27/08/2021

Evening

Corporate Office: Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph. 011-47623456

Time : 3 hrs.
Answers & Solutions M.M. : 300

for
JEE (MAIN)-2021 (Online) Phase-4
(Physics, Chemistry and Mathematics)

IMPORTANT INSTRUCTIONS :
(1) The test is of 3 hours duration.

(2) The Test Booklet consists of 90 questions. The maximum marks are 300.

(3) There are three parts in the question paper A, B, C consisting of Physics, Chemistry and
Mathematics having 30 questions in each part of equal weightage. Each part has two sections.

(i) Section-I : This section contains 20 multiple choice questions which have only one correct
answer. Each question carries 4 marks for correct answer and –1 mark for wrong answer.

(ii) Section-II : This section contains 10 questions. In Section-II, attempt any five questions out of
10. There will be no negative marking for Section-II. The answer to each of the questions is
a numerical value. Each question carries 4 marks for correct answer and there is no negative
marking for wrong answer.

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 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

PART–A : PHYSICS
Answer (2)
SECTION - I
Sol. Charge on C1, q1 = C1V = 2VC
Multiple Choice Questions: This section contains 20 Charge on C2 and C3 are same
multiple choice questions. Each question has 4 choices  q2 = q3 = CeqV
(1), (2), (3) and (4), out of which ONLY ONE is correct. = 4VC
 q1 : q2 : q3 = 1 : 2 : 2
Choose the correct answer :
3. An antenna is mounted on a 400 m tall building.
1. A coaxial cable consists of an inner wire of radius What will be the wavelength of signal that can be
‘a’ surrounded by an outer shell of inner and outer radiated effectively by the transmission tower upto
radii ‘b’ and ‘c’ respectively. The inner wire carries a range of 44 km?
an electric current i0, which is distributed uniformly (1) 75.6 m (2) 37.8 m
across cross-sectional area. The outer shell carries
(3) 605 m (4) 302 m
an equal current in opposite direction and
distributed uniformly. What will be the ratio of the Answer (3)
magnetic field at a distance x from the axis when
Sol. d  2RhT
(i) x < a and (ii) a < x < b ?

x2 b2  a2  44  103  2  6400  103  hT

(1) (2)
b2  a2 x2
 hT  151.25 m

a2 x2 
(3) (4) ∵ lantenna 
x2 a2 4
Answer (4)    4l
Sol. (i) x < a
considering, hT = l = length of antenna
0I0 x
B1   = 4 × 151.25 = 605 m
2a2
4. Match List-I with List-II.
(ii) a < x < b
List-I List-II
 I
B2  0 0 (a) RH(Rydberg constant) (i) kg m–1s–1
2x
(b) h(Planck’s constant) (ii) kg m2s–1
2
B1 x
  (c) B(Magnetic field (iii) m–1
B2 a2
energy density)
2. Three capacitors C1 = 2 F, C2 = 6 F and C3 = 12
(d) (coefficient of viscocity) (iv) kg m–1s–2
F are connected as shown in figure. Find the ratio
of the charges on capacitors C 1 , C 2 and C 3 Choose the most appropriate answer from the
options given below:
respectively:
(1) (a)-(iii), (b)-(ii), (c)-(iv), (d)-(i)
D
(2) (a)-(iv), (b)-(ii), (c)-(i), (d)-(iii)
A C2 C3 B
(3) (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)
(4) (a)-(iii), (b)-(ii), (c)-(i), (d)-(iv)
C1 Answer (1)
Sol. Unit of Rh = m–1
V Unit of h = ET = kg m2s–1
(1) 2 : 3 : 3 (2) 1 : 2 : 2 Unit of B = kg m–1s–2
(3) 2 : 1 : 1 (4) 3 : 4 : 4 Unit of  = kg m–1s–1

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 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

5. Figure shows a rod AB, which is bent in a 120° 6. Water drops are falling from a nozzle of a shower
circular arc of radius R. A charge (–Q) is uniformly onto the floor, from a height of 9.8 m. The drops fall

distributed over rod AB. What is the electric field E at a regular interval of time. When the first drop
at the centre of curvature O? strikes the floor, at that instant, the third drop begins
to fall. Locate the position of second drop from the
y floor when the first drop strikes the floor.
A
(1) 2.45 m

O 60° 120° x (2) 7.35 m

60°
R (3) 2.94 m
B (4) 4.18 m
Answer (2)
3 3Q
(1) (iˆ)
8 2  0R 2 2H
Sol. T   T  2 sec
g
3 3Q
(2) ( iˆ) at t = 0  1st drop
2 2
8   0R
at t = t  2nd drop
at t = 2t  3rd drop
3 3 Q ˆ
(3) (i )
80R2 1
 2t  2  t 
2
3 3 Q
(4) (iˆ) h
1  1
 g  ( t)2     9.8 
1
162 0R2 2 2 2

Answer (1) 9.8 3

 HF  9.8    9.8  7.35 m
4 4
7. The colour coding on a carbon resistor is shown in
dq
the given figure. The resistance value of the given
 dE resistor is:

Sol.

Gold
Red
Greed
Violet
E   dE cos 
(1) (7500 ± 750) 
 /3 (2) (5700 ± 375) 
K  ( Q) Rd
    cos  (3) (5700 ± 285) 
2 R2
 /3 R
3 (4) (7500 ± 375) 
Answer (4)
3 KQ
 [sin ]/3/3
2 R2
Sol.
V G
3 KQ 2 3
  GR
2 R 2
R = 75 × 100 ± 5%
 3 3  R = 7.5 k ± 5%
 E (iˆ)
2 2  R = (7500 ± 375) 
8   0R
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 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

8. The boxes of masses 2 kg and 8 kg are connected
by a massless string passing over smooth pulleys.
Calculate the time taken by box of mass 8 kg to
strike the ground from rest. (use g = 10 m/s2):
10. Curved surfaces of a plano-convex lens of
refractive index 1 and a plano-concave lens of
refractive index 2 have equal radius of curvature
as shown in figure. Find the ratio of radius of
curvature to the focal length of the combined
lenses.

