+ Five stebion Addendum for “EMERGENCY MANAGEMENT PLAN” SAF-WP-IMS-003 REVISION 4 DATED 09.04.13 DO NOTE Following are the changes to the procedure: 1, Addition of Spill Control Procedures for Nitric Acid and Caustic. 2. Change in FCC Location (Page # 26) 3. Change in the location of Assembly Point # 1 (Page # 111) @ noure | PREPARED BY REVIEWED BY 7_APPROVED BY at Ue Rab i Farah bal esa Sion Tame | —“Wohanmag Usman DeI0E OD O00 | UM HSE cE pan[DOCUMENT CODE | SAF-WP-IMS-003 [REV. #] 04 [ REV. DATE [08/04/2013] PAGE, 1of6 9.6 Accidental Nitric Acid Release Composition / Component Information: Hazardous ingredient HNO, commonly has 58-60% concentration of HNOs, rest is essentially water: same safely regulations apply for concentrations from 20 to <60%. It is highly corrosive in nature. General Characteristi Components Weight % Nitric Acie 560% ae z | CONTROLLED Water Balance | copys. * q.. Hazards and Potential Health Effects: | 90 NOT OUPLiCATE Nitric acid is corrosive and can cause severe bums to all parts of the body. Its vapors are corrosive to the respiratory tract and may cause pulmonary edema which could prove fatal. Precautions: Avoid breathing, avoid ingestion, avoid contact with eyes, use under adequate ventilation Overexposure Conditions: Acute: effects predominate and their severity is such that significant repeated or prolonged exposure is unlikely Chronic: Repeated exposure to high levels produces adverse effecis on lung and teeth Inhalation: Fumes are corrosive to the respiratory tract and will cause severe coughing, sore thro: and labored breathing. Fluid buildup on the lung (pulmonary edema) may occur up to 48 hours ‘exposure and could prove fata ‘Skin Contact: Liquid splashes may produce severe burns to skin as nitric acid is highly corrosive to all parts of the body. Eye Contact: Liquid splashes may produce severe burns to skin and may cause serious damage toceyes. Ingestion: Wil immediately cause damage to the gastro-intestinal tract. Decomposition: Decomposition products include nitrogen oxides and hydrogen. Environment: Nitric acid is harmful to aquatic ie Other: Not classed as oxidizing agent. Can display oxidizing properties and react with combustiole materials. May react violently with reducing agents, metals and a number of other substances. First Aid: Speedy response is essential. Immediately remove contaminated clothing. Obtain medical attention immediately. Move the injured person to fresh air at once. ae = More te Hoses aoe el WHEN I'v RED ‘Administer oxygen if competent person is available. eee - Perform artificial respiration, if breathing has stopped or shows sign of failing, Obtain immediate medical attention. {In case of Skin Contact - Drench with water, remove contaminated clothing and wash or shower the affected skin with plenty of water. Obtain immediate medical attention In case of Eye contac Immediately irigate the eyes with eyewash solution or clean water for at least 10 minutes ~ Continue irigation until medical attention can be obtained. Hold eyelids open during flushing In case of Ingestion: ROUTE PREPARED BY REVIEWED BY ‘APPROVED BY Jus REFERENCE Name | assan.tan!