SECTION A

Question 1.
If 2 gm of NaOH is present is 200 ml of its solution, its molarity will be
(a) 0.25
(b) 0.5
(c) 5
(d) 10

Answer: (a) 0.25

Question 2.
The atmospheric pollution is generally measured in the units of
(a) mass percentage
(b) volume percentage
(c) volume fraction
(d) ppm

Answer: (d) ppm

Question 3.
A 5% solution of cane-sugar (molecular weight = 342) is isotonic with 1% solution of substance A. The
molecular weight of X is
(a) 342
(b) 171.2
(c) 68.4
(d) 136.8

Answer: (c) 68.4

Question 4.
234.2 gm of sugar syrup contains 34.2 gm of sugar. What is the molal concentration of the solution.
(a) 0.1
(b) 0.5
(c) 5.5
(d) 55

Answer: (b) 0.5

Question 5.
H2S is a toxic gas used in qualitative analysis. If solubility of H 2S in water at STP is 0.195 m. what is the
value of KH?
(a) 0.0263 bar
(b) 69.16 bar
(c) 192 bar
(d) 282 bar

Answer: (d) 282 bar

SECTION B
6. State Raoult’s law for a solution containing volatile components. Write two characteristics of
the solution which obeys Raoult’s law at all concentrations.
7. What mass of ethylene glycol (molar mass = 62.0 g mol -1) must be added to 5.50 kg of water to
lower the freezing point of water from 0 to – 10°0 (k f for water = 1.86 K kg mol-1).
8. Write two differences between an ideal solution and a non-ideal solution.
9. State Henry’s law. What is the effect of temperature on the solubility of a gas in a liquid?
SECTION C
10. Define the terms ‘osmosis’ and ‘osmotic pressure’. What is the advantage of using osmotic
pressure as compared to other colligative properties for the determination of molar masses of
solutes in solutions?
11. A solution of glycerol (C3H8O3) in water was prepared by dissolving some glycerol in 500 g of
water. This solution has a boiling point of 100.42°C while pure water boils at 100°C. What mass
of glycerol was dissolved to make the solution?
(Kb for water = 0.512 K kg mol-1)  
12. A solution containing 15 g urea (molar mass = 60 g mol -1) per litre of solution in water has the
same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol -1) in water.
Calculate the mass of glucose present in one litre of its solution. 
13. Urea forms an ideal solution in water. Determine the vapour pressure of an aqueous solution
containing 10% by mass of urea at 40°C. (Vapour pressure of water at 40°C = 55.3 mm of Hg)
OR
What is meant by positive deviations from Raoult’s law? Give an example. What is the sign of Δmix H for
positive deviation?