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One way to start the study of heat is by defining some concepts such as
temperature.
However, this is associated with other previous concepts such as thermal
equilibrium.
Thermal equilibrium:
It is the state that is reached when macroscopic variables such as pressure, volume
and temperature do not vary over time.
Two bodies are in thermal equilibrium when they reach the same temperature.
It is also an initial way of defining what temperature is.
Temperature is the variable that determines the state of thermal equilibrium of the
systems.
CONCEPT OF TEMPERATURE
The previous definition defines temperature from a macroscopic point of view, that is,
at the level of concrete, visible, palpable objects or substances.
Can we define temperature from a molecular point of view? That's how it is:
Microscopic definition of temperature.
Temperature is a measure of the average kinetic energy of the molecules of a
substance.
The higher the temperature, the higher the average kinetic energy and vice versa.
Temperature Measurement
Thermometric properties. They are those properties of substances that present variation in their
magnitude when the temperature changes, for example the pressure of a gas that increases when
the temperature changes. Another thermometric property is volume. Bodies expand when the
temperature increases. And we can mention others such as electrical resistance or color.
The thermometer is the instrument used to measure temperature. This works based on some
thermometric property such as thermal expansion. A very common one is the mercury
thermometer. Currently there are ways to measure temperature based on infrared radiation that
any body emits.
Temperature Scales
We will see the basic scales to measure temperature:
• Celsius scale. It is the most widely accepted in the world.
Proposed by the Swedish Anders Celsius in 1742. In short, it is
based on the melting and boiling points of water under normal
conditions.
• Fahrenheit scale. It was one of the first proposed scales. It is
due to the German physicist Gabriel D. Fahrenheit in 1714. His
reference points are: the temperature of a mixture of water,
ice and salt, and the average temperature of the human
body.
• Kelvin scale. It is an absolute scale since it measures
temperature based on what it physically represents, that is, the
average molecular kinetic energy of substances. Its lower limit
is the absolute zero of temperatures. (0 K)
Conversion of Temperature Scales
To convert a temperature of one scale to another
we have the following expressions:
• From Celsius to Fahrenheit:
°F = (°Cx1.8) + 32
Thermal expansion is the result of a change in the average distance between the
atoms of a substance.
L=?
Concept of Heat
HEATH: Energy that transfers when there is a temperature difference.
UNITS OF HEAT
CALORIE: Amount of heat needed to raise the temperature of 1 gram of water in 1 °
C.
KILOCALORIE: Amount of heat needed to raise the temperature of 1 kilogram of
water in 1 °C.
B.T.U. Amount of heat needed to raise the temperature of 1 pound of water in 1°F.
Since heat is a form of energy, the SI unit of energy is the joule, therefore, that will be
the heat unit that we will preferably use.
Specific Heat
The answer is: the one with the lowest specific heat, as it
will need less heat per unit mass and for each degree of
temperature change. In this case it will be glycerin since its
specific heat is 2,420 J/kg°C, while water is 4,186 J/kg°C.
CHANGES OF PHASE AND LATENT HEAT
Matter presents in one of these three phases
• FUSION: It is the passage from the solid phase to the liquid phase at a
certain temperature.
In the link you will find a simulation of the phase changes of a substance
from the solid to the gaseous state.
• BOILING: It is the passage from the liquid phase to the gas phase at a certain
temperature.
• CONDENSATION: It is the passage from the gas phase to the liquid phase at a
certain temperature.
Solution:
Locate the process described in the graph of temperature vs heat, from -15 ° C to 15 ° C.
We note that three heat calculations are required:
1. Sensitive heat to raise ice temperature from -15 °C to 0 °C.
2. Latent heat of fusion to convert ice at 0 °C into water at 0 °C and
3. Sensible heat to raise the water temperature from 0 °C to 15 °C.
Necessary data:
Cice=2093J/kg°C
Cice=4186J/kg°C
Lf water=333,000 J/kg
m = 2.9 kg
T0 = -15°C
Tf water= 0°C
15°C
T= 15°C
-15°C
continua...
1. Calor sensible
3. Calor sensible
1. Conduction
2. Convection
3. Radiation
HEAT TRANSMISSION BY CONDUCTION
• Transmission by conduction occurs when energy propagates due to collisions between the
particles, so that in each collision the particles give up part of their kinetic energy to the
particles with which they interact, all without there being net transport of matter.
• This type of transmission is the one that takes place when a metal bar is heated at one end: at
that point the metal particles begin to move faster, collide with neighboring particles and the
energy is transmitted until reaching the other end, which increases its temperature. This type of
transmission is characteristic of solids, since liquids conduct very poorly and gases practically
do not conduct.
• Within solids there are very good conductors, such as metals, and bad conductors, such as
wood or paper.
• Important: In conduction, energy is transported due to collisions between particles, without
there being a net displacement of matter.
HEAT TRANSMISSION BY CONVECTION
Transmission by convection is typical of fluids (liquids and gases). In it there is a transport of energy
associated with the displacement of masses of fluid within the fluid itself, due to the differences in density
caused by the different temperatures of some areas.
• The atmosphere or the oceans have dynamics due to this form of heat transmission.
• Important: In convection, energy spreads due to the difference in density between hot and cold fluids.
In it there is transport of matter.
HEAT TRANSMISSION BY RADIATION
• The two previous means of transmission require a material medium,
however we continuously receive energy from the Sun through the
cosmic vacuum, so there must be a third form of heat transmission:
it is radiation transmission. All bodies radiate energy, the more
when the their temperature is higher.
• Depending on the temperature, the radiation emitted may or may
not be visible. Thus, at low temperatures it is not visible, while
increasing this the object begins to glow from red to white. This
phenomenon makes possible to determine the temperature of a
body.
• Important: Radiation is the propagation of energy through
electromagnetic waves that all bodies emit due to having a
temperature above absolute zero. In it energy is transported
without matter transport.
THERMODYNAMICS
In other words: "the heat added to a system is equal to the change in the internal energy
of the system plus the work done."
The 1st law of thermodynamics is a variant of the law of conservation of energy, energy is
neither created nor destroyed, it only changes shape.
Laws of Thermodynamics
2nd law: The first law of thermodynamics does not establish any restriction to
changes in energy due to heat flow, that is what the second law deals with, which
can be presented in several ways:
• Heat flows spontaneously from high-temperature bodies to low-temperature
bodies and is not the opposite direction.
• Heat energy cannot be completely transformed into mechanical work or vice
versa.
• It is impossible to build a machine that operates in perpetual motion.