2
1

8 kg

20 cm
2 kg
(1) 2 – 1
(2) 1 – 2
(1) 0.4 s
1
(2) 0.25 s (3)   
2 1
(3) 0.34 s
(4) 0.2 s 1
(4)   
1 2
Answer (1)
Answer (2)
2T T
1 2
1 1 1
Sol.  
a f f1 f2
Sol. 2 8 kg 2 kg a

 1  1
 (1  1)    (2  1)   
80 20 R  R
80 – 2T = 4a ...(1)
R
T – 20 = 2a ...(2)  (1  1)  (1   2 )  (1  2 )
f
From (1) and (2)
11. A player kicks a football with an initial speed of
a = 5 m/s2 25 ms–1 at an angle of 45° from the ground. What
are the maximum height and the time taken by the
2H 2  20  2 football to reach at the highest point during motion?
t   0.4 s
a/2 100  5 (Take g = 10 ms–2)
9. A mass of 50 kg is placed at the centre of a uniform (1) hmax = 10 m, T = 2.5 s
spherical shell of mass 100 kg and radius 50 m. If
(2) hmax = 15.625 m, T = 1.77 s
the gravitational potential at a point, 25 m from the
centre is V kg/m. The value of V is: (3) hmax = 3.54 m, T = 0.125 s
(1) +2G (2) –60G (4) hmax = 15.625 m, T = 3.54 s
(3) –20G (4) –4G Answer (2)
Answer (4)
1
252 
GM Gm u2 sin2  2
Sol. V    Sol. hmax    15.625 m
R r 2g 2  10

( G)50 (G)(100)
  1
25 50 25 
u sin  2  1.77 s
T 
= – 4G g 10

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 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

12. Two discs have moments of intertia I1 and I2 about Sol. Current sensitivity = 2 div/mA
their respective axes perpendicular to the plane and
50
passing through the centre. They are rotating with So full scale current  mA
angular speeds, 1 and 2 respectively and are 2
brought into contact face to face with their axes of = 25 mA
rotation coaxial. The loss in kinetic energy of the Full scale voltage = 50 mV
system in the process is given by:
V
So, Resistance   2
I1I2 2 I
(1) (I  I ) (1  2 )
1 2 14. The light waves from two coherent sources have
same intensity I1 = I2 = I0. In interference pattern the
(1  2 )2 intensity of light at minima is zero. What will be the
(2) intensity of light of maxima?
2(I1  I2 )
(1) 5 I0
(2) I0
(I1  I2 )2 12
(3) (3) 4 l0
2(I1  I2 )
(4) 2 l0
Answer (3)
I1I2 2
(4) 2(I  I ) (1  2 )
 
2
1 2 Sol. Imax  I1  I 2
Answer (4)
 
2
Sol. Using conservation of angular momentum  2 I0  4 I0

I11 + I22 = (I1 + I2) 15. For a transistor  and  are given as
IC IC
I11  I2 2  and  
 IE IB . Then the correct relation
I1  I2
between  and  will be:
1 2 1 2
Loss in KE.  I11  I2 2 1 
2 2 (1)  

2
1 I  I   
 (I1  I2 )  1 1 2 2  (2)  
2  I1  I2  1– 
(3)  = 1
2
1 (I   I  ) 
 (I112  I2 22 )  1 1 2 2 (4)  
2 2(I1  I2 ) 1– 
Answer (2)
I1I2
 (1  2 )2 Sol. We know, IE = IC + IB
2(I1  I2 )
IC IC
13. For full scale deflection of total 50 divisions, 50 mV  IC 
 
voltage is required in galvanometer. The resistance
of galvanometer if its current sensitivity is 2 div/mA
1 1
will be   1
 
(1) 4 
(2) 2  1 1 1 
 1 
(3) 5    
(4) 1 

Answer (2) 
1 

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 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

16. A constant magnetic of 1 T is applied in the x > 0
region. A metallic circular ring of radius 1 m is
moving with a constant velocity 1 m/s along the
x-axis. At t = 0 s, the centre O of the ring is at
x = –1 m. What will be the value of the induced emf
in the ring at t = 1 s? (Assume the velocity of the
ring does not change)
19. A monochromatic neon lamp with wavelength of
670.5 nm illuminates a photo-sensitive material
which has a stopping voltage of 0.48 V. What will be
the stopping voltage if the source light is changed
with another source of wavelength of 474.6 nm?
(1) 0.96 V

(2) 1.25 V
 (3) 1.5 V
O
(4) 0.24 V
x=0 x
Answer (2)
(1) 2 V (2) 2 V
(3) 1 V (4) 0 V hc
Sol.    eV1
Answer (1) 1

Sol. At t = 1 s, centre of ring is on verge of boundary

hc
 = Bvl    eV2
2
l = 2R
=1×1×2
hc hc
  e(V2  V1 )
17. If force (F), length (L) and time (T) are taken as the  2 1
fundamental quantities. Then what will be
dimension of density:
hc  1 1
(1) [FL–3T2] (2) [FL–3T3] V2    V1
e   2 1 
(3) [FL–4T2] (4) [FL–5T2]
Answer (3) V2 = 1.25 V
Sol. F = M1L1T–2 20. If the rms speed of oxygen molecules at 0°C is
 = M1L–3 160 m/s, find the rms speed of the hydrogen
molecules at 0°C.
 = [F]a[L]b[T]c
M1L–3 = [M1L1T–2]a[L]b[T]c (1) 40 m/s

 a = 1, b = –4, c = 2 (2) 80 m/s

 = F1L–4T2 (3) 640 m/s

18. The height of victoria falls is 63 m. What is the (4) 332 m/s
difference in temperature of water at the top and at
the bottom of fall? Answer (3)

[Given 1 cal = 4.2 J and specific heat of water

3RT
= 1 cal g–1° C–1] Sol. Vrms 
M
(1) 0.147°C (2) 1.476°C
(3) 14.76°C (4) 0.014°C VO  160
2
Answer (1)
Sol. By principle of calorimetry
MO
mgh = mcT VH  VO  2
2 2 MH
2
103 × 4.2 × T = 630
T = 0.147°C = 640 m/s

6
 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

Sol. Pz = 2 W
SECTION - II
Vz = 10 V
Numerical Value Type Questions: This section contains
Iz = 0.2 A (max)
10 questions. In Section II, attempt any five questions out
Izmax × RS = (14 – 10)
of 10. The answer to each question is a NUMERICAL
VALUE. For each question, enter the correct numerical RS = 20 
value (in decimal notation, truncated/rounded-off to the 4. An ac circuit has an inductor and a resistor of
second decimal place; e.g. 06.25, 07.00, –00.33, –00.30, resistance R in series, such that XL = 3R. Now, a
capacitor is added in series such that XC = 2R. The
30.27, –27.30) using the mouse and the on-screen virtual
ratio of new power factor with the old power factor of
numeric keypad in the place designated to enter the
the circuit is 5 : x. The value of x is ____
answer.
Answer (1)

1. A heat engine operates between a cold reservoir at R R 1

Sol. cos 2   
temperature T2 = 400 K and a hot reservoir at Z2 R 2  (xL  x C )2 2
temperature T1. It takes 300 J of heat from the hot
reservoir and delivers 240 J of heat to the cold R R 1
cos 1   
reservoir in a cycle. The minimum temperature of Z1 10 R 10
the hot reservoir has to be _______ K.
Answer (500) cos 2 5

cos 1 1
W 300  240 T
Sol.     1 2 5. Two simple harmonic motion, are represented by the
Q 300 T1 equations

 T1 = 500 K.  
y1  10 sin  3t  
 3
2. A tuning fork is vibrating at 250 Hz. The length of
the shortest closed organ pipe that will resonate
with the tuning fork will be _______ cm.

y 2  5 sin3t  3 cos3t 
(Take speed of sound in air as 340 ms–1) Ratio of amplitude of y1 to y2 = x : 1. The value of x is
____
Answer (34) Answer (1)