/ Muhammad Usman Matures |f Foren ibat ueshi_| ise 4g 7 0 843 \s capa [onDOCUMENT CODE | SAF-WP-IMS-003 [REV. #] 04 | REV. DATE [08/04/2013] PAGE 2016 = Do not induce vomiting, Ifthe person is conscious, wash out mouth with water and give 2 or 3 glasses of water or milk to drink, ‘Obtain immediate medical attention and transpor the patient to hospital Further Medical Treatment: Spill Control Measures: } Ge : 3 ieceaiat CN / CAN H <2 ara PLANT 21 oriemar ca a 5 WHEN IN RED - Following exposure the patient should be kept under medical review for at least 48 hours {as delayed pulmonary edema may develop a ie Action Plan: Use chemical protection suit with Self Contained Breathing Apparatus (SCBA). Use Aqueous Film Forming Foam to cover nitric acid spill and thus prevent evaporation into large vapor clouds. Use foam to blanket vapor cloud from an upwind position till condition is, under control Water curtain should be formed in the downwind area of HNO; vapors to prevent HNO; vapor ‘exposure to people. Use hydrants in such a way tht hydrants located exactly in the downwind direction are not used for water curtain formation, Emergency Response Team (ERT) must have available with them at least 10 escape masks with NOx cartridges (Blue color) for evacuation of any personnel trapped in heavy cloud of acid vapors. ERT must make sure that they enter the acid cloud with full protective clothing with Toure [PREPARED BY REVIEWED BY TPPROVED BY [WS REFERENCE fas | eet ark ada gy |e ponte Owen | pee ate 08643 waar ions Besscsin | sere UM ASE) Ganon [retold cms: 42.110)3 DOCUMENT CODE | SAF-WP-IMS-003 | REV. #| 04 [ REV. DATE [08/04/2013] PAGE 30f6 SCBA, 5. Evacuate people from downwind areas immediately. If downwind areas are operating units then those operating units must be shut down as per procedure so that operating staff may leave the area safely. Personnel, involved in shut down of downwind operating areas being affected by toxic acid vapor, should wear SCBA while conducting shut down operations till evacuation to safe area so that acid vapor may not affect them. Evacuation of effected colony area should be carried out if wind direction is from acid Storage Tank towards the Housing Colony. Market mosque loud speakers should be used to inform people about the emergency in addition to the emergency siren for level-2 emergency. Appropriate Spill Control Resources: = Foam, water and dry powder. Use a water spray to cool fire-exposed containers and structures, Specific hazards if the product is involved in a Fire: Not combustible, but having oxidizing properties it may react with many combustible ‘materials causing Fires and releasing toxic fumes (nitrogen oxides). ‘May explode on contact with a powerful reducing agent. Reacts with most common metals to liberate hydrogen which can form explosive mixtures with air ° Toxic fumes (oxides of nitrogen) may be given off. Special Fire Fighting protection: Wear self-contained breathing apparatus and full protective clothing. Other Information: Collect large amounts of contaminated extinguishing water separately, do not allow reaching sewerage or effluent systems. Accidental Release Measures: Personal protection: Put on protective equipment before entering danger area - Ventilate area of spill or leak to disperse vapors. Environmental protection: - Take care to avoid the contamination of watercourses and drains. Inform appropriate authority in case of accidental contamination of watercourses, Friiecs Greniae merits aa alae pe ation ee cal ° See la aaee orpee eriaee ec come cesta pln, neiazatin fs gonealyreured co aaa Beg ger eres Coste eee ee peeteei ce Nate ae ea et rele ord eve eee Pure lege amounts ino containers Cortmot souk petrol be of stainless steel 1.4541 (ON 17440) or plas: (PVC possibly polyethylene). Detach naearel ceed cel ore ee Handling and Storage: Handling: "Wear eye and hand protection when handling small quantities ROUTE [PREPARED BY REVIEWED BY TPROVED BY [WS REFERENCE ee ee asusras —_P romanigpl cuss _| ice. 4a7 Date | owoarta Jt mat a Sa aan rae Make pare eter] one-s2110[bocumENT CODE | SaF-WP-IMs-003 [REV.