CM Test 1

FIITJEE – Phase Test (JEE-Advanced)
PHYSICS, CHEMISTRY & MATHEMATICS
Pattern - CPT-1 QP Code: PAPER - 1

BATCH – CM Monthly Test_Class-XI_Test-1-(PCM) JEEA
Time Allotted: 3 Hours Maximum Marks: 180
 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & C in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Two Parts.

(i) Part-A (01-06) – Contains six (06) multiple choice questions with partial marking, which have ONE or
MORE THEN ONE correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: 1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will result
in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in 1
marks, as a wrong option is also darkened.
(ii) Part-A (07-10) – This section contains Two (02) List-Match Sets, each List-Match set has Two (02) Multiple
Choice Questions. Each List-Match set has two lists: List-I and List-II. FOUR options are given in each
Multiple Choice Question based On List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question. Each question carries +3 Marks for correct combination
chosen and -1 marks for wrong options chosen.
(ii) Part-C (01-08) contains eight (08) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals and round off the value to Two decimal places (e.g., 6.25, 7.00, -0.33, -
.30, 30.27, -127.30) and each question carries +3 marks for correct answer and there will be no negative
marking.
Name of the Candidate: ________________________________________________
Batch: _________________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
FIITJEE Patna Centre, 2nd floor, Saday Bhawan, Marwari Awas Complex, Fraser Road, Patna, Ph. : 9534599992, 9534699992
e-mail – info.patna@fiitjee.com , website: www.fiitjee.com
IT2025 CM Monthly Test_Class-XI_Test-1-(PCM) JEEA 2
S
SEEC
CTTIIO
ONN--1
1 :: P
PHHY
YSSIIC
CSS
PART – A
(Multi Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE OR MORE may be correct.
1. Pick the correct statements:

(A) Average speed of a particle in a given time is never less than the magnitude of the
average velocity.

dv d 
(B) It is possible to have a situation in which  0 but v 0
dt dt
(C) The average velocity of a particle is zero in a time interval. It is possible that the
instantaneous velocity is never zero in the interval.
(D) The average velocity of a particle moving on a straight line is zero in a time interval. It
is possible that the instantaneous velocity is never zero in the interval. (Infinite acceleration
is not allowed)
2. If velocity of the particle is given by v  x , where x denotes the position of the particle
and
initially particle was at x = 4, then which of the following are correct?
(A) at t = 2 sec, the position of the particle is at x = 9.
(B) Particle acceleration at t = 2 sec. is 1 m/s2.
1
(C) Particle acceleration is m / s2 throughout the motion.
2
(D) Particle will never go in negative direction from it’s starting position.
3. A block is thrown with a velocity of 2 ms–1 (relative to ground) on a belt, which is moving
with constant velocity 4 ms–1in opposite direction of the initial velocity of block. If the block
stops slipping on the belt after 4 sec of the throwing then choose the correct statements(s)
(A) Displacement with respect to ground is zero after 2.66 sec and magnitude of
displacement with respect to ground is 12 m after 4 sec.
(B) Magnitude of displacement with respect to ground in 4 sec is 4 m.
(C) Magnitude of displacement with respect to belt in 4 sec is 12 m.
(D) Displacement with respect to ground is zero in8/3 sec.
4. Two swimmers A and B start swimming from different

position on the same bank as shown in figure. The
swimmer A swims at angle 90º with respect to the river to
reach point P. He takes 120 second to cross the river of
width 10m. The swimmer B also takes the same time to
reach the point P
(A) velocity of A with respect to river is 1/6 m/s.
(B) river flow velocity is 1/4 m/s.
(C) velocity of B along y-axis with respect to earth is 1/3 m/s.
(D) velocity of B along x-axis with respect to earth is 5/24 m/s.
space for rough work
5. From an inclined plane two particles are projected with same speed
at same angle , one up and other down the plane as shown in
figure. Which of the following statement (s) is/are correct?
(A) The particles will collide the plane with same speed
(B) The times of flight of each particle are same
(C) Both particles strikes the plane perpendicularly
(D) The particles will collide in mid air if projected simultaneously and time of flight of each
particle is less than the time of collision
6. The x-component of the resultant of several vectors –

