Mole Concept Stoichiometry

DPP

1. 6.02 × 1020 molecules of urea are present in 100 ml of its solution. The concentration of urea
solution is - [AIEEE 2004]
(a) 0.001 M (b) 0.01 M (c) 0.02 M (d) 0.01 M

2. If we consider that 1/6, in place of 1/12, mass of carbon atom is taken to be the relative atomic
mass unit, the mass of one mole of a substance will [AIEEE 2005]
(a) decrease twice (b) increase two fold
(c) remain unchanged (d) be a function of the molecular mass of the
substance

3. Two solution of a substance (non electrolyte) are mixed in the following manner. 480 ml of 1.5M
first solution + 250 ml of 1.2 M second solution what is the molarity of the final mixture ?
[AIEEE 2005]
(a) 2.70 M (b) 1.344 M (c) 1.50 M (d) 1.20 M

4. How many moles of magnesium phosphate, Mg3(PO4)2 will contain 0.25 mole of oxygen atoms ?
[AIEEE 2006]
(a) 3.125 × 10–2 (b) 1.25 × 10–2
(c) 2.5 × 10–2 (d) 0.02

5. Density of a 2.05M solution of acetic acid in water is 1.02 g/ml. The molality of the solution is.
[AIEEE 2006]
(a) 1.14 mol kg–1 (b) 3.28 mol–1
(c) 2.28 mol kg–1 (d) 0.44 mol kg–1

6. The density (in g mL–1) of a 3.60 M sulphuric acid solution that is 29%
(H2SO4 molar mass = 98 g mol–1) by mass will be [AIEEE 2007]

(a) 1.22 (b) 1.45 (c) 1.64 (d) 1.88

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Mole Concept Stoichiometry
7. In the reaction 2Al(s) + 6HCl → 2Al3+ (aq) + 6Cl− (aq) + 6Cl− (aq) + 3H2 O(g) [AIEEE 2007]
(a) 6L HCl(aq) is consumed for every 3L H2 produced.

(b) 33.6 L H2(g) is produced regardless temperature and pressure for every moles that reacts.

(c) 67.2 L H2(g) at STP is produced for every mole Al that reacts.

(d) 11.2 L H2(g) at STP is produced for every mole HCl(aq) consumed.

8. A 5.2 molal aqueous solution of methyl alcohol CH3OH, is supplied., What is the mole fraction of
methyl alcohol in the solution? [AIEEE 2011]
(a) 0.086 (b) 0.050 (c) 0.100 (d) 0.190

9. The density of a solution prepared by dissolving 120g of urea (mol. mass = 60 u) in 1000 g of
water is 1.15 g/mL. The molarity of this solution is- [AIEEE 2012]
(a) 2.05 M (b) 0.50 M (c) 1.78 M (d) 1.02 M

10. The molarity of a solution obtained by mixing 750 mL of 0.5 (M) HCl with 250 mL of 2(M)HCl
will be: [JEE Main 2013]
(a) 1.00 M (b) 1.75 M (c) 0.975 M (d) 0.875 M

11. The ratio of masses of oxygen and nitrogen in a particular gaseous mixture is 1 : 4. The ratio of
number of their molecule is [JEE Main 2014]
(a) 1:8 (b) 3 : 16 (c) 1:4 (d) 7 : 32

12. 1 gram of a carbonate (M2CO3) on treatment with excess HCl produces 0.01186 mole of CO2. The
molar mass of M2CO3 in g mol–1 is : [JEE Main 2017]

(a) 11.86 (b) 1186 (c) 84.3 (d) 118.6

13. The most abundant elements by mass in the body of a healthy human adult are:
Oxygen (61.4%); Carbon (22.9%); Hydrogen (10.0%); and Nitrogen (2.6%).
The weight which 75 kg person would gain if all 1H atoms are replaced by 2H atoms is :
[JEE Main 2017]
(a) 10 kg (b) 15 kg (c) 37.5 kg (d) 7.5 kg
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Mole Concept Stoichiometry
14. The ratio of mass percent of C and H of an organic compound (CxHyOz) is 6 : 1. If one molecule
of the above compound (CxHyOz) contains half as much oxygen as required to burn one molecules
of compound CxHy completelyto CO2 and H2 O.The empirical formula of compound CxHyOz is

[JEE Main 2018]

(a) C3H4O2 (b) C2H4O3 (c) C3H6O3 (d) C2H4O

15. How many moles of electron weight one kilogram ? [IIT 2002]
1 6.023 1
(a) 6.023 × 1023 (b) × 1031 (c) × 1054 (d) × 108
9.108 9.108 9.108×6.023

