GENERAL CHEMISTRY 2 (CHM02)

RITTEN WORK 2B – SOLUTIONS

Name : Ronna Ituralde & John Cudal Date:
02-26-20
Section: IS202

PROBLEMS:

1. What is the mole fraction of urea, CO(NH2)2, in a solution prepared by dissolving 4.8 g
of urea in 30.3g of methanol, CH3OH?

2. What is the mass percent of an aqueous sodium hydroxide solution in 1000 g of H 2O

if the molality of NaOH is 10.7m?

3. How many grams of Al are required to react with 35mL of 2.0M hydrochloric acid,
HCl?

__ HCl + __ Al → __ AlCl3 + __ H

4. How many milliliters of 0.10 M Pb(NO3)2 are required to react with 75 mL of 0.20 M NaI?

__ Pb(NO3)2 + __ NaI → __ PbI2 + __ NaNO3

5. The volume of a 32.4% (by mass) solution is 179.1mL. The density of the solution is
1.296 g/mL. What is the mass of solute in this solution?

6. A 12.0% sucrose solution by mass has a density of 1.05 g/cm3. What mass of sucrose
is present in a 53.0 mL sample of this solution?

7. Calculate the molarity of a solution of magnesium chloride with a concentration of

27.0 mg/mL.

8. What is the molality of a 19.4 M sodium hydroxide solution that has a density of 1.54
g/mL?

9. If the concentration of sodium carbonate in water is 12.8 ppm, what is the molarity of
Na2CO3 (aq)? The molar mass of Na 2CO3 is 106.0 g/mol. Assume the density of the
solution is 1.00 g/mL.
10. A 15 meter by 12 meter pool of water has a depth of 2.2 meters. What mass of silver
ion is present in the reservoir if the concentration of silver ion is 0.14ppm? (1m 3 =
1000 L; assume the density of the solution is 1.00 g/mL)

11. What concentration of silver nitrate (in ppm) is present in 7.1 × 10 –7 M AgNO3 (aq)?
For very dilute aqueous solutions, you can assume the solution's density is 1.0 g/mL.
The molar mass of AgNO3 is 169.9 g/mol.

12. What mass of Zn(NO3)2 must be diluted to a mass of 1.00 kg with H 2O to prepare 97
ppm Zn2+ (aq)?

13. The solubility of 1-pentanol in water is 2.7g per 100 g of water at 25 °C. What is the
maximum amount of 1-pentanol that will dissolve in 2.1 g of water at 25°C?

14. What is the freezing point depression (ΔT) of a 12.6-m solution of ethylene glycol
(antifreeze) in water? Ethylene glycol is a nonelectrolyte, and the freezing point
depression constant of water is 1.86 °C/m.
15. Propyl alcohol, C3H7OH, is a nonelectrolyte. A 0.370-mol sample of propyl alcohol is
dissolved in 1.75 kg of water. If the boiling point elevation constant (Kb) of water is
0.512 °C/m, what is the boiling point elevation of the solution?

16. Rubidium chloride, RbCl, is a strong electrolyte. What is the freezing point of a
solution formed by dissolving 15.0 g of RbCl in 0.125 kg of water? The molar mass of
RbCl is 121 g/mol, and the freezing point depression constant (Kf) for water is 1.86
°C/m.

17. Hydrogen bromide, HBr, is a strong electrolyte in water. What is the boiling point
elevation (ΔT) of a solution containing 125 g of HBr in 1.75 kg of water? The molar
mass of HBr is 80.9 g/mol, and the boiling point elevation constant (Kb) of water is
0.512 °C/m.

18. What is the osmotic pressure (Π) of a solution containing 0.125 mol of a
nonelectrolyte in 0.500 L of solution at 25°C? R = 0.0821 L·atm/mol·K.

19. Calcium nitrate, Ca(NO3)2, is a strong electrolyte. A solution contains 4.75 g of

calcium nitrate in 125 mL of solution. What is the osmotic pressure (Π) of this
solution at 37°C? The molar mass of calcium nitrate is 164 g/mol, and R = 0.0821
L·atm/mol·K.
20. The partial pressure of O2 in your lungs varies from 25mmHg to 40mmHg. What mass
of O2 can dissolve in 1.0 L of water at 25 °C if the partial pressure of O 2 is 40mmHg?

