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  • Phenol 1

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    Atharva Ganju
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    Phenol 1 (1)

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    14 views6 pages

    Phenol 1

    Uploaded by

    Atharva Ganju

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
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    (CHEMISTRY) Phenol is treated with exce: (A) 4~ bromophenol (C) a mixture of 2~ and 4 bromophenois of bromine water at room temperature. (8) 2, 4 - dibromophenol (0) 2, 4, 6 - tribromophenol Phenol on treatment with dilute HN (A) 2, 4, 6 - tinitrophenol (©) 4-nitrophenol 10s at room temperature yields: (8) 2-nitrophenol (0) a mixture of 2- and 4 ~ nitrophenols, Preno| is Prepared industrially by heating chlorobenzene with aqueous NaOH at 360°C under hig pressure: z CHCl+ NaOH Em 0 4 op The reaction involves (A) Sxl mechanism (8) $2 mechanism (C) benzyne mechanism {Dy addition elimination mechenism Benzenediazonium chloride on heating with water yields mainly (A) phenol (8) chlorobenzene {(Q) benzyl alcohot (D) benzene Sodium benzenesulphonate is fused with solid NaOH and then acidified with dilute H»S0,, ‘The product formed is (A) 3-hydroxybenzenesulhonie acid (B) phenol (C) thiophenot (D) benzene Consider the following sequence of reactions that yields phenacetin, an analgesic and antipyretic drug fa O~ (A) 36) No» ‘The structure of phenacetin (C) is (a) 9cocH, 2 Paracetamol, an antipyretic drug is prepared by acetylation of p ~ aminophenol with one equivales of acetic anhydride in the presence of pyridine: On 242_+(¢)(phenacetin) OCH,CHy (DB) 9CHCHy (BOW co) ( ) “coc, NM, Nricoch, NHICOCH, b +(CHCo,0—= > NH ‘The structure of paracetamol is UIZ __ (CHEMISTRY) When phenol is treated with a solution of Br, in CS; at 0°C, the major Pet emedig (a) OH (8) SH cn oH (0) SH Br Or & Br Among the compounds: oH OH OH a) E : : ~No, 0 O NO, Be CHy OCH 0 o aw ow ‘The order of acidity is (A)MI>M>V>IV>1 B)>i>t>Iv>Vv (C) > V>ll>Iv>1 (D)t>Ml>Vv>vior Which of the following does not possess a carboxy group? (A) Salicylic acid (B) Anthranilic acid (C) Picric acid _(D) o-Toluic acid When phenol is heated with chloroform and aqueous NaOH and subsequently acidified, the majo: product formed is (A) p-hydroxybenzaldehyde (B) salicyladehyde (C) salicylic acid (D)_ benzaldehyde Phenol is heated with phtalic anhydride in the presence concentrated H2SOs. The product formed is, (A) salicylic acid (8) p-hydroxybenzenesulphonic acid (C) phenolphthalein (0) fuorescein Consider the following reaction: OH + (CH,CO),C-oHM22 The major product formed is (A) O6(CHols (BR) OH © oH (D) Ochs O o™ O oO (CH), Sou For the reaction sequence OH OCH GEES (A) 2 (8) [Ine asterk epresents “C] ‘The end product (B) is OH (B) OH © ocH, och UIZ © Grco—8 cH, (CHEMISTRY) ( * ntaorcr)d ocr, 15. Sodium phenoxide is heated with CO, und. e. The resulting is acidified with dilute HCI. The product formed is mainly 2 under pressure, The resulting (A) salicylic acid We se ciae (C) 4-hydroxybenzoie acid {Dy tyronybonzldehy de 16, Aspirin an analgesic drugs, is obtained by acetylation of (A) 2-aminobenzoie acid z {B) 2-hydroxybenzoie acid (C) 2-hydroxybenzenesulphonic acid {D) 2-aminobenzenesulphonic acid 17. Consider the following sequence of reaction: Cots BIES3-(A) (8) +(0) The product (B) and (C) are @ OH ®) ‘and CHsCHOHCH, «© CH(CHs)2 Oo and CHsCOCHs 18, 2-Phenoxyethanol, CstOCH:CH;OH is heated with an excess of concentrated hydrobromic acid. ‘Ie product obtained are (a) (B) Br and HOCH,CH,Br OH and BrCH,CH,OH © (D) Br and CH,CH,Br OH and BrCH,CH,8r 19. For the reaction: C,H,OCH,CH = CHCH, "<> ‘The product obtained is (A) oil © oH OF and CH3COCH, ‘and CH,CHOHCH,OH ich of the following reacts with both Nat1CO; and NaOH? Oo 8) oo” © 4 oH (D) NO» 2, 24, 26. 2B. UIZ Which of the following reagents is not able to distinguish between phenol and (A) Aqueous NaOH (B) Aqueous FeCl; (C) Metalic sodium (D) Aqueous Bra (CHEMISTRY) ethanol? ier te following sequence of reactions san (A) —s>(B)| major product) ‘The product (B) is (a) OCOCH, ® OH oO OL © Oe ) OCHs Hyco © - IL ° Benzyl phenyl ether, CcH;OCH,CiHs is heated with hydriodie acid, The products obtained are ” ©-» and Or 7 Or and © cH,oH c ° On Om ° Oroe(O)o Bakelite is condensation copolymer of (A) phenol and acetaldehyde (B) urea and formaldehyde (©) phenol and formaldehyde (D) aniline and benzaldehyde From a mixture of o ~ and p — nitrophenols the components are usually separated by (A) fractional crystallization (B) chromatography (©) fractional distillation |_£B) steam disilation Consider the following sequence of reactions: OH Onn CHy ‘The product (B) is (A) OH Got (CH,COOH ‘CHOHCOOH CH (9H Hs Fi on ie Hy Which of the following is the most acidic? oe... OC" F 28. Which ofthe following reactions will not result in the formation of anisole? (A) C,H,0H + (CH, }, 80, "> (B) C,H,0H+ CHI (C) G.H,OH+CH.N, —> (D) C,H,OH+CH.Mgl—> = 29, Salicyelic acid is treated with excess of bromine water. The product formed is “ Br @) Br on OH Br er ‘COOH itrophenol (II) and p-nitrophenol (IV) is 30. The order of increasing boiling points of ethanol (1), phenol (Il), 0~ (A)II

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