.6  10 C K mol
Mass of electron : me = 9.1  10
−31
kg
= 1.987  2 Cal
−1 −1
−12 2 2 K mol
Permittivity of free space :  0 = 8.85  10 C /N −m
Avogadro’s Number Na = 6.023  10 23
Density of water :  water 3
= 10 kg / m
3
−34
5 2 Planck’s constant h = 6.625 10 J .s
Atmospheric pressure : Pa = 10 N / m −27
Gas constant : R = 8.314 J = 6.625 10 erg .s
1 Faraday = 96500 coulomb
K −1 mol −1 1 calorie = 4.2 joule
−27
1 amu = 1.66 10 kg
−19
1 eV = 1.6  10 J
Atomic No: H = 1, He = 2, Li = 3, Be = 4, B = 5, C = 6, N = 7, O = 8, F = 9, Ne = 10, Na = 11,
Mg = 12, Si = 14, Al = 13, P = 15, S = 16, Cl = 17, Ar = 18, K = 19, Ca = 20,
Cr = 24, Mn = 25, Fe = 26, Co = 27, Ni = 28, Cu = 29, Zn = 30, As = 33, Br = 35,
Ag = 47, Sn = 50, I = 53, Xe = 54, Ba = 56, Pb = 82, U = 92.
Atomic masses: H = 1, He = 4, Li = 7, Be = 9, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23,

Mg = 24, Si = 28, Al = 27, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52,
Mn = 55, Fe = 56, Co= 59, Ni = 58.7, Cu = 63.5, Zn = 65.4, As = 75, Br = 80,
Ag = 108, Sn = 118.7, I = 127, Xe = 131, Ba = 137, Pb = 207, U = 238.
3
Section – I (Physics)
PART – A
(Multi Correct Choice Type)
This part contains 6 Multiple Choice Questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
1. The equation of the stationary wave is

 2ct   2x 
y = 2A sin   cos  
     
Which of the following statements is wrong?
(A) the unit of ct is same as that of  (B) the unit of x is same as that of 
(C) the unit of 2 c/ is same as that of 2x/t (D) the unit of c/ is same as that of x/
    
2. The two vectors A and B are drawn from a common point and C = A + B , then angle between
 
A and B is
(A) 90º if C2 = A2 + B2 (B) greater than 90º if C2 < A2 + B2
(C) greater than 90º if C2 > A2 + B2 (D) less than 90º if C2 > A2 + B2
3. Consider the motion of the tip of the minute hand of a clock. In one hour
(A) the displacement is zero (B) the distance covered is zero
(C) the average speed is zero (D) the average velocity is zero
4. Path of three projectiles are shown in figure. It T1, T2 and T3 are time of fights and ignoring air
resistance –
y
1 3
2
x
R
1.5 R
2R
T1 + T3
(A) T1 > T3 (B) T1 < T3 (C) T2 = (D) T1 = T2 = T3
2
5. As shown in figure two blocks A and B of mass 1kg each are connected by an ideal string that
passes over a smooth pulley that is fixed on a smooth fixed wedge as shown. If the ratio of normal
4  4
reaction on block A and on block B is , then:  sin53o = 
3  5
A B
 53º
4 4
(A) cos = (B) sin =
5 5
g g
(C) acceleration of blocks is m/s2 (D) acceleration of blocks is m/s2
10 5
4
6. A block rests on a rough inclined plane as shown in figure. A horizontal force (F) is applied to it

(A) Normal reaction on the block is F sin  + mg cos 
(B) Frictional force is zero when F cos  = mg sin 
(C) The value of limiting friction is µ(mg sin  + F cos )
(D) The value of limiting friction is µ(mg sin – F cos)
PART – A
(Matching-List Type)
This part contains 4 questions. Match the statements in List - I with the statements in List - II and choose
the correct option given below the question. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
7. Match List-I with List-II:

