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A Hybrid Modeling for the Real-time Control and

Optimization of Compressors
Xudong Ding1,2, Lei Jia Wenjian Cai, Changyun Wen Guiqing Zhang
1 2
School of Control Science and School of Electrical and Electronic School of Information and Electrical
Engineering Engineering Engineering
Shandong University Nanyang Technological University Shandong Jianzhu University
Jinan 250061, China Singapore 639798, Singapore Jinan 250101, China
e-mail:xdding@ntu.edu.sg e-mail:ewjcai@ntu.edu.sg e-mail:qqzhang@sdjzu.edu.cn

Abstract—This paper proposes a hybrid compressor model In the open literatures, most of them are found in the
for the purpose control and optimization of vapor compression International Compressor Engineering Conference at Purdue,
systems. Unlike those existing models, this model is determined and most of them are related to compressor performance,
by only the inlet and outlet conditions of compressor without internal leakage, multi staged designs, and scroll wrap designs.
requiring detailed geometric specifications, and only the variables Among the consulted studies, the models are divided into three
responsible to the system performance, which can be measured wide classes: black-box models, theoretical models and hybrid
and controlled, are selected as the input/output (I/O) of the models.
models. The model is derived based on the concept of volumetric
efficiency and the assumption of a polytropic compression The black-box models [1-3] are typically represented by
process. The unknown empirical parameters of the model are some equations, which numerically relate the output of the
identified by the nonlinear least squares methods. The system of interest (e.g. cooling capacity or energy demand) to
effectiveness of the proposed model is validated by the the influential input (e.g. operating conditions). The required
compressor catalogs data obtained from the manufactures. output is the dependent variables and the input is the
Results show that the model is accurate and robust and gives a independent variables of the mathematical function, which is to
better match to the real performances of compressors over the be derived by curve-fitting the function to a set of known
entire operating range than the existing models. This model is output/input data. For the model development, there is less
expected to have wide applications in real time control and emphasis on the theoretical derivation of equations and more
optimization of vapor compression systems.
on the processing and manipulating of the plant data. This is
Index Terms—Compressor, Hybrid model, I/O Selection,
particularly beneficial when there is a lack of knowledge
Parameter identifications, Least squares methods. required to form the equations and determine plant parameters
but there is an abundance of process data. Obviously,
I. INTRODUCTION application of such a model is subject to restrictions, e.g. it
cannot reflect the effects of any factors the influence of which
Compressors are widely employed in food processing,
was omitted in the model derivation; and the predictions will be
chemical and air conditioning/refrigeration industries, but
unreliable when the model is applied to situations outside the
consume large amounts of energy every year. A feature of
set of conditions based upon which is was derived.
these systems operation is that the ambient temperature and the
thermal load from the heat source are likely to vary The theoretical models are derived based on the physical
considerably. This requires that the inlet and delivery pressures laws that govern the processes taking place in the system and
for the compressor vary with the operation conditions to sustain the state of the working substances within and crossing the
a sound condensing temperature at the condenser and a sound system boundary. Hiller and Glicksman [4] reported a detailed
evaporating temperature at the evaporator, respectively, so as to compressor model of reciprocating compressors and compared
improve energy efficiency of the systems. Since the the simulation results with experimental data. Duffy [5]
compressor is run by engine, it must operate under a wide developed a computer model of centrifugal compressor which
range of rotating speeds, affecting its refrigerating capacity. is capable of calculating the steady state operation of one or
Recent advances in variable-speed drive technology offer several compressors operating in any combination of series and
tremendous opportunities for improving energy efficiency and parallel operation. Schein et al. [6] developed a computer
machine reliability in industry systems. The compressor speed model in Visual Basic which predicts the power, capacity, and
can be continually adjusted so as to modulate the heat efficiencies of a scroll compressor for given operating
exchanger capacity to match the actual thermal load. As a conditions and scroll designs. Tian et al. [7,8] developed
result, compressor capacity modulation becomes an essential mathematical models of variable displacement wobble plate
part of these systems operation. Hence, a simple, reliable, yet compressor and variable displacement swash plate compressor,
accurate model which can predict the performance of operating respectively. The models were obtained by combining with the
compressor is of significant importance for performance three sub-models of control mechanism, moving components
simulation, optimization and control. dynamics and compression process. There are merits and
limitation of using this approach. Since the predictions of such
However, since the fact of this field is technologically and
models bear physical meaning, it is easier to detect modeling
production oriented, and strongly influenced by competition,
errors, input errors (e.g. unrealistic boundary conditions) or
there are only a few published papers for compressor modeling.

