TUTORIAL 1 (Additional Questions)

1) Calculate the number of moles of the indicated species:

i) 8.75 g of Mn3O4. (0.0382 mol)
ii) 167.2 mg of CaC2O4. (1.30x10-3 mol)

2) Calculate the number of millimoles of the indicated species:

i) 40.0 g of NaHCO 3. (476.2 mmol)
ii) 850 mg of MgNH4PO4. (6.204 mmol)

3) Calculate the number of millimoles of solute in:

i) 2.00 L of 3.25 x 10-3 M KMnO4. (6.5 mmol)
ii) 750 mL of 0.0555 M KSCN. (41.6 mmol)
iii) 250 mL of a solution that contains 5.41 ppm of CuSO 4. (8.47x10-3)
iv) 650 mL of a solution that contains 4.96 ppm of Pb(NO 3)2. (9.74x10-3)

4) What is the mass in milligrams of solute in:

i) 26.0 mL of 0.250 M sucrose (342 g/mol) (2223 mg)
ii) 2.92 L of 4.76 x 10-3 M H2O2 (472.6 mg)
iii) 3.50 L of a solution that contains 21.7 ppm of SnCl2 (75.95 mg)
5) A solution contains 118.5 g KI per liter solution. Calculate the concentration in
i) %w/v (11.85%)
ii) %w/w (10.99%)

Given the density of the solution at 25 0C is 1.078 g/mL.

6) Methanol, CH3OH (32.0 g/mol) has a density of 0.79 g/mL. If 54.0 mL methanol is added with
water to a volume of 500.0 mL, calculate the concentration of the methanol Solution in
i) percent v/v (10.8%)
ii) percent w/v (8.53%)
iii) molarity (2.67 M)

7) The density of methanoic acid, HCOOH is 1.22 g/mL. If 33.5 mL of methanoic acid is
dissolved in water to a volume of 250 mL, calculate the concentration of methanoic acid in
i) %v/v (13.4%)
ii) %w/v (16.35%)
8) Calculate the molar concentration of HNO 3 in a solution that has a specific gravity of 1.42 and
is 70.5% HNO3 (w/w).
(15.89 M)

9) A 12.5% (w/w) NiCl2 (129.61 g/mol) solution has a density of 1.149 g/mL. Calculate
i) The molar concentration of NiCl2 in the solution (1.11M)
ii) The molar Cl- concentration of the solution (2.22 M)

10) Calculate the molar concentration of H3PO4 commercial reagent that is 86% (w/w) and has
a specific gravity of 1.71.
(18.01 M)