KV BHAWANIPATNA, SUMMER ASSIGNMENT

Subject - Chemistry Class – XII 2023-24 Topic: Solution Part-1

1. Calculate the molarity of pure water.

2. 25 mL of 3.0 M HNO3 are mixed with 75 mL of 4.0 M HNO3. If the volumes are additive, What is
the molarity of the final mixture?
3. What is molarity of a solution obtained by mixing 750 mL of 0.5 M HCl with 250 mL of 2 M HCl.
4. 120 g of Urea ( MM = 60 ) was dissolved in 1 kg of water. if the density of the resultant solution is
1.2 g/mL, then what is molarity of the solution.
5. In which ration of volumes 0.4 M HCl and 0.9 M HCl are mixed such that the concentration of the
resultant solution beocmes 0.7 M?
6. 100 mL of an acid solution is neutralised by 50 mL of NaOH solution containing 0.2 g NaOH. What
is concentration of acid solution.
7. Concentrated HNO3 is 63 % by mass and density of 1.4 g/ml. How many millilitres of this solution
are required to prepare 250 mL of 1.2 M HNO3 solution:
8. 50 ml of 20.8% (w/v) BaCl2 solution and 100 ml of 9.8% (w/v) H2SO4 solutions are mixed. What
is molarity of Cl - ions in the resulting solution. ( At wt. Ba 137)
9. What is the mole fraction of a solute in 1.00 molal aqueous solution.
10. Equal volumes of 0.1 M AgNO3 and 0.2 M NaCl solutions are mixed. What is concentration of
NO3- ions in the mixed solution.
11. A person is suffering from lead poisoning if its concentration in him is more than 15 micrograms of
lead per decilitre of blood. What is concentration in parts per billion.
12. One kilogram of sea water sample contains 6 mg of dissolved oxygen. What is concentration of O 2
in the sample in ppm.
13. What is the molarity of HCl if density of the solution is 1.17 g/cc?
14. 20 mL, 0.1 M H3BO3 solution on complete neutralisation require how many mL of 0.05 M NaOH.
15. The density of a 3.6 M sulphuric acid solution that is 29% H2SO4 by mass. What is molarity?
16. 15 g of an unknown molecular substance was dissolved in 450 g of water. The resulting solution
freezes at -0.34 oC. What is the molar mass of the substance? ( Kf for water = 1.86 K kgmol-1)

17. What mass of ethylene glycol ( molar mass = 62 g mol-1) must be added to 5.5 Kg of water to
lower the freezing point of water from 0 oC to -10.0 oC? ( Kf for water = 1.86 K kgmol-1).
18. 100 mg of a protein is dissolved in enough water to make 10 mL of a solution. If this solution has
an osmotic pressure of 13.3 mm Hg at 25 oC, what is the molar mass of protein.
( R = 0.0821 L atm mol-1K-1 and 760 mm Hg = 1 atm)
20. What concentration of N2 be present in a glass of water at room temperature? Assume a
temperature of 25oC, a total pressure of 1 atm and mole fraction of nitrogen in air of 0.78.
[ KH for N2 = 8.42 x 10-7 M/mm]
21. 18 g glucose (C6H12O6 ) is added to 178.2 g of water. What is the vapour pressure of water for
this aqueous solution at 1 atm.
22. The freezing point of water is depressed by 0.37°C in 0.01 molal NaCl solution. The freezing point
of 0.02 molal solution of urea is depressed by....?
23. A 5.2 molal aqueous solution of methyl alcohol, CH3 OH, is supplied. What is the mole fraction of
methyl alcohol in the solution ?
24. Solutions A, B, C and D are 0.1 M glucose, 0.05 M NaCl, 0.05 M BaCl2 and 0.1 M A1C13 respec
tively. Which of the following pairs is isotonic ?
25. The freezing point depression constant for water is 1.86° Cm–1. If 5 g Na2SO4 is dissolved in 45 g
water, the freezing point is changed by –3.82°C. Calculate the van’t Hoff factor for Na 2 SO4 ?

