CONFI

DENTI
AL* 2 SET296
2/1STPM 201
9

SECTI 5mar
ONA[1 ks]

Ans
weral
lques
tions

1 Wh
i c
hofth
efol
lowi
ngi
onswi
llbedef
lec
tedmos
tinamas
sspec
tromet
er?
35 +
A Cl
37 +
B Cl
C 35Cl+
2
35 37 +
D ClCl

2 Wh
ichoft
hef
oll
owi
ngi
onsc
ont
ainsh
alf
-fi
ll
edd-
orbi
tal
s?
A Mn+
2+
B Cr
C Fe2+
D Cu+

3 Wh
ichoft
hef
oll
owi
ngc
ont
ains3unpai
redel
ect
rons?
3+
A Cr ,Al3+,
Cu2+
3+
B Cr ,Al3+
C Al3+,
Cu2+
3+
D Cr

Whi
chofth
efol
lowi
ngwi
llnotf
ormah
ydr
ogenbondwi
thanot
herofi
tsown
4
mol
ecul
e?
A CH3OH
B CH3CHO
C CH3NH2
D CH3COOH

5 Whichofthefoll
owingstatementsiscorr
ec t?
A anyc ovalentc ompoundst hatcontainbothh y
drog
enandox y
genini
ts
molecul
e
canf or
mh ydrogenbond
B ac oval
entmol ecul
ec annotbeanelec t
roly
te
Cc omparedt oioniccompounds, c
oval
entc ompoundsar
egener
all
ymore
sol
ublein
polarsolvent

96
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AL*
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DENTI
AL* 3 SET296
2/1STPM 201
9

Dioni
ccompoundscanbedi
sti
ngui
shedf
rommet
alsbyt
hei
rel
ect
ric
al
c
onduc
tiv
ity
i
nthesoli
dandli
qui
dstat
es

6 Wh
ichoft
hef
oll
owi
ngmol
ecul
esh
ast
hes
mal
les
tbondang
les?
A H2O
B BF3
C NH3
D BeCl
2

Wh
ichoneoft
hefol
lowi
ngg
ass
ampl
esc
ont
ainst
heg
reat
estnumberofmol
es
7
?
A 50dm3at1at
mand400K
B 40dm3at2at
mand5
00K
C 30dm3at3at
mand6
00K
D 20dm3at4at
mand700K

Graph
itecanbeus
edasal
ubr
icantbutdi
amondc
annot
.Th
isi
sbec
aus
e
8
gr
aphit
ehas
A mobileions
B del
ocal
isedel
ect
rons
C ah
exag
onalar
rang
ementofat
omsi
nth
elay
ers
Dv
anderWaal
sfor
cesbet
weent
hel
ayer
sofat
oms

96
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DENTI
AL*
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DENTI
AL* 4 SET296
2/1STPM 201
9

9 Whi
chgraphwouldconf
irmthatt
herateofdecomposi
tionofh
ydr
ogen
per
oxi
dei sf
irs
torderwit
hrespectt
oh y
drogenper
oxide?
A
Rateofdec
ompos
iti
onof
[H2O2]

[
H2O2]

Rateofdec
ompos
iti
onof
[H2O2]

[
H2O2]

Rateofdec
ompos
iti
onof
[H2O2]

[
H2O2]
D

Rateofdec
ompos
iti
onof
[H2O2]

96
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DENTI
AL*
 CONFI
DENTI
AL* 5 SET296
2/1STPM 201
9

[
H2O2]

1
0 Inthereacti
onP+Q→ R+S, t
herateequationi
sfoundexper
imentall
yt obe
Rate=k[P]
Ifthequanti
tyofQwasaddedtoalarg
eex cessofP,whi
chofthef
ollowing
graphsshowingt
hech
angeinthec
oncentrat
ionofQwi t
htime,
isli
kelytobe
correc
t?
A
[
Q]

t
ime

[
Q]

t
ime

C
[
Q]

t
ime

[
Q]

96
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DENTI
AL*
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DENTI
AL* 6 SET296
2/1STPM 201
9

t
ime

1
1 Wh
ichofthef
ollowi
ngistrueabouttheef
fec
tofacat
aly
st?
AItaffec
tstheposit
ionofequil
ibr
iuminarev
ers
ibl
ereac
tion
BI
taf
fec
tst
heent
hal
pyc
hang
eofar
eac
tion
CI
tinc
reas
est
her
ateoff
orwar
dreac
tion
DI
tinc
reas
est
heequi
li
bri
umc
ons
tantf
ort
hef
orwar
dreac
tion

1
2 Forwh
ichequi
li
bri
umdoesKch
avenouni
t?
A C(s)+H2O(g) CO(g)+H2(g
)
B Cu2+( 2+
aq) +4NH3(
aq) [Cu(
NH3)
4] ( aq)
C N2O4(
g) 2NO2(
g)