(2n  1) v  
Sol. f  Sol. y1  10 sin  3t  
4l  3 

lmin 
v
 34 cm

y 2  5 sin3t  3 cos3t 
4f
 
3. A zener diode of power rating 2 W is to be used as  10 sin  3t  
 3 
a voltage regulator. If the zener diode has a
breakdown of 10 V and it has to regulate voltage A1
1
fluctuated between 6 V and 14 V, the value of RS A2
for safe operation should be _____ .
6. The ratio of the equivalent resistance of the network
(shown in figure) between the points a and b when
RS switch is open and switch is closed is
x : 8. The value of x is ____.
Unregulated Regulated R 2R
voltage voltage

S b
a

Answer (20) 2R R

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 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

Answer (9) Answer (15)

4R Sol. Possible number of wavelength = nC2

Sol. Req when switch is closed =
3
= 15

3R 9. A plane electromagnetic wave with frequency of 30

Req when switch is open = MHz travels in free space. At particular point in
2
space and time, electric field is 6 V/m. The magnetic
field at this point will be x × 10–8 T. The value of x
3R
Ropen 9 is _______.
 2 
Rclose 4R 8 Answer (2)
3 Sol. |E| = E0sin (t + )

7. Wires W 1 and W 2 are made of same material |B| = B0sin (t + )

having the breaking stress of 1.25 × 109 N/m2. W1
and W2 have cross-sectional area of 8 × 10–7 m2
and 4 × 10–7 m2, respectively. Masses of 20 kg and
10 kg hang from them as shown in the figure. The
maximum mass that can be placed in the pan
without breaking the wires is ___ kg.
(Use g = 10 m/s2)
W1
20 kg
W2
10 kg
B B0 1
 
E E0 C
|B| = 2 × 10–8 T
10. A bullet of 10 g, moving with velocity v, collides head-
on with the stationary bob of a pendulum and recoils
with velocity 100 m/s. The length of the pendulum is
0.5 m and mass of the bob is 1 kg. The minimum
value of v = ______ m/s so that the pendulum
describes a circle.
(Assume the string to be inextensible and g = 10 m/s2)

pan
0.5 m

v
Answer (40)
10 g 1 kg
(m  30)g
Sol. 1   1.25  109
8  10 7
Answer (400)
 m + 30 = 100
Sol. For pendulum to describe circle
m = 70
vB/min  5  10  0.5  5 m/s
(m  10)g
2   1.25  109
4  10 7 pbullet initial = 0.01 × v
psystem final = 0.01 (–100) + 1 × 5
m + 10 = 50
m = 40 v
 (0.01)( 100)  5 
 40 kg is safest maximum mass 100

8. X different wavelengths may be observed in the

v
spectrum from a hydrogen sample if the atoms are 4
100
exited to states with principal quantum number
n = 6? The value of X is ______. v = 400

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 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

PART–B : CHEMISTRY

SECTION - I Answer (2)

Multiple Choice Questions: This section contains
OH O– O
20 multiple choice questions. Each question has
K2CO3 Br
4 choices (1), (2), (3) and (4), out of which ONLY ONE is Sol.
SN 2
correct.
(Attack is on least
hindered position)
Choose the correct answer :
1. Choose the correct statement from the following : 3. In stratosphere most of the ozone formation is
assisted by :
(1) The standard enthalpy of formation for alkali
metal bromides becomes less negative on (1) Visible radiations (2) Ultraviolet radiation
descending the group (3) γ-rays (4) Cosmic rays
(2) The low solubility of CsI in water is due to its Answer (2)
high lattice enthalpy
Sol. Ozone in the stratosphere is a product of UV
(3) Among the alkali metal halides, LiF is least radiations acting on dioxygen (O2) molecules.
soluble in water
UV
(4) LiF has least negative standard enthalpy of O2 (g) ⎯⎯⎯ → O(g) + O(g)
(free oxygen atoms)
formation among alkali metal fluorides
Answer (3) UV

O(g) + O2 (g)  O3 (g)
Sol. Alkali Enthalpies 4. Which one of the following chemicals is responsible
(Δf H°) kJ/mol
metal of formation for the production of HCl in the stomach leading to
MF MBr irritation and pain?
Li –612 –350
H
Na –569 –360 NNH2
K –563 –392
(1)
Rb –549 –389
Cs –531 –395
NH2
LiF has most negative standard enthalpy of HO
formation among alkali metal fluorides.
(2)
LiF is least soluble because of high lattice energy. N
H
2. The major product of the following reaction, if it
occurs by SN2 mechanism is : CO
(3) NH
OH
SO 2
K2CO3
+ Br
acetone HN
(4)
NH 2
N
O O
Answer (4)
(1) (2)
Sol. Histamine stimulates the secretion of pepsin and
hydrochloric acid in the stomach.
O
Structure of histamine is :
O
O
(3) (4) HN

NH2
N

9
 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

5. The major product (A) formed in the reaction given 7. The compound/s which will show significant
below is : intermolecular H-bonding is/are

CH3 – CH2 – CH – CH 2 – Br
NO2
CH 3OH
H
+ CH 3O A OH N CH3
(Major
product)
O
CH3 – CH2 – CH – CH2 Br
HO

(1) (b)
(a)
OCH3

CH3 – CH2 – C = CH2

(2)
OH

CH3 – CH2 – CH – CH2 – OH

(3)
(1) (a) and (b) only (2) (c) only
CH3 – CH2 – CH – CH2 – OCH3 (3) (a), (b) and (c) (4) (b) only
Answer (4)
(4)

Answer (2)
O + O–
N H
H O
CH3 – CH 2 – C – CH 2 – Br H 3C – CH 2 – C = CH 2 Sol. (a)

CH3O
Sol.
Intramolecular
6. Which one of the following reactions will not yield H-bonding
propionic acid?
(1) CH3CH2CH3 + KMnO4(Heat), OH–/H3O+ NH CH 3 Intramolecular
(b) C H-bonding
(2) CH3CH2COCH3 + OI–/H 3O
+
is not possible
O here. So,
(3) CH3CH2CH2Br + Mg,CO2 dry ether/H3O+ HO
intermolecular
(4) CH3CH2CCl3 + OH–/H3O+ H-bonding is
prominent
Answer (3)

Mg
Sol. CH3 CH2 CH2Br CH3 CH2CH2MgBr Because of large steric
crowding, intermolecular
O=C= O OH H-bonding is difficult

O 8. The oxide that gives H 2 O 2 most readily on

+
H3O treatment with H2O is
CH3 CH2 CH2COOH CH3CH2CH2 C O –MgBr
Butanoic (1) SnO2 (2) PbO2
Acid
(3) BaO2·8H2O (4) Na2O2

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 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