#] 04 [REV. DATE [08/04/2013] PAGE 40f6 Provide adequate ventilation in view of insidious action of the fumes. ‘When diluting, ahvays add acid to water not water to acid. ‘Wear full protective equipment where there is a risk of leaks or splashes, Use protective masks, Protective gloves; Safety goggles. Do not store near food stuff. Storage: Store in cool, ventilated area, away from potential sources of heat and direct sunlight. Keep away from combustible materials, reducing agents, strong bases. Protect containers from corrosion and physical damages. - Containers should preferably be of stainless steel, 1.4541 (DIN 17440). Seek advice from the manufacturer ifn doubt. Exposure Control and Personal Protection: Exposure Control: Occupational exposure Limits: TLV/TWA: 2 ppm = 5.2mgim® Precautionary and Engineering Measures: Local exhaust ventilation, Provide safety showers and ‘eye washing facility at any location where skin or eye contact can occur, Personal Protection: Wear suitable breathing apparatus if exposure levels exceed the recommended limits. Wear PVC gloves, rubber boots and PVC sult. Use chemical safety goggles or full face shield, Physical and Chemical Properties: General Information: | Appearance / Color: Colorless to yellow liquid. Physical Condition: Liquid, | Ci § | DONC! oUPLICATE | Physical and chemical Information: pH: <1.0 (no dilution) + Freezing point -17°C (20%); - 22°C (60%), + Boiling point 103.4°C (20%); 120.4°C (60%), Flammability limits in air; None ‘Solubility in water Miscible in all proportions Density at 20°C (glcm3) 1.1150 (20%); 1.3667 (60%) ORIGINAL | WHEN IN RED ea od ROUTE PREPARED BY REVIEWED BY ‘APPROVED BY IMS REFERENCE - ee eee A oe ee SO ron aoe ro feet Fairlane Fearne \" TERI gk Aca oe 7 fowrsiaa. yeeDOCUMENT CODE | SAF-WP.IMS.003 [REV. #] 04 | REV. DATE [08/04/2013] PAGE 5of6 97 Accidental Caustic Soda Release: Chemical Name and Formula Caustic Soda NaOH Potential Acute Health Effects: Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant corrosive), of ingestion, of inhalation. The amount of tissue damage depends on length of contac’ Eye contact can result in comeal damage or blindness. Skin contact can produce inflammation and biistering. Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking, unconsciousness or death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or occasionally, blistering Potential Chronic Health Effects: The substance may be toxic to mucous membranes, upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure of the eyes to a low level of dust can produce eye irtation. Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory iritation or lung damage. r } ORIGINAL , Physical and Chemical Properties: | WHEN Ww RED Boiling Point Range: 1388°C ae ee pH: 13-14 (0.5% Sol) a a ‘Solubility In Water: Soluble. | con ED ‘Appearance/Odor: White deliquescent flakes with no odor. | coe Melting PointiFreezing Point: 623° NOT 9 ig Point: 623°C. | 20 NOT GuPLICATE Fire / Spill Control Measures: Flash Point: None. Extinguishing Media: Not considered a fire hazard. Use any means suitable for extinguishing surrounding fire. Flammable Limits: None Fire Fighting Procedures: Coo! fire-exposed containers with water spray to prevent container ‘weakening and possible rupture. Do not enter confined spaces without self-contained breathing apparatus (SCBA) and structural firefighter’s protective clothing, Unusual Fire and Explosion Hazards: Not considered an explosion hazard. Stability and Reactivity: