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Innovative Project Kamini Sharma Mommamad Ewaz Gopal Mohan
Innovative Project Kamini Sharma Mommamad Ewaz Gopal Mohan
GEOLOGY
Most of the known lithium minerals are found in coarsely
Geochemistry and Mineralogy crystalline granites known as lithium-cesium-tantalum (LCT)
pegmatites. In terms of lithium resources, the most important
minerals are spodumene and petalite (both lithium aluminium
In most geologic settings, Lithium is found only as a trace
silicates) and the pink mica lepidolite (potassium lithium
element, measured in parts per million (ppm). Earth’s mantle
aluminium silicate). The main lithium mineral in sedimentary
contains 1.6 ppm lithium and the oceanic crust contains 4.3 rocks is the clay hectorite [55]. More information on lithium
ppm [55]. The upper continental crust (that is, rocks typically minerals is provided in Table 1
at Earth’s surface on land) contains an average of 20 ppm
lithium [55]; at this abundance, lithium ranks about 30th Lithium is extremely soluble. During weathering of rocks, it tends
among the elements, behind copper but ahead of lead, tin, and to be removed in solution and carried to the sea by rivers. Thus,
silver. lithium would be expected to have built up in the oceans in the
Lithium is classed as a large-ion lithophile element: as a same way that a build-up of sodium has made the oceans salty.
cooling magma starts to crystallize minerals, lithium stays in Yet, remarkably, seawater contains less than 1 ppm lithium. The
the remaining melt until near the end. Active plate tectonics likely explanation is that seawater lithium is scavenged in trace
over Earth’s history have concentrated lithium in the quantities by clay minerals and accumulates in sea-floor oozes
continental crust through the partial melting of the mantle [55].
beneath mid-ocean ridges and volcanic arcs. The melt, or
Deposit Types Present and potential sources of lithium worldwide
magma, rises and then cools to become new rock in Earth’s
are broken down by deposit type, as follows: closed-basin brines,
crust, bringing much of the available lithium with it.
58 percent; pegmatites (including lithium-enriched granites), 26
Among the common rock or sediment types, the highest percent; lithium-clays (hectorite), 7 percent; and oilfield brines,
lithium concentrations are in shales (which average 66 ppm), geothermal brines, and lithium-zeolites (jadarite), 3 percent each
deep-sea clays (which average 57 ppm), and low-calcium [55].
granites (which average 40 ppm) [55]. These trace
concentrations are insufficient for an ore deposit or even for Lithium-Cesium-Tantalum Pegmatite Deposits
the formation of minerals in which lithium is part of the
chemical formula. When present only in trace concentrations Granitic pegmatites are igneous rocks distinguished by an
such as these, lithium atoms substitute for other metals extremely coarse but variable grain size and by other unique
(typically magnesium) in common rock-forming minerals. textures, particularly what are known as graphic intergrowths [55].
Lithium minerals form only when rare combinations of Pegmatites are composed primarily of the major minerals in
favorable factors line up [55]. granite, namely quartz, albite (sodium feldspar), potassium
feldspar, and the white mica muscovite, plus smaller amounts of
. garnet, tourmaline, biotite, and apatite. In addition to the lithium
minerals petalite, lepidolite, and spodumene,
Fig, 1 Schematic cross section showing the concentric arrangement of lithium-cesium-tantalum (LCT) pegmatites (small purple, blue, and green
bodies) around a parental granite pluton. In this model, common pegmatites form near the parent, whereas pegmatites with enrichments in
incompatible elements (indicated by chemical symbols) and corresponding rare minerals form farther away [55] Be, beryllium; Cs, cesium; Li,
lithium; Nb, niobium; Rb, rubidium; Sn, tin; Ta, tantalum [55].
LCT pegmatites may contain the cesium ore mineral, pollucite; Pegmatite deposits or districts. Bradley and McCauley [55] and
the tantalum ore mineral, columbite tantalite; the beryllium ore Bradley and others [55] have summarized tectonic factors in
mineral, beryl; and the tin ore mineral, cassiterite. pegmatite genesis. LCT pegmatites are found in the metamorphic-
LCT pegmatites may also yield gemstones and high-value igneous hinterlands of orogenic belts and are a consequence of
museum specimens of rare minerals. Gemstones include the plate convergence.
beryl varieties aquamarine, emerald, and heliodor; the lithium Most LCT pegmatites formed during collision between continents
bearing tourmaline variety elbaite (“watermelon tourmaline”); or microcontinents and are associated with Aluminium-rich
and the spodumene varieties hiddenite, kunzite, and triphane. granites that originated by melting of metamorphosed sedimentary
LCT pegmatites are also mined for feldspars, muscovite, and rocks. On a regional scale, LCT pegmatites tend to occur in
ultrapure quartz. The diversity of mineral species in the most districts alongside fertile granites, with the highest concentration
complex LCT pegmatites is impressive; at the Tanco deposit in of lithium and other incompatible elements in the more distal
Manitoba, Canada, for example, 105 minerals have been pegmatites (fig. 1). Individual pegmatites take various shapes,
identified [55]. LCT pegmatites are famous among geologists ranging from tabular dikes and sills to irregular bodies.
and mineral collectors for their huge crystals.