Answer (4)
O
Sol. Na2O2 gives H2O2 readily. (This is Merck’s method CH3MgBr + –
Sol. BrMg
of preparation of H2O2.)
O –
O
SnO2, PbO2 are oxides and can’t give peroxide on
hydrolysis. For 1 mole → 3 moles of CH3MgBr is used.
9. The correct order of ionic radii for the ions, P3–, S2– (2 moles required for ester and 1
, Ca2+, K+, Cl– is
mole for acidic H of ethyne)
(1) K+ > Ca2+ > P3– > S2– > Cl– 12. Lyophilic sols are more stable than lyophobic sols
(2) P3– > S2– > Cl– > Ca2+ > K+ because,
(3) P3– > S2– > Cl– > K+ > Ca2+ (1) The colloidal particles are solvated
(4) Cl– > S2– > P3– > Ca2+ > K+ (2) The colloidal particles have positive charge
Answer (3) (3) The colloidal particles have no charge
Sol. For isoelectronic species, as nuclear charge (4) There is a strong electrostatic repulsion
increases radius decreases. between the negatively charged colloidal
Greater the positive charge, lesser the size of ion. particles
Greater the negative charge, larger the size of ion.
Answer (1)
∴ P3– > S2– > Cl– > K+ > Ca2+
Sol. Lyophilic sols are more stable because they are
10. Which one of the following is formed (mainly) when solvated in solution. They are also called as solvent
red phosphorus is heated in a sealed tube at 803
loving.
K?
13. Which one of the following tests used for the
(1) Yellow phosphorus (2) β-Black phosphorus
identification of functional groups in organic
(3) α-Black phosphorus (4) White phosphorus
compounds does not use copper reagent?
Answer (3)
(1) Seliwanoff’s test
Sol. Black phosphorus has two forms : α-black and
(2) Barfoed’s test
β-black.
(3) Benedict’s test
α-black phosphorus is formed when red
phosphorus is heated in a sealed tube at 803 K. (4) Biuret test for peptide bond

11. Given below are two statements : Answer (1)

Sol. Seliwanoff’s test → Resorcinol dissolved in conc
Statement I : Ethyl pent-4-yn-oate on reaction HCl.
with CH3MgBr gives a 3°-alcohol. All other test use copper based reagent.
Statement II : In this reaction one mole of ethyl 14. The correct structures of A and B formed in the
pent-4-yn-oate utilizes two moles of following reactions are :
CH3MgBr. OH
O O
In the light of the above statements, choose the
H2 /Pd O B
most appropriate answer from the options given A
C 2H 5OH 1.0 eq.
below:
NO2
(1) Both Statement I and Statement II are true O
(2) Statement I is false but Statement II is true
OH O CH3
(3) Statement I is true but Statement II is false
A: , B:
(4) Both Statement I and Statement II are false (1)

Answer (3) NH2 NH2

11
 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

O O CH3
O CH3 O CH3 CH 3
NC
(3)
(2) A : , B:
CH3
NH2 NH CH3 O CH 3

O CH 3
OH OH O (4) CH3

CH3
(3) A : , B: CH3
Answer (4)
NH2 NH2 Sol.
OH OH CH 3 CH3
BrMgN=C –
O MgBr
+
NC O
2CH 3MgBr
(4) A : , B:
CH 3
CH3
+
H3O
O
NH2 NH CH3 CH3
C O=C OH
O H3C H 3O+
CH 3
Answer (4)
OH OH OH 16. The addition of dilute NaOH to Cr3+ salt solution will
O O give :
H 2/Pd O (1) A solution of [Cr(OH)4]—
Sol.
C 2H 5OH (1 eq)
(2) Precipitate of [Cr(OH)6]3–

NO2 NH2 NH CH3 (3) Precipitate of Cr2O3(H2O)n

(4) Precipitate of Cr(OH)3
(A) O
(N is more Answer (4)
(B)
basic than O)
(Major)
Sol. Cr 3+ + OH– ⎯⎯→ Cr ( OH)3
15. Which one of the following is the major product of ( green ppt )
the given reaction?
If NaOH is present in excess, then
CH3
–
NC O (i) 2CH 3 MgBr Cr ( OH)3 + OH– ⎯⎯→ Cr ( OH)4 
+
(ii) H 3O ( green solution)
(iii) H 2SO 4, heat
CH3 17. Potassium permaganate on heating at 513 K gives
a product which is
CH3
(1) Paramagnetic and green
NC CH 3 (2) Paramagnetic and colourless
(1) (3) Diamagnetic and colourless
(4) Diamagnetic and green
CH3
Answer (1, 2)
O CH 3
513K
Sol. 2KMnO4 ⎯⎯⎯→ K 2MnO4 + MnO2 + O2
CH 3 Paramagnetic Paramagnetic
(2) CH3 ( Green ) ( Colorless )

NTA Answer → (1)

CH3 Probable Answer → 1, 2 both
12
 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

18. Which one of the following is used to remove most 1. When 5.1 g of solid NH4HS is introduced into a two
of plutonium from spent nuclear fuel? litre evacuated flask at 27°C, 20% of the solid
(1) I2O5 (2) BrO3 decomposes into gaseous ammonia and
hydrogen sulphide. The K p for the reaction at
(3) O2F2 (4) ClF3 27°C is x × 10–2. The value of x is ______. (Integer
Answer (3) answer)

Sol. O2F2 oxidises plutonium to PuF6 and the reaction is [Given R = 0.082 L atm K–1 mol–1]
used in removing plutonium as PuF6 from spent Answer (6)
nuclear fuel. Sol. NH4HS(s)  NH3(g) + H2S(g)
Initially : 0.1 mole — —
At equil.: 0.1 – 0.02 0.02 mole 0.02 mole
19. Match List -I with List -II : = 0.08
List-I List-II nT = 0.02 + 0.02 = 0.04
(Name of ore/mineral) (Chemical formula) nTRT 0.04 × 0.082 × 300
PT = = = 0.492 atm
a. Calamine (i) ZnS V 2
b. Malachite (ii) FeCO3  0.492  0.492 
KP =    = 6.05 × 10−2
c. Siderite (iii) ZnCO3  2  2 
d. Sphalerite (iv) CuCO3.Cu(OH)2 ∴ x = 6 (nearest integer)
(1) (a)-(iii), (b)-(iv), (c)-(i), (d)-(ii) 2. Data given for the following reaction is as follows:
(2) (a)-(iii), (b)-(ii), (c)-(iv), (d)-(i) FeO(s) + C(graphite) ⎯⎯
→ Fe(s) + CO(g)
(3) (a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)
Δ f Ho ΔSo
(4) (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i) Substance
(kJ mol−1 ) (J mol−1K −1 )
Answer (4)
FeO(s) −266.3 57.49
Sol. Calamine — ZnCO3
C(graphite) 0 5.74
Malachite — Cu(OH)2.CuCO3
Fe(s) 0 27.28
Siderite — FeCO3
CO(g) −110.5 197.6
Sphalerite — ZnS
The minimum temperature in K at which the
20. Hydrolysis of sucrose gives:
reaction becomes spontaneous is_______. (Integer
(1) α-D-(–)-Glucose and β-D-(–)-Fructose answer)
(2) α-D-(+)-Glucose and α-D-(–)-Fructose Answer (964)
(3) α-D-(–)-Glucose and α-D-(–)-Fructose
Sol. FeO(s) + C(graphite) ⎯⎯
→ Fe(s) + CO(g)
(4) α-D-(+)-Glucose and β-D-(–)-Fructose
Answer (4) Δ f Ho (reaction) = (0 + ( −110.5)) − ( −266.3)
HO = 155.8 kJ/mol
C12H22O11 ⎯⎯⎯
2
→ C6H12O6 + C6H12O6
Sol. Sucrose α-D-( + ) -Glucose β-D-( – ) −Fructose
ΔSo (reaction) = 27.28 + 197.6 − (57.49 + 5.74)
SECTION - II = 224.88 − 63.23
Numerical Value Type Questions: This section contains = 161.65 J mol–1 K −1
10 questions. In Section II, attempt any five questions out
For spontaneity
of 10. The answer to each question is a NUMERICAL
VALUE. For each question, enter the correct numerical ΔG = ΔH − TΔS ( ΔG = 0)
value (in decimal notation, truncated/rounded-off to the
ΔH = T ΔS
second decimal place; e.g. 06.25, 07.00, –00.33, –00.30,
30.27, –27.30) using the mouse and the on-screen virtual ΔH 155.8 × 1000
T= = = 963.8
numeric keypad in the place designated to enter the ΔS 161.65
answer.
≈ 964 (nearest integer)
13
 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