(A) is equal to the sum of the x-components of the vectors
(B) may be smaller than the sum of the magnitudes of the vectors
(C) may be greater than the sum of the magnitudes of the vectors
(D) may be equal to the sum of the magnitudes of the vectors
PART – A: (MatrixMatch Type)

This section contains TWO (02) Matching List Sets. Each set has TWO Multiple Choice Question.
List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY
ONE of these four options satisfies the condition asked in the Multiple Choice Question.
x2
Trajectory of particle in a projectile motion is given as y  x  . Here, x and y are in meters. For
80
this projectile motion, match the following with g = 10 m/s2
Column – I Column – II
(A) Angle of projection (in degrees) (P) 20
(B) Angle of velocity with horizontal after 4s (Q) 80
(in degrees)
(C) Maximum height (in metres) (R) 45
(D) Horizontal range (in metres) (S) 30
(T) 60
7. Which of the following option is correct:

(A) A → R, B → P (B) A → R, D → Q
(C) B → P, C → R (D) A → P, B → R
8. Which of the following option is correct

(A) A → Q, B → R (B) B → R, C → P
(C) B → R, C → P (D) B → R, C → Q
Column – I Column – II
(A) Time for a boat to cross river of width  (P) 
  
by the shortest distance ( v - velocity of u

boat with respect to water; u - velocity of
 
water)   u
(B) Time for two particles moving with (Q) 
 
velocities  and u in opposite directions   u2
2
to meet each other (initial separation of
particles is  )
(C) Time for a boat to cross a river of width  (R) 
  
in the shortest time (  - velocity of boat  u

with respect to water; u - velocity of
water)
(D) Time for a boat to travel a distance  (S) 
 
downstream (  - velocity of boat with 

respect to water; u - velocity of water)
(T) 
u  2
2
9. Which of the following option is correct

(A) A → PQ, B → R (B) A → PR, B → R
(D) D → PQ, C → RT (D) B → PR, C → R
10. Which of the following option is correct:

(A) C → S, D → P (B) C → PR, D → T
(C) A → ST, B → PQ (D) B → R, D → PR
PART – C : Numerical Answer Type

Part-C (01-08) contains eight (08) Numerical based questions, the answer of which maybe
positive or negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each
question carries +4 marks for correct answer and there will be no negative marking.
      
1.  
If A  B  C  0, then A. B  C  .................
2. A pebble is thrown vertically upwards from a bridge

with an initial velocity of 4.9 m/s. It strikes the water
after 2 s. If acceleration due to gravity is 9.8 m/s2. Find
the velocity (in m/s) with which the pebble strikes the
water.
3. A driver takes 0.20 s to apply the brakes after he sees a need for it. This is called the
reaction time of the driver. If he is driving a car at a speed of 54 km/h and the brakes
cause a deceleration of 6.0 m/s2, find the distance travelled by the car after he sees the
need to put the brakes on.
dv
4. A body moves so that it follows the following relation   v 2  2v  1where v is speed in
dt
m/s and t is time in second. If at t = 0, v = 0 then the speed (in m/s) when acceleration is
one fourth of its initial value, is K m/s. Find K.
     
5. If a  3, b  4 and a  b  5, then a  b is equal to
     
   a  b 
2 2
6. If a  b  144 and a  4, then b is equal to
7. The velocity-time graph of the particle moving along a straight line

is shown. The rate of acceleration and deceleration is constant
and it is equal to 5 ms–2. If the average velocity during the motion
is 20ms–1, then find the value of t in second.
8. A butterfly is flying with velocity 10iˆ  12ˆj m/s and wind is blowing
along x axis with velocity u. If butterfly starts motion from A and
after some time reaches point B, find the value of u in m/s.
S
SEEC
CTTIIO
ONN--2
2 :: C
CHHE
EMMIIS
STTR
RYY
PART – A
1. Which of the following sets of orbitals have at least one common nodal plane?
(A) 3p x ,3dxz (B) 3p z ,3dyz (C) 3dxy ,3dxz (D) 3dyz ,3dz2
2. The wave functions of 3s and 3pz orbitals are given by

1/2 3/2
1  1   z   4zr 4z 2r 2   Zr /3a0
 3s       6   e
9 3  4   a0   a0 9a02 
1/2
1  3   z  2zr   2zr   zr /3a0
 3pz   4   a   4  3a   3a  e cos 
9 3   0  0  0 
From these we can conclude that