The largest spodumene crystal yet found is 14 meters (m) long Lithium-Enriched Granites
(from South Dakota) the largest beryl crystal, 18 m; and the
largest potassium feldspar crystal, 49 m [55]These finds are all Some muscovite-bearing granites include zones that are enriched
the more remarkable because pegmatites are believed to have in the elements such as lithium, tantalum, tin, and fluorine. At the
crystallized in a matter of days to years [55]. Yichun Mine in Jiangxi Province, China, the top of a biotite-
The main producers of lithium from pegmatites are Australia, muscovite granite grades into muscovite granite and then into
Brazil, China, Portugal, and Zimbabwe. The world has lepidolite granite, which has been mined for lithium and tantalum
hundreds of known deposits and some of these (for example, in [56]. Lithium-enriched granites are closely related to LCT
Quebec, Canada) contain large reserves of lithium that have pegmatites, and the two have not been distinguished from one
not been mined. another in recent global assessments of lithium resources [57,56] .
Kesler and others [55] estimated lithium resources for 20 of the
world’s most important
Karnataka’s Mandya district [Figure 2 and 3]. The data provided a
total estimation of available Li2O as about 30,300 tonnes over an
Exploration for Lithium-Cesium-Tantalum Pegmatite Deposits area of 0.5 km x 5 km, which works out to about 14,100 tonnes of
lithium metal.
The search for new LCT pegmatite districts begins with the
knowledge that all LCT pegmatites were emplaced into Also, recent core drilling in a small area of 30 m X 440 m at
orogenic belts [55]. The global age distribution provides a Marlagala has led to an estimated 1,600 t of Li with an average
first-order filter in the search for new LCT pegmatites in grade of 0.246 wt%, [57,58,59].
unexplored regions. The potential for giant deposits seems So, our aim was to validate the deposit presence by the help of
greatest in Archean (2,500 Ma and older) collision zones. Most Remote sensing and GIS to map out the relevant Lithology-Rock
LCT pegmatites intruded metamorphosed sedimentary rocks, types, Structure Lineaments, and Geobotanical metal anomalies
typically at conditions of medium pressure and medium to high using Geological, Geophysical and Remote sensing satellite data
temperatures (greenschist to amphibolite facies) [55]. New to demarcate the areas with presence of Lithium deposit or its
deposits are likely to be found within a few kilometres of a direct and indirect indicators. Using the provided information we
“fertile” granite, which generally are large enough (typically chose an Area of Interest (AOI) of 692 Km2 shown in the Figure3.
several square kilometres in area) to be known already from
routine geologic mapping. Fertile granites are identified by the
presence of distinctive minerals, such as muscovite,
tourmaline, and garnet; by anomalously high concentrations of
such trace elements as cesium, lithium, rubidium, tin, and
tantalum; and by low concentrations of the major elements
calcium, iron, and magnesium [55] Around a fertile granite, the
more distal LCT pegmatites are
more likely to be enriched in lithium (Fig. 1). Weathering of
LCT pegmatites can result in both soil anomalies and indicator
minerals. Smith and others [55] demonstrated that arsenic,
beryllium, antimony, and tin form a 12-by-20-km halo in
lateritic soils around the Greenbushes pegmatite; niobium,
tantalum, and boron form a smaller, 1-by-5-km halo.
Cassiterite, tantalite, elbaite, and spessartine are sufficiently
dense and durable to serve as heavy indicator minerals for
lithium that can be found by panning unconsolidated
sediments.
Fig 3- Satellite Image of the Areas (red rectangle) and Points (yellow
pins) of Interest. Source- Google Earth Engine.
The dataset used in the study was acquired from Bhuvan portal of
Geological Survey of India and Earth Explorer website of United
States Geological Survey. Bhuvan portal was used to download
various vector shape files of AOI depicting Lithology,
Mineralization, related abandoned and active quarry, Lineaments
and its types such as faults, fractures, folds types, major rivers and
ponds. Magnetic and Gravity anomaly point data of AOI was also
acquired from Bhuvan.
Earth Explorer website was used to acquired Landsat 8 collection
Fig. 2 Map showing study area.[56] 2 level 2 OLI/TIRS satellite imagery of the study area. Image of
November month, of year 2018 was selected as then most of the
land was covered with vegetation which was used to create
II. STUDY AREA
stressed vegetation anomaly map of the AOI.
Software used was ArcMap of ArcGIS suite to overlay and
In the Year 2020, the researchers at the Atomic Minerals manipulate the data and create final maps.