16. In which of the following number of atoms are maximum ? [IIT-2003]

(a) 24 gms C (b) 27 gms of Al (c) 56 gms of Fe (d) 108 gms of Ag

17. Given that the abundances of isotopes 54Fe, 56Fe and 57Fe are 5%, 90% and 5%, respectively, the
atomic mass of Fe is - [IIT-2009]
(a) 55.85 (b) 55.95 (c) 55.75 (d) 56.05

18. Dissolving 120 g of urea (mol. wt. 60) in 1000 g of water gave a solution of density 1.15 g/mL.
The molarity of the solution is - [IIT-2011]
(a) 1.78 M (b) 2.00 M (c) 2.05 M (d) 2.22 M

19. Amongst the following, the pair having both the metals in their highest oxidation state is :
[JEE 2004, 3/84]

(a) [Fe(CN)6]3– and [Co(CN)6]3– (b) CrO2Cl2 and MnO4–

(c) TiO2 and MnO2 (d) [MnCl4]2– and [NiF6]2–

20. Dissolving 120 g of urea (mol. wt. 60) in 1000 g of water gave a solution of density 1.15 g/mL.
The molarity of the solution is :. [JEE 2011, 3/160]
(a) 1.78 M (b) 2.00 M (c) 2.05 M (d) 2.22 M

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Mole Concept Stoichiometry
21. In an organic compound of molar mass 108 g mol–1 C, H and N atoms are present in 9 : 1 : 3.5 by
weight. Molecular formula can be : [AIEEE 2002, 3/225]
(a) C6H8N2 (b) C7H10N (c) C5H6N3 (d) C4H18N3

22. When KMnO4 acts as an oxidising agent and ultimately forms MnO2− 2+
4 , MnO2 , Mn2 , O3 and Mn ,
then the number of electrons transferred in each case is : [AIEEE 2002, 3/225]
(a) 4, 3, 1, 5 (b) 1, 5, 3, 7 (c) 1, 3, 4, 5 (d) 3, 5, 7, 1

23. Which of the following is a redox reaction? [AIEEE 2002, 3/225]

(a) NaCl + KNO3 NaNO3 + KCl

(b) CaC2O4 + 2 HCl CaCl2 + H2C2O4

(c) Mg (OH)2 + 2 NH4Cl MgCl2 + 2 NH4OH

(d) Zn + 2 AgCN 2 Ag + Zn (CN)2

24. Which of the following concentration factor is affected by change in temperature ?

[AIEEE 2002, 3/225]
(a) Molarity (b) Molality (c) Mole fraction (d) Weight fraction

25. What volume of hydrogen gas at 273 K and 1 atm pressure will be consumed in obtaining 21.6 g
of elemental boron (atomic mass = 10.8) from the reduction of boron trichloride by hydrogen-
[AIEEE 2003, 3/225]
(a) 44.8 lit. (b) 22.4 lit. (c) 89.6 lit. (d) 67.2 lit.

26. 6.02 × 1020 molecules of urea are present in 100 ml of its solution. The concentration of urea
solution is - [AIEEE 2004, 3/225]
(a) 0.001 M (b) 0.01 M (c) 0.02 M (d) 0.1 M

27. The oxidation state of Cr in [Cr(NH3)4Cl2]+ is : [AIEEE 2005, 1½/225]

(a) +3 (b) +2 (c) +1 (d) 0

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Mole Concept Stoichiometry
28. Two solution of a substance (non electrolyte) are mixed in the following manner. 480 ml of 1.5M
first solution + 520 ml of 1.2M second solution. What is the molarity of the final mixture ?
[AIEEE 2005, 3/225]
(a) 2.70 M (b) 1.344 M (c) 1.50 M (d) 1.20 M

29. Which of the following chemical reactions depicts the oxidizing behaviour of H2SO4?
[AIEEE-2006, 3/165]
(a) 2HI + H2SO4 → I2 + SO2 + 2H2O

(b) Ca(OH)2 + H2SO4 → CaSO4 + 2H2O

(c) NaCl + H2SO4 → NaHSO4 + HCl

(d) 2PCl5 + H2SO4 → 2POCl3 + 2HCl + SO2Cl2

30. How many moles of magnesium phosphate, Mg3(PO4)2 will contain 0.25 mole of oxygen atoms?
[AIEEE-2006, 3/165]
(a) 0.02 (b) 3.125 × 10-2 (c) 1.25 × 10-2 (d) 2.5 × 10-2

