Semi-Final Summative Test

Name Rexie Lyne C. Descallar Score

Date of
Year & Section Grade 12 – STEM 1 Submission March 30, 2022

ITEM NO. 11
1. A work of 657 J is done on a system that releases 434 J of heat. What is the energy change in the
system?
GIVEN:
Heat Added, q = +657J
Work Done, w = -434J

UNKNOWN:
Energy Change = ?

COMPUTATION:
∆E = q + w
∆E = 657 J + (−434 J)
∆𝐄 = 𝟐𝟐𝟑 𝐉

2. Which system does more work?

a. ∆E = 221 J, q = 357 J b) ∆E = −404 J , q = 395 J

GIVEN: GIVEN:
Internal Energy ∆E = 221 J Internal Energy ∆E = -404 J
Heat (q) = 357 J Heat (q) = 395 J

UNKNOWN: UNKNOWN:

Work Done (w) = ? Work Done (w) = ?

COMPUTATION: COMPUTATION:
∆E = q + w ∆E = q + w
𝑤 = ∆E − q
𝑤 = ∆E − q
𝑤 = 221 J − 357 J
𝑤 = 221 J − 357 J
𝒘 = −𝟕𝟗𝟗 𝐉
𝒘 = −𝟏𝟑𝟔 𝐉

ANSWER: System A does more work.

3. Write the thermochemical equations for the following reactions:

a.) Heat energy of 566.0 kJ is absorbed when 2 mol carbon dioxide decomposes to carbon
monoxide and oxygen gas.

H = 1132.0 KJ 𝟐𝐂𝐎𝟐 → 𝟐𝐂𝐎 + 𝐎𝟐

b.) Combustion of 1 mol sulfur to produce sulfur trioxide releases 395.3 kJ of heat energy.

H = -395.3 KJ 𝐒 + 𝐎𝟑 → 𝐒𝐎𝟑

4. Octane, a major component of gasoline, burns according to the reaction:

2C8H18 (l) + 25O2 (g) → 16CO2 (g) + 18H2O (g) ∆H = -1.10 x 104 kJ

Calculate the heat evolved when 355 g of octane burns.

GIVEN:
Mass of C8H18 = 355g
−1.10 ×104 KJ
Conversion Factor = 2 mol C8 H18

UNKNOWN:
Heat Evolved = ?
COMPUTATION:
1 mol C8 H18 −1.10 ×104 KJ
heat evolved = 355g C8 H18 × 114.23g C8 H18
× 2 mol C8 H18
= −𝟏𝟕𝟎𝟗𝟐. 𝟕𝟏 𝐊𝐉

= −𝟏𝟕𝟎𝟗 × 𝟏𝟎𝟑 𝐊𝐉
5. Methanol undergoes combustion according to the equation:

2CH3OH (l) + 3O2 (g) → 2CO2 (g) + 4H2O (l) ∆H = -1452.8 Kj

Find the amount of heat given off from the combustion of 323.2 g CH3OH.

GIVEN:
Mass of CH3OH = 323.2g
−1452.8 KJ
Conversion Factor = 2 mol CH OH
3

UNKNOWN:
Heat Evolved = ?
COMPUTATION:
1 mol CH3 OH −1452.8 KJ
heat evolved = 323.2g CH3 OH × 32.04G CH3 OH
× 2 mol CH3 OH
= −𝟕𝟑𝟐𝟕. 𝟒𝟖 𝐊𝐉

= −𝟕. 𝟑𝟑 × 𝟏𝟎𝟑 𝐊𝐉
6. Calculate the ∆H0rxn for the reaction C (graphite) + 2H2 (g) → CH4 (g)

From the following enthalpy changes:

C (graphite) + O2 (g) → CO2 (g) ∆H = -393.5 kJ

2H2 (g) + O2 (g) → 2H2O (l) ∆H = -571.6 kJ
CH4 (g) + 2O2 (g) → CO2 (g) + 2H2O (l) ∆H = -890.4 kJ

COMPUTATION:
𝐶(𝑔𝑟𝑎𝑝ℎ𝑖𝑡𝑒) + O2(g) → CO4(g) ∆H = −393.5 KJ
2H2(g) + O2(g) → 2H2 O(1) ∆H = −571.6 KJ
CO2(g) + 2H2 O(1) → 2O2(g) + CH4(g) ∆H = 890.4 KJ
𝐶(𝑔𝑟𝑎𝑝ℎ𝑖𝑡𝑒) + 2H2(g) → CH4(g) ∆𝐇°𝐫𝐱𝐦 = −𝟕𝟒. 𝟕 𝐊𝐉