Stability: Stable under normal use conditions. Conditions to Avoid: Moisture, dusting and incompatibes. Incompatibility: Avoid contact with acids, moisture, strong oxidizing agents, and powdered metals. Hazardous Decomposition Products: Oxides of Sodium. Hazardous Polymerization: Will not occur. Storage and Handling: Precautions To Be Taken In Handling and Storage: Always store in tightly sealed, properly labeled, original container. Store in a cool, dry ventilated area. Prevent physical damage, Keep away from sources of heat, moisture and incompatibles. Other Precautions: Follow Label Instructions and Precautions. ROUTE PREPARED BY REVIEWED BY ‘APPROVED BY is REFERENCE Name__| Hassan Jami Muhammad Usmar MatWeb Famunigbatouresds | ice 4.47 Date oan ‘nar am \ Ta yA af ann Zoe bg} cs:a21DOCUMENT CODE | SAF-WP-IMS-003 [REV. #] 04 | REV. DATE [08/04/2013] PAGE 6 of6 Health and First Aid: Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immedietely Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention Inhalation: If inhaled, remove to fresh air. f not breathing, give artificial respiration. If breathing is difficult, give, oxygen. Get medical attention immediately. Serious Inhalation: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING; It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband | } ORIGINAL Exposure Control and Personal Protection: WHEN IN RED Eye Protection: Eye Protection when handling. Goggles, safety glasses with side shields or full. face shield are recommended, Respiratory Protection: Where adequate ventilation is not available an approved respirator must bbe worn. Skin Protection: Wear impervious clothing, including boots, gloves, apron or coveralls, 2s appropriate to prevent skin contact, Ventilation: General Mechanical ventilation to prevent dusting from exceeding control limits. Protective Clothing: Selection of protective clothing depends on potential exposure conditions and may include gloves, boots, suits and other protective items, ee Other Equipment: Eye wash station and drench shower in close proximity. cont Rotten Accidental Release Measures: DO NOT DUPLICATE Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Completely contain the spilled material with dikes, sandbags, ete. and prevent run off into ground, surface water or sewers. Recover as much caustic a8 possible into container for disposal. Liquid material can be removed with 2 vacuum truck if available. Flush with excess water and neutralize remaining caustic with dilute HCL, citric acid to maintain pH between 6 to 8 ROUTE PREPARED BY REVIEWED EY APPROVED BY JS REFERENCE Name | Hassan Jami /Mubammad Usmape| —__Mab-Ur Rab ana pas cures | se. 447 Dawe | oeroara saomns J Yah fms sig. /Sign. 88/8 UM (HSE) Ew (tod go-~| OMS: 4.2.1 (6)[DOCUMENT CODE [ saFawP-i15-000 [REV.#] 04 [REV.DaTE [ooioam07o] PAGE| 2oci Tie 6.6.4. Formation and Location of Emergency Control Center 6.6.4.1. Front Control Center (FCC) Front Control Centre comprises of the following 1. Production Manager (FCC Leader) 2. Training Manager 3. Unit Manager HSE 4. Coordination Engineer (works as ESL) 5. Concemed Shift Engineer (works as ESL till Coordination Engr. arrives) 6 Unit Manager Ammonia 7 Unit Manager Utities 8 Unit Manager Nitric Acid Unit Manager Urea 10. Unit Manager CAN 41. Unit Manager NP 42. Unit Manger PH & S 13. Unit Manager L.CO2 6.6.4.2 FCC Locations | SONTROLYED | copy # e Following are the preferable locations for establishing Front Control Centre | DO NOT OL Uhde Building (APM Office) |n case of wind direction from NAST to Ammonia plant, FCC wil be