D CH3OH(
l)+CH3CO2H(
l) CH3CO2CH3(
l)+H2O(
l)

1
3 Whati
sthepHoft
hesolut
ionfor
medwhen5 m3of0.
0c 50moldm-3s
ulph
uri
c
3 -
3
ac
idisaddedt
o50cm of0.5
0moldm sodi
umh y
drox
ide?
A 0.6 B 1.
2
C 7.
0 D 1
3.4

1
4 Thesolubil
it
yproductsofs i
lverchlori
deands i
lverchromat
e(VI)at298Kar
e
asfoll
ows:
0-10mol2
Ksp(AgCl) =1 .
0x1 dm-6
0 moldm-9
-
12 3
Ksp(Ag2CrO4)=2.
5x1
Whichofthefol
lowings tatementsi snottrue?
A Additi
onofhydrochloricaciddec reasesthesolubi
li
tyofsi
lverchl
ori
de
B Additionofaqueoussodiumc hl
oridedecreasesthesolubi
lit
yofs il
ver
c
hloride
CAddi tionofaqueousammoni aincreasesthesolubi
li
tybothofs i
lver
c
hlorideand
sil
verc hr
omate(VI)
D Additionofsil
verni
trateint
oas olut
ioncont
ainingequalconcentrati
onsof
c h
lorideandc hr
omateionspr eci
pitatesawhitesoli
dfirst

1
5 Anaqueouss ol
uti
oncont
ai ngX2+i
ni onsformsaprec ipi
tatewh enanaqueous
sol
uti
onofs odiumhy
droxideisaddedtoit.
Thesolubili
tyofthepreci
pitat
eis
0-3g
dm-3andi 0-11mol3
9.
86x1 t
ssolubil
itypr
oductis1.
96x1 dm-9at25ºC.What

96
2/1 CONFI
DENTI
AL*
 CONFI
DENTI
AL* 7 SET296
2/1STPM 201
9

i
sth
erel
ati
vemol
ecul
armas
soft
hepr
eci
pit
ate?
A 31
.3 B 5
8.0
C 74.
0 D 99.
4

Sec
tionB[ 15marks]
Ans
weral lques
tionsi
nthiss
ect
ion.

1
6 Th
etabl
esh
owst
heph
ysi
calpr
oper
tiesofas
ubs
t eP.
anc

St
age Tr
ipl
epoi
nt Cri
tical
point
Temper at
ure 0.
01 374.1
°
(C)
Press
ur e(atm) 0.
006 218.
3
(
a)Bas
edont heabovedat
a,sket
chandl
abelth
eph
asedi
agr
amoft
hes
ubstanc
e
P.
[2marks]

(
b)Sug
ges
tac
hemi
calc
ompoundt
hath
asas
imi
larpat
ter
n. [
1mar
k]

…………………………………………………………………………

(c)Ex
plai
nth
eanomal
ousbeh
avi
ouroft
hes
ubs
t eP.
anc [
2
mar
ks]

……………………………………………………………………………………….
.

……………………………………………………………………………………….
.
.

(d)Atthesamediag
ramin(
a),
sket
chadi
agr
amt
osh
owt
heef
fec
tof
g
luc
ose
di
ssolv
esint
hesubst eP.
anc [
1mar
k]

96
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DENTI
AL*
 CONFI
DENTI
AL* 8 SET296
2/1STPM 201
9

17 Ex per
imentwereconduct
edtostudyt
her
ateofr
eac
tionr
epr
esent
edbyt
he
equat
ionbelow:
2NO(
g)+2H2(g)N2(g
)+2H2O(g)
I
nit
ialc
onc
ent
rat
ionsandr
atesofr
eac
tionar
egi
veni
nth
etabl
ebel
ow.
Ex
per
iment I
nit
ialConc
ent
rat
ion(
mol
dm I
nit
ialr
ateoff
ormat
ionofN2
-
3
) moldm-3mi
( n-1)
[
NO] [
H2]
1 0.
006
0 0.
001
0 1
. 0-4
80x1
2 0.
006
0 0.
0020 3.
6 0-4
0x1
3 0.
001
0 0.
006
0 0. 0-4
30x1
4 0.
0020 0.
006
0 1
. 0-4
20x1

(a) (i) Determineth

eorderofreac
tionforeachoft
her
eac
tant
s,NO
andH2fromt
hedat
ag i
venanddesr
ibeyouranswer. [4
marks
]

Or
derwi
thr
espec
ttoNO:
…………………………………………
Or
derwi
thr
espec
ttoH2:
………………………………………….
.