3. The first order rate constant for the decomposition 5. Two flasks I and II shown below are connected by a
of CaCO3 at 700 K is 6.36 × 10–3 s–1 and activation valve of negligible volume.
energy is 209 kJ mol–1. Its rate constant (in s–1) at
600 K is x × 10–6. The value of x is _____. (Nearest
integer)

[Given R = 8.31 J K–1 mol –1; log 6.36 × 10–3 =

–2.19, 10–4.79 = 1.62 × 10–5]

Answer (16)
When the valve is opened, the final pressure of the
Sol. k1 = 6.36 × 10–3 s–1 T1 = 700 k system in bar is x × 10–2. The value of x is ____.
(Integer answer)
Ea = 209 kJ/mol
[Assume - Ideal gas; 1 bar = 105 Pa; Molar mass of
k2 = x × 10–6 s–1 T2 = 600 k N2 = 28.0 g mol–1, R = 8.31 J mol–1 K–1]
Answer (84)
k E 1 1
ln 2 = a  − 
k1 R  T1 T2  2.8
Sol. Number of moles of flask I = = 0.1
28

 x × 10 −6  209 × 103  1 1  0.2 1

log   =  −  =
Number of moles of flask II =
 6.36 × 10  8.31 × 2.303  700 600 
−3
28 140

log(x × 10 −6 ) = −4.79 1
0.1(300 − T) = (T − 60)
140
x × 10−6 = 1.62 × 10−5
T = 284 K
x = 16.2  16 (Nearest integer)
 1 1 
+ × 8.31 × 284
4. The number of optical isomers possible for n RT  10 140 

PT = T = = 84.2
[Cr(C2O4)3]3– is ______. VT 3

Answer (2)
≈ 84 (nearest integer)
Sol.
6. The number of photons emitted by a
monochromatic (single frequency) infrared range
finder of power 1 mW and wavelength of 1000 nm,
in 0.1 second is x × 1013. The value of x is _____.
(Nearest integer)
(h = 6.63 × 10–34 Js, c = 3.00 × 108 ms–1)
Answer (50)
Sol. Power = 1 mW
= 10–3 J in 1 sec.
= 10–4 J in 0.1 sec.

nhc
∴ Energy =
λ

n × 6.63 × 10 −34 × 3 × 108

10 −4 =
1000 × 10 −9

n = 50.2 × 1013

∴ x ≈ 50

14
 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

7. 40 g of glucose (Molar mass = 180) is mixed with 9. The number of species having non-pyramidal
200 mL of water. The freezing point of solution is shape among the following is _____.
_____ K. (Nearest integer)
(A) SO3
[Given : Kf = 1.86 K kg mol–1; Density of water =
1.00 g cm–3; Freezing point of water = 273.15 K] (B) NO3−
Answer (271)
(C) PCl3

40
Sol. Moles of glucose = (D) CO32−
180

Answer (3)
ΔTf = iK f m (i = 1 for glucose)

Sol. –
40 × 1000 O O O
–
= 1× 1.86 ×  Mass of water = 200 g 
180 × 200   S +
N P
 as d = 1 g/mL  –
C
O O O O Cl Cl –
O
= 2.06 Cl O
Trigonal Trigonal Pyramidal Trigonal
∴ Freezing point = Tf – ΔTf planar planar planar

= 273.15 – 2.06
10. The resistance of a conductivity cell with cell
= 271.09 constant 1.14 cm –1, containing 0.001 M KCl at
298 K is 1500 Ω. The molar conductivity of
 271 0.001 M KCl solution at 298 K in S cm2 mol–1 is
_____. (Integer answer)
8. 100 g of propane is completely reacted with
1000 g of oxygen. The mole fraction of carbon Answer (760)
dioxide in the resuting mixture is x × 10–2. The
value of x is _____. (Nearest integer) l
Sol. Cell constant = = 1.14 cm−1
a
[Atomic weight : H = 1.008; C = 12.00; O = 16.00]

Answer (19) C = 0.001 M

T = 298 K
Sol. C3H8 + 5O2 3CO2 + 4H2O
R = 1500 Ω
100 1000
Moles – –
initial 44 32
1 l  1
k= = × 1.14
1000 100 × 5 300 400 R  a  1500
Moles – –
final 32 44 44 44

k × 1000
Λm =
C
300
44
Mole fraction of CO2 =
19.89 + 6.81 + 9.09 1
× 1.14 × 1000
1500
=
= 19.02 0.001

∴ x = 19 = 760 S cm2 mol–1

15
 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

PART–C : MATHEMATICS

SECTION - I 4(a  b )  16(a  b )2 – 48ab

 x
Multiple Choice Questions: This section contains 20 24
multiple choice questions. Each question has 4 choices (a  b ) ± a2  b2 – ab
=
(1), (2), (3) and (4), out of which ONLY ONE is correct. 6
Choose the correct answer : d 2V
 24 x – 4(a  b )
1. A box open from top is made from a rectangular dx 2
sheet of dimension a × b by cutting squares each = 4(6x – (a + b)) < 0
of side x from each of the four corners and folding
up the flaps. If the volume of the box is maximum, a  b – a 2  b2 – ab
For
then x is equal to 6

a  b – a 2  b2 – ab
a  b – a2  b2  ab  Hence Vmax at x =
(1) 6
6
2. If the solution curve of the differential equation
(2x – 10y3)dy + ydx = 0, passes through the points
a  b – a 2  b2 – ab (0, 1) and (2, ), then is a root of the equation
(2)
6
(1) 2y5 – y2 – 2 = 0 (2) y5 – y2 – 1 = 0
(3) y5 – 2y – 2 = 0 (4) 2y5 – 2y – 1 = 0
a  b – a2  b2 – ab
(3) Answer (2)
12
Sol. 2xdy – 10y3 dy + ydx = 0

a  b  a2  b2 – ab dy y
(4)  
6 3
dx 10 y – 2 x

Answer (2)
dx 10 y 3 – 2 x
Sol.  
x dy y

dx 2 x
   10 y 2 (Linear D.E.)
dy y
b – 2x b

2
dy
I.F. = e  y  y2
x

2 10 y 5
a – 2x
  d ( xy )  5
a
V = (a – 2x) (b – 2x)x
 xy 2 = 2y 5  C
for maximum volume
 (0, 1)
dV C=– 2
0
dx
 –2(b – 2x)x + (a – 2x)(–2)x + (a – 2x)(b – 2x) = 0  2y 5 – xy 2 – 2  0