(A) No. of nodal surfaces for 3pz and 3s orbitals is equal
(B) The angular nodal surface of 3pz orbital has the equation    / 2
(C) The radial nodal surfaces of 3s orbital and 3pz orbital are at equal distance from the
nucleus
(D) 3s electrons have greater penetrating power into the nucleus in comparison to 3p
electrons
3. Consider the following redox reaction:

H2O  AX  BY   HA  YO  BX 2 unbalanced 
It is also known that oxidation number of X = - 2 and neither X nor water is involved in the
redox process. (In compound BY, B is cation and consider its oxidation number < 4). If the
given reaction is balanced with smallest whole number coefficients, then:
(A) Sum of stoichiometric coefficient of all the component is 8
(B) Sum of stoichiometric coefficient of all the component is 9
(C) Stoichiometric coefficient of AX is 6
(D) Stoichiometric coefficient of HA is 4
4. Which of the following statement(s) is/are incorrect?

(A) Molar volume of every gas at STP is 22.4 L
(B) Under critical conditions compressibility factor is 1
(C) For any gas Boyle’s temperature (TB) is greater than critical temperature (TC)
(D) At absolute zero temperature kinetic energy of gas is 3R/8
5. At STP, 1L of a sample of air containing SO2 as impurity is treated with required ozonised
air and then passed through water. The resultant solution requires 40 ml of 0.01 M NaOH
for complete neutralisation. The % of SO2 by volume in the air is:
(A) 2.24 (B) 4.48 (C) 0.224 (D) 0.448
6. Three identical vessel A, B and C are connected by tube of negligible volume. Vessel A
contain 5 moles of H2 and 10 moles of O2 Tap - 1 is now opened for some time (keeping
tap - 2 closed) so that gases diffuses in to vessel B. Vessel B after some time contain 4
moles of H2 and some oxygen. Now tap - 2 is opened for some time keeping tap - 1 closed
and if vessel C is now found to contain 1 mole of H2, then moles of O2(g) in vessel C is ?
Tap - 1 Tap - 2
A B C
(A) 0.28 moles (B) 0.125 moles (C) 0.5 moles (D) 1 moles

Match the following:

For hydrogen like species
List – I List – II
(i) Transition from n = 4 to n = 2 (P) Total six distinct spectral lines
(ii) Transition from n = 6 to n = 3 (Q) Balmer series
(iii) Transition from n = 5 to n = 2 (R) One of the emitted photon has

36

5RH
(iv) Transition from n = 4 to n = 1 (S) One of the emitted photon has
144

7RH
(T) Lyman series
7. Match each transition from List – I to the properties mentioned in List – II.
(A) i → Q,R; ii → P,S; iii → P,Q; iv → P,R,T
(B) i → P,S,T; ii → Q,R,S; iii → P,Q; iv → P,Q,R
(C) i → P; ii → Q; iii → P,R; iv → R,S,T
(D) i → R,S; ii → P,S,T; iii → P,S; iv → Q,R,S
8. Which of the following is not correctly matched?

(A) i → P; ii → Q; iii → Q,S; iv → P,S
(B) i → Q; ii → Q,R; iii → T; iv → Q
(C) i → R,S; ii → P,Q,T, iii → P,R,T; iv → P,Q
(D) i → P,Q; ii → P,R,T; iii → Q,S,T; iv → P,R
Match the following:
List – I List – II
(i)  Cu NO3 2  NO  H2O
Cu  HNO3  (P) Redox Reaction
(ii) P4  OH  H2O 
 PH3  H2PO2 (Q) Disproportionation reaction
(iii)  SO 42  CO32  NO3
NH4 SCN  (R) Eq. wt. of underlined substance =
M
3
(iv) NH4NO2 
 N2  H2O (S) Eq. wt. of underlined substance =
4M
3
(T) Eq. wt. of underlined substance =
M
24
9. Which of the following is correctly matched?

(A) i → P; ii → Q,R; iii → S,T; iv → R
(B) i → S; ii → P,R; iii → T; iv → P
(C) i → P,Q; ii → Q,T; iii → T; iv → P ,S
(D) i → Q,R; ii → P,Q,R; iii → T; iv → P,S,T
10. Which of the following is not correctly matched?