List - I List - II
(I) Kinetic energy (P) [ML–1 T–2]
(II) Work (Q) [ML2T–2]
(III) Pressure (R) [MLT–2]
(IV) Force (S) [ML2T2]
(T) [MLT–1]
Codes:
I II III IV
(A) Q P S R
(B) Q Q P R
(C) P Q T S
(D) R P Q T
 
8. If A = 2î + 3 ĵ − k̂ and B = î + 2 ĵ + 2k̂ then:
List - I List - II
→ →
(I) | A B| (P) 11
→ →
(II) |A −B| (Q) 6
→ →
(III) A.B (R) 35
→ →
(IV) | A+ B| (S) 90
Codes:
I II III IV
(A) P Q S R
(B) R P Q S
(C) P Q R S
(D) S P Q R
5
9. List-II shows the nature of graph corresponding to situations in List-I. Match the correct graphs.
List - I List - II
A

B
Sinusoidal (sine curve or
(I) (P)
m C cosine curve)
A light wire ABC supports a mass 'm' as shown

in figure. The wire passes over a fixed ideal
pulley at B and is firmly fixed to vertical wall at
A. The net force by the wire on pulley is F
Graph of variation of F with .
frictionless ideal pully
1
m1
2
(II) m2 (Q) Straight line inclined to x-axis
In the system shown the mass of uniform string
is mS. Here 1 and 2 are the lengths of the
cord from respective masses to the pulley.
Graph of acceleration of system as function
of 2.
x=0 x=L
x
 
(III) Consider a uniform string of mass M attached (R) Straight line parallel to x-axis
to a rigid walls. Each end of the string makes
an angle  with the horizontal.
Graph of variation of x component of
tension versus x.
smooth
rough surface
surface
m
1
m2

A wedge of mass m2 is placed on a rough
(IV) surface. A small block of mass m1 can move (S) Parabolic curve
along the frictionless incline of the wedge,
friction is sufficient to prevent any motion of
wedge.
Graph of variation of x component of
acceleration of centre of mass as function
of wedge angle .
Codes:
I II III IV
(A) P Q R P
(B) Q R S P
(C) Q P R S
(D) R P S Q
6
10. As shown block C of mass 5 kg is pulled by a force F and its acceleration is found to be 3 m/s 2.
The masses of blocks A and B are 10 kg and 5 kg respectively while the string passing over ideal
pullies is ideal and is under tension T. If acceleration of blocks A and B are a1 and a2 respectively
then if all surfaces are smooth and g = 10 m/s2 –
F C
aC = 3 m/s2
T
A B
List - I List - II
(I) F (P) 2
(II) T (Q) 1
(III) a1 (R) 55
(IV) 2 a2 (S) 70
Codes:
I II III IV
(A) R Q P S
(B) S R Q P
(C) P R S Q
(D) Q R S P
PART – C
(Numerical Based with Single Digit Integer as Answer)
This part contains 8 questions. The answer to each question is a single digit integer ranging from 0 to 9
(both inclusive).
1. Force applied by water jet from a pipe depends upon (i) velocity of water (ii) density of water
(iii) cross-sectional area of pipe. How many times force will be increased if velocity of a water is
increased 2 times?
2. A 2m wide truck is moving with a speed of 5 5 m/s along a straight horizontal road. A man starts
crossing the road with a uniform speed v when the truck is 4m away from him. The minimum value
of v (in m/s) to cross the truck safely is-
 