 12x2 + x(–2a – 2b – 2b – 2a) + ab = 0 (Put x = 2 gives equation whose root is )

 12x2 – 4(a + b)x + ab = 0 i.e. y5 – y2 – 1 = 0

16
 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

3. Let A(a, 0), B(b, 2b + 1) and C(0, b), b  0, |b|  1 b


1, be points such that the area of triangle ABC is
 2 x  ab
1 sq. unit, then the sum of all possible values of a b x
1–
is 2x
 2bx  x 2  (a  b )2 x – b(a  b )
2b –2b2
(1) (2)
b 1 b 1  x2 – 2ax + b(a + b) = 0
5. Let [] be the greatest integer less than or equal to
2 –2b . The set of all values of  for which the system
2b
(3) (4)
b 1 b 1 of linear equations x + y + z = 4, 3x + 2y + 5z =
3, 9x + 4y + (28 + [])z = [] has a solution is
Answer (2)
(1) (–, – 9)  [–8, ) (2) [–9, –8)
a 0 1 (3) R (4) (–, – 9)  (–9, )
1
Sol. Area = b 2b  1 1  1 Answer (3)
2
0 b 1 Sol. x + y + z = 4
 (a(2b + 1 – b) – b(–b) = ±2 3x + 2y + 5z = 3
 a(b + 1) = ±2 – b2 9 x  4y   28     z  []
2 2
2b 2  b For unique solution   0
 a or
b 1 b 1
1 1 1
–2 – b 2  2 – b 2 –2b 2
Sum of values of a =  3 2 5 0
b 1 b 1
9 4 28  [ ]
4. Two poles, AB of length a metres and CD of length
a + b (b  a) metres are erected at the same   56  2[ ] – 20  – 1 84  3[ ] – 45   1(–6)  0
horizontal level with bases at B and D. If BD = x
1  36  2[ ] – 39 – 3[ ] – 6  0
and tan ACB  , then
2  [ ]  – 9
(1) x2 – 2ax + a(a + b) = 0
   (–, – 9)  [–8,  )
(2) x2 + 2(a + 2b)x – b(a + b) = 0
and if [] = – 9, x = y = z = 0 gives infinite
(3) x2 + 2(a + 2b)x + a(a + b) = 0
solution.
(4) x2 – 2ax + b(a + b) = 0
 for R set of equations have solution.
Answer (4)

Sol. ∵ tan  
1 6. If lim  
x 2  x  1  ax  b, then the ordered pair
x 
2
(a, b) is
b
tan    1  1
x (1)  1,  (2)  –1, – 
C  2  2
  1  1
b
  (3)  –1,  (4)  1, – 
A  2  2
bx Answer (4)
a+b
a
a Sol. L  lim x 2  x  1 – ax
x 

B x D
( x 2 – x  1) – (ax )2
ab = xlim
and tan        x 2 – x  1  ax
x

17
 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

Answer (4)
(1  a2 )x 2  x  1
L = xlim Sol. 3x2 + 4x + 2 > 0 x  R (∵ D < 0)
 x 2 – x  1  ax
(3x2 + 4x + 3)2 – (k + 1)(3x2 + 4x + 3)(3x2 + 4x +
For limit to exist finitely 1 – a2 = 0
2) + k(3x2 + 4x + 2)2 = 0
1
–1   3x2  4x  3 
2
 3x2  4x  3 
x  1 x
lim  lim     (k  1)   k  0 ...(i)
 L = x  1 1  3x2  4x  2   3x2  4x  2 
x 2 – x  1  ax x 
1  a    
x x2
3x 2  4x  3
Let t
–1 3x 2  4x  2
L= b
1 a
3x 2  4x  2  1 1
For b to be finite, a  –1 t  1
2 2
3x  4x  2 3x  4x  2
–1  2 
 a = 1, b = 3x 2  4x  2   ,  
2 3 
1 2 2 3 3 4 1  3
7. If 0 < x < 1 and y  x  x  x  ....., then   0, 
2
2 3 4 3x  4x  2  2 
1 1  5
the value of e1 + y at x  is t  1   1, 
2
2 3x  4x  2  2 
 5
1 2  t2 – (k + 1)t + k = 0 where t   1,  ...(ii)
(1) 2e (2) e  2
2
 5
1 (ii) should have at least one root in  1, 
(3) 2e2 (4) e  2
2 (t – 1)(t – k) = 0
Answer (2)
t = 1, t = k
1 2 2 3 3 4
Sol. y  x  x  x  .....  5
2 3 4  k   1, 
 1   1  1  2
  1   x 2   1   x 3   1   x 4  .....
 2  3  4 9. Each of the person A and B independently tosses
 x 2 x3 x 4  three fair coins. The probability that both of them

 x 2  x 3  x 4  .....   
 2

 3

4
 ..... 


get the same number of heads is :
1
x2  x2 x3 x 4  (1)
8
(2) 1
  x   x     ..... 
1 x  2 3 4 
  5 5
x (3) (4)
y   ln 1  x  8 16
1 x
Answer (4)
1
y 1  ln 1  x  Sol. Let Ai  A gets i heads
1 x
1
 ln 1 x 
1 1 Bi  B gets i heads
y 1   ln(1 x ) 
e  1
e x  1
e x e  (1  1
x) e x
 3 
1 1 P  P    A i  Bi  
 at x  y  e2 
 i 0


2 2
8. The set of all values of k > –1, for which the  3 
equation (3x2 + 4x + 3)2 – (k + 1) (3x2 + 4x + 3)  P   P(A i )P(Bi ) 
 
(3x2 + 4x + 2) + k(3x2 + 4x + 2)2 = 0 has real roots,  i 0 
is  P(A0 )P(B0 )  P(A1)P(B1)  P(A2)P(B2)  P(A3 )P(B3)
 1 3  1  1 1 3 3 3 3 1 1
(1)  ,   {1} (2)   , 1        
 2 1  2  8 8 8 8 8 8 8 8
 5 5
(3) [2, 3) (4)  1,  
 2 16

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 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