21. An unopened soda can has an aqueous CO2 concentration of 0.0506 m at 25 °C.
What is the pressure of CO2 gas in the can?

22. A 35.0-g sample of ethylene glycol, HOCH2CH2OH, is dissolved in 500.0 g of water.

The vapor pressure of water at 32 °C is 35.7 mmHg. What is the vapor pressure of
the water-ethylene glycol solution at 32 °C? (Ethylene glycol is nonvolatile.)

23. You add 0.255 g of an orange, crystalline compound whose empirical formula is
C10H8Fe to 11.12 g of benzene. The boiling point of the benzene rises from 80.10 °C
to 80.26 °C. What are the molar mass and molecular formula of the compound? (Kb
of benzene is 2.53°C/m)

24. A solution is prepared by dissolving 0.6706 g of oxalic acid (H 2C2O4) in enough water
to make 100.0 mL of solution. A 10.00-mL aliquot (portion) of this solution is then
diluted to a final volume of 250.0 mL. What is the final molarity of the oxalic acid
solution?
25. Nitrous oxide, N2O, laughing gas, is used as an anesthetic. Its Henry’s law constant is
2.4× 10−2 mol/kg ∙ bar. Determine the mass of N 2O that will dissolve in 500 mL of
water, under an N2O pressure of 1.00 bar. What is the concentration of N 2O in this
solution, expressed in ppm (ρH2O= 1.00 g/mL)?

26. What is the molarity of the solution containing 46.92 grams of FeCl3 dissolved in 120
mL of solution?

27. Determine the mass of MgCl2 contained in a 35.0 mL aliquot of 0.241 M MgCl2
solution.

28. Determine the molality of a solution in which 26.88 grams of AlF3 has been dissolved
in 2,200 grams of water?

29. Determine the %M/M of copper in an alloy when 10 kg of Cu is mixed with 250 kg of
Zn?
30. A student made a solution by adding water to 75 mL of ethanol until the total volume
became 375 mL. What is the percent of ethanol in the solution?

31. How will you make 200mL of a 15% salt in water solution?

32. How will you make 500mL of 4% acetic acid solution in water?

33. Brass is an alloy that contains copper and zinc. If the concentration of zinc in the
jewelry is relatively low, the brass becomes inexpensive and produces a gold color
jewelry. If the pendant contains 1.7 grams of zinc, what is the percent mass of zinc if
the pendant weighs 35 grams?

34. What is the mass of water needed to prepare 1.20 m solution using 0.6 mol
propylene glycol (C3H8O2)?
35. If 382 grams of sodium chloride is present in a 2649 mL solution, what is the
molarity?

36. How much 0.05 M hydrochloric acid could be made from diluting 10M HCl of 250mL
volume?

37. Determine the amount of pyrazine (C 4H4N2) dissolved in 1.50 kg of carbon

tetrachloride to lower the freezing point by 4.4 ˚ C? The constant freezing point for
CCl4 is 30 ˚ C/m.

38. Determine the freezing point of a solution containing 186 g trichothecin (C 19H24O5) in
0.750 kg benzene (C6H6). If pure benzene has a freezing point of 5.5 ˚C, the Kf is
5.12 C/m.

39. About 4.0% by weight dissolved solid, mostly NaCl, is present in seawater. What is
the normal boiling point of seawater? Note: i
40. At 0.9789 atm, the boiling point of water is 99.4 ˚C. What is the mass of NaCl should
be added to 3.5Kg of boiling water to raise it to 100 ˚C?

41. A 0.065 M aqueous nitrous acid (HNO 3) solution has an osmotic pressure of 0.90 atm
at 23.1 °C. Calculate the van’t Hoff factor of the acid.

42. A pressure of 24.90 mmHg was found to be in an aqueous solution. Water is the
solvent and has a vapor pressure of 25.756 mmHg at 25 ˚ C. What is the mole
fraction of solute in this solution?

43. The vapor pressure of water at 25 0C is 23.8 mmHg. Determine the vapor pressure of
1kg solution that is 2.50 m of glucose (C6H12O6).

44. The solubility of an unknown gas is 0.745 g/L with pressure of 2.34 atm in a solution.
What is the concentration of the gas when the pressure is increased to 5.39 atm?

45. A stock solution of sodium hydroxide has a concentration of 5.00 M. How

many mL of it are required to make 355 mL of a 1.35 M solution?