3. If a1 and a 2 are two non collinear unit vectors and if | a1 + a 2 | = 3 , then the value of (a1 − a 2 ) .
n
(2a1 + a 2 ) is . Find n.
10
4. Two men P & Q are standing at corners A & B of square ABCD of side 8 m. They start moving
along the tank with constant speed 2m/s and 10 m/s respectively. The time when they will meet for
the first time, in second is -
10 m/s C
B
2 m/s
A D
7
1
5. The diagram shows variation of with respect to time (where v is in m/s).
v
1 s 
 
vm
45º
t(s)
3
 m
What is the instantaneous acceleration of body at t = 3 sec.  in  ?
 s2 
6. A particle is projected towards north with speed 20m/s at an angle 45º with horizontal. Ball get
horizontal acceleration of 7.5 m/s2 towards east due to wind. Range of ball (in meter) is R. Find
R
the value of .
10
7. A ball is projected in upward direction with a speed of 20 m/s. Find the distance (in meter) travelled
by it in last second of its ascending motion. (g = 10 m/s2)
8. A small ball of mass M = 3 kg is attached to two identical springs of constant k = 10 N/m, which are
attached to floor and roof. The springs have unstretched length l/2 where l = 1 m. At what distance
(in m) from the ceiling ball remain at equilibrium?
8
Section – II (Chemistry)
PART – A
1. One mole of (NH4)2SO4 contains

(A) 28 g of nitrogen (B) Two moles of di-hydrogen(H2)
(C) One mole of sulphur atom (D) (6.023  1023  4) atoms of oxygen
2. Which of the following set(s) of quantum numbers is/are not allowed?

(A) n = 3,  = 0, m = 0, s = + ½ (B) n = 4,  = 2, m = 1, s = - ½
(C) n = 3,  = 0, m = +1, s = + ½ (D) n = 4,  = 1, m = -1, s = - ½
3. The atomic number or iron is 26. Which of the following statement(s) is/are correct for it?
(A) It contains four unpaired electrons
(B) It contains eight electrons with  = 0
(C) The spin magnetic moments of Fe+ and Fe3+ ions are same
(D) Fe2+ and Fe4+ are isoelectronic species
4. Which of the following molecule is planar?

(A) H2O (B) BCl3 (C) ICl2− (D) XeF4
5. Which of the following property(ies) of group-1 elements increase(s) on moving down the group?
(A) Size of atoms (B) Ionic radius (C) Ionization energy (D) Nuclear charge
6. Which of the following orbital(s) has/have more than one radial node?
(A) 3s (B) 4p (C) 3d (D) 5f
PART – A
7. Match the number of moles with their amount:

List - I List - II
(I) 0.1 mol (P) 4480 mL of CO2 at STP
(II) 0.2 mol (Q) 0.1 g-atom of iron
(III) 0.25 mol (R) 1.5  1023 molecules of oxygen gas
(IV) 0.5 mol (S) 9 mL of water
(T) 200 mg of hydrogen gas
Codes:
I II III IV
(A) Q,T P R S
(B) P Q,T R R
(C) Q P,T R S
(D) P Q R,T R
9
8. Match the series of hydrogen spectrum with their characteristics (H atoms):

List - I List - II
(I) Lyman series (P) Visible region
(II) Balmer series (Q) Infrared region
(III) Paschen series (R) Ultraviolet region
(IV) Bracket series (S) n2 = 4 to n2 = 3
(T) n2 = 5 to n2 = 1
Codes:
I II III IV
(A) R P Q,S Q
(B) R,T P,S Q,T R
(C) R,T P Q,S Q
(D) R P Q,T R

List – I (Atomic Number) List – II (Block)
(I) 12 (P) s-block
(II) 26 (Q) p-block
(III) 17 (R) d-block
(IV) 58 (S) f-block
Codes:
I II III IV
(A) P R S Q
(B) S R P Q
(C) P R Q S
(D) R P S Q
10. Which of the following represents correctly matched List-I and List-II:
List - I List - II
(I) CH 4 (P) Tetrahedral
(II) NH 3 (Q) See-saw
(III) I3− (R) Pyramidal
(IV) SF4 (S) Linear
(T) Bent
Codes:
I II III IV
(A) P R T Q
(B) P Q T R
(C) P R S Q
(D) P Q S T
PART – C
(both inclusive).
1. How many maximum number of orbitals are present in the third orbit of hydrogen atom?
2. What is the molarity of Na+ ions in 4 M Na2SO4 solution?
3. How many electron(s) is/are present in the valence shell of the atom which has the highest value
of electron gain enthalpy in the periodic table?
10
4. What is the sum of the principal quantum numbers of two orbits of hydrogen atom between which
an electron transition forms the first line of Lyman series?
5. Find the total number of species having linear shape?