978-1-4244-2800-7/09/$25.00 ©2009 IEEE 3256 ICIEA 2009


problems with the number solution processes (e.g. divergence In the present study, to satisfy the requirements of the
in iterative calculations) by examining if the values of the actual engineering practice, only the variables that can easily be
model outputs are reasonable or physically possible, which is measured and controlled are to be selected as the
especially important to debugging of the model during the Inputs/Outputs of the model, as illustrated in Figure 1. There
development stage. However, for complex compressors, such are four input variables to the compressor model: discharge
models can be rather complicated and often require input of a pressure, Pdisc , inlet temperature, Tin , suction pressure, Psuct ,
large set of parameters for description of the physical exit temperature, Tout , shell temperature, Tshell , and
characteristics of the compressor. This, in turn, can limit their
application, as the required information can be difficult to compressor speed, RPM . The output variables from the
obtain. compressor model are mass flow rate, m , and compressor
power, Powerelec , respectively. Since we model the steady-
The hybrid models (or named as semi-empirical models)
are obtained based on thermodynamic principles, but the state compressor, the inlet mass flow rate and the outlet flow
unknown parameters are identified using a large data base. rate are equal; namely, m  in = m out = m .
Popovic et al. [9] presented a semi-empirical model of the
positive displacement reciprocating compressor using this Pdisc
method. The model needs data on pressure, temperature, mass Psuct m out
flow rates, at the compressor inlet and the outlet and power Tout
m in
input. The model took into account the energy transactions that Powerelec
occur between compressor and its surroundings. Dagmar [10] Tin Tshell
developed a similar model for the domestic refrigerator/freezer RPM
compressor to reliably interpolate and/or extrapolate Fig. 1. Compressor conceptualization
experimental compressor data. The model can be used to The following is a simple description for the refrigerant
estimate the refrigerant mass flow rate and power using as few compression process of a reciprocating compressor. Refrigerant
as four experimental data points. Unfortunately, such models vapor at low pressure and temperature enters the compressor
are only suitable for the type of reciprocating compressor and a shell through suction line and is heated as it cools the motor
universal model is lack. and other parts, and mixes with hot plenum gas along the
The goal of this study is to find a model that can predict the refrigerant suction path. After compression in the cylinder, high
performance of a compressor (i.e. the mass flow rate or temperature and pressure refrigerant gas discharges through a
capacity and the electrical power input) for a range of operating muffler, rejecting heat to the plenum gas before exiting via the
conditions. The first step of modeling is to derive an discharge line.
appropriate formulation from the energy and material balance, The compressor model includes two more features related
and thermodynamic principles. After a mathematical to the capacity control in the real-time optimization application.
expression for the model has been determined, the unknown The first is related to mass flow rate evaluation; and the second
parameters in the model equation can be evaluated by nonlinear is related to the evaluation of the actual power input. In the
least squares methods in which attempt is made to minimize the following section, we firstly develop the theoretical models of
total error between the model predictions and the known compressors based on the concept of volumetric efficiency and
operating data. The merit of the model is that it takes the assumption of a polytropic compression process.
advantages of both physical and empirical modeling
approaches and can accurately predict performance in wide A. The mass flow rate
operating range and in real-time, which can significantly The concept of the volumetric efficiency is widely used to
reduce the computational burden and increase the prediction calculate the mass flow rate of a compressor [9]. The
accuracy. The model is verified with the experimental data volumetric efficiency ηv is defined as the mass of vapor that is
taken from the compressor catalogs data obtained from the
manufactures. The results show that the model can achieve actually pumped divided by the mass of vapor that the
accurate performance estimation over the entire operation compressor could pump if it could handle the total piston
range. displacement at the suction state. It is given by the following
equation:
II. THEORETICAL MODEL AND DESCRIPTION
⎡ 1