(A) i → P; ii → Q; iii → T; iv → R
(B) i → S; ii → R; iii → T; iv → P
(C) i → R; ii → ,S; iii → P; iv → S
(D) i → P,S; ii → P,R; iii → T; iv → P

1. If total number of exchange pairs for dn - configuration are 13 then what is the value of n?
w
2. A 75 gm, 4%   aqueous NaOH solution is distilled for some time. The water collected
w
has a mass of 25 gm. To this distilled solution x gm KOH(s) is added, so that molality of
OH- ion in the resulting solution becomes 5 m. Find the value of x.
3. The graph of compressibility factor (Z) v/s P for 1 mol of a real gas is shown in following
diagram. The graph is plotted at 273 K temperature. If slope of graph at very high pressure
dZ 1
 atm1 then calculate volume of 1 mol of real gas molecules in L/mol.
dP 2.8
 22.4 1 1 
Given : NA  6  10 ,R  273 L atm K mol 
23
 
Z dz 1
 atm1
dp 2.8
P
4. Given is an equation of state for real gas, where A and B are constants
A 2B
PV  RT   2
V V
Find compressibility factor (Z) at critical point.
5. A magnesium ribbon, when burnt in air, left an ash containing MgO and Mg3N2. The ash
was found to consume 0.6 mol of HCl according to the reactions
MgO  HCl   MgCl2  H2O
Mg3N2  HCl   MgCl2  NH4 Cl
The solution so obtained is treated with excess of NaOH, then 0.1 mol of NH3 is evolved.
(NaOH + NH4Cl   NH3 + H2O + NaCl). The mass in gram of magnesium burnt is
……….
6. An electron practically at rest, is initially accelerated through a potential difference of 100

0
volts. It has a de-Broglie wavelength = 1 A It then get retarted through 19 volts and then
0
has a wavelength =  2 A . A further retardation through 32 volts changes the wavelength
0   2
to  3 A . What is the value of 3 ?
1
7. 2.3 gm of a mixture of NO2 and N2O4 has a pressure of 0.82 atm at temperature T K and
V 1
volume V litres. If    L K 1 . What would be the partial pressure of NO2 gas?
T
  300
[Assume all NO2 was formed from decomposition of N2O4. Gas constant R = 0.082 L atm
mol-1 k-1]
8. A 7.1 g sample of bleaching powder suspended in H2O was treated with enough acetic
acid and KI solution. Iodine thus liberated required 80 mL of 0.2 N hypo solution for
titration. Calculate the % of available chlorine.
S
SEEC
CTTIIO
ONN--3
3 :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
1. If f(x) = x  1  2 x  1 , then :
(A) f(x) = – 1 has exactly two roots (B) f(x) = 1 has exactly two roots
(C) f(x) = 2 has exactly one root (D) f(x) = 3 has no root
2. Which of the following statements are true :

(A) log2 3 < log9 8 (B) log4 3 < log6 8 (C) log3 8 < log2 5 (D) log4 15 > log3 10
3. The equation logx2 16 + log2x 64 = 3 has :

(A) two real solutions (B) one rational solution
(C) one integral solution (D) one irrational solution
4. The equation sin6 x + cos6 x = a2 has a real solution, if :

 1  1 1 1 
(A) a  (–1, 1) (B) a    1,   (C) a    ,  (D) a   , 1
 2   2 2 2  
5. Consider f(x) = 1  x 2 and g(x) = 1  1  x 2 . Let D f & Dg be domain of f(x) & g(x)
respectively and R f & R g be range of f(x) & g(x) respectively. Then :
(A) Df  Dg (B) Df  Dg (C) R f  R g (D) R f  R g
6. Let n1 be number of solutions of the equation (0.1)x  log0.1 x and n2 be number of solutions
of the equation (0.01)x  log0.01 x . Then :
(A) n1 = 1 (B) n1 = 3 (C) n2 = 1 (D) n2 = 3

Consider f(x) = 2 x 2 – 4 | x | 3 . Match the following :

Column –  Column – 
(I) Number of solutions of f(x) = 1, is (p) 2
(II) Number of solutions of f(x) = 2, is (q) 3
(III) Number of solutions of f(x) = 4, is (r) 4
(IV) Number of solutions of f(x) = 6, is (s) 6
(t) 8
7. Which of the following options is correct ?