established in Unde Building (APM Office) 2. Ammonia Conference Room (Beside Coordination Engineer Office) In case of wind direction from NAST to Admin. Building, CAN plant or Colony Jamia mosque, FCC will be established in Ammonia Conference Room (Beside Coordination Engineer Office). Nore: FCC leader has the authority to relocate FCC if warranted by conditions at that time. FCC may be reestablished at any suitable location near declared emergency area on FCC Leader disposal as required by the situation after reaching dedicated FCC locations @ _| eC dedicated ofices keys will be placed in Key box provided at the entrance doors to ensure availability of these offices during off duty hours. ORIGINAL WHEN IN RED ROUTE PREPARED BY REVIEWED BY ‘APPROVED BY TMS REFERENCE Tame: Tiuhammad Usman Wat Ur Rab) Farrah igbal Guresh Date oooarz013 caez013 = Pororzors ns6.447 < ee cadmas rae unse, MOS, Dr oman (jolelye-DOCUMENT CODE | SAF-WP-IMS-003 REV. #] 04 [REV. DATE [09/04/2013] PAGE | 111 of 118 Attachment-2 ASSEMBLY POINTS HEAD COUNT LEADERS | assemauy weno. | ASSEN” | assemmuy ee cxourn |] arovrs | arouse | cnouro «| | GON, | ‘teapers ANT 1 AREAS NAMER Pio | NAMEEP.No | NAMERPNo | NAMES P.NC Te RT CO TOT oT aurea : sugars | Wen, veel Comal oon. | SYEERMEOR | SUPSRECE | surenvson | surcavsce ana | mrnonror | Unfwesre ied eel byes ae an | FRONT OF | Utvwesr | GeuM Gotta "pun wsssinPhe | (usar | Toute | Mme ACO. | Cetin vet baton 20 aes ies feo Mart. Re Ofces “CO 2 | nce | ‘Ammonia, UTWest Cont Room, | ‘nomena. “Gone Room, es vermovecr | Sum Comer, Page | rrnonror | \CEROEST | Pana Siem Aci Ofces | supcavisor | surensor | suecrwsor | suremusce 2 | Mgrowror | eNac. | 5rSeraarNewtioune Aton | Sumamaacs | SipRauEOS | sueceysoe | Seen cutive | Grom tion Waranop tbsemy, | eee | 'axoa | “puovice’ | Pnoties Cooling Tower (New), Electrical | Geet isa Saot 230216, nine | mEisun ow int Co8 Po ee T Fie Say Secon Canteen 1 = Uibscy, kann Often Ale row oF | UMOKCH-S | Feces "Acaun Onces ss | sUpeRvoR | suPeRvsoR | so @ | MER |, taor | verison Moses a “pumny | “Ghiseen" | “Uneeues | Seas | stanon | S*CHEMST | Cree ner “Ener teem | Eneisse | Piotsie one | | art FM Amaia Gf Aa pier ee : esr se 1 | OF BALKIE: |} Coots | sexecr, | ie sale Sect, wie Acs om, | | Sone | SELECT. | CINEN” Soon Tram Nan surenvigon | surenvson | suscausce ws | | nc EAS ny | Un tandig CaN Cece | Shesewec® | SURERSOR | ueemuson | gurstuasce FMaNT) | Piet Caton aoe, PANU | pnesace | “pasast” | “Pao | Mature Ene. FE | ua, U.cas, UT Wes Mae Acs {Oise Stow esc Tanng sursauson | seeayson | SUPERUSOR ars | TEGHWCAL | sefeuan) | pM UTEea FA Anmoie, PM | Menem | Mnormad | MemMnaeT | pepo tramnc | “Grex | Gena Ukien. Cosorenten | aumenente | P Noss Pao | Park ‘mt AN Cxycal Past E Sere | ee | Tectnicl Tring Centar CAN = capa ‘ordre Se, Gane CAN TWEEN | sa umm | fuk Stee Now CaN Bop Sere, 3 |osaac | surcavsox | surcevson | suesmuson | suecausos ©) | SENS, | seein | 825 Setesueraetan ta | ehewra | a Tyas aaa ronenao | Aaah) | Soe nee See Net Tm | atorPnoner | Phos | phoves | Prova sr | aN aang, ew CaN Bap Sire | nsrithenr | Saba Stee Nb Hordig WP Bok surenuison reson | SUPERMSOE + | apy | INFRONT oF Soe. NP Lowr ‘Sere WP Pr superson | SiSER Jone Orree | EAST, | Boctenl emt Gursiaion nes | Meh Oman ar sad 5 om ALENGR. | Key'raen® PRU NP, Coen paste proate . Agent Store, Teccmraperrpesien \ f ORIGINAL | | WHEN IN RED \ coe \ ROUTE PREPARED BY REVIEWED BY “APPROVED BY | WS REFERENCE ‘lame Wiherad Usman Ta Ur Rab Farah aba Guar Date caoa013 eaoanore carazora | Hse: 447 E aus 42:1 Ce Te Tn aE. Glouon 710