Angeles, Mark P.

3094
MTW 01:30 PM – 05:30 PM
Topic: Assignment no. 2
Content: Solve the remaining supplementary problems: 4,5,6,7,8,9,11-25
4. A 2.5 gram sample of ground water was found to contain 5.4 microgram of Zn+2, what is this
concentration in parts per million.

5. Determine the molarities of the following solutions:

a. 2.37 moles of KNO3 are dissolved in enough water to give 650 mL of solution.
b. 25.0 g of NaOH are dissolved in enough water to give 2.50 L of solution.

6. Express in formality the concentration of each of the following solutions:

a. 28.4% NH3 by weight, having a density of 0.808 g/mL
b. 36.0 % HCl by weight, having a density of 1.19 g/mL

7. How many grams of solute are in 500 mL of 6F HCl?

8. Calculate the molality of a solution made by dissolving 10.0 g AgNO3 (MW = 169.9) in 275 g
of water.

9. A 4.10 molal solution of H2SO4 has a density of 1.21 g/mL. What is the molar concentration
of the solution? What is the normality?

11. Calculate the equivalent weight of the following solutes:

a. Na3PO4 b. H2SO4 c. Al(OH)3

12. Calculate the normality of the solution that results when 4.00 g of Al(NO3)3 (MW = 213.0)
is dissolved in enough water to give 250.0 mL of solution.

13. A solution contains 10.0 g of glucose (MW= 180) and 85.0 g of water. What is the mole
fraction of glucose in the solution? What is the mole percent glucose in the solution?

14. What are the mole fractions of ethyl alcohol, C2H5OH and water, in a solution made by
dissolving 11.5 g of ethanol in 27 g water?

15. What volume of concentrated HCl should be used to prepare 500.0 mL of a 3.00 M HCl
solution? Concentrated HCl solution is 12.0 M.

16. A solution of H2SO4 containing 50.0% H2SO4 by mass has a density of 1.40 g/mL. Express
its concentration in terms of mole fraction, mole percent, molarity, molality and normality.
17. How many grams of solute are required to prepare each of the following aqueous solutions?
a. 500.00 mL of a 0.500M urea solution , CO (NH2)2
b. 500.0 mL of 1.50 N H3PO4 solution
c. 1.0 liter of a 2.o M CaBr2 solution
d. 1.0 kg of a 5.0 % by mass glucose, C6H12O6

18. What is the normality of each of the following solutions as an acid or as a base?
a. 2.0 liters of 18M H2SO4 diluted to 100 liters
b. 140 mL of a 12 M HCl diluted to 2.0 liters

19. How many grams of ethanol are there in a liter-volume of wine (D = 0.934 g/mL) that is
12.0% by mass ethanol, C2H5OH? 12% by volume ethanol?( D of pure ethanol = 0.789 g /mL).

20. What is the molarity of concentrated HBr solution if the acid is 48.0% by mass HBr? ( D=
1.50 g/ mL)

21. What volume of concentrated HNO3 should be used to prepare 1.0 liter of 0.15M HNO3?
Concentrated HNO3 is 70.0 % by mass HNO3 with a density of 1.42 g/mL .

22. A 100mL sample of concentrated H2SO4 is diluted with water until the final volume is 500
mL. Concentrated H2SO4 is 96.0% by mass with a density of 1.84 g/mL. What is the normality
and molarity of the new solution?

23. Commercial aqueous nitric acid has a specific gravity of 1.42 and is 16M. Calculate the %
HNO3 by mass in the solution.

24. Propylene glycol, C3H6(OH)2, is sometimes used in automobile antifreeze solutions. If an

aqueous solution has a mole fraction of propylene glycol equal to 0.10, calculate : a) %
propylene glycol by mass; b) molality of the solution.

25. Caffeine, C8H10N4O2, is a stimulant found in coffee and tea. If a solution of caffeine in
chloroform , CHCl3, as a solvent has a concentration of 0.085 molal, calculate: a) % caffeine by
mass, b) mole fraction of caffeine.