31. Density of a 2.05M solution of acetic acid in water is 1.02 g/ml. The molality of the solution is :
[AIEEE-2006, 3/165]
(a) 1.14 mol kg–1 (b) 3.28 mol kg–1
(c) 2.28 mol kg–1 (d) 0.44 mol kg–1

32. In the reaction 2AI(s) + 6HCl(aq) 2Al3+(aq) + 6Cl–(aq) + 3H2 (g) [AIEEE-2007, 3/120]
(a) 6L HCl(aq) is consumed for every 3L H2 produced.
(b) 3.6 L H2(g) is produced regardless temperature and pressure for every moles that reacts.
(c) 67.2 L H2(g) at STP is produced for every mole of Al that reacts .
(d) 11.2 L H2(g) at STP is produced for every mole of HCl(aq) consumed.

33. The density (in g mL–1) of a 3.60 M sulphuric acid solution that is 29% (H2SO4 molar mass = 98 g
mol–1) by mass will be : [AIEEE-2007, 3/120]
(a) 1.22 (b) 1.45 (c) 1.64 (d) 1.88
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Mole Concept Stoichiometry

34. A 5.2 molal aqueous solution of methyl alcohol, CH3OH, is supplied. What is the mole fraction of
methyl alcohol in the solution? [AIEEE-2011, 3/120]
(a) 0.100 (b) 0.190 (c) 0.086 (d) 0.050

35. The molality of a urea solution in which 0.0100 g of urea, [(NH2)2CO] is added to 0.3000 dm3 of
water at STP is : [Re. Paper AIEEE-2011, 3/120]
(a) 5.55 × 10–4 (b) 33.3 m (c) 3.33 × 10–2 m (d) 0.555 m

36. The density of a solution prepared by dissolving 120 g of urea (mol. mass = 60 u) in 1000 g of
water is 1.15 g/mL. The molarity of this solution is : [AIEEE-2012, 4/120]
(a) 0.50 M (b) 1.78 M (c) 1.02 M (d) 2.05 M

37. How many moles of air are there in the lungs of an average adult with a lung capacity of 3.8 L .
(Assume that the person is at 1.0 atm pressure and has normal body temperature at 37oC).
(a) 0.15 mol (b) 0.25 mol (c) 1.15 mol (d) 2.25 mol

38. If 0.32 gm of an organic compound containing sulphur produces 0.233g of BaSO4 Then the
percentage of sulphur in it is-
(a) 10 (b) 15 (c) 20 (d) 25

39. Which of the following concentration factor is affected by change in temperature ?

(a) Molarity (b) Molality (c) Mole fraction (d) Weight fraction

40. The specific gravity of a HNO3 solution is 1.42 and it is 70% w/w. The molar concentration of
HNO3 is :
(a) 15.8 (b) 31.6 (c) 11.1 (d) 14.2

41. 64 g of an organic compound has 24 g carbon and 8 g hydrogen and the rest is oxygen. The
empirical formula of the compound is :
(a) CH4O (b) CH2O (c) C2H4O (d) None of these

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Mole Concept Stoichiometry
42. For the following reaction : Na2CO3 + 2HCl 2NaCl + CO2 + H2O
106.0 g of Na2CO3 reacts with 109.5 g of HCl.
Which of the following is/are Incorrect.
(a) The HCl is in excess.
(b) 117.0 g of NaCl is formed.
(c) The volume of CO2 produced at NTP is 22.4 L.
(d) None of these

43. When a certain amount of octane, C8H18, is burnt completely, 7.04 gm CO2 is formed. What is the
weight of H2O formed, simultaneously ?
(a) 1.62 gm (b) 6.48 gm (c) 3.24 gm (d) 2.28 gm

44. A 500 g toothpaste sample has 0.4 g fluoride concentration. The fluoride concentration in terms of
ppm will be :
(a) 200 (b) 400 (c) 500 (d) 800

45. A gaseous hydrocarbon gives upon combustion 0.72 g of water and 3.08 g of CO2. The empirical
formula of the hydrocarbon is : [JEE Mains-2013]
(a) C7H8 (b) C2H4 (c) C3H4 (d) C6H5

46. The molarity of a solution obtained by mixing 750 mL of 0.5 (M) HCl with 250 mL of 2(M)HCl
will be : [JEE Mains-2013]
(a) 0.975 M (b) 0.875 M (c) 1.00 M (d) 1.75 M

