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PHYSICS
1. A vernier caliper has 1 mm marks on the main scale. It has 20 equal divisions on the Vernier scale
which match with 16 main scale divisions. For this Vernier caliper, the least count is-
(A) 0.02 mm (B) 0.05 mm (C) 0.1 mm (D) 0.2 mm
2. A heavy uniform chain lies on a horizontal table-top. If the coefficient of friction between the chain and
table surface is 0.25, then the maximum fraction of length of the chain, that can hang over one edge of
the table is-
(A) 20% (B) 25% (C) 35% (D) 15%
3. A rough vertical board has an acceleration 'a' so that a 2 kg block pressing against it does not fall. The
coefficient of friction between the block and the board should be-
a
2 kg
(A) > g/a (B) < g/a (C) = g/a (D) > a/g
4. An intense stream of water of cross-sectional area A strikes a wall at an angle with the normal to the
wall and returns back elastically. If the density of water is and its velocity is v, then the force exerted
on the wall will be-
(A) 2 Av cos (B) 2Av2 cos (C) 2Av2 (D) 2Av
5. A particle of mass m moving with a velocity u makes an elastic one dimensional collision with a
stationary particle of mass m establishing a contact with it for extremely small time T. Their force of
contact increase from zero to F0 linearly in time T/4, remains constant for a further time T/2 and
decreases linearly from F0 to zero in further time T/4 as shown. The magnitude possessed by F0 is-
F
F0
t
O T/4 3T/4 T
mu 2mu 4mu 3mu
(A) (B) (C) (D)
T T 3T 4T
6. In a bicycle the radius of rear wheel is twice the radius of front wheel. If rF and rr are the radii, vF and vr
are speeds of top most points of front and rear wheel respectively, than-
(A) v r = 2 v F (B) v F = 2 v r (C) v F = v r (D) v F > v r
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7. A rod of length L and mass M is bent to form a semi-circular ring as shown in figure. The moment of
inertia about XY is-
X
9. A man holds an umbrella at 30° from vertical behind himself to avoid rain. He, then, runs at a speed of
10 ms–1 and finds the raindrops to be hitting vertically. Speed of the raindrops w.r.t. earth and w.r.t. the
running man are
30°
(A) 20 ms–1, 10 ms–1 (B) 10 ms–1,20 3 ms–1 (C) 10 3 ms −1 , 20 ms −1 (D) 20 ms–1,10 3 ms–1
10. A bird flies for 4 s with a velocity of v = | t − 2 | m / s in a straight line, where t is time in seconds. It
covers a distance of
11. One second after projection, a stone moves at an angle of 45°; two seconds after projection it moves
horizontally. Its angle of projection is (in degree):
(A) 60 (B) tan–1 (4) (C) tan–1 (3) (D) tan–1 (2)
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12. From the circular disc of radius 4 R two small disc of radius R cut off. The centre of mass of the new
structure will be :
y
R
x
4R
(A)
R ˆ ˆ
5
i+j( ) (B)
3R ˆ ˆ
15
−i + j ( ) R
(C) − iˆ + ˆj
5
( (D) − )
3R ˆ ˆ
14
i+j ( )
13. The potential energy of a body of mass M is :
U = ax + by
where x and y are position co-ordinates of the particle. The acceleration of the particle is:
(a + b2 )
1/ 2
(a + b)
2 1/ 2
a 2 + b2 a+b
(A) (B) (C) (D)
m m m m
14. Two satellites 1 and 2 orbiting with the time periods T1 and T2 , respectively, lie on the same line as
shown in figure. After what minimum time, again the satellites will remain on the same line? Assume
that the two satellites should lie in same side of the center of their concentric circular paths.
2
1
T1T2 TT T +T T −T
(A) T ' = (B) T ' = 1 2 (C) T ' = 1 2 (D) T ' = 1 2
T1 − T2 T1 + T2 T1T2 T1T2
15. A particle moving with kinetic energy K makes a head on elastic collision with an identical particle at
rest. Find the maximum elastic potential energy of the system during collision.
K K
(A) K (B) (C) (D) zero
2 4
16. The breaking stress of a material is 106 N/m2. If the density of the material is 3 × 103 kg/m3, what should
be the minimum length of the material so that is breaks by its own weight? (Take g = 10 m/s2)
(A) 0.33 m (B) 3.33 m (C) 33.3 m (D) none of these
17. Figure shows the vertical cross-section of a vessel filled with liquid of density ρ. The normal thrust per
unit area on the walls of the vessel at point P, as shown will be –
P
θ H
O Qh
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CHEMISTRY
18. The sodium salt of methyl orange has 7% sodium. What is the minimum molecular weight of the
compound? [Atomic mass of Na = 23]
If 3 mole of KI and 2 moles I2 are reacted with excess of HNO3, volume of NO2 gas evolved at STP is
(Molar volume of gas at STP is 22.4 L/mol)
(A) 739.2 L (B) 1075.2 L (C) 44.8 L (D) 67.2 L
20. With what velocity should an α-particle travel towards the nucleus of a copper atom so as to arrive at a
distance 10−13 m from the nucleus of the copper atom ? Atomic number of copper is 29. Mass of alpha
particle is 4 amu.