(A) (I)  (t), (II)  (s) (B) (I)  (t), (III)  (p)
(C) (II)  (s), (III)  (p) (D) (III)  (q), (IV)  (q)

(A) (I)  (t), (III)  (q) (B) (II)  (r), (IV)  (q)
(C) (III)  (r), (IV)  (q) (D) (I)  (q), (IV)  (q)
Match the following :
Column –  Column – 
(I) Number of solution of sin2  + 3 cos  = 3 in [– , ], is (p) 0
(II) Number of solution of sin x tan 4x = cos x in (0, ), is (q) 1
2

(III) Number of solution of (1 – tan2 ) sec2  + 2tan = 0 in (   / 2,  / 2) , is (r) 2
If [sin x] + [ 2 cos x] = – 3, x  [0, 2], then [sin 2x] is equal to ([.]
(IV) (s) 4
denotes greatest integer function)
(t) 5

(A) (I)  (q), (II)  (r) (B) (II)  (t), (III)  (s)
(C) (I)  (t), (IV)  (p) (D) (III)  (r), (IV)  (p)

(A) (II)  (s), (IV)  (p) (B) (I)  (t), (II)  (t)
(C) (I)  (q), (IV)  (p) (D) (I)  (q), (III)  (r)

1. Let a, b, c, d are positive integers such that 2logab = 3 and 4logcd = 5. If (a – c) = 9, then
the value of (b – d) is :
4a 1
2. If  1 and a  is an odd integer, then number of possible values of 'a ' , is :
a2  1 a
2
 4x – 60
3. The sum of all real values of ' x ' satisfying the equation (x 2  5x  5)x = 1 is :
4. Let ,  ( –   2nn  ) are different values of  satisfying the equation

5k
5 cos  – 12 sin  = 11. If the value of sin ( + ) = – , then find the value of k.
169
 3   x
5. If x   ,  , then 4 cos2    + 4 sin4 x  sin2 2x is equal to :
 2  4 2
6. Find the number of integral values of , for which equation 4 cos x + 3 sin x = 2 + 1
has a solution.
5n  1  32n  1  23n  1
7. If L = lim , (n  N), then the value of L is equal to :
n  5n  1  3 2n 1  23n  1
 2 1 
8. If L = lim   , then the value of 8L is equal to :
x 1 1  x 2
 x  1 
FIITJEE
MONTHLY ASSESSMENT
PHYSICS, CHEMISTRY & MATHEMATICS
CM – TEST [BATCHES – 2325]
Answer Key
PHYSICS CHEMISTRY MATHEMATICS

(SECTION – I) (SECTION – II) (SECTION – III)
1. ABC P110301 1. ABC C110112 1. ABCD M112002
2. ACD P110302 2. ABD C110113 2. BC M112003
3. BCD P110308 3. A C110204 3. ABCD M112003
M111401,
4. BD P110309 4. ABD C110209 4. BD
M111403
5. BD P110905 5. D C111102 5. AC M112004
6. ABD P110207 6. B C111208 6. AD M112003
7. B P110304 7. A C110103 7. A M112002
8. C P110304 8. B C110103 8. C M112002
M111401,
9. A P110309 9. B C111101 9. B
M111403
M111401,
10. D P110309 10. C C111101 10. C
M111403
Numerical Value Numerical Value Numerical Value
1. 0 P110203 1. 8 C110107 1. 93 M112003
2. 14.7 P110301 2. 9 C110206 2. 2 M112001
3. 21.75 P110301 3. 2 C111204 3. 3 M112003
4. 1.5 P110302 4. 0.33 C111209 4. 24 M111401
5. 5 P110201 5. 6 C110202 5. 2 M111401
6. 3 P110203 6. 0.31 C110105 6. 6 M111403
7. 5 P110301 7. 0.41 C111207 7. 9 M112005
8. 6 P110313 8. 8 C111102 8. 4 M112005
Hints & Solutions
Physics
1. Distance travelled is always greater than the displacement of the particle.
1
2. u  2 m / s and a  m / s2
2
  1   1
3. s b, g  u b, g t  a b, g t 2 and s b, belt  u b, belt t  a b, belt t 2
2 2
10 
4.   120 and 120  v w, g  30
v A, W
5. Trajectory of one projectile w.r.t other projectile is straight line.


