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Course Objectives
Reservoir fluids
Phase behaviour
June 5, 2015
Course Objectives
Reservoir fluids
Reservoir fluids
Gas properties
Oil properties
Properties of formation water
Phase behaviour
Phase behaviour
Phase envelope
Flash calculations
Course Objectives
Reservoir fluids
Reservoir fluids
Fluid samples
Gas properties
In classifying gases, a number of its physical properties are of great
importance to the petroleum engineer and the petroleum industry.
Some of these are:
I Specific gravity (γg )
I Viscosity (µg )
I Formation Volume Factor (Bg )
I Solubility (R)
I Other thermo-chemical and thermo-physical properties:
I heating value
I heat capacity
I latent heat
I thermal conductivity
I enthalpy
I entropy etc.
Fluid properties (l.akanji@abdn.ac.uk) 12/66
Outline Reservoir fluids
Course Objectives Gas properties
Reservoir fluids Oil properties
Phase behaviour Properties of formation water
Figure 2 : Compressibility
factor chart for natural
gases. Courtesy of the
GPSA.
Fluid properties (l.akanji@abdn.ac.uk) 16/66
Outline Reservoir fluids
Course Objectives Gas properties
Reservoir fluids Oil properties
Phase behaviour Properties of formation water
Pseudo-critical graphs
Pseudo-critical graphs
PM
ρg = (8)
ZRT
Specific gravity of a gas is the ratio of its density to that of dry air.
Mgas P
ρgas ( m )gas
γgas = = Vm = RT
Mair P
(9)
ρair ( V )air RT
Mg Mg
γgas = = (10)
Mair 29
If the gas is a mixture, Mg = Ma
where:
µi = viscosity of component i in the gas phase
yi = mole fraction of component i in the gas phase
Mi = molecular weight of component i in the mixture
Fluid properties (l.akanji@abdn.ac.uk) 22/66
Outline Reservoir fluids
Course Objectives Gas properties
Reservoir fluids Oil properties
Phase behaviour Properties of formation water
ZT
Bg = S (12)
P
P std
S= (13)
Z std T std
Units: Bg = res-cu-ft/scf-gas where the standard conditions (std) P
and T are generally defined in
Europe: P = 1.00 bar ; T = 273.15 K
USA: P = 14.7 psia (1.01325 bar); T = 60.0o F (15o C).
Fluid properties (l.akanji@abdn.ac.uk) 23/66
Outline Reservoir fluids
Course Objectives Gas properties
Reservoir fluids Oil properties
Phase behaviour Properties of formation water
1 1 ∂Z
cg = − (16)
P Z ∂P
For gas mixtures:
1 1 ∂Z
cr = cg Pc = − (17)
Pr Z ∂Pr
Oil properties
I If the reservoir exists above the
bubble point pressure, an infinite
amount of gas can dissolve in the
oil, and the reservoir is said to be
undersaturated
I A reservoir may also exist at the
bubble point with or without an
initial gas-cap
I Oil properties normally
encountered in the governing flow
equations include density,
compressibility, formation volume
factor, viscosity and solubility of Figure 5 : Gas cap drive reservoir
gas in oil
Fluid properties (l.akanji@abdn.ac.uk) 26/66
Outline Reservoir fluids
Course Objectives Gas properties
Reservoir fluids Oil properties
Phase behaviour Properties of formation water
ρo lb − oil/cuf t. − oil
γo = = (18)
ρw lb − H2 O/cuf t. − H2 O
In the petroleum industry another gravity known as AP I gravity is
used and is defined as:
o 141.5
AP I = − 131.5 (19)
γo
o 141.5
AP I = − 131.5 (20)
γo
I Gas: infinite
I Gas condensate: 3 − 30
Mscf/stb
I Volatile oil: 2 − 3 Mscf/stb
I Black oil: 0.1 − 2 Mscf/stb
I Heavy oil: negligible
I Asphalts/bitumens: zero
Figure 8 : Typical graph of solution
GOR versus pressure
1 ∂ρo
Co = ( )T (21)
ρo ∂P
Liquid viscosity
Gas hydrates
I Natural gas and liquid water will combine to form gas hydrates
which are ice-like solids which forms at P and T normally
encountered in natural gas pipelines
I Gas hydrates are crystalline compounds formed by the chemical
combination of natural gas and water under P and T which are
not as low as the freezing point of water
Applications
Practical applications
Phase behaviour
Figure 14 : Phase diagram of a wet gas reservoir (from Arnold and Stewart,
2008)
The ”white oils” or high shrinkage oils (Fig. 16) have reservoir
temperature below the critical temperature.
Figure 16 : Phase diagram of a high shrinkage oil reservoir (from Arnold and
Stewart, 2008)
Figure 17 : Phase diagram of a low shrinkage oil reservoir (from Arnold and
Stewart, 2008)
Flash calculations
Flash calculations
yi Vi /V
Ki = = (23)
xi Li /L
yi = mole fraction of vapour component i in the mixture
xi = mole fraction of liquid component i in the mixture
Vi = moles of component i in the vapour phase
V =total moles in the vapour phase
Li =moles of component i in the liquid phase
L =total mole in the liquid phase
Flash calculations
Ki Fi
Vi = 1 (24)
V /L + Ki
Fi
Li = Ki
(25)
V /L +1
where Fi = total moles of component i in the fluid
Flash calculations
F
L= (26)
1 + (V /L)
Flash calculations
Estimate (V/L) ?
Calculate
?
Vi and Li
Sum to get
?
V and L
Compare
?
results
Flash calculations
References