Ze 2 Ze 2 Ze 2 Ze 2
(A) + (B) + (C) + (D) +
8πε0 r 4πε 0 r 2πε 0 r 16πε0 r
(3) Stronger Lewis acid character of BF3 as compared to BCl3 is due to the presence of highly
electronegative fluorine atoms.
Which of the statements given above is / are correct?
(A) 2 and 3 (B) 3 only (C) 1 and 2 (D) 1 only
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24. Match List-I (Name of the Compound) with List-II (Structure / Geometry of the Molecule) and select
the correct answer using the codes given below the lists:
List-I List-II
(Name of the Compound) (Shape of the Molecule)
a. Chlorine trifluoride 1. Triangular planar
b. Boron trifluoride 2. Triangular pyramidal
c. Nitrogen trifluoride 3. T-shaped
d. Sulphur hexafluoride 4. Regular octahedral
Code:
A. B. C. D.
(A) 2 1 3 4
(B) 3 4 2 1
(C) 2 4 3 1
(D) 3 1 2 4
25. Choose the correct option for the following molecule in view of chemical bonding?
Cl H
C=C=C=C
H Cl
(A) non-planar (B) µ ≠ 0 (C) both (A) and (B) (D) None of these
26. Both N(SiH 3 )3 and NH(SiH 3 )2 compounds have trigonal planar skeleton. Incorrect statement about
both compounds is:
(B) N–Si bond length in NH(SiH 3 ) 2 > N–Si bond length in N(SiH 3 )3
(C) N–Si bond length in NH(SiH3 ) 2 < N–Si bond length in N(SiH 3 )3
(D) Back bonding strength of each "N–Si" back bond in NH(SiH 3 ) 2 > that in N(SiH 3 )3
(C) SF6 < PF5 < SiF4 : order of lewis acidic character
28. Aluminium reacts with an aqueous solution of sodium hydroxide to give hydrogen and
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29. Match the column I with column II and mark the appropriate choice.
Column I Column II
(A) (a) → (iii), (b) → (iv), (c) → (ii), (d) → (i) (B) (a) → (ii), (b) → (iv), (c) → (iii), (d) → (i)
(C) (a) → (i), (b) → (ii), (c) → (iv), (d) → (iii) (D) (a) → (iii), (b) → (ii), (c) → (i), (d) → (iv)
30. Two structures of H 2O 2 are shown below. Identify the phases X and Y of H 2O2 .
H H
95 pm 98.8 pm
147.5pm 145.8 pm
111.5° 90.2°
94.8° 101.9°
H H
(X) (Y)
(A) (X) is the structure of H 2O 2 in gas phase and (Y) in solid phase
OH OH HO O
Me
Ph O Me
H
O (1) O (2) (3)
(A) (1) > (2) > (3) (B) (1) < (2) < (3) (C) (1) > (2) < (3) (D) (1) < (2) > (3)
32. The IUPAC name of the following compound is
(A) 1-ethyl-2,2-dimethylcyclohexane
(B) 2,2-dimethyl-1-ethylcyclohexane
(C) 1,1-dimethyl-2-ethylcyclohexane
(D) 2-ethyl-1,1-dimethylcyclohexane
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33. Arrange the following carbocations in decreasing order of their stability.
