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Physics SECTION – I
PART – A
Straight Objective Type
PART-A (01 – 04) Contains 04 Multiple Choice Questions which have Only One Correct answer. Each question
carries +3 marks for correct answer and –1 mark for wrong answer.
(A)
2M L I 0 (B)
MI 0
(C)
2M L I 0 (D)
M L I0
R R R R
4. A small ball thrown with an initial velocity u directed at an angle = 37° above the horizontal collides
inelastically (e = 1/4) with a vertical massive wall moving with a uniform horizontal velocity u/5
towards ball. After collision with the wall, the ball returns to the point from where it was thrown.
Neglect friction between ball and wall. The time t from beginning of motion of the ball till the
moment of its impact with the wall is (tan37° = 3/4)
3u 18u 54u 54u
(A) (B) (C) (D)
5g 25 g 125 g 25 g
PART-A (05 – 10) Contains 06 Multiple Choice Questions which have One or More Than One Correct answer.
Each question carries Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are)
darkened. Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened. Zero Marks: 0 If none of the bubbles is darkened. Negative Marks: -2 In all
other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will result
in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in -2
marks, as a wrong option is also darkened.
7. Charges Q1 and Q2 lie inside and outside respectively of a closed Gaussian surface S. Let E be the field
at any point on S and be the flux of E over S:
(A) If Q1 changes, both E and will change
(B) If Q2 changes E will change
(C) If Q1 0 and Q2 0 then E 0 but 0
(D) If Q1 0 and Q2 0 then E 0 but 0
9. Velocity and acceleration vector of a charged particle moving in a magnetic field at some instant are
v 3iˆ 4 ˆj and a 2iˆ xˆj . Select the correct alternative (s)
(A) x = -1.5
(B) x = 3
(C) magnetic field is along z-direction
(D) kinetic energy of the particle is constant
10. A wire is bent to form a semi-circle of radius a. The wire rotates about its B ×
× ×
one end with angular velocity . Axis of rotation being perpendicular to ×
plane of the semicircle. In the space, a uniform magnetic field of induction
B exists along the axis of rotation as shown in figure. Then
Q
P
(A) potential difference between P and Q is equal to 2Ba2.
(B) potential difference between P and Q is equal to 2 2 B a 2 .
(C) P is at higher potential than Q.
(D) P is at lower potential than Q.
PART-C (01 – 03) Contains 03 Numerical Based questions with Non-Negative Integer as answer, ranging from
0 to 9 and each question carries +4 marks for correct answer and no negative marking for wrong answer.
1. Two identical particles each having charge q =2mC are very m,q
v0
far apart. They are given velocity v0 = 2 m/s parallel to each
other such that initial perpendicular separation between d
m,q
them is d = 2mm. If the subsequent minimum separation
between them is 2d, find the loss in their total kinetic v0
energy. (in J)
40
2. A finite square grid, each link having resistance is fitted in a
21
resistance less conducting circular wire. Determine equivalent resistance B
between A and B. (in )
PART-C (04 – 09) Contains 06 Numerical based questions, the answer of which maybe positive or negative
numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +2 marks for
correct answer. If the numerical value has more than two decimal places, truncate/round-off the value to
TWO decimal places. There is no negative marking.
5. In the shown electrical network at t<0, key was placed on (1) till 1 2
the capacitor get fully charged. Key is placed on (2) at t=0.
Determine the time (in milli seconds) when the energy in both
capacitor and inductor will be same for the first time. E L
(Take: L = 4 mH, C = 40mF & π=3.14 ) C
a
9. In a series LCR circuit, the difference of the frequencies at which current amplitude falls to 1/ 2 of
R
the current amplitude at resonance is . Find the value of ‘k’. (Take: π=3.14 )
kL
Chemistry SECTION – II
PART – A
PART-A (01 – 04) Contains 04 Multiple Choice Questions which have Only One Correct answer. Each question
carries +3 marks for correct answer and –1 mark for wrong answer.