A detailed thermodynamic model of a compressor is ⎢ ⎛ Pdisc ⎞ n ⎥ vsuct
ηv = 1 + C − C ⋅ ⎜ ⎟ ⋅ (1)
extremely complex due to the inherently complicated structure ⎢ Psuct ⎠ ⎥ vb
⎢⎣ ⎝
of the compressor and refrigerant flow pathways, along which ⎦⎥
heat transfer and pressure vary substantially and rapidly. For where C is the clearance volume ratio, n is the ploytropic
some applications (e.g. design of variable-speed drives) such exponent, vsuct and vb are the specific volume of the working
detailed modeling is necessary. However, our hypothesis is that
fluid in suction line conditions and in the cylinder after the
the requirements for optimization of operating compressor are
intake, respectively.
much less demanding, so a steady-state model which can
reflect the influence of the basic operating variables on the The volumetric efficiency can also be expressed in terms of
compressor performance is enough. mass flow rate m and displacement volume V . It is the mass
flow rate that is actually pumped divided by the mass of the

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working fluid if the entire piston displacement volume were Win n 1
⎡ n −1 n −1

filled with the working fluid at the suction conditions. Powerin = =  n ⎢ P2 n − P1 n ⎥
mK (10)
t n −1 ⎣ ⎦
m ⋅ vs uct If the heat transfer between the working fluid and
ηv = (2)
V ⋅ RPM compressor casing at the inlet and outlet of the compressor is
where RPM is the compressor motor speed. considering, the energy obtained by the working fluid includes
the absorbed heat at compressor inlet and the rejected heat at
Combining equations (1) and (2) leads to the following the compressor outlet and can be represented by
expression for the mass flow rate.
QWF = Powerin + Qin − Qout (11)
⎡ 1
⎤ V ⋅ RPM
m = ⎢1 + C − C ⋅ ( Pdisc Psuct ) n ⎥ (3) where Qin and Qout are the heat transfer rate of the compressor
⎣ ⎦ vb
at the inlet and the outlet, respectively. The principal modes of
For the given compressor, it is reasonable to assume that heat transfer considered inside the compressor casing are
the value of clearance volume ratio C and the displacement conduction and convection. The conduction heat transfer is
volume V remain constant. Moreover, if the fact that the state expressed as
of the re-expanded clearance vapor is slightly different is
neglected, the specific volume vb can be approximately kAΔT
Qcond = (12)
regarded as a constant, namely, the specific volume after taking Δx
in fresh working fluid is equal to the specific volume of the where k is the thermal conductivity, A is the heat transfer area,
working fluid. By letting a1 = (1 + C ) ⋅ V vb , a2 = − C ⋅ V vb Δx is the distance of heat transfer, and ΔT is the temperature
difference between the working fluid and compressor casing.
and a3 = 1 n , Equation (3) can be further simplified to The convective heat transfer is given by Newton’s law of
cooling,
m = ⎡ a1 − a2 ( Pdisc Psuct ) 3 ⎤ ⋅ RPM
a
(4)
⎣ ⎦ Qconv = hAΔT (13)
In Equation (4), the fluid property factors and compressor
where h is the heat transfer coefficient. The total heat transfer
geometric factors are lumped into several constant parameters,
between the working fluid and the compressor casing is
which can be determined either by manufacturers’ catalogue
obtained by
data or by real time experimental data. Therefore, the mass
flow rate can be sufficiently described by the function of three ⎛ kA ⎞
basic operating variables, i.e., Pdisc , Psuct and RPM . Q = Qcond + Qconv = ⎜ + hA ⎟ ΔT (14)
⎝ Δx ⎠
B. The energy obtained by the working fluid Thus, the heat transfer rate of the compressor at the inlet
In practice, since most compression and expansion and the outlet, Qin and Qout , are expressed as
processes are approximately polytropic processes, the model is
firstly developed from a polytropic compression process which ⎛k A ⎞
Qin = ⎜ i i + hi Ai ⎟ (Tshell − Tin ) (14a)
satisfies the following relationship: ⎝ Δxi ⎠
Pv n = K = constant ( n = 1.0 ~ 1.5 ) (5) ⎛k A ⎞
Qout = ⎜ o o + ho Ao ⎟ ( Tout − Tshell ) (14b)
where P is pressure, v is specific volume and n is a constant ⎝ Δxo ⎠
called the polytropic exponent. By raising both sides of this
where Tin and Tout are the temperature of the working fluid at
equation to the 1 n power and rearranging it, we obtain
the inlet and outlet of the compressor, respectively, and Tshell is
1
v = ( K P)n (6) the compressor shell temperature.
The mechanical work input to the working fluid can be Substituting Equations (10), (14a) and (14b) into Equation
calculated from the following integral: (11) and rearrange it as