CH3 CH3 CH3 +
CH2
+
(I) (II) (III) (IV)
+
+
(A) III > II > IV > I (B) I > II > IV > III (C) IV > III > I > II (D) I > III > II > IV
34. Five milliliter of 0.1M Pb(NO3)2 is mixed with 10 mL of 0.02 M KI. The amount of PbI2 precipitated
will be: 67-(b)
(A) 10–3 mol (B) 10–4 mol (C) 2×10–4 mol (D) 4×10–3 mol
MATHEMATICS
35. If a cos 2 3α + b cos 4 α = 16cos6 α + 9cos 2 α is an identity, then
(A) a = 1, b = 24 (B) a = 3, b = 24 (C) a = 4, b = 2 (D) a = 7, b = 18
36. The area of the triangle on the Argand plane formed by the points −z, iz, z − iz, is
1 2 2 3 2
(A) z (B) z (C) z (D) None of these
2 2
1 1 2
37. If α, β be the roots of x 2 − a ( x − 1) + b = 0 , then the value of + + is
2
α − aα 2
β − aβ a+b
4 1
(A) (B) (C) 0 (D) None of these
a+b a+b
(C) ( abc )
2/3
(A) 1 (B) abc (D) abc
n
α
45. If α and β are the roots of the equation x 2 − 2x + 2 = 0 , then the least value of n for which = 1 is
β
(A) 2 (B) 5 (C) 4 (D) 3
46. {
Let S = x ∈ R : x ≥ 0 and 2 x −3 + x ( ) }
x − 6 + 6 = 0 . Then, S
α2 + 1
47. x − ( x − ( cos α + sin α ) ) ≥ 0 , α > 0
α
α2 + 1 α2 + 1
(A) x ≤ cos α − sin α or x ≥ (B) x ≤ − cos α + sin α or x ≥
α α
α2 + 1 α2 + 1
(C) x ≤ − cos α − sin α or x ≥ (D) x ≤ cos α + sin α or x ≥
α α
48. If O be the origin and if the co-ordinates of any two points Q1 & Q 2 be ( x1 , y1 ) & ( x 2 , y 2 ) respectively,
(A) x1x 2 − y1y 2 (B) x1y1 − x 2 y 2 (C) x1x 2 + y1y 2 (D) x1y1 + x 2 y 2
a 1 + a 2 + ... + a p p2 a6
49. Let a 1 , a 2 , a 3 ,.... be terms of an AP. If = , p ≠ q then is equal to
a 1 + a 2 + ... + a q q2 a 21
11 41 7 2
(A) (B) (C) (D)
41 11 2 7
50. Let U be the universal set containing 700 elements. If A, B are subsets of U such that n ( A ) = 200,
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CLASS 11th MATH MOVING TO CLASS 12th MATH
ANSWER KEY
SET - A
PHYSICS 14. (A) 26. (B) 38. (B)
1. (D) 15. (B) 27. (C) 39. (C)
2. (A) 16. (C) 28. (C) 40. (A)
3. (A) 17. (B)
29. (D) 41. (A)
4. (B) CHEMISTRY 30. (A) 42. (D)
5. (C) 18. (C) 31. (A) 43. (D)
6. (C) 19. (A) 32. (D) 44. (C)
7. (A) 20. (C) 33. (A) 45. (C)
8. (C)
21. (A) 34. (B) 46. (C)
9. (D)
22. (B) 47. (D)
10. (B) MATHEMATICS
23. (C) 48. (C)
11. (D) 35. (A)
24. (D) 49. (A)
12. (D) 36. (C)
13. (A) 25. (D) 50. (C)
37. (C)
20 VSD = 16 MSD
1 VSD = 0.8 MSD
Least count = MSD – VSD = 1 mm –0.8 mm = 0.2 mm.
2. (A)
µ 0.25 l
l' = l = l = = 20% of l .
µ + 1 0.25 + 1 5
3. (A)
For the limiting condition upward friction force between board and block will balance the weight of the block.
i.e. F > mg
F
R
m ma
mg
⇒ µ ( R ) > mg
⇒ µ ( ma ) > mg
g
⇒µ>
a
4. (B)
Linear momentum of water striking per second to the wall Pi = mv = Avρ v = Av 2 ρ , similarly linear momentum
of reflected water per second Pr = Av 2 ρ .
Now making components of momentum along x-axis and y-axis.
Y
Pi
Pr cosθ θ Pi cosθ
X
Pr θ
Pr sinθ
Pr sinθ
Change in momentum of water per second = Pi cos θ + Pr cos θ = 2 Av 2 ρ cos θ
By definition of force, force exerted on the Wall = 2 Av2 ρ cos θ.
5. (C)
Change in momentum = Impulse = Area under force-time graph
∴ mv = Area of trapezium
r
r v re
v rm
10. (B)
The velocity time graph for given problem is shown in the figure.