6.  a    a i    a  j    a  k
i ix iy iz
x2
7-8. yx
80
dy
tan    1    450
dx x 0
dy
For maximum height 0
dx
2x
1  0  x  40 m
80
Horizontal range x = 80 m
Speed of projection = 20 2 m / s
  
9-10. V b, g  V b, w  V w, g
Numerical Value
     
1. A, B and C must be coplanar, hence, A r B  C  
2. Let height of the bridge be h then
1
h  4.9  2   9.8   2 
2
2
 h = 9.8 m
Velocity with which the ball strikes the water surface
v = u + at
 v = 4.9 + 9.8  2 = 14.7 m/s
3. Distance covered by the car during the application of brakes by driver

 5 
s1  ut   54    0.2   15  0.2  3.0 meter
 18 
After applying the brakes; v = 0 u = 15 m/s, a = 6 m/s2 s2 = ?
225
Using v2 = u2 – 2as  0 = (15)2  2  6  s2  12 s2 = 225  s2   18.75 meter
12
So, total distance = 3 + 18.75 = 21.75
4. at t = 0 a = -1 m/s2
1 3
   v 2  2v  1  v  m / s
4 2
5. Use triangle law of vector addition.

  
6. a  b  ab sin , a.b  ab cos 
1
7. 500   25  2t   25  5t
2
12
8. tan370 
 u  10 
Chemistry
1. (A) 3p x ,3dxz have YZ common nodal plane

(B) 3p z ,3dyz have XY common nodal plane
(C) 3dxy ,3dxz have YZ common nodal plane
2. (A) Total nodal surface in 3s = 2

Total nodal surface in 3p = 2
(B) Angular nodle in 3p, cosθ = 0  θ = π/2
zr
(C) Let x
a0
4
Radial node in 3s: 6  4x  x 2  0
9
93 3 93 3
x  ,
2 2
2x
Radial node in 3p: 4  0 x6
3
Hence their radial nodes are not at equal distance
(D) It is a fact
3. The balanced equation is:

H2O  2AX  BY   2HA  YO  BX2
4. (A) Molar volume of ideal gas is 22.4 L

(B) Under critical conditions, Z = 3/8
(C) TB = a/Rb, Tc = 8a/27Rb
(D) At absolute 0 temp, K.E. of gas = 0
5. SO2  O3 
 SO3  O2
SO3  H2O  H2SO4
meq. Of NOH = 40  0.01 = 0.4 = meq. Of SO2
∴ mols of SO2 = (0.4  10-3)/2 = 2  10-4
= 2  10-4  22.4 L
= 4.48  10-3 L
∴ % of SO2 = [(4.48  10-3)/1]  100 = 0.448
6.
T-1 T-2
5  H2
10  O2
A B C
rH2 5 32 1 Vessel B Now in vessel B
    16 4 moles of H2 so moles of O2 rH2 4 32 rH2 8
rO2 10 2 2   
are
rH2 rO2 2 2 rO2 1
2 rH2 4
 rO2    2moles rH
rO2 1 2 2 so rO2  2
8
If vessel C has 1 mole H2 then
1
n O2   0.125
8
7 & 8.
(n2  n1 )(n2  n1  1)
Total number of emitted lines/photons =
2
When n2 = 2 to ∞, n1 = 1 then lines lie in Lyman series
When n2 = 3 to ∞, n1 = 2 then lines lie in Balmer series
1 1 1
 RH Z2  2  2 
  n1 n2 
9 & 10.
4M
 3Cu NO3 2  2NO  4H2O; EHNO3 
3Cu  8HNO3  (Redox reaction)
3
M
P4  3OH  3H2O 
 PH3  3H2PO2 ; EP4  (Redox & disproportionation reaction)
3
M
 SO 42  CO32  NO3 ; ENH4SCN
NH4 SCN   (Oxidation)
24
M
NH4NO2 
 N2  H2O; ENH4NO2  (Redox reaction)
3
Numerical Value
1. d8 – configuration have (4 + 3 + 2 + 1 + 2 + 1 = 13) exchanges
2. w solute  3 gm, w solution  75  25  50 gm
nOH 
3