Win = ∫ VdP = ∫ mvdP (7) n 1


⎡ n −1 n −1
⎤ ⎛k A ⎞
QWF =  n ⎢ P2 n − P1 n ⎥ + ⎜ i i + hi Ai ⎟ (Tshell − Tin )
mK
Substituting Eq. (2) into Eq. (3), we have n −1 ⎣ ⎦ ⎝ Δxi ⎠
(15)
⎛ ko Ao ⎞
+ ho Ao ⎟ (Tout − Tshell )
1 1
Win = mK n ∫ (1 P ) n dP (8) −⎜
⎝ Δxo ⎠
Eq. (4) is integrated: For the steady stable flow, it is reasonable to assume the
value of K , A and Δx remain constant. Moreover, k and h are
n 1
⎡ n −1 n −1
⎤ approximately constants if the temperature difference is not too
Win = mK n ⎢ P2 n − P1 n ⎥ (9)
n −1 ⎣ ⎦ big [11]. Thus, Equation (15) can be simplified as the following
Thus, the power input to the working fluid can be equation:
represented by
QWF = b1m ⎡⎣ Pdisc
b2 b2
− Psuct ⎤⎦ + b3 ( Tshell − Tin ) − b4 (Tout − Tshell ) (16)

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n 1
n −1 ki Ai Once the delivery coefficient and the actual power obtained
where b1 = Kn , b2 = , b3 = + hi Ai and by the working fluid are determined, the actual electrical power
n −1 n Δxi input to the compressor can be obtain from Equation (17).
ko Ao
b4 = + ho Ao . These four empirical parameters can be III. PARAMETER IDENTIFICATION
Δxo
identified from the manufacture catalogue data or experiment To establish the models, variables Pdisc , Ps uct , RPM ,
data. Tin , Tout , Tshell , m , Powerelec , PowerWF and η are required.
C. The actual electrical power input to the compressor The measurement of pressures and temperatures are relatively
easy, which can be obtained by the readings of pressure and
Because of the losses due to non-isentropic compression temperature transducers installed at corresponding locations.
and expansion in the compressor, the theoretical power given Similarly, the electrical power can be measured by the power
by Equation (16) is usually much lower than that required by meter installed on the compressor motor and the compressor
the actual machine. Generally, delivery efficiency is used to speed can be estimated by the frequency of the motor driven
account for the irreversibilities in the actual machine, and the the compressor. However, accurate measurement of the mass
actual electrical power input to the compressor is given by flow rates is difficult, especially when the flow is turbulent. In
Powerelec = QWF η (17) addition, flow meters are much more expensive than pressure
and temperature transducers. Therefore, for engineering
where η is the delivery coefficient, which accounts for all applications, the mass flow rate can be obtained from the
capacity losses. The losses include: 1) those due to the loss of expansion valve connected to the evaporator by measuring the
capacity as a result of gas leakage; 2) those caused by the heat pressure difference across the expansion valve to calculate its
transfer between the working fluid and the compressor casing; flow rate by this correlation:
and 3) those due to frictional effects and motor inefficiencies.
These losses are considered by a volumetric coefficient, ηv , a m WF = Cv Av ρv ΔP (21)
thermal coefficient, ηT , and a motor efficiency, η motor , where Cv is the coefficient of expansion valve; Av is the valve
correspondingly. Therefore, the delivery coefficient may be opening area; +P is the pressure difference across the
defined as a product of three coefficients: expansion valve and ρv is the density of working fluid at the
η = ηv ⋅ηT ⋅η motor (18) valve inlet. The energy obtained by the working fluid and the
delivery coefficient can be computed using the following
In all performance losses associated with a compressor, the equations:
main one is gas leakage. Gas leakage occurs whenever a gap
exists between regions of different pressures. The leakage QWF = m ( H out − H in ) (22)
process not only reduces the quantity of fresh refrigerant, but
also increases the temperature of the gas prior to the QWF
η= (23)
compression process. The temperature increase is a result of the Powerelec
mixing of the fresh suction gas with leaked gas. The density where H in and H out are the enthalpy of the working fluid at
and mass flow rate of the gas are reduced as a result of the
the inlet and outlet of the compressor, respectively, which can
temperature increase. The reduced mass flow rate will
be computed by the NIST database based on the measurement
ultimately decrease the compressor’s cooling capacity. As a
of the pressures and temperatures [13].
rule, the performance impacts associated with internal leakage
are measured by the volumetric efficiency. To determine the empirical parameters of the models, the
following three optimization problems have to be solved:
Substituting Eq. (1) into Eq. (18) we obtain
N
⎡ 1
⎤ v
η = η0ηTη motor = ⎢1 + C − C ⋅ ( Pdisc Psuct ) n ⎥ ⋅ suct ⋅ηT ⋅η motor (19)
min E ( β ) = min ∑ ( f ( xi , β ) − yi )2 (24)
i =1
⎣ ⎦ vb
Since they are non-linear unconstraint optimization
For the above mentioned reasons, it is reasonable to assume problems, several existing algorithms can be used to find the
that the value of the specific volume remain constant, namely, solution. Here, Levenberg–Marquardt method [12] is
vb = vsuct . Moreover, if ηT , η motor and n are regarded as implemented, which incorporates a constant or variable scalar
constants, Equation (19) can be simplified as number to deal with problems related to singularities and is an
effective algorithm for small residual problems. The downhill
η = c1 + c2 ( Pdisc Psuct )
c3
(20) iteration direction can be obtained by solving the following
vsuct v equations:
where c1 = (1 + C ) ⋅ ⋅ηT ⋅η motor , c2 = −C ⋅ suct ⋅ηT ⋅η motor
vb vb (J T
)
J + λ diag ( J T J ) δ = J T ⎡⎣ y − f ( β ) ⎤⎦ (25)
and c3 = 1 n . These three empirical parameters can be
where J is the Jacobian matrix.
identified from the manufacture catalogue data or experiment The method has the nice property that, for some scalar
data. Δ related to λ , the vector δ is the solution of the constrained