C2H2, CO2, SnCl2, HCN, O3, OF2, XeF2
6. How many moles of water weigh 90 gram?
7. 2 A ( g) + 4B ( g) ⎯⎯
→ 2C ( g)
How many moles of ‘C’ is produced by complete reaction between two moles each of A and B?
8. The value of successive ionization energies of an atom is given as follows:

10.2, 24.8, 33.6, 1800.9, 2530.6, etc
How many total number of atom(s) is/are present in the formula of the oxide of the metal?
11
Section – III (Mathematics)

PART – A
7
1. If A lies between 270º & 360º and sin A = – , then
25
336 A 2 A 1 A 2
(A) sin 2A = – (B) cos = (C) tan =– (D) sin =–
625 2 5 2 7 2 10
2. Which of the following statements are possible a, b, m and n being non-zero real numbers?
(A) 4 sin2  = 5 (B) (a2 + b2) cos  = 2ab
(C) (m2 + n2) cosec  = m2 – n2 (D) sin  = 0.2375
3. In a class of 30 pupils, 12 take needle work, 16 take physics and 18 take history. If all the 30 students take
at least one subject and no one takes all three then the number of pupils taking 2 subjects is
(A) 16 (B) 6 (C) 8 (D) 20
4. Consider the following relations :

(1) A − B = A − ( A  B)
(2) A = ( A  B)  ( A − B)
(3) A − (B  C) = ( A − B)  ( A − C)
which of these is/are correct
(A) 1 and 3 (B) 2 only (C) 2 and 3 (D) 1 and 2
2
3 log x − log x
3
5. If x1 and x2 are the solution of the equation x 3 = 100 3 10 , where base of logarithm is 10,
then
(A) x1x2 = 1 (B) x1. x2 = x1 + x2 (C) log x 2 . x1 = –1 (D) log (x1. x2) = 0
2
−log x 2
6. The solutions of the equation | x − 1 |(log x ) = |x –1|3, where base of logarithm is 10 are-
1
(A) x = 2 (B) x = (C) x = 1000 (D) x = 100
10
PART – A

List - I List - II
(I) cot (/4 + ).cot (/4 – ) (P) tan 56º
(II) sin (45º + ) – cos (45º – ) (Q) 1
cos 11º + sin11º
(III) (R) 3/2
cos 11º − sin11º
(IV) sin2 75º – sin2 15º (S) 0
12
Codes:
I II III IV
(A) S R P Q
(B) P S Q R
(C) P R S Q
(D) Q S P R

List - I List - II
(I) Number of integers for which | x + 2 | − x  2 (P) One
Number of values of x satisfying
(II) (Q) Infinitely many
x + 1 − x −1 = 4x −1
Number of positive values of x satisfying
(III) (R) No solution
x2 − 5 | x | +6 = 0 are
(IV) Number of integer satisfying x − 5 − 9 − x  1 are (S) two
Codes:
I II III IV
(A) Q R S P
(B) Q,R P Q,S Q,R,S
(C) Q R,P Q,S P
(D) S R,S P Q

List - I List - II
sin 2 
(I) = (P) – sin 2
1 + cos 2
1 + sin  − cos 
(II) = (Q) tan 
1 + sin  + cos 
sin  + sin 2 
(III) = (R) tan 6
1 + cos  + cos 2 
2
  
(IV) 1 − 2sin  +   = (S) tan /2
 4 
Codes:
I II III IV
(A) P R S Q
(B) Q S Q P
(C) S P Q R
(D) P S Q P
10. Let cos  + cos  = a and sin  + sin  = b .

