SOLUTIONS

2008(DELHI)
1 State Henry’s law correlating the pressure of a gas and its solubility in a solvent and 2
mention two applications of the law.
2 Calculate the temperature at which a solution containing 54 g of glucose, (C 6 H12 O6 ) in 3
250 g of water will freeze. (Kf for water =1.86 K mol kg -1 )
3 State Raoult’s law for solutions of volatile liquids. Taking suitable examples explain the 2
meaning of positive and negative deviations from Raoult’s law.
OR
Define the term osmotic pressure. Describe how the molecular mass of a substance can
be determined by a method based on measurement of osmotic pressure?
2008(ALL INDIA)
4 Define osmotic pressure. How is it that measurement of osmotic pressures is more 2
widely used for determining molar masses of macromolecules than the rise in boiling
point or fall in freezing point of their solutions?
OR
Derive an equation to express that relative lowering of vapour pressure for a solution is
equal to the mole fraction of the solute in it when the solvent alone is volatile.
5 Calculate the amount of KCl which must be added to 1 kg of water so that its freezing 3
point is depressed by 2 K. (Kf for water =1.86 K kg mol-1, Atomic mass K = 39, Cl = 35.5)
2009(DELHI)
6 Differentiate between molality and molarity of a solution. What is the effect of change in 2
temperature of a solution on its molality and molarity?
7 100 mg of a protein is dissolved in just enough water to make 10.0 mL of solution. If this 3
solution has an osmotic pressure of 13.3 mm Hg at 25 oC, what is the molar mass of the
protein? (R = 0.0821 L atm mol–1 K–1 and 760 mm Hg = 1 atm.)
8 Calculate the freezing point depression expected for 0.0711m aqueous solution of
Na2 SO4. If this solution actually Freezes at -0.320°C, what would be the value of van't
Hoff factor? (Kf for water is 1.86°C mol-1).
2009(ALL INDIA)
9 (a) Define the following terms: 5
(i) Mole fraction
(ii) Van’t Hoff factor
(b) 100 mg of a protein is dissolved in enough water to make 100 mL of a solution. If this
solution has an osmotic pressure 13.3 mm Hg at 25° C, what is the molar mass of
protein? (R = 0.0821 L atm mol–1 K–1 and 760 mm Hg = 1 atm.)
OR
What is meant by:
(i) Colligative properties
(ii) Molality of a solution.
(b) What concentration of nitrogen should be present in a glass of water at room
temperature? Assume a temperature of 25° C, total pressure of 1 atmosphere and mole
fraction of nitrogen in air of 0.78. [KH for nitrogen = 8.42 × 10–7 M/mm Hg]
2009(FOREIGN)
10 Differentiate between molality and molarity of a solution. What is the effect of rise in 2
temperature on molality and molarity of the solution?
11 Calculate the freezing point depression for 0.0711 m aqueous solution of sodium 3
sulphate, if it is completely ionised in solution. If this solution actually freezes at – 0.320
°C, what is the value of Van’t Hoff factor for it at the freezing point? (Kf for water is
1.86°C mol–1)
12 What is ‘reverse osmosis’? 1
2010(DELHI)
13 Non-ideal solutions exhibit either positive or negative deviations from Raoult's law. What 2
are these deviations and why are they caused? Explain with one example for each type.
14 A solution prepared by dissolving 1.25 g of oil of winter green (methyl salicylate) in 99.0 g 3
of benzene has a boiling point of 80.31°C. Determine the molar mass of this compound.
(B.P. of pure Benzene = 80.10°C and Kb for benzene = 2.53°C kg mol–1)
15 A solution of glycerol (C3H8O3; molar mass = 92 g mol-1) in water was prepared by 3
dissolving some glycerol in 500 g of water. This solution has a boiling point of 100.42°C.
What mass of glycerol was dissolved to make this solution? Kb for water = 0.512 K kg
mol-1.
2010(ALL INDIA)
16 Define the terms, ‘osmosis’ and ‘osmotic pressure’. What is the advantage of using 2
osmotic pressure as compared to other colligative properties for the determination of
molar masses of solutes in solutions.
17 What mass of NaCl (molar mass = 58.5 g mol–1) must be dissolved in 65 g of water to 3
lower the freezing point by 7.5°C? The freezing point depression constant, Kf , for water
is 1.86 K kg mol–1. Assume van’t Hoff factor for NaCl is 1.87.
18 What mass of ethylene glycol (molar mass = 62.0 g mol–1) must be added to 5.50 kg of 3
water to lower the freezing point of water from 0°C to – 10.0°C? (Kf for water = 1.86 K kg
mol–1)
19 Differentiate between molarity and molality of a solution.
20 15 g of an unknown molecular substance was dissolved in 450 g of water. The resulting 3
solution freezes at – 0.34°C. What is the molar mass of the substance? (Kf for water =
1.86 K kg mol–1).
2010(ALL INDIA)
21 (a) Non-ideal solutions exhibit either positive or negative deviations from Raoult's law. 5
What are these deviations and how are they caused?