47. The % by volume of C4H10 in a gaseous mixture of C4H10, CH4 and CO is 40. When 200 ml of the
mixture is burnt in excess of O2. Find volume (in ml) of CO2 produced.
(a) 30 M, 75 m (b) 75m, 30 M (c) 7.5 m, 30 M (d) None of these

48. The mole fraction of a given sample of I2 in C6H6 is 0.2. The molality of I2 in C6H6 is
(a) 0.32 (b) 3.2 (c) 0.032 (d) 0.48

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Mole Concept Stoichiometry
49. What is the number of moles of Fe(OH)3 that can be produced by allowing
1 mole of Fe2S3, 2 mole of H2O and 3 mole of O2 to react
2Fe2S3 + 6H2O + 3O2 → 4Fe (OH)3 + 6S
(a) 2 (b) 1.34 (c) 3.52 (d) None of these

50. 74 gm of a sample on complete combustion gives 132 g of CO2 and 54 g of H2O. The molecular
formula of the compound may be
(a) C5H12 (b) C4H10O (c) C3H6O2 (d) C3H7O2

51. For the reaction,

2x + 3y + 4z → 5w
Initially if 1 mole of x, 3 mole of y and 4 mole of z is taken. If 1.25 mole of w is obtained then %
yield of this reaction is
(a) 25% (b) 50% (c) 75% (d) None of these

52. The number of water molecules present in 0.20 g sample of CuSO4 . 5H2O (Molar mass = 249.7)
is [NSEC-2011]
(a) 1.2 × 1021 (b) 2.14 × 1021 (c) 2.14 × 1022 (d) 1.2 × 1023

53. The vapour density of gas A is four times that of B. If the molecular mass of B is M then
molecular mass of A is : [NSEC-2012]
(a) M (b) 4M (c) M/4 (d) 2M

54. Chlorine can be prepared by reacting HCl with MnO2. The reaction is represented by the equation:
MnO2(s) + 4HCL(aq) Cl2(g) + MnCl2(aq) + 2H2O(l)
Assuming the reaction goes to completion, what mass of concentrated HCl solution (36.0% HCl
by mass) is needed to produce 2.50 g of Cl2 [NSEC-2007]
(a) 5.15 g (b) 14.3 g (c) 19.4 g (d) 26.4 g

55. A currency counting machine counts 60 million notes per day. A bank has an many notes as
number of oxygen atoms in 24.8 g of Na2S2O3.5H2O (M.W. = 248)
How many days would be required to count these notes ? [NSEC-2008]
(a) 9.33 × 1017 (b) 7.03 × 1010 (c) 8.03 × 1015 (d) 6.66 × 10–12
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Mole Concept Stoichiometry
56. The total number of electrons present in 8.0 g of methane is [NSEC-2004]
(a) 4.8 × 1024 (b) 3.01 × 1024 (c) 4.8 × 1025 (d) 3.01 × 1023

12 13
57. The percentage abundances of C and C are 98.9 and 1.1 respectively. The average mass of
carbon (in a.m.u) is [NSEC-2005]
(a) 12.111 (b) 12.981 (c) 12.011 (d) 12.891

58. The percentages of C, H and N in an organic compound are 40%, 13.3% and 46.7%. The empirical
formula of this compound is [NSEC-2006]
(a) CH2N (b) CH4N (c) CH5N (d) C3H9N3

59. 17.1 grams of aluminum sulfate Al2(SO4)3 is dissolved in enough water to prepare 1.00 L of
solution .What is the molarity of the sulfate ion the solution? (Neglect any hydrolysis)
[NSEC-2007]
(a) 1.67 x 10–2 M (b) 5.00 x 10–2 M (c) 1.50 x 10–1 M (d) 2.50 x 10–1 M

60. The molality of a sulphuric acid solution is 0.2. Calculate the total weight of the solution having
1000 g of solvent.
(a) 1000 g (b) 1098.6 g (c) 980.4 g (d) 1019.6 g

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Mole Concept Stoichiometry

Answers

1. b 2. c 3. b 4. a 5. c
6. a 7. d 8. a 9. a 10. d
11. d 12. c 13. d 14. b 15. d
16. a 17. b 18. c 19. b 20. c
21. a 22. c 23. d 24. a 25. d
26. b 27. a 28. b 29. a 30. b
31. c 32. d 33. a 34. c 35. a
36. d 37. a 38. b 39. a 40. a
41. a 42. d 43. c 44. d 45. a
46. b 47. a 48. b 49. b 50. c
51. b 52. b 53. b 54. b 55. c
56. b 57. c 58. b 59. c 60. d

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