List I List II
2ab
cos ( +  )
(A) (P)
( a + b2 )
2
b
(B) sin ( +  ) (Q)
a
cos ( −  )
( a 2 − b2 )
(a + b2 )
(C) (R) 2
13
(D) tan
 +
(S)
(a 2
+ b2 − 2 )
2 2
Codes:
I II III IV
(A) R P S Q
(B) P R Q S
(C) R Q P S
(D) Q S P R
PART – C
(both inclusive).
1. The smallest integer satisfying log 1 x − 1 + 2 = log 1 x − 3 , is

6 6
( log10 2) + log10 8.log10 5 + ( log10 5 ) is

3 3
2. The value of
 9 7 9
3. The expression 2cos .cos + cos + cos simplifies to an integer P. Find the value
17 17 17 17
of P.
4. (
The value of expression 1 − cot 23o )(1 − cot 22 ) is equal to :
o
5. If tan ( + x) tan ( − x) = 1 for all x, then value of cot

2
 must be
6. If x + log10(2x +1) = log106 + x log105 then the value of x is...................
7. If sec (x – y), sec x and sec (x + y) are in A.P, then cos2 x − cos y is equal to ______ .
8. Value of 4 cos 36° – 4 cos 72° + 4 sin 18° cos 36° is
14
FIITJEE INTERNAL TEST

Batch: LKITN224B02,C06 (PINNACLE - XI)
IIT-JEE 2024
PHASE – I PAPER – I
ANSWERS
DATE: 18.09.2022
PHYSICS
Part – A
1. D 2. ABD 3. AD 4. CD
5. AC 6. AB 7. B 8. D
9. A 10. B
Part – C
1. 4 2. 5 3. 5 4. 3
5. 3 6. 5 7. 5 8. 2
CHEMISTRY
Part – A
1. ACD 2. C 3. ABC 4. ABCD
5. ABD 6. AB 7. A 8. C
9. C 10. C
Part – C
1. 9 2. 8 3. 7 4. 3
5. 4 6. 5 7. 1 8. 5
MATHEMATICS
Part – A
1. AC 2. BD 3. A 4. D
5. ACD 6. ABC 7. D 8. A
9. A 10. A
Part – C
1. 1 2. 1 3. 0 4. 2
5. 1 6. 1 7. 1 8. 3

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FIITJEE Phase Test (JEE-Advanced)

PHYSICS, CHEMISTRY & MATHEMATICS

Time Allotted: 3 Hours Maximum Marks: 180

B. Filling of OMR Sheet

C. Marking Scheme For All Sections.

Name of the Candidate :____________________________________________

Atomic masses: H = 1, He = 4, Li = 7, Be = 9, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23,

1. The equation of the stationary wave is

7. Match List-I with List-II:

A light wire ABC supports a mass 'm' as shown

1. One mole of (NH4)2SO4 contains

2. Which of the following set(s) of quantum numbers is/are not allowed?

4. Which of the following molecule is planar?

7. Match the number of moles with their amount:

8. Match the series of hydrogen spectrum with their characteristics (H atoms):

9. Match List-I with List-II:

2. What is the molarity of Na+ ions in 4 M Na2SO4 solution?

5. Find the total number of species having linear shape?

6. How many moles of water weigh 90 gram?

8. The value of successive ionization energies of an atom is given as follows:

Section – III (Mathematics)

4. Consider the following relations :

7. Match List-I with List-II:

8. Match List-I with List-II:

9. Match List-I with List-II:

10. Let cos  + cos  = a and sin  + sin  = b .

1. The smallest integer satisfying log 1 x − 1 + 2 = log 1 x − 3 , is

( log10 2) + log10 8.log10 5 + ( log10 5 ) is

5. If tan ( + x) tan ( − x) = 1 for all x, then value of cot

6. If x + log10(2x +1) = log106 + x log105 then the value of x is...................

8. Value of 4 cos 36° – 4 cos 72° + 4 sin 18° cos 36° is

FIITJEE INTERNAL TEST

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