Directorate, a unit of India's Atomic Energy Commission,
estimated India’s first lithium reserves of 14,100 tonnes in a
IV. METHODOLOGY AND RESULTS
small patch of land surveyed in the southern Karnataka district,
according to a paper in journal Current Science [57,58,59]. The
survey showed presence of 1,600 tonnes of lithium resources To create layers depicting suitable areas of Mineral deposit
in the igneous rocks of the Marlagalla-Allapatna region of presence, we created five maps of Lithology, Structure, Gravity
anomaly, Magnetic anomaly, and Geobotanical anomaly. The Out of these rocks Igneous intrusions such Pegmatites, Granites
details and relevance of each type is mentioned as follows; along with surrounding Amphibolite and meta-igneous and
A. Lithological Map sedimentary country rocks have potential to host Hydrothermal
Lithium mineralization [55]. Extent and spatial position of these
The Rock types of the study area are mostly of Archean and rock types can be accessed through this lithological map.
Paleoproterozoic age. The area is part of West Dharwar Craton
comprising Dharwar Subgroup and Peninsular Gneissic
complex. It consist of rocks of Kibbanahalli formation of
Bababudan group and Karighatta formation of Sargur group,
Main lithologies in these formations are Granite Gneiss,
Granitoid, Migmatite Gneiss, Fuchsite kyanite quartzite,
Garnet-Staurolite-Kyanite-Muscovite Quartzite, Amphibolite,
Banded Iron Formation, Banded Magnetite Quartzite,
Limestone, Meta-Pyroxenite, Garnet Mica schist, Meta-
Ultramafite, Acidic Intrusives such as Felsite, Quartz veins,
Pegmatites and Basic Intrusives such as Dolerite.[Fig.4]
Fig. 4 -Lithological map of the study area showing various rock types, presence of mineralization commodity and area of active and
abandoned quarries.
.
B. Structural Map
structural/Lineament belts, shear zones, faults, fractures,
The Structures can govern; (a) the distribution of metallogenic contacts, folds, joints or intersections of specific
provinces within orogenic belts or platforms, (b) the distribution structural/lineament features is important in planning mineral
of ore-bearing regions and fields within the metallogenic exploration strategy[61].
provinces and (c) the localization of ore deposits in a particular In our study area we delineated many major and minor
ore field [60]. lineaments [Fig 5] by creating their map in ArcGIS software, a
Remote sensing data on suitable scales can throw valuable light fault/fracture density map can be created by using this structural
on the relationship of global, mega, and minor structural features map. Association of Lineaments with drainage and other surface
with mineral deposits. Deduction of information regarding water bodies reveals more about the tectonic geology of the
localization of mineral deposits by certain types of geological terrain.[61]
Fig. 5 -Structural map of the study area showing various major and minor lineaments such as fracture, Joint, fault, fold and its type.
C. Magnetic Anomaly Map with mineralisation.[62] Here we had magnetic anomaly
point data, which was used as a input to create a continuous
Magnetic anomaly patterns [Fig. 6] can be used as a tool for interpolation surface using statistical Natural Neighbour
mapping lithology, metamorphic zones and hydrothermal Interpolation technique depicting areas of high or low
alteration systems, as well as identifying structures that may magnetic susceptibility associated with metalliferous rock
control passage of magmas or hydrothermal fluids associated type or mineralization.
Fig. 6 -Magnetic Anomaly Map of the study area showing areas of high or low magnetism in rocks, points represents the coordinates
where magnetic anomaly was observed.
D. Gravity Anomaly Map mineralization can be identified by gravity anomaly as they’ll have
Here, we had point data of gravity anomalies which we used to
Bouguer anomaly maps are used to identify additional potential create a gravity anomaly map using Natural Neighbor Interpolation
areas of mineralization [63]. Gravity maps show areas with high in ArcGIS.
density bedrocks and large dense intrusive bodies (E.g.-
Granites) as such areas locally have observed gravity value
higher than the surroundings. Thus, the source rock of lithium
Fig. 6 -Gravity Anomaly Map of the study area showing areas of high or low gravity/density in rocks, points represents the coordinates
where gravity anomaly was observed.
E. Geobotanical Anomaly Map This idea has been used since the early stage of satellite remote
sensing, and change in reflectance spectra of plants with metal
Vegetation stress is known to be caused by absorption of any absorption (particularly heavy metal) has been investigated [64].
metal type, which manifests as physiological declines in This absorption induces vegetation stress by interfering with
growth rate, photosynthetic activity, and chlorophyll content chlorophyll activity and inhibiting water suction from soils and
[64] However, the magnitude of stress, which manifests as water supply to leaves. The wavelength ranges from visible to
change in reflectance spectra, varies with metal and vegetation near infrared (VNIR; 400–1400 nm),
type [64].