x
,m5
 3 / 40  1 / 56   1000
40 56 47
x=9
Pb
3. Z  1 at high pressure
RT
dZ b 1 RT 22.4 273
  b  
dP RT 2.8 2.8 273 2.8
 4 
 4  NA  r 3 
 3 
 4  volume of 1 mol gas
5.6
∴ volume of 1 mol of gas molecules = 2
2.8
A 2B
4. PV  RT  
V V2
RT A 2B
P  
V V2 V3
dP
At critical point, 0
dV
dP RT 2A 6B
∴  2  3  4 0
dV V V V
RTV 2  2AV  6B  0
Discriminant(D) = 4A 2  4  RT  6B  0
A2 6B A3
TC  , VC  , PC 
6RB A 108B2
Pv 1
Z  C C   0.33
RTC 3
5. Mg  air 
 MgO Mg3N2
0.25mol 0.1 0.05
MgO 2HCl 
 MgCl2  H2O
0.1 mol 0.2 mol
Mg3N2  8HCl 
 3MgCl2  2NH4 Cl
0.05 0.4mol 0.1mol
NaOH
NH3
0.1 mol
∴ mass of Mg burnt = 0.25 × 24 gm
= 6 gm
6. For an electron
150 0
De-Broglie wavelength (  )= A
V
Where, V = Accelerating potential
150 0 150 0
According to question 1  A A
100 10
150 0
150 0
2  A A
100  19 9
150 0
150 0
3  A A
100  19  32 7
1 1

 3   2 7 9 20
    0.314746
1 1 63
10
7.
N2O4  g  2NO2
a 0 initial mols
ax 2x final mols
 total mass of mixture = 2.3 gm
2.3
2  3   a  x   92  2x  46  a 
92
PV = nRT
1
0.82   nR   a  x  2x   0.082
300
1 2.3 1 1
ax   x x
30 92 30 120
 PNO2 V   2x   RT
1
PNO2  2   0.082  300
120
 0.41 atm
80  0.2
8. moles of iodine = moles of chlorine = × 10–3 = 8 × 10–3
2
8  71 10 3
So, required % = × 100% = 8 %
7.1
Mathematics
1. Draw the graph of y = f(x) = |x + 1| – 2 |x – 1|.
2. log2 3 > 1, log9 8 < 1 log2 3 > log9 8

log4 3 < 1, log6 8 > 1 log4 3 < log6 8
log3 8 < 2, log2 5 > 2 log3 8 < log2 5
log4 15 < 2, log3 10 > 2 log4 15 < log3 10
3. logx2 16 + log2x 64 = 3  4 logx2 2 + 6 log2x 2 = 3

4 6 2 6
 + =3  + =3
log2 x 2 log2 2x log2 x 1  log2 x
Put log2 x = t
2 6
 + =3
t 1 t
t = –1/3, 2 log2 x = –1/3, 2 x = 2 1/3 , 4
4. sin6 x + cos6 x = a2 1 – 3 sin2 x cos2 x = a2  

 4 1– a2 = 3 sin2 2x
0  4 (1 – a2)  1 
 1–a 0 2 & 4 – 4a2 3
– 1 a 1 & a –1/2 or a  1/2
a    1,  1/ 2   1/ 2, 1
5. f(x) = 1  x 2 ; Domain = [–1, 1] and Range = [0, 1]
g(x) = 1  1  x 2 ; Domain = [–1, 1] and Range = [0, 1]
6. Draw the graphs.

7. & 8. Draw the graph of y = x 2 – 4 | x | 3 .
9. & 10. (I) sin2  + 3 cos  = 3 cos  = 1

(II) sin x tan 4x = cos x  sin 4x sin x – cos 4x cos x = 0  cos 5x = 0
(III) (1 – tan2 ) sec2  + 2tan  = 0  (1 – tan4 ) + 2tan  = 0
2 2
 2x = x2 – 1, where x = tan2 See the graph.
 (IV) [sin x] + [ 2 cos x] = – 3 [sin x] = – 1 and [ 2 cos x] = – 2. Hence, [sin 2x] = 0
Numerical Value
1. b2 = a3 = k  b = k1/2, a = k1/3 and d4 = c5 =   c = 1/5, d = 1/4

