CHAPTER PRACTICE PROBLEMS PHENOL Predict the products (A), (B), @) C,Hon—s i each of the following sequence (A) Sse (@)_te_(¢) (0) CAH = CH, ea (A) an BO (0) BE (©) CHOH— wate (A) — B20 9/8)" 4(0) ©) cHonS8222 (4) Stason == 4(8)+(6) (e) on (Cons Sat (A) 352 (8) — ® 8 *(A) r+ (B) 23" (6) (g) OCH, 3S 9(a) tase ae 7) (1) C.H,OH3E (A) (8) (¢)_™ (0) oO CH, Ox 2g (4) (0) 0) CH (m) C,H,NH, —pese0->(A)—80-4(B) ® oe 12 (0) 48340 (0) rot (A) KE (g)__ Hates (P) C4H, Pe >(A) MS @ ON. th sem (4) +(C) (*) CyHLOH—SiE2 (A) (8) 9 yor ” ow Ni ions (q) ma (@) 2 5(0)APTER PRACTICE PROBLEMS: (CHEMISTRY) ive mechanism forthe following transformations: (@) OH ) oH Bu,cH=cn, oH Give reasons forthe following: tile but both m ~ and p—nitrophenols are not {a) o-Nitropenol is steam — volat {hy Phenol fs more acidic than eylohexanol but less acidic chan benzoic acid 1 and highly activating in electephilic aromatic {6 The OHI group in phenol is ortho, para ~ directing substitution reactions. (@ 2146 Tenitrophenol iberates CO: from NaHHCOs but phenol does nok {© Reaction of phenol with H.SO, at 60°C gives mainly o ~ hydroxypenzenesulphonic tives mainly p— hydroxybenzenesulphonic acid with alkyl halides in presence of anhydrous AICI; is unsatisfactory (0) Friedel ~ Crafts alkylation of pheno! {@) Cyclfenanol reacts with HBr to give cyclohexyl bromide but phenol doesnot reat XOX OK OXF id but at 100°C