1 3 3
 [ x  1] [ x  2] [ x  3]   A ,B   ,C  
  2 8 8
10. Let A   [ x ] [ x  3] [ x  3]  , where [t] denotes
 [x] 1 1 1
 [ x  2] [ x  4]  1 dt 3 dt 3 dt
2  1 t 2 8  1  3t 2  8  3  t 2
 
the greatest integer less than or equal to t. If 0 0 0

det(A) = 192, then the set of values of x is the  3 1  3 1 

interval =      
8 8 3 3 8 3 6
(1) [60, 61) (2) [65, 66)
 3 (2  3)
(3) [62, 63) (4) [68, 69) =  
8 16 16
Answer (3)
 1  sin x  1  sin x   
[ x  1] [ x  2] [ x  3] 12. If y ( x )  cot 1   , x   ,   ,
 1  sin x  1  sin x 2 
Sol. A  [ x ] [ x  3] [ x  3]  
[x] [ x  2] [ x  4]
dy 5
then at x  is
[x]  1 [x]  2 [x]  3 dx 6
 [x] [x]  3 [x]  3
1
[x] [x]  2 [x]  4 (1)  (2) 0
2
C3  C3 – C2, C2  C2 – C1 1
(3) –1 (4)
[x]  1 1 1 2
 [x] 3 0 Answer (1)
[x] 2 2 x x
Sol. ∵ 1  sin x  sin  cos and
2 2
(Expanding by C3)
x x
 1 2[ x]  3[ x]   2  3[ x]  3  [ x]   [ x]  2  2[ x]  3  1  sin x  sin  cos
2 2
= 3[x] + 6  x 
 2sin 
y ( x )  cot 1  2  cot 1  tan x     x
|A| = 192  
 2cos x   2  2 2
3[x] + 6 = 192  2
[x] = 62 dy 1

x  [62, 63) dx 2
1 13. The area of the region bounded by the parabola
xdx
11. The value of the integral  is (y – 2)2 = (x – 1), the tangent to it at the point
(1  x )(1  3 x )(3  x )
0 whose ordinate is 3 and the x-axis is

 3  3 (1) 4 (2) 6
(1) 4  1  6  (2) 8  1  2  (3) 10 (4) 9
   
Answer (4)
 3  3
(3) 4  1  2  (4) 8  1  6  Sol.
   
P
Answer (2) (0, 3)
(2, 3)
Sol. Put x = t2 (0, 2)
(1, 2)
1
2t 2
 2
)(1  3t 2 )(3  t 2 )
dt
0 (1  t (–4, 0)

2t 2 A B C
  
2 2 2 2 2
(1  t )(1  3t )(3  t ) 1 t 1  3t 3  t2 Equation of tangent at P(2, 3) is 2y – x = 4

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 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

Required area 16. The angle between the straight lines, whose
direction cosines are given by the equations
3
1 2 1 2l + 2m – n = 0 and mn + nl + lm = 0, is
= 2 (2  4)   (( y  2)  1)dy  2 (1 2)
0  
(1) (2)
3 3 2
 ( y  2)3 
= 3  y  3  6  9
1  4  1  8 
 3 0 (3)   cos   (4) cos  
9 9
14. A differential equation representing the family of
parabolas with axis parallel to y-axis and whose Answer (2)
length of latus rectum is the distance of the point Sol. ∵ 2l + 2m – n = 0 …(i)
(2, –3) from the line 3x + 4y = 5, is given by
and mn + nl + lm = 0 …(ii)
2 2
d y d x From equation (i) and (ii)
(1) 11  10 (2) 11  10
dx 2 dy 2
(m + l) (2l + 2m) + lm = 0
2 2
d x d y 2l2 + 5lm + 2m2 = 0
(3) 10  11 (4) 10  11
2 2
dy dx 2l2 + 4lm + lm + 2m2 = 0
Answer (1)
2l(l + 2m) + m(l + 2m) = 0
11
Sol. ∵ Length of latus rectum =  (2l + m) (l + 2m) = 0
5
 D.R.s of lines are < 1, –2, –2 > and < 2, –1, 2 >
2 11
Let equation of parabola : ( x  a )  ( y  b) Here l1l2 + m1m2 + n1n2 = 0
5
11 dy  Lines are perpendicular to each other.
 2( x  a ) 
5 dx 17. The Boolean expression (p  q)  ((r  q)  p) is
equivalent to
11 d 2 y
 2 (1) (p  q)  (r  q) (2) (q  r)  (p  q)
5 dx 2
(3) (p  r)  (p  q) (4) (p  q)  (r  q)
d 2y
 11  10
dx 2 Answer (1)

15. Let M and m respectively be the maximum and Sol.

p q
minimum values of the function f(x) = tan–1(sinx +
  p  q   r  q   p
cosx) in 0,  . Then the value of tan(M – m) is
 2
equal to
r
(1) 2  3 (2) 2  3 This is equivalent to (p  q)  (r  q)
(3) 3  2 2 (4) 3  2 2 18. If two tangents drawn from a point P to the parabola
y2 = 16(x – 3) are at right angles, then the locus of
Answer (4)
point P is
 
Sol. Range of sinx + cosx for x  0,  is [1, 2] (1) x + 2 = 0 (2) x + 4 = 0
 2
(3) x + 1 = 0 (4) x + 3 = 0
So, M  tan1 2 and m = tan–11
Answer (3)
 2  1
 M  m  tan1  Sol. From directrix of parabola perpendicular tangent are
 2  1 
  drawn.

2 1 and directrix of parabola y2 = 16(x – 3) is x = –1

 tan(M  m )  32 2
2 1  Required locus is x + 1 = 0

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 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

19. Let Z be the set of all integers, (x + y + z – 1) +(2x + 3y – z + 4) = 0


A  ( x, y )  Z  Z : ( x  2)2  y 2  4 ,   (1 + 2)x + (1 + 3)y + (1 – )z + (4 – 1) = 0 …(i)
∵ This plane is parallel to x-axis
B  ( x, y )  Z  Z : x 2  y 2  4 and  1 i (1 + 2) + 0 i (1 + 3) + 0 i (1 – ) = 0

C  ( x, y )  Z  Z : ( x  2)2  ( y 2  2)2  4  

1
2
If the total number of relations from A  B to
 Required equation of plane is
A  C is 2p, then the value of p is
(1) 16 (2) 49 1 3
 y  z3  0
(3) 25 (4) 9 2 z
Answer (3)  y – 3z + 6 = 0
Sol. The set A and set B are represented as : 
 r i ( j  3k )  6  0
(0, 2) (A B)
SECTION - II
Numerical Value Type Questions: This section contains
(–2, 4) (0, 0) (2, 0) (4, 0) 10 questions. In Section II, attempt any five questions out
of 10. The answer to each question is a NUMERICAL
VALUE. For each question, enter the correct numerical
value (in decimal notation, truncated/rounded-off to the
 A  B = {(0, 0), (1, 0), (2, 0), (1, 1), (1, –1)} second decimal place; e.g. 06.25, 07.00, –00.33, –00.30,
The set A and set C are represented as : 30.27, –27.30) using the mouse and the on-screen virtual
numeric keypad in the place designated to enter the
answer.