Part-2

1) Calculate masses of cane sugar and water required to prepare 250 g of 25% solution of cane sugar.
[ Ans = 62.5g,
187.5g]
2) One litre of sea water weight 1050 g and contains 6 x 10-3 g of dissolved oxygen gas. Calculate
the concentration of the dissolved oxygen in ppm. Ans = 5.71 ppm]
3) Find out the molarity, molality and mole fraction of 15% H2SO4 ( density = 1.02 gcm-3)
[ Ans = 1.56M, 1.8 m, 0.031]
4) Mole fraction of ethanol in ethanol-water system is 0.25. What is the % concentration of ethanol
by weight of the solution? [ Ans =
46%]
5) Calculate boiling point of solution when 2 g of Na 2SO4 (M = 142 g mol–1) was dissolved in 50 g
of water, assuming Na2SO4 undergo complete ionization. ( Kb = 0.52Kkg/mol) [AI 2016]

6) Vapour pressure of water at 20°C is 17.5 mm Hg. Calculate vapour pressure of water
at 20°C when 15 g of glucose (Molar mass = 180) is dissolved in 150 g of water. [2015]
7) Vapour pressure of chloroform and dichloromethane at 298 k are 200 mm Hg and 415 mm Hg
respectively. i) Calculate the vapour pressure of the solution prepared by mixing 25.5 g of
chloroform and 40 g of dichloromethane ii) mole fractions of each component in vapour phase.
[Ans = 347.9 mm,
0.18]
8) 2 g of benzoic acid dissolved in 25 g of benzene shows a depression in freezing point equal to
1.62 K. Kf for benzene is 4.9. What is the % association of acid if it forms dimer in solution?
[Ans -
99.2%]
9) A 5 % solution of cane sugar in water has freezing point of 271 K. Calculate the freezing point of
5% glucose in water if freezing point of pure water is 273.15 K. [Ans - 269.065 K]
10) At 300 k 36 g of glucose present in a L of its solution has an osmotic pressure of 4.98 Bar. If the
osmotic pressure of the solution is 1.52 bars at the same Temp. what would be its concentration.
[Ans - 0.061
M]
11) Determine the amount of CaCl2 ( i = 2.47 ) dissolved in 2.5 L of water such that its osmotic
pressure is 0.75 atm at 300 K. [Ans - 3.4 g]
12) Determine the osmotic pressure of a solution prepared by dissloving 25 mg of K 2SO4 in 2 L of
water at 25 oC, assuming that it is completly dissociated. [Ans - 5.27 x 10-3 atm]
13) Ethylene glycol is a common automobile antifreeze. Cal the freezing point of a solution
containing 12 g of this substance in 100 g of water. Would it be advisable to keep this substance
in the car radiator during summer. Kf for water = 1.86 K kg/mol, Kb for water = 0.512 K kg/mol
[Ans - 269.28
K ,Yes]
14) Find von’t Hoff factor for a compound which undergoes tetramerization in an organic solvent?
15) The degree of dissociation of Calcium nitrate in a dil aqueous solution containing 14 g of the salt
per 200 g of water at 373 K is 70%. If the vapour pressure of water is 760 mm of Hg, Calculater
the vapour pres sure of the solution. [ Ans = 757.04 mm of Hg ]
16) What mass of NaCl (molar mass = 58.5 g mol 1) must be dissolved in 65 g of water to lower the
freezing point by 7.5° C ? The freezing point depression constant,
Kf for water is 1.86 K kg mol–1. Assume van’t Hoff factor for NaCl is 1.87. [2010]
17) Calculate the depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is
added to 250 g of water. Ka = 1.4 x 10-3, Kf = 1.86. [Ans - 0.65 oC]
18) Give reasons :
(i) When mercuric iodide is added to an aqueous solution of KI, the freezing point is raised.
(ii) At higher attitudes, people suffer from a disease called anoxia, In this disease , they become
weak and can’t think clearly.
(iii) Aquatic animals feel more comfortable in cold water rather than hot water.
(iv) At hill stations people use pressure cooker to cook food.
(v) An. CaCl2 or Rock salt is sprinkled on road covered with snow. Which salt is better?
19) Differentiate with 2-2 example for each : a) Ideal and Non-ideal solution b) solutions showing
+ve and –ve deviation from Raoult’s Law. C) minimum and maximum boiling azeotrope.