Now a – c = 9  k1/3 – 1/5 = 9
Let k1/3 = 25, 1/5 = 16  k = 253 = 56 and  = 165 = 220
 b = (56)1/2 = 125, d = (220)1/4 = 32
4 1
2. 1  2 – 4 + 1  0 + 4
2  1 
1 3 5
+ =3 2 – 3 + 1 = 0  =
 2
2
 4x  60
3. (x 2  5x  5)x 1
x2 – 5x + 5 = 1 x2 + 4x – 60 = 0 x2 – 5x + 5 = –1
x = 1, 4 x = – 10, 6 x = 2, 3 (x = 3 is not valid)
Hence, x = 1, 2, 4, 6, –10
4. 5 cos  – 12 sin  = 11  5 – 12 tan  = 11 sec 

25 + 144 tan2  – 120 tan  = 121 + 121 tan2 
120 96
23 tan2  – 120 tan  – 96 = 0 ; tan  + tan = , tan  tan  = –
23 23
120 120
tan ( +) =  sin ( + ) = –
119 169
 x  x
5. 4 cos2  –  + 4 sin4 x  4 sin2 x cos2 x = 4 cos2  –  + |2 sinx|
4 2 4 2
 x   
= 4 cos2  –  – 2 sin x = 2  1  cos  – x   – 2 sin x
4 2  2 
6. – 5  2 + 1  5  – 6  2 4  – 3  2
5n  1  3 2n  1  23n  1 5.5n  3.9n  2.8n 3

7. L = lim n 1 2n  1 3n  1
= lim = = 9
n  5 3 2 n  1 1 1 1/ 3
.5n  .9n  .8n
5 3 2
 2 1   2 1  2  (1  x) 1
8. L = lim   = lim    = lim = lim = 1/2
x 1 1  x2
 x  1  x  1 (1  x)(1  x)
 1 x  x  1 (1  x)(1  x) x  1 (1  x)

CM Test 1

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

CM Test 1

Uploaded by

Copyright:

Available Formats

FIITJEE – Phase Test (JEE-Advanced)

PHYSICS, CHEMISTRY & MATHEMATICS

Pattern - CPT-1 QP Code: PAPER - 1

Time Allotted: 3 Hours Maximum Marks: 180

B. Filling of OMR Sheet

C. Marking Scheme For All Two Parts.

Name of the Candidate: ________________________________________________

Batch: _________________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

1. Pick the correct statements:

4. Two swimmers A and B start swimming from different

6. The x-component of the resultant of several vectors –

PART – A: (MatrixMatch Type)

7. Which of the following option is correct:

8. Which of the following option is correct

space for rough work

9. Which of the following option is correct

10. Which of the following option is correct:

PART – C : Numerical Answer Type

space for rough work

2. A pebble is thrown vertically upwards from a bridge

7. The velocity-time graph of the particle moving along a straight line

space for rough work

2. The wave functions of 3s and 3pz orbitals are given by

From these we can conclude that

3. Consider the following redox reaction:

4. Which of the following statement(s) is/are incorrect?

PART – A: (MatrixMatch Type)

Match the following:

(iii) Transition from n = 5 to n = 2 (R) One of the emitted photon has

space for rough work

8. Which of the following is not correctly matched?

Match the following:

9. Which of the following is correctly matched?

10. Which of the following is not correctly matched?

space for rough work

PART – C : Numerical Answer Type

space for rough work

6. An electron practically at rest, is initially accelerated through a potential difference of 100

space for rough work

2. Which of the following statements are true :

3. The equation logx2 16 + log2x 64 = 3 has :

4. The equation sin6 x + cos6 x = a2 has a real solution, if :

space for rough work

PART – A: (MatrixMatch Type)

Consider f(x) = 2 x 2 – 4 | x | 3 . Match the following :

7. Which of the following options is correct ?

8. Which of the following options is correct ?

Match the following :

9. Which of the following options is correct ?

10. Which of the following options is correct ?

space for rough work

PART – C : Numerical Answer Type

4. Let ,  ( –   2nn  ) are different values of  satisfying the equation

space for rough work

PHYSICS CHEMISTRY MATHEMATICS

Hints & Solutions

1. Distance travelled is always greater than the displacement of the particle.

5. Trajectory of one projectile w.r.t other projectile is straight line.

3. Distance covered by the car during the application of brakes by driver

5. Use triangle law of vector addition.

1. (A) 3p x ,3dxz have YZ common nodal plane

2. (A) Total nodal surface in 3s = 2

Batch: _______ Date of Examination :_