C 1. Let S be the mirror image of the point Q(1, 3, 4) with

(0, 2) respect to the plane 2x – y + z + 3 = 0 and let
R(3, 5, ) be a point of this plane. Then the square
A
of the length of the line segment SR is ______.
(2, 0)
Answer (72)
(A C) Sol. Let S be (x1, y1, z1)
x1 – 1 y1 – 3 z1 – 4 2  1– 3  4
   –2 
 A  C = {(1, 1), (2, 0), (2, 1), (2, 2), (3, 2)} 2 –1 1 2  (–1)2  12
2

 Total number relations from A  B to A  C = 25×5  x1 = –3, y1 = 5, z1 = 2

 p = 25 Hence S is (–3, 5, 2)
20. The equation of the plane passing through the line as R(3, 5, y) lies on 2x – y + z + 3 = 0

of intersection of the planes r i (i  j  k )  1 and  6 – 5 +  + 3 = 0   = –4
 Hence R is (3, 5, –4)
r i (2i  3 j  k )  4  0 and parallel to the x-axis is
(SR)2 = 36 + 0 + 36 = 72
 
(1) r i (i  3k )  6  0 (2) r i ( j  3k )  6  0 2. The probability distribution of random variable X is
  given by :
(3) r i ( j  3k )  6  0 (4) r i (i  3k )  6  0
X 1 2 3 4 5
Answer (2)
P( X ) K 2K 2K 3K K
Sol. Equation of plane passing through line of
 Let p = P(1 < X < 4 | X < 3). If 5p = K, then  is
intersection of planes r i (i  j  k )  1 and equal to ______.

r i (2i  3 j  k )  4  0 is Answer (30)

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 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

 1  X  4  P ((1  X  4)  ( X  3)) Sol. 3 × 722 + 2 × 1022 – 44

Sol. p  P  
 X 3  P ( X  3) = 3 × (1 + 6)22 + 2 (1 + 9)22 – 44

P ( X  2) 2K 2
    3  22 C0 22 C1(6)  22 C2 (6)2  ....  22 C22 (6)22 
P ( X  3) K  2K 3  

1 2  22 C0 22 C1(9)  ..... 22 C22 (9)22  – 44

Also, K + 2K + 2K + 3K + K = 1  K   
9
= 3.22C0 + 18k1 + 2.22C018k2 – 44
2 1
Now, 5p = K  5      = 30
3 9 Remainder when divided by 18 = 3 + 2 – 44 = –39
Remainder = (–39 + 54) – 54  15 – 54
2e x  3e – x 1
3. If  x –x
dx  (ux + vloge(4ex + 7e–x)) + C, = 15
4e  7e 14
6. Let z1 and z2 be two complex numbers such that
where C is a constant of integration, then u + v is
equal to ______. 
arg( z1  z2 )  and z 1, z 2 satisfy the equation
4
Answer (07)
|z – 3| = Re(z). Then the imaginary part of z1 + z2
Sol. Write 2ex + 3e–x = A(4ex + 7e–x) + B(4ex – 7e–x) is equal to _______.

Comparing both sides Answer (6)

4A + 4B = 2 ...(i) Sol. z1 = x1 + iy1 and z2 = x2 + iy2 and z1 – z2 = (x1 –

x2) + 2(y1 – y2)
7A – 7B = 3 ...(ii)
  y  y2  
arg( z1  z2 )   tan1  1 
13 1 4  x1  x2  4
on solving A  and B 
28 28
y1 – y2 = x1 – x2 …(i)

2e x  3e – x
 13 x –x
1 x
 28 (4e  7e )  28 4e – 7e
–x
 dx |z – 3| = Re(z)  |[x – 3) + 2y| = x
I  4e x  7e – x dx   
 4e x  7e – x

 (x – 3)2 + (y)2 = x2
 
 3
y2  6 x  
13 1  2
 x ln(4e x  7e – x )  C
28 18
Let point on this parabola
13 1 3  3 
Comparing LHS and RHS gives u  and v  2 2 6
2 2  2  at1 , 2at1  and  2  at2 , 2at2  , where a 
 u+v=7     4
y1 – y2 = x1 – x2
4. Let A(sec, 2tan) and B(sec, 2tan), where
2a(t1 – t2) = a(t12 – t22)

    , be two points on the hyperbola 2x2 – y2 = t1 + t2 = 2
2
2. If (, ) is the point of the intersection of the Now, img(z1 + z2) = y1 + y2
normals to the hyperbola at A and B, then (2)2 is = 2a(t1 + t2)
equal to ______.
6
Answer (*) = 2  (2)  6
4
Sol. Points A and B do not lie on the given curve so it
is not possible to solve the question with given 7. Two circles each of radius 5 units touch each other
data. at the point (1, 2). If the equation of their common
tangent is 4x + 3y = 10, and C 1 (, )
5. 3 × 722 + 2 × 1022 – 44 when divided by 18 leaves and C 2 (, ), C 1  C 2 are their centres, then
the remainder ______. |( + ) ( + )| is equal to _______.
Answer (15) Answer (40)

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 JEE (MAIN)-2021 Phase-4 (27-08-2021)-E

–4
M= 3  X B2  XG2
Sol. (variance)overall =  ( X )2
50
2920  8730
=  (15)2  8
5 5 50
C1 C2
P(1, 2)  = 17, 2 = 8
9. Let S = {1, 2, 3, 4, 5, 6, 9}. Then the number of
elements in the set T = {A  S : A   and the sum
of all the elements of A is not a multiple of 3} is
3 4 3 _______.
MC1C2   cos   , sin  
4 5 5 Answer (80)
x 1 y  2 Sol. There 2 numbers of the type 3 + 1, 2 numbers of
Point    5 (by parametric form of line)
4 3 the type 3 – 1 and 3 numbers of the type 3.
5 5 So number of subsets whose sum of divisible by 3
x – 1 = ± 4 or y – 2 = ± 3
 23 i( 2C02  2C12  2C22 )
x = 5, y = 5 or x = –3, y = –1
C1(5, 5) and C2(–3, –1) = 48

|( + ) ( + )| = |(5 + 5) (–3 –1)| = 40 Required number of subsets = 27 – 48 = 80

10. Let S be the sum of all solutions (in radians) of the
8. An online exam is attempted by 50 candidates out
equation sin4 + cos4 – sin cos = 0 in [0, 4].
of which 20 are boys. The average marks obtained
by boys is 12 with a variance 2. The variance of 8S
Then is equal to _______.
marks obtained by 30 girls is also 2. The average 
marks of all 50 candidates is 15. If  is the average
marks of girls and 2 is the variance of marks of 50 Answer (56)
candidates, then  + 2 is equal to _______. Sol. (sin2 + cos2)2 – 2sin2 cos2 – sin cos = 0
Answer (25) Let sin·cos = t, 1 – 2t2 – t = 0

Sol. Sum of marks of boys  X B  240 1

2t2 + t – 1 = 0  t OR –1
2
Total marks   X  750
1
sin ·cos  
So, sum of marks of girls = 510   XG 2 sin  cos   1
sin2  1 sin2  2
 X B2  XG2  5 9 13
  (12)2  2 and  ( XG )2  2  , , , ,
(Not Possible)
20 30 4 4 4 4
 X B2 S = 7
 X B2  2920 and  (17)2  2
30
8s
 56
  XG2  8730 

‰‰‰

23