96
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DENTI
AL*
 CONFI
DENTI
AL* 9 SET296
2/1STPM 201
9

(
ii) Wr
itet
heov
eral
lrat
elawf
ort
her
eac
tion. [
1
mar
k]
………………………………………………………………………………….
.
(
b) Cal
cul
atet
hev
alueoft
her
atec
ons
tant
,kf
ort
her
eac
tioni
ncl
udi
ng
t
heuni
ts.
[
2mar
ks]

(
c) Forex
per
iment2,
cal
cul
atet
hec
onc
ent
rat
ionofNOr
emai
ningwh
en
ex
act
lyone-
hal
foft
heor
igi
nalamountofH2h
adbeenc
ons
umed.
[
2mar
ks]

Sec
ti 30mar
onC[ ks
]
Ans
wera
nytwoquest
ionsi
nthiss
ect
ion.

18( a)Themas
sspect
rum(
noti
nsc
ale)ofanal
coh
olwi
tht
hemol
ecul
arf
ormul
a
ofC3H8Oi
ssh
ownbel
ow.

(
i) Giv
et wopos
sibl
eionst
hatar
eres
pons
ibl
eforeac
hoft
hepeaks
wi
thmas
s43and45.
[
4marks]

(
ii) Sug
ges
tth
est
ruc
tur
alf
ormul
aoft
heal
coh
ol.
Giv
ear
eas
onf
ory
our
sug
gesti
on. [4
marks
]

(
iii
)Wh
ats
pec
iesi
sres
pons
ibl
efort
hepeakatmas
s61? [
1mar
k]

96
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DENTI
AL*
 CONFI
DENTI
AL* 1
0 SET296
2/1STPM 201
9

(b)Accordi
ngt oBohr
’satomicpostul
ates,t
heexit
edelec
tronswi
llf
allback
t
othelowerenergylevel
sbyemi tti
ngas pecif
icamountofenergyandproduc
ing
s
eri
esofli
nes.
Byus i
ngtheenerg
yl eveldi
agr
am,

(i
)drawthet
ransi
tionofelec
trons
(th
efi
rstt
hreel
ines
)th
atr
esul
ti
ng
i
nthef
ormat
ionofLymans
eriesandBalmerseri
es. [2
mar
ks]

(
ii)i
dent
ifyt
hel
inewh
ichh
ast
hel
ong
estwav
eleng
th. [
1mar
ks]

(c)Theactualelect
roni
cconfi
gurati
onofCus howirreg
ularit
yaspr
edi
ctedby
Auf
bauPri
ncipl
e.Explai
ntheseanomalouselec
troni
cc onf
igur
ations.
[3mar
ks]

1
9( a)St
ateandexpl
ainhowther
ateconstantk1andk-1oft
hef
orwar
dandbac
kwar
d
r
eacti
onsandth
eequil
ibri
umconst
antKC,
, oft
hereac t
ion

H2(g) +I
2(g
) 2HI(g
); ∆H=Pos
iti
ve
wouldc
hange,i
fatal l,
(i
) int h
epres enceofac at
alyst
, [4
mar
ks](i
i) wit
haninc reas
ei nt
emper at
ur e. [
4mar
ks]

°
(b)Whenonemolofhydr
ogeni
odi
dei
nav
ess
elofv
olume1
.0dm3i
sst
oredat444C,
i
tis22%dec
omposed.
Calcul
ate

(i
)th
eequili
bri
umcons tantforreac
tion [
3
mar
ks]
2HI
(g
) H2(g) +I2(
g),

(i
i)thenumberofmolesofhydr
ogeniodideformedatequi
li
bri
um whentwo
mol
es
°
ofhy
drogenandonemol
eiodinear
eh eatedat444Cinavess
elofvolume
10dm3.
. [4marks]

20(
a)Propan-1-
olhasaboili
ngpointof .Waterhasaboi
li
ngpointof .
Propan-
1-olandwaterf
ormanaz eotropicmixt
ureatboi
li
ngpoint wi
tha
composit
ionof72%propan-1-
oland28%wat erbymass.
(i
)Wh atismeantbyazeotropi
cmixture? [1marks]
(i
i)Sketchaboili
ngpoint
-composi
ti
ondi agramforpr
opan-1
-olandwat
er.
[3

96
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DENTI
AL*
 CONFI
DENTI
AL* 1
1 SET296
2/1STPM 201
9

mar
ks]
(i
ii
)Bas edont hesketc
hin(a)(i
i),
expl
ainwh
athappenswhentheprocessof
frac
tionaldist
ill
ati
oniscarri
edoutonamix
tureofpropan-
1-olandwater
t
hat
contains50%ofpropan-
1-olbymass. [7marks]

(b)Stateandexpl
ainwh
ath
appenswh
ens
oli
dsi
lverc
hlor
idei
ssh
akenwit
h
aqueous
potassi
umiodi
de. [
4marks
]
[Ksp:AgCl= ]

96
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DENTI
AL*