Quuestion#01:

Solution:

boron atomic number 5

electronic configuration=1 s2 , 2 s2 , 2 p1
flourine atomic number=9

electronic configuration=1 s2 , 2 s2 , 2 p5

Question#02:

Solution:

( 23.985∗79 )+ ( 24.986∗10 )+(25.982∗11)

Relative abundance=
100
1894.815+249.86+285.802
Relative abundance=
100
Relative abundance=24.30477 amu
Question#03:

Solution:

Hg+2 N H 4 I → Hg I 2 + H 2+ 2 N H 3

2 Fe+6 HCl→ 2 FeC l3 +3 H 2

Question#04:

Solution:

A=meth ane
So for A all properties are of methane. As it has low melting point (-183) and boiling point (-
162). It also bad electrical conductor in solid as well as molten state.
B=silicondioxide
B is silicon dioxide. As its bad electrical conductor in solid and molten state.

C=iron
Iron is good electrical conductor in both state and have high boiling and melting points.

D=sodium chloride
D is sodium chloride because it is excellent conductor in molten state but bad conductor of
electricity in solid state and it has high boiling and melting points.

Question#05:

Solution:

Eth a nol ( C H 3 C H 2 OH )=351 K

Boiling point of ethanol is 351K because there are less extensive hydrogen bonding between ethanol
molecules than water molecules, thus less energy needed to vaporize.

Eth a ne ( C H 3 C H 3 )=184 K

Ethane has lower boiling point 184K because of their non polar nature and their atoms have not very
much electronegativity.

but a ne ( C H 3 C H 2 C H 2 C H 3 ) =272 K

In butane there is only weak vander waal forces, the forces between molecule are much less. So it
boils at freezing point of water 0C.

Question#06:

Solution:

According to VSEPR theory ClF3 is AB3 type.

Type Electron pair total bond Arrangement of pair Shape

 AB3 3 Triangular plane

In such molecule, central atom contain three bonding electron pair which are arranged at max
distance apart at angle 175o, gives a triangular plane. The Cl is surround by three F atoms and make
an angle of 175o.F-Cl-F.

Question#07:

Solution:

KJ
∆ H f H 2 O2=−187.8
mol
KJ
∆ H f H 2 O=−285.8
mol
for 2 H 2 O2=−2∗187.8

¿−375.6 KJ /mol
for 2 H 2 O=−2∗285.8

¿−571.6 KJ /mol
∆ H r =(−571.6)−(−375.6)
KJ
∆ H r =−196
mol
Question#08:

Solution:

Molar mass of I 2=253.81 g/mol

6g
moles of I 2=
g
253.81
mole
moles of I 2=0.0236 gmole

mol a rity of I 2=0.0236 mole /1 L

mole
mol a rity of I 2=0.0236
L
Molar mass of KI =166 g/mol
50 g
moles of KI =
g
166
mole
 moles of KI =0. 301 gmole
mol a rity of KI =0. 301mole /1 L
mole
mol a rity of KI =0. 301
L
Initial chemical raction:
−¿ ↔ I 3 ¿
I 2+ I

From reaction molar ration of I2 and I3 is 1:1.hence we have 0.301 mole of I-and 0.278 moles
remains so 0.0230 moles of I- must be consumed to produce 0.0230 mole of I-3. Also 0.230
moles of I2 get consumed to produce 0.0230 mole of I-3

I2 I- I3
Initial 0.0236 0.301 0
Change -0.0230 -0.0230 0.0230
Final 0.0006 0.278 0.0230

[ I3 ]
K c=
[ I 2] ¿ ¿
0.0230
K c=
0.0006∗0.278
K c =138.55

Question#09:

Solution:

1. BH3

Oxidation state of hydrogen is -1 and therefore B has +3.

oxid ation st a te=−1+ 3=2

2. CH3-Mg-Br

Oxidation state of CH3 is -3, Mg has +2 and Br has -1.

oxid ation st a te=−3+2−1=0

oxid ation st a te=−2
3. NaH

In sodium hydride the hydrogen is present as a hydride ion H -. so Na has +1 and H has -1 oxidation
state.

oxid ation st a te=−1+ 1=0