2
v(m/s)
4
0
2 t (sec)
Distance travelled S = Area under curve = 2 + 2 = 4 m
11. (D)
The direction of motion of projectile at the instant t is
v y u sin α − gt
tan θ = =
vx u cos α
What t = 1, θ = 45°; hence u sin α – g = u cos α
X cm = =
2
(
x1A1 − x 2 A 2 − x 3A3 0 π16R − 3R πR − 0
2
)
=−
3R ( )
A1 − A 2 − A 3 16πR − πR − πR
2 2 2
14
Similarly
3R
y cm = −
14
r
Scm = X cm ˆi + ycm ˆi = −
3R ˆ ˆ
14
( )
i+ j
13. (A)
dU dU
Fx = − =− a and Fy = − =− b
dx dy
Net force, F − = Fx2 + Fy2 = a 2 + b 2
F a 2 + b2
∴ Acceleration = =
m m
14. (A)
t 2
2
1
1
O t=0
Let the satellites 1 and 2 describe angles 1 and 2 at the center of earth during a time t, respectively. Suppose 2
is ahead of 1 by an angle . We can write
= 2 − 1
They will be again lie on same line after a minimum time T ′ say. For this = 2 . This gives 2 − 1 = 2 .
Dividing T ′ both sides,
2 1 2
We have − =
T′ T′ T′
2 1
Substituting = 2 and = 1 , we have
T′ T′
2 2
= 2 − 1 where 2 =
T′ T2
2
and 1 = .
T1
1 1 1
Then, = −
T ′ T2 T1
TT
This gives T ′ = 1 2
T1 − T2
15. (B)
When both particles collide, momentum will be conserved.
A B
m m v0/2
Velocity of A will decrease and B will increase and till the time both masses have same velocity elastic potential
energy will increase and after that it will decrease and kinetic energy will become zero. At the instant when
v
potential energy is maximum, their velocity will be same (which will be o )
2
2 2
1 1 v 1 v
0 + mv02 = m 0 + m 0 + P.E.
2 2 2 2 2
1 1
P.E. = mv02 = K
4 2
16. (C)
Weight mg ALρg
Breaking stress, S = = = = Lρg
area A A
S 106
L= = = 33.3m
ρg (3 × 103 ) × 10
17. (B)
liquid pressure is always normal to the surface Hence thrust per unit area at point P = (H – h) ρg.
CHEMISTRY
18. (C)
23 7
Let the Molar mass of sodium salt of methyl orange is M. Then =
M 100
19. (A)
2KI + I 2 + 22HNO3 → 2HIO3 + 2KIO3 + 22NO 2 + 10H 2O
3 moles 2 moles
22
KI is L.R. ⇒ moles of NO2 formed = × 3 = 33moles
2
Volume at NTP = 33×22.4 = 739.2L
20. (C)
1 q ⋅q 2q1 ⋅ q 2
For the distance of closest approach, mv 2 = 1 2 or v =
2 ( 4πε0 ) r ( 4πε0 ) mr
(9 × 109 ) × 2 × (2 × 1.6 × 10−19 ) × (29 × 1.6 × 10−19 )
= = 6.35 × 106 m / s
(4 × 1.66 × 10−27 ) × 10−13
21. (A)
1 1 1 Ze 2 Ze 2
K.E. = − (P.E.) = − − . =
2 2 4πε 0 r 8πε0 r
22. (B)
At radial node | ψ | = 0
x2 – 8x + 12 = 0 ⇒ (x – 6) (x – 2) = 0
2r
when x – 2 = 0 ⇒ x =2 ⇒ = 2, i.e., r = a 0 (Middle value)
a0
2r
when x – 6 = 0 ⇒ x = 6 ⇒ = 6 ⇒ r = 3a0 (Maximum)
a0
23. (C)
In BF3, there is back bonding from Fluorine to Boron and hence it’s weaker lewis acid. Also when
Nitrogen from sigma coordinate bond with boron in the adduct, then the pie coordinate bond between
Fluorine to Boron is broken.
24. (D)
F .. F
: F F F
N
F Cl F B S
: F F
F F F F F
F
Triangular planer Pyramidal Octahedral
T - shaped
25. (D)
Cl H
C C C C
H Cl
Hence, µ = 0
26. (B)
In NH(SiH 3 ) 2 electron density or lone pair at N-atom is involved in back bonding only with two empty
3d-orbitals of two silicon atoms while in N(SiH 3 )3 it is involved with three empty 3d-orbitals of three
silicon atoms. Strength of back bonding in NH(SiH 3 ) 2 is higher than in N(SiH 3 )3 hence, N–Si bond
length in NH(SiH 3 ) 2 is less than that of in N(SiH 3 )3 .
27. (C)
Correct order of Lewis acidic character: SiF4 > PF5 > SF6 . Although, S has vacant 3d-orbitals but it
cannot accept co-ordinate bond from Lewis base due to steric crowding factor as S-atom is already
bonded to six F-atom.
28. (C)
29. (D)
30. (A)
31. (A)
As the number of resonating structure of conjugate base increases, the acidic strength increases.