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subproblem of minimizing J δ + ( y − f ( β ) )
2
2 subject to
2

β ≤ Δ [14]. This makes it less effective than that of Gauss-


2
Newton search direction but more robust.
IV. MODEL VALIDATION
To validate the simplicity and effectiveness of the proposed
models, a curve fit method for representing compressor test
data provided by ARI Standard 540 [1] is used to make a
comparison. The method was firstly described in ARI Standard
540 at 1991, and was revised at 1999. The method uses a
bivariate cubic polynomial with cross-terms to describe the
mass flow rate (or capacity) and the electrical power input as a
function of saturated evaporating and condensing temperatures
(Equation 27).
X = a0 + a1Te + a2Tc + a3TeTc + a4Te2 + a5Tc2 + a6Te3
(26) Fig. 2. Catalog fittings of mass flow rate by the proposed model and ARI
+ a7Tc Te2 + a8TeTc2 + a9Tc3 model
where X is the mass flow rate or the electrical power input;
a0 ~ a9 are the curve fit parameters, which are determined by a
computer program written by ARI called SURFACEC; Te and
Tc are the saturated suction temperature and the saturated
discharge temperature, respectively. The method is commonly
used by compressor manufacturers to generate maps of
compressor performance using calorimeter data.
In order to quantitatively show the performances of the
model prediction, the fitness of the model is evaluated through
the relative error ( ER ) of every predicted point and root mean
square of the relative error ( ERMS ), which are defined,
respectively, by
Relative error
Dreal − Dcalc
ER = ×100% (27) Fig. 3. Catalog fittings of power input by the proposed model and ARI model
Dreal
Root mean square of the relative error
2
⎛ Dreal − Dcalc ⎞
N

∑ ⎜
i =1 ⎝ Dreal

ERMS = ⎠ ×100% (28)
N
where N is the number of fitted points, Dcalc is the value of
point i predicted by the model and Dreal is the value of point
i acquired from manufacture catalogue data or experimental
data.
The calorimeter testing data provided by compressor
manufacturers are used to identify the empirical parameters.
The fitting results of each model are given in Figures 2–4,
where the calculated value is plotted as a function of the
catalogue data. The Relative Error of each model is shown in
Figure 5. Fig. 4. Catalog fittings of delivery efficiency by the proposed model and ARI
model