2. Pressure over an ideal binary liquid solution containing 10 moles each of liquid A and B is gradually
decreased isothermally. At what pressure, half of the total amount of liquid will get converted into
vapour? ( PA° =200torr, PB° =100torr ):
(A) 150 torr
(B) 166.5 torr
(C) 133.3 torr
(D) 141.4 torr
HO H
HBr
H3C
PBr3
S CH3
(A) (B)
HO H
H
H3C
TsCl, Py
3
NaN I equivalent
CH3
(C) (D) I I
(1) MeOH
(2) red P4 Br2
(3) NH excess ,
'P'
O O O 3 major
(4) H3O
COOH
NH 2
NH 2 HOOC COOH
(A) (B)
(C) NH 2 NH 2 (D) NH 2
PART-A (05 – 10) Contains 06 Multiple Choice Questions which have One or More Than One Correct answer.
Each question carries Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are)
darkened. Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened. Zero Marks: 0 If none of the bubbles is darkened. Negative Marks: -2 In all
other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will
result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in -
2 marks, as a wrong option is also darkened.
5. Which of the following is/are true about products ‘A’ and ‘B’
O
'A'+HCOO
HCHO excess
Ph OH -
7. Which of the following solutions are isotonic with 0.2 M NaCl ( = 1) solution at identical
temperature ( = degree of dissociation)
(A) 0.2 M MgCl2( = 0.5) solution.
(B) 18 gm Glucose present in 250 ml solutions.
(C) 0.5 mol of Al(NO3)3 ( = 0.4) present in 4 ltr. Solution
(D) 1 mol of AlCl3 ( = 0.2) present in 4 ltr. solution.
8. An unknown carbohydrate C12H22O11 reacts with Tollen’s reagent to form a silver mirror. An -
glycosidase has no effect on the carbohydrate, but a -galactosidase hydrolysis it to D-galactose and
D-mannose. When the carbohydrate is methylated (using CH3I and Ag2O) and then hydrolysed with
dilute HCl, the products are 2, 3, 4, 6-tetra-O-methylgalactose and 2, 3, 4-tri-O-methylmannose. The
structure for the carbohydrate is
HO
OH O
H O
(A)
HO OH
H CH 2 O
HO OH
OH
HO
H
HO
OH O
O
(B) H
HO OH
H CH 2 O
HO OH
H
HO
OH
HO
OH O
H OH
HO O
(C) H
CH 2 O
HO OH
OH
OH H
HO
OH O
H OCH 3
HO O
(D) H
CH 2 O
HO OH
OCH 3
OH H
10. Which of the following would give positive brown ring test (with no white ppt.)?
(A) Pb(NO3)2
(B) NaNO3
(C) Bi(NO3)3
(D) Ba(NO3)2
PART-C (01 – 03) Contains 03 Numerical Based questions with Non-Negative Integer as answer, ranging from
0 to 9 and each question carries +4 marks for correct answer and no negative marking for wrong answer.
1. One mole of a substance is cooled at the rate of 0.04 KJ/min as shown in the graph
800 A
B C
temp in K 400
100 D
5 10 40 50
time in minutes
As represent cooling of liquid, BC represent conversion of liquid to solid, CD represent cooling of
solid. The entropy of fusion is ………. J/mol/K
3. Calculate the pH at which the following conversion (reaction) will be at equilibrium in basic medium
I2 (s) I– (aq.) + IO3– (aq.)
When the equilibrium concentrations at 300 K are [I–] = 0.10 M and [ IO3– ] = 0.10 M.
{Given G f (I–, aq.) = – 50 KJ/mol,
G f ( IO3– , aq.) = – 123.5 KJ/mol,
G f (H2O, ) = – 233 KJ/mol
G f (OH–, aq.) = – 150 KJ/mol
25
R (Gas constant) = J/mol–K
3
Log e = 2.3}
4. The coagulation of 300 ml of a +ve collide took place when 0.5475 gm HCl was added to it without
changing the volume significantly. The flocculation value of HCl for the collide is.
5. A cube shaped crystal of a metal, 1.5 mm of an edge, was vapourised to 0.5 litre. Flask. The pressure
of vapours was 6.08 mm Hg at 727C. The structure solid metal is body centre cubic, if volume of
each unit cell of this Crystal is P × 1028 m3, then find the value of ‘P’?
R = 0.08 atm L/K-mol), NA = 6 × 1023.