(b) What mass of NaCl (molar mass = 58.5 g mol–1) must be dissolved in 65g of water to
lower the freezing point by 7.50°C? The freezing point depression constant, Kf for water
is 1.86 K kg mol–1. Assume van't Hoff factor for NaCl is 1.87.
OR
(a) Define the terms osmosis and osmotic pressure. What is the advantage of using
osmotic pressure as compared to other colligative properties for the determination of
molar masses of solutes in solution?
(b) A solution prepared from 1.25 g of oil of wintergreen (methyl salicylate) in 99.0 g of
benzene has a boiling point of 80.31°C. Determine the molar mass of this compound.
(Boiling point of pure benzene = 80.10°C and Kb for benzene = 2.53°C kg mol–1).
2010(FOREIGN)
22 (a) Differentiate between molarity and molality for a solution. How does a change in 5
temperature influence their values?
(b) Calculate the freezing point of an aqueous solution containing 10.50 g of MgBr2 in
200 g of water. (Molar mass of MgBr2= 184 g) (Kf for water = 1.86 K kg mol–1)
OR
(a) Define the terms osmosis and osmotic pressure. Is the osmotic pressure of a solution
a colligative property? Explain.
(b) Calculate the boiling point of a solution prepared by adding 15.00 g of NaCl to 250.00
g of water. (Kb for water = 0.512 kg mol–1), (Molar mass of NaCl = 58.44 g)
23 (a) State the following: (i) Henry’s law about partial pressure of a gas in a mixture. (ii)
Raoult’s law in its general form in reference to solutions.
(b) A solution prepared by dissolving 8.95 mg of a gene fragment in 35.0 mL of water has
 an osmotic pressure of 0.335 torr at 25°C. Assuming the gene fragment is a non-
electrolyte, determine its molar mass.
OR
(a) Differentiate between molarity and molality in a solution. What is the effect of
temperature change on molarity and molality in a solution?
(b) What would be the molar mass of a compound if 6.21g of it dissolved in 24.0 g of
chloroform form a solution that has a boiling point of 68.04°C. The boiling point of pure
chloroform is 61.7°C and the boiling point elevation constant, Kb for chloroform is
3.63°C/m.
2011(ALL INDIA)
24 State the following: (i) Raoult’s law in its general form in reference to solutions. 2
(ii) Henry’s law about partial pressure of a gas in a mixture.
25 A solution prepared by dissolving 8.95 mg of a gene fragment in 35.0 mL of water has an 3
osmotic pressure of 0.335 torr at 25°C. Assuming that the gene fragment is a non-
electrolyte, calculate its molar mass.
26 What mass of NaCl must be dissolved in 65.0 g of water to lower the freezing point of 3
water by 7.50°C? The freezing point depression constant (Kf) for water is 1.86 C/m.
Assume van’t Hoff factor for NaCl is 1.87. (Molar mass of NaCl = 58.5 g).
27 Differentiate between molality and molality values for a solution. What is the effect of 2
change in temperature on molarity and molality values?
2011(FOREIGN)
28 State Henry’s law about partial pressure of a gas in a mixture. 1
29 Differentiate between molarity and molality of a solution. Explain how molarity value of a 2
solution can be converted into its molality.
30 A 0.561 m solution of an unknown electrolyte depresses the freezing point of water by 2
2.93°C. What is Van’t Hoff factor for this electrolyte? The freezing point depression
constant (Kf) for water is 1.86°C kg mol–1.
31 State Raoult’s law in its general form with respect to solutions. 1
2012(DELHI)
32 A 1.00 molal aqueous solution of trichloroacetic acid (CCl3COOH) is heated to its boiling 3
point. The solution has the boiling point of 100.18°C. Determine the van’t Hoff factor for
trichloroacetic acid. (Kb for water = 0.512 K kg mol–1)
OR
Define the following terms: (i) Mole fraction (ii) Isotonic solutions (iii) Van’t Hoff factor
(iv) Ideal solution
33 Calculate the amount of KCl which must be added to 1 kg of water so that the freezing 3
point is depressed by 2 K. (Kf for water = 1.86 K kg mol–1)
34 A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in 500 3
g of water. This solution has a boiling point of 100.42 °C while pure water boils at 100 °C.
What mass of glycerol was dissolved to make the solution? (Kb for water = 0.512 K kg
mol–1)
35 15.0 g of an unknown molecular material was dissolved in 450 g of water. The resulting 3
solution was found to freeze at – 0.34 °C. What is the molar mass of this material? (Kf for
water = 1.86 K kg mol–1)
2012(ALL INDIA)
36 (a) Define the following terms: (i) Mole fraction (ii) Ideal solution 5
(b) 15.0 g of an unknown molecular material is dissolved in 450 g of water. The resulting
solution freezes at – 0.34°C. What is the molar mass of the material? (Kf for water = 1.86
K kg mol–1)
OR
(a) Explain the following: (i) Henry’s law about dissolution of a gas in a liquid.