32. (D)
2-Ethyl-1,1-dimethylcyclohexane
6 1
2
5 3
4
33. (A)
Number of alpha hydrogen : (III)>(II)> (IV). (I) is least stable because bridge head carbon canot be sp2
hybridised.
34. (B)
MATHEMATICS
35. (A)
( )
2
⇒ 9cos2 α + 16cos6 α = a 4cos3 α − 3cos α + b cos 4 α
Above is an identity, so
a = 1, b − 24 = 0
a = 1, b = 24
36. (C)
Let z = x + iy , then coordinates in ordered pair of the points corresponding to the complex numbers
−z,iz and z − iz are ( − x, − y ) , ( − y, x ) and ( x + y, y − x ) , respectively. Hence area of triangle
−x −y 1 −x − y 1
1 1
= −y x 1 = −y x 1
2 2
x+y y−x 1 0 0 3
R 3 → R 3 + ( R1 + R 2 )
3
2
3
2
( 3 2
−x 2 − y2 = x 2 + y 2 = z
2
)
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37. (C)
⇒ α 2 − aα + a + b = 0 and β 2 − aβ + a + b + 0
∴α 2 − aα = β2 − aβ = −a − b
1 1 2 1 1 2
Now, + + = + + =0
2
α − aα 2
β − aβ a + b − (a + b) − (a + b) a + b
38. (B)
x + x − 1− x =1
⇒ x − 1− x =1− x
⇒ x − 1− x =1+ x − 2 x
⇒ − 1− x =1− 2 x
⇒ 1 − x = 1 + 4x − 4 x
⇒ 4 x = 5x
16
∴x = or 0 .
25
16
Now x = 0 does not satisfy but x = satisfies the equation.
25
39. (C)
m ( m − 1)
n = m C2 =
2
n ( n − 1) m ( m − 1) m ( m − 1)
∴ n C2 = = − 1
2 2.2 2
1
(
= m ( m − 1) m 2 − m − 2
8
)
1
= m ( m − 1)( m + 1)( m − 2 )
8
( m + 1) m ( m − 1)( m − 2 ) m +1
= 3 = 3. C4
4!
40. (A)
7!
Total ways without restriction = = 1260
2!2!
Number of ways when R’s come together
6!
= A [R R ] A N G E = = 360
2!
∴ Required number of ways = 1260 − 360 = 900
(a + b) + (c + d )
We get ( a + b )( c + d ) ≤
2
2
⇒ M≤ ⇒ M ≤1
2
Also, a, b, c, d are positive. Therefore
M = ( a + b )( c + d ) > 0
∴0 < M ≤ 1
42. (D)
y = − x is Q ( −b, −a )
4sin 3 θ 4cos3 θ
+ = 4 ( cos θ − sin θ )
1 + cos θ 1 − sin θ
or 4sin θ (1 − cos θ ) + 4cos θ (1 + sin θ ) = 4cos θ − 4sin θ
or sin θ = 0 ⇒ θ = nπ
For θ = ( 2m + 1) π, 1 + cos θ = 0
45. (C)
Given, α and β are the roots of the quadratic equation, x 2 − 2x + 2 = 0
2
⇒ ( x − 1) + 1 = 0
2
⇒ ( x − 1) = −1
⇒ x − 1 = ± i [where i = −1]
⇒ x = (1 + i ) or (1 − i )
Clearly, if α = 1 + i , then β = 1 − i
n
α
According to the question = 1
β
n
1+ i
⇒ =1
1− i
n
(1 + i )(1 + i )
⇒ = 1 [by rationalization]
(1 − i )(1 + i )
n
1 + i2 + 2i 2i
n
⇒ = 1 ⇒ = 1 ⇒ in = 1
1 − i2 2
So, minimum value of n is 4. Q i4 = 1
46. (C)
We have 2 x − 3 + x ( )
x −6 +6 = 0
Let x −3 = y
⇒ x = y+3
∴ 2 y + ( y + 3)( y − 3) + 6 = 0
⇒ 2 y + y2 − 3 = 0
2
⇒ y + 2 y −3 = 0
⇒ ( y + 3)( y − 1) = 0
⇒ y ≠ −3 ⇒ y = 1
⇒ y = ±1 ⇒ x − 3 = ±1
⇒ x = 4, 2 ⇒ x = 16, 4
47. (D)
For α > 0 using AM ≥ GM
Q2(x2,y2)
O(0,0)
( )
Q n A / ∩ B/ = n ( A ∪ B )
/
= n ( U ) − n ( A ∩ B)
n ( A ∪ B) = n ( A ) + n ( B) − n ( A ∩ B)
( )
Hence, n A / ∩ B/ = n ( U ) − n ( A ∪ B ) = 700 − 400 = 300
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