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V. CONCLUSION
A simple compressor model for control and optimization of
vapor compression systems was proposed in this paper. The
model starts from fundamental equations based on the energy
and material balance, and thermodynamic principles, but
captures only few key operational characteristic parameters to
predict their performances. The parameters can be easily
determined by the data either from a manufactures’ catalog or
real time operation. Unlike the ARI method, the proposed
model not only reflects the influence of ambient conditions, but
also has good characteristic of extrapolation and interpolation.
The calorimeter testing data provided by compressor
manufacturers were used to identify and validate the proposed
models, and the results showed that all models can achieve
accurate performance estimation over the entire operation
range.
Fig. 5. Relative errors for catalog fittings by the two models.
Comparing the proposed model with the ARI model and the The significance of the developed model is that it can be
experimental data, it can be easily seen that: easily applied to real-time optimization of vapor compression
systems. Our next work is to develop model based control and
a) In the range of operating temperatures where optimization methods and test them on the pilot plant built in
measured data were provided, the errors of all the our Laboratory.
models between curve fit and measured data are very
small and the predicted values look reasonable. REFERENCES
However, the predicted values generated with the ARI
curve fit show that extrapolation and even
[1] ARI Standard 540-91 “A method for presentation of compressor
interpolation can lead to very inaccurate predictions. performance data”. Air-conditioning and refrigeration institute, 1991.
b) Although the predicted values of the mass flow rate [2] A.E. Dabiri, C.K. Rice, “A compressor simulation model with
corrections for the level of suction gas superheat,” ASHRAE Transaction
and electrical power seem to fit the data reasonably 1981; 87(2): 771-80.
well for some data sets, as seen in figures 2~4. But the
[3] L.W. Marriott, “Control of a refrigeration compressor calorimeter of
relative errors are considerably greater for mass flow minimum testing time,” Ph.D. Thesis, University of Michigan (1973).
rate than for the electrical power, as seen in figure 5. It [4] C.C. Hiller, L.R. Glicksman, “Detailed modeling and computer
is caused from the assuming that measurement errors simulation of reciprocating refrigeration compressors,” Processing of
are responsible but mass flow rate measurements are the Purdue compressor technology conference 1976; 12-17
actually more likely to be inaccurate than electrical [5] J.P. Duffy, “Process engineering applications of centrifugal
power measurements. compressor,” Proceedings of Canadian Chemical Engineering
Conference 1983; 1: 310-7.
c) ARI method is an entirely empirical model and [6] C. Schein, R. Radermacher, “Scroll compressor simulation model,”
incapable of considering effect of the ambient Journal of Engineering for Gas Turbines and Power 2001; 123(1): 217-
conditions. Extending this model to variable ambient 25.
temperature requires more coefficients, which [7] C.Q. Tian, C.P. Dou, X.J. Yang, X.T. Li, “A mathematical model of
increases the complexity for model identification. variable displacement wobble plate compressor for automotive air
conditioning system,” Appl Therm Eng 2004; 24 (17–18): 2467–86.
In summary, the new proposed model is simple and [8] C.Q. Tian, Y.F. Liao, X.T. Li, “A mathematical model of variable
accurate for engineering applications. It focuses on the displacement swash plate compressor for automotive air conditioning
characteristics of exiting compressors and the effect of ambient system,” International Journal of Refrigeration 2006; 29(2): 270–80.
conditions. The advantages of the purposed model are evident [9] P. Popovic, H.N. Shapiro, “A semi-empirical method for modeling a
reciprocating compressor in refrigeration systems,” ASHRAE
through a comparison with ARI model, which vary in their Transaction 1995; 101(2):367-82.
degree of complexity and the different purposes of modeling.
[10] I.J. Dagmar, T.R. Douglas, A.K. Sanford, “A semi-empirical method for
The comparison is summarized in Table 1. representing domestic refrigerator/freezer compressor calorimeter test
TABLE I data,” ASHRAE Transactions 2000; 106: 122-30.
COMPARISON OF TWO COMPRESSOR MODELS [11] R.L. Perry, Thermodynamics for engineering technology, California:
Compressor model ARI model New model Wadsworth Inc.; 1984.
Number of parameters 10 3 or 7 [12] J. Nocedal, S.J. Wright, Numerical optimization, New York: Springer
Parameters need to adjust when Verlag, Inc.; 1999.
Yes No
operation conditions change
[13] NIST chemistry webbook: NIST Standard Reference Database Number
Geometric data No No
69, June 2005 Release, <http://webbook.nist.gov/chemistry/>.
Iterative computation No No
Modeling technique Empirical Hybrid [14] P. R. Gill, W. Murray, M. H. Wright, The Levenberg-Marquardt Method,
Model application Control and London: Academic Press, pp. 136-137, 1981.
Simulation
optimization

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