8. How many grams of sucrose (M. wt. = 342) should be dissolved in 100 g water in order to produce a
solution with a 105.0°C difference between the freezing point and the boiling temperatures of the
solution? (Given: Kf = 1.86 C/m, Kb = 0.51°C/m)
9. MgAlx O y , is found in the Spinel structure in which O2– ions constitute CCP lattice, Mg2+ ions occupy
1/8
th
of the Tetrahedral voids and Al3+ ions occupy half of the Octahedral voids. Find the total +ve
electronic charge contained in one unit cell.
PART-A (01 – 04) Contains 04 Multiple Choice Questions which have Only One Correct answer. Each question
carries +3 marks for correct answer and –1 mark for wrong answer.
1. If one root is the square of the other root of the equation x2 + px + q = 0, then the relation between p
and q is
(A) p3 q(3p 1) + q2 = 0 (B) p3 q(3p + 1) + q2 = 0
(C) p3 + q(3p 1) + q2 = 0 (D) p3 + q(3p + 1) + q2 = 0
2. Consider f(x) = x3 + ax2 + bx + c. Parameters a, b, c are chosen, respectively, by throwing a die three
times. Then the probability that f(x) is an increasing function is
(A) 5/36 (B) 8/36
(C) 4/9 (D) 1/3
xcot 4x
4. lim is equals
x 0 sin2 xcot2 2x
(A) 2 (B) 0
(C) 4 (D) 1
PART-A (05 – 10) Contains 06 Multiple Choice Questions which have One or More Than One Correct answer.
Each question carries Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are)
darkened. Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened. Zero Marks: 0 If none of the bubbles is darkened. Negative Marks: -2 In all
other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will
result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in -
2 marks, as a wrong option is also darkened.
5. Let a, b, x and y be real numbers such that a – b = 1 and y ≠ 0. If the complex number z = x + iy
az b
satisfies Im = y, then which of the following is(are) possible value(s) of x?
z 1
(A) 1 1 y2 (B) 1 1 y2
(C) 1 1 y2 (D) 1 1 y2
6. If p and q are chosen randomly from the set {1, 2, 3, 4, 5, 6, 7, 8, 9, 10} with replacement, then the
probability that the roots of the equation x2 + px + q = 0
(A) are real is 33/50 (B) are imaginary is 19/50
(C) are real and equal is 3/50 (D) are real and distinct is 3/5
a 1 0
8. If f(x) = ax a 1 , then f(2x) f(x) is divisible by
ax 2 ax a
(A) x (B) a
(C) 2a + 3x (D) (D) x2
PART-C (01 – 03) Contains 03 Numerical Based questions with Non-Negative Integer as answer, ranging from
0 to 9 and each question carries +4 marks for correct answer and no negative marking for wrong answer.
5x 8 7x 6 1
1. If f(x) = x 2
1 2x 7
dx , (x 0), f(0) = 0 and f(1) =
K
, then the value of K is ______
2. The minimum number of times a fair coin needs to be tossed, so that the probability of getting
atleast two heads is atleast 0.96, is .............
3. Let A, B, C, D be real matrices such that AT = BCD; BT = CDA, CT = DAB and DT = ABC for the matrix S =
ABCD, the least value of k such that Sk = S is ..............
PART-C (04 – 09) Contains 06 Numerical based questions, the answer of which maybe positive or negative
numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +2 marks for
correct answer. If the numerical value has more than two decimal places, truncate/round-off the value to
TWO decimal places. There is no negative marking.
1
bounded by the tangent T, ellipse E, lines x = 1 and x = 5 is 5 + + cos1 , then | + +
5
| is equal to ________.
fx
2tdt
5. If f : R R is a differentiable function and f(2) = 6, then lim
x 2 x 2 is kf(2), then k is __________
6
10
K
2 10 2
6. If CK = 22000L, then L is equal to ________.
K 1
7. Let be a complex cube root of unity with 1. A fair die is thrown 3 times. If r1, r2 and r3 are the
number obtained on the die, then the probability that r 1 r 2 r 3 0 is a/b, then a + b is _____
8. The integral
sin2 x cos2 x 1
dx is equal to
C , then k3 is _________
sin x cos
2
5 3
x sin x sin x cos x cos x
2 3 2 5 k 1 tan x 3
9. A number is chosen at random from the set {1, 2, 3, ..., 2000}. Let p be the probability that the
chosen number is a multiple of 3 or a multiple of 7. Then, the value of 500 p is ______