 (ii) Boiling point elevation constant for a solvent.
(b) A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in
500 g of water. This solution has a boiling point of 100.42°C. What mass of glycerol was
dissolved to make this solution? (Kb for water = 0.512 K kg mol–1)
37 What are n-type semiconductors? 1
2012(FOREIGN)
38 At 25°C the saturated vapour pressure of water is 3.165 kPa (23.75 mm Hg). Find the 3
saturated vapour pressure of a 5% aqueous solution of urea (carbamide) at the same
temperature. (Molar mass of urea = 60.05 g mol–1)
39 (a) Define any two of the following terms: (i) van’t Hoff factor (ii) Mole fraction (iii) 2
Ebullioscopic constant (b) State Raoult’s law.
OR
The density of water of a lake is 1.25 g (mL)–1 and one kg of this water contains 92 g of
Na+ ions. what is the molarity of Na+ ions in the water of the lake? (Atomic mass of Na =
23.00 u)
40 Calculate the freezing point depression expected for 0.0711 m aqueous solution of 3
sodium sulphate. If the solution actually freezes at – 0.320 °C, what is the actual value of
van’t Hoff factor at this temperature? (Kf for water = 1.86 K kg mol–1)
2013(DELHI)
41 18 g of glucose, C6H12O6 (Molar Mass = 180 g mol–1) is dissolved in 1 kg of water in a 2
sauce pan. At what temperature will this solution boil? (Kb for water = 0.52 K kg mol–1,
boiling point of pure water = 373.15 K)
42 Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 10 –2 g of 3
K2SO4 in 2 L of water at 25oC, assuming that it is completely dissociated. (R = 0.082 L atm
K–1 mol–1, Molar mass of K2SO4 = 174 g mol–1).
2013(ALL INDIA)
43 (a) State Raoult’s law for a solution containing volatile components. How does Raoult’s 5
law become a special case of Henry’s law?
(b) 1.00 g of a non-electrolyte solute dissolved in 50 g of benzene lowered the freezing
point of benzene by 0.40 K. Find the molar mass of the solute. (Kf for benzene = 5.12 kg
mol–1)
OR
(a) Define the following terms: (i) Ideal solution (ii) Azeotrope (iii) Osmotic pressure
(b) A solution of glucose (C6H12O6) in water is labelled as 10% by weight. What would be
the molality of the solution? (Molar mass of glucose = 180 g mol–1)
2013(FOREIGN)
44 Measurement of which colligative property is preferred for determination of molar mass 1
of biomolecules?
45 Henry’s law constant (kH) for the solution of methane in benzene at 298 K is 4.27 ×10 5 2
mm Hg. Calculate the solubility of methane in benzene at 298 K under 760 mm Hg.
46 (i) Why is an increase in temperature observed on mixing chloroform and acetone? 2
(ii) Why does sodium chloride solution freeze at a lower temperature than water?
47 Why is glass considered a supercooled liquid? 1
48 What type of deviation is shown by a mixture of ethanol and acetone? What type of 2
azeotrope is formed by mixing ethanol and acetone?
2014(DELHI)
49 What are isotonic solutions? 1
50 Calculate the mass of compound (molar mass = 256 g mol–1) to be dissolved in 75 g of 2
benzene to lower its freezing point by 0.48 K (Kf = 5.12 K kg mol–1).
51 Define an ideal solution and write one of its characteristics. 2
52 Some liquids on mixing form ‘azeotropes’. What are ‘azeotropes’? 1
53 State Henry’s law. What is the effect of temperature on the solubility of a gas in a liquid? 2
54 State Raoult’s law for the solution containing volatile components. What is the similarity 2
between Raoult’s law and Henry’s law?
2014(ALL INDIA)
55 (a) Define the following terms: 5
(i) Molarity (ii) Molal elevation constant (Kb)
(b) A solution containing 15 g urea (molar mass = 60 g mol–1) per litre of solution in
water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass =
180 g mol–l) in water. Calculate the mass of glucose present in one litre of its solution.
OR
(a) What type of deviation is shown by a mixture of ethanol and acetone? Give reason.
(b) A solution of glucose (molar mass = 108 g mol–1) in water is labelled as 10% (by
mass). What would be the molality and molarity of the solution? (Density of solution =
1.2 g mL–1)
2014(FOREIGN)
56 (a) State Raoult’s law for a solution containing volatile components. Name the solution 5
which follows Raoult’s law at all concentrations and temperatures.
(b) Calculate the boiling point elevation for a solution prepared by adding 10 g of CaCl2 to
200 g of water. (Kb for water = 0.512 K kg mol–1, Molar mass of CaCl2 = 111 g mol–1)
Examination Papers 369
OR
(a) Define the following terms: (i) Azeotrope (ii) Osmotic pressure (iii) Colligative
properties
(b) Calculate the molarity of 9.8% (w/w) solution of H SO 2 4 if the density of the solution
is 1.02 g mL–1. (Molar mass